CHEMISTRY

1. Solid fuel used in rocket is a mixture of Fe2O and Al (in ratio 1 : 2). The heat evolved (kJ) per gram of the
mixture is_____ (nearest integer)
Given: 𝛥𝐻 (𝐴𝑙 𝑂 ) = −1700 𝑘𝐽 𝑚𝑜𝑙
𝛥𝐻 (𝐹𝑒 𝑂 ) = −840 𝑘𝐽 𝑚𝑜𝑙
Molar mass of Fe, Al and O are 56, 27 and 16 g mol–1 respectively.
2. Given
(A) 2CO(g) + O2(g) → 2CO2 (g) 𝛥𝐻 = –x kJ mol–1
(B) C (graphite) + O2 (g) → CO2 (g) 𝛥𝐻 = –y kJ mol–1
The 𝛥𝐻 for the reaction
C(graphite) + O2(g) → CO(g) is
x  2y x  2y 2x  y
(a) (b) (c) (d) 2y - x
2 2 2
3. Consider the following date
Heat of combustion of H2(g) = –241.8 kJ mol–1
Heat of combustion of C(s) = –393.5 kJ mol–1
Heat of combustion of C2H5OH(I) = –1234.7 kJ mol–1
_______ kJ mol–1 (Nearest integer)
4. At 25oC, the enthalpy of the following processes are given:
H2 (g) + O2 (g) → 2OH(g) H o = 78 kJ mol–1
H2 (g) + ½ O2 (g) → H2O(g) H o = –242 kJ mol–1
H2 (g) → 2H(g) H o = 436 kJ mol–1
1/2O2 (g) → O(g) H o = 249 kJ mol–1
What would be the value of X for the following reaction? ____ (nearest integer)
H2O(g) → H(g) + OH(g) H o = XkJ mol–1
5. 0.3 g of ethane undergoes combustion at 27oC in a bomb calorimeter. The temperature of calorimeter system
(including the water) is found to rise by 0.5oC. The heat evolved during combustion of ethane at constant
pressure is _____ kJ mol–1. (nearest integer)
Given: the heat capacity of the calorimeter system is 20 kJ K–1 mol–1.
Assume ideal gas behavior.
Atomic mass of C and H are 12 and 1 g mol–1 respectively).
6. Enthalpies of formation of CCl4(g), H2O(g), Co2(g) and HCl(g) are –105, –242, –394 and –92 KJ mol–1 (nearest
integer)
CCl4(g) + 2H2O(g) → CO2(g) + 4HCl(g)
7. 28.0 L of CO2 is produced on complete combustion of 16.8 L gaseous mixture of ethane and methane at 25oC
and 1 atm. Heat evolved during the combustion process is ______kJ. Given: H C (CH4) = –900 kJ mol–1 H C
(C2H4) = –1400kJ mol–1
8. The enthalpy of combustion of propane, graphite and dehydration at 298 K are –2220.0 kJ mol–1 respectively.
The magnitude of enthalpy of formation of propane (C3H8) is ____ kJ mol–1. (nearest integer)
9. For combustion of one mole of magnesium in an open container at 300K and 1 bar pressure.  C H o = –601.70
kJ mol–1, the magnitude of change in internal energy for the reaction is ______kJ. (nearest integer)
10. For complete combustion of methanol
3
CH3OH (1) + O2(g) → CO2(g) + 2H2O(1)
2
the amount of heat produced as measured by bomb calorimeter is 726 kJ mol–1 at 27oC. The enthalpy of

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 combustion for the reaction is –x kJ mol–1, where x is _____. (nearest integer)
Given : R = 8.3 JK–1 mol–1)
11. At 25oC and 1 atm pressure, the enthalpy of combustion of benzene (1) and acetylene (g) are –3268 kJ mol–1
and –1300 kJ mol–1, respectively. The change in enthalpy for the reaction 3 C2H2(g) → C6H6(1), is
(a) + +324 kJ mol–1 (b) + 632 kJ mol–1 (c) – 632 kJ mol–1 (d) – 732 kJ mol–1
o
12. At 25 C and 1 atm pressure, the enthalpies of combustion are as given below:
Substance H2 C (graphite) C2H6(g)
C H o
–286.0 –394.0 –1560.0
kJmol –1
The enthalpy of formation of ethane is:
(a) + 54.0 kJmol –1 (b) –68.0 kJ mol–1 (c) –86.0 kJ mol–1 (d) +97.0 kJ mol–1
13. The heat of combustion of ethanol into carbon dioxide and water is –327 kcal at constant pressure. The heat
evolved (in cal) at constant volume and 27oC (if all gases behave ideally) is (R = 2 cal mol–1 K–1)_______.
14. The standard heat of formation   f H 0298  of ethane (in kJ/mol–1), if the heat of combustion of ethane,
hydrogen and graphite are –1560, –393.5 and –286 kJ/mol, respectively is________.
15. The difference between H and U  H  U  , when the combustion of one mole of heptanes (1) is carried
out at a temperature T, is equal to:
(a) –4 RT (b) –3 RT (c) 4 RT (d) 3 RT
16. (i) C (graphite) + O2(g) → CO2(g);  r H o = x kJ mol–1
1
(ii) C (graphite) + O2(g) → CO2(g);  r H o = y kJ mol–1
2
1
(iii) CO(g) + O2(g) → CO2(g);  r H o = z kJ mol–1
2
Based on the above thermochemical equations, find out which one of the following algebraic relationships is
correct?
(a) x = y + z (b) z = x + y (c) y = 2z – x (d) x = y – z
17. The combustion of benzene (1) gives CO2(g) and H2O (1). Given that heat of combustion of benzene at
constant volume is –3263.9 kJ mol–1 at 25oC; heat of combustion (in kJ mol–1) of benzene at constant pressure
will be: (R = 8.314 JK–1 mol–1)
(a) 4152.6 (b) –452.46 (c) 3260 (d) –3267.6
18. For which of the following reactions, H is equal to U ?
(a) N2(g) + 3H2(g) → 2NH3(g) (b) 2HI(g) → H2(g) + I2(g)
(c) 2 SO2 (g) + O2 (g) → 2SO3(g) (d) 2 No2 (g) → N2O4 (g)
19. Given
C(graphite) + O2(g) → CO2(g);  r H o = –393.5 kJ mol–1
1
H2(g) + O2(g) → H2O(I);  r H o = –285.8 kJ mol–1
2
CO2(g) + 2H2O(I)→ CH4(g) + 2O2(g);  r H o = + 890.3 kJ mol–1
Based on the above thermochemical equations, the value of  r H o at 298 K for the reaction,
C(graphite) + 2 H2(g) → CH4(g) will be:
(a) + 74.8 kJ mol–1 (b) + 144.0 kJ mol–1 (c) – 74.8 kJ mol–1 (d) – 144.0 kJ mol–1
20. For a reaction, A(g) → A(1); H = –3 RT. The correct statement for the reaction is:
(a) H  U  O (b) H  U  O (c) H  U (d) H  U
21. The heats of combustion of carbon and carbon monoxide are –393.5 and –283.5 kJ mol–1, respectively. The
heat of formation (in kJ) of carbon monoxide per mole is:
(a) –676.5 (b) –110.5 (c) 110.5 (d) 676.5
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 22. For complete combustion of ethanol,
C2H5OH(1) + 3O2(g) → 2CO2(g) + 3H2O(1)
the amount of heat produced as measured in bomb calorimeter, is 1364.47 kJ mol–1 ar 25oC. Assuming
ideality, the enthalpy of combustion,  c H , for the reaction will be: (R = 8.314 kJ mol–1)
(a) –1366.95 kJ mol–1 (b) –1361.95 kJ mol–1 (c) –1460.95 kJ mol–1 (d) –1350.50 kJ mol–1
23. Given :
1
(i) H2(g) + O2(g) → H2O(1);
2
H 298K = –285.9 kJ mol–1
o

1
(ii) H2(g) + O2(g) → H2O(g);
2
H o298K = –241.8 kJ mol–1
The molar enthalpy of vapourisation of water will be:
(a) 241.8 kJ mol–1 (b) 22.0 kJ mol–1 (c) 44.1 kJ mol–1 (d) 527.7 kJ mol–1
24. The difference between the reaction enthalpy change   r H  and reaction internal energy change   r U  for
the reaction:
2C6H6(1) + 1502(g) → 122CO2(g) + 6H2O(1)
at 300 K is (R = 8.314 J mol–1 K–1)
(a) 0 J mol–1 (b) 2490 J mol–1 (c) –2490 J mol–1 (d) –7482 J mol–1
25. Consider the reaction:
4NO2(g) + O2(g) → 2N2O5(g),  r H = –111 kJ
If N2O5(s) is formed sublimation for N2O5 in the above reaction, the  r H value will be:
(given H of sublimation for N2O5 is 54 kJ mol–1)
(a) + 54 kJ (b) + 219 kJ (c) –219 J (d) –165kJ
26. On the basis of the following thermochemical data:
(  f H o H  (aq) = 0)
H2O(1) → H+ (aq) + OH– (aq); H = 57.32 kJ
1
H2(g) + O2 (g) → H2O(1); H = –286.20 kJ
2
The value of enthalpy of formation of OH– ion at 25oC is:
(a) –228.88 kJ (b) +228.88 kJ (c) –343.52 kJ (d) –22.88 kJ
27.  H  U  for the formation of carbon monoxide (CO) form its elements at 298K is: (R = 8.314 J K–1 mol–1)
(a) –2477.57 J mol–1 (b) 2477.57 J mol–1 (c) –1238.78 J mol–1 (d) 1238.78 J mol–1
28. Consider the reaction: N2 + 3H2 → 2NH3 carried out at constant temperature and pressure. Of H and U
are the enthalpy and internal energy changes for the reaction, which of the following expressions is true?
(a) H  U (b) H  U (c) H  U (d) H  0

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 ANSWER KEY
Ques. 1 2 3 4 5 6 7 8 9 10
Ans. 4 A 278 499 1006 173 925 –103.7 600 727
Ques. 11 12 13 14 15 16 17 18 19 20
Ans. C C –326400 –192.5 A A D B C D
Ques. 21 22 23 24 25 26 27 28
Ans. B A C D D A D B

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