GC Columns

GC Column Selection ...............................................................................90

Structures, Properties, Polarities and Uses for DM Columns ...............................90
Column Phase Cross Reference ...........................................................................91

GC Guard Columns ..................................................................................92

Guard Columns / Transfer Lines ............................................................................92
Ordering Information .............................................................................................92

DikmaCap™ (DM) Capillary Columns ......................................................93

DM-1 / DM-1MS .....................................................................................................93
DM-5 / DM-5MS .....................................................................................................94
DM-5MS / LB .........................................................................................................95
DM-1HT / DM-5HT .................................................................................................96
DM-35 / DM-35MS .................................................................................................97
DM-1701 ................................................................................................................98
DM-17 / DM-17MS .................................................................................................99
DM-200 / DM-200MS ...........................................................................................100
DM-225 ................................................................................................................101
DM-Wax ...............................................................................................................102
DM-InertWax ........................................................................................................103
DM-FFAP .............................................................................................................104
DM-2330 ..............................................................................................................105
DM-2560 ..............................................................................................................106
DM-PLOT Alumina (Al2O3) ...................................................................................107
DM-PLOT Alumina / Na2SO4 ................................................................................108
DM-PLOT Alumina / KCl ......................................................................................109
DM-PLOT MS 5A .................................................................................................110
M PL S S U ......................................................................................111
DM-PLOT CFC .....................................................................................................112
DM-PONA ............................................................................................................113
DM-TCEP .............................................................................................................114
DM Series SimDist Metal .....................................................................................115
DM-2887 / DM-2887 Metal ..................................................................................116
DM-BDTG Metal ..................................................................................................117
DM-Volatile Amine................................................................................................118
DM-5 Amine .........................................................................................................119
DM-35 Amine .......................................................................................................120
DM-Wax Amine ....................................................................................................121
DM-624 / DM-624MS ...........................................................................................122
DM-TVOC.............................................................................................................123
DM-PAH ...............................................................................................................124
DM-FAMEWAX .....................................................................................................125
 DikmaCap™ (DM)

Structures, Properties, Polarities and Uses for DM Columns

DM-1 / DM-1MS / DM-1HT DM-5 / DM-5MS / DM-5HT DM-5MS / LB
100% Dimethyl polysiloxane 5% Diphenyl 5% Diphenyl
95% Dimethyl polysiloxane 95% Phenyl arylene dimethyl polysiloxane

CH3 CH3 CH3 CH3 CH3

Si O Si O Si O ( Si O )x ( Si O ) y ( Si Si O )
CH3 CH3 CH3 CH3 CH3
100% 5% 95%
Polarity: Non-polar Polarity: Slightly polar Polarity: Slightly polar
Application: Solvents, natural gases, petroleum Application: Flavors, aromatic hydrocarbons, Application: Semi-volatile / volatile compounds,
products, etc. environmental compounds, etc. phenols, aromatic hydrocarbons, PCBs
GC Columns

DM-624 / DM-624MS DM-35 / DM-35MS DM-1701

6% Cyanopropylphenyl 35% Diphenyl 14% Cyanopropylphenyl
94% Dimethyl polysiloxane 65% Dimethyl polysiloxane 86% Dimethyl polysiloxane
C N C N
CH3
(CH2)3 CH3 (CH2)3 CH3
Si O Si O
Si O Si O Si O Si O
CH3
CH3 CH3
35% 65%
6% 94% 14% 86%
Polarity: Slightly polar Polarity: Intermediately polar Polarity: Intermediately polar
Application: Insecticides, alcohols, Application: Pesticides, PCBs, herbicides Application: Alcohols, oxygenates, PCBs
volatile organic compounds

DM-17 / DM-17MS DM-200 DM-225

50% Diphenyl 100% Trifluoropropylmethyl polysiloxane 50% Cyanopropylmethyl
50% Dimethyl polysiloxane 50% Phenylmethyl polysiloxane
CF3 C N
CH3
C2H4 (CH2)3
Si O Si O
Si O Si O Si O
CH3
CH3 CH3 CH3
50% 50% 100% 50% 50%
Polarity: Intermediately polar Polarity: Intermediately polar, special Polarity: Polar
Application: Triglycerides, steroids, PAEs selectivity for compounds containing lone Application: Adipic acid monomethyl ester,
pair electron groups sugars, FAMEs
Application: Solvents, alcohols, etc.

DM-2330 DM-Wax / DM-InertWax

90% Biscyanopropyl Polyethylene glycol
10% Cyanopropylphenyl polysiloxane
H H
C N C N

(CH2)3 (CH2)3 C C O

Si O Si O H H
(CH2)3 Polarity: Polar
10% Application: FAMEs, flavors, solvents,
C N
aromatic hydrocarbons
90%
Polarity: Polar
Application: cis / trans FAMEs, dioxins, rosin acids

90 www.dikmatech.com
 DikmaCap™ (DM)

Column Phase Cross Reference

DikmaCap™ Phase Agilent SGE Restek Supelco
DM-1 100% Dimethyl polysiloxane HP-1, DB-1, CP-Sil 5 CB BP-1 Rtx-1, MXT-1 SPB-1
DM-1HT 100% Dimethyl polysiloxane DB-1ht, VF-1ht - Rxi-1HT -
DM-1MS 100% Dimethyl polysiloxane HP-1, HP-1ms, DB-1, DB-1ms, Ultra 1, BP-1 Rxi-1MS SPB-1,
(low bleed) VF-1ms, CP-Sil 5 CB Low Bleed / MS Equity-1
DM-5 5% Diphenyl HP-5, DB-5, CP-Sil 8 CB BP-5 Rtx-5, MXT-5 SPB-5
95% Dimethyl polysiloxane
DM-5HT 5% Diphenyl DB-5ht, VF-5ht - Rxi-5HT -
95% Dimethyl polysiloxane
5% Diphenyl SPB-5,
DM-5MS 95% Dimethyl polysiloxane HP-5, HP-5ms, DB-5, Ultra 2, CP-Sil 8 CB BP-5 Rxi-5MS Equity-5
(low bleed)
5% Diphenyl DB-5ms, DB-5ms UI, VF-5ms,
DM-5MS / LB 95% Phenyl arylene dimethyl polysiloxane CP-Sil 8 CB Low Bleed / MS BPX-5 Rxi-5Sil MS SLB-5MS
(low bleed)

GC Columns
DM-35 35% Diphenyl HP-35, DB-35 BPX-35, Rtx-35 SPB-35,
65% Dimethylpolysiloxane BPX-608 SPB-608
DM-35MS 35% Diphenyl DB-35ms, VF-35ms BP-35 Rxi-35Sil MS -
65% Dimethyl arylene polysiloxane
DM-1701 14% Cyanopropylphenyl HP-1701, PAS-1701, DB-1701, BP-10 Rtx-1701 SPB-1701
86% Dimethyl polysiloxane CP-Sil 19 CB, VF-1701ms
DM-17 50% Diphenyl HP-50+, HP-17, DB-17, DB-608, CP-Sil 24 CB - Rxi-17 SPB-50
50% Dimethyl polysiloxane
DM-17MS 50% Diphenyl HP-17, DB-17, DB-17ms, CP-Sil 24 CB, BPX-50 Rxi-17Sil MS -
50% Dimethyl arylene polysiloxane VF-17ms
DM-200 100% Trifluoropropylmethyl DB-210, DB-200, VF-200ms - Rtx-200 -
polysiloxane
DM-200MS 100% Trifluoropropylmethyl VF-200ms - Rtx-200MS -
polysiloxane (low bleed)
DM-225 50% Cyanopropylmethyl HP-225, DB-225, CP-Sil 43 CB BP-225 Rtx-225 SPB-225
50% Phenylmethyl polysiloxane
DM-Wax Polyethylene glycol HP-INNOWax, CP-Wax 52 CB, VF-WAXms - Stabilwax Supelcowax 10
DM-InertWax Polyethylene glycol HP-Wax, DB-Wax, CP-Wax 52 CB BP-20 Rtx-Wax -
DM-FFAP Polyethylene glycol HP-FFAP, DB-FFAP, CP-Wax 58 CB BP-21 Stabilwax-DA Nukol
90% Biscyanopropyl SP-2330,
DM-2330 10% Cyanopropylphenyl polysiloxane - BPX-70 Rt-2330 SP-2331,
SP-2380
DM-2560 Biscyanopropyl polysiloxane HP-88, CP-Sil 88 - Rt-2560 SP-2560
DM-PLOT Alumina Aluminum oxide GS-Alumina, HP-PLOT S, CP-Al2O3 PLOT - - -
DM-PLOT Alumina / Na2SO4 Aluminum oxide
Na2SO4 deactivation
GS-Alumina, HP-PLOT S,
CP-Al2O3 / Na2SO4 PLOT - Rt-Alumina BOND / Na2SO4 Alumina Sulfate PLOT

DM-PLOT Alumina / KCI Aluminum oxide GS-Alumina / KCI, HP-PLOT Al2O3 / KCI, - Rt-Alumina BOND / KCI Alumina Chloride PLOT
KCI deactivation CP-Al2O3 / KCI PLOT
DM-PLOT CFC - - Rt-Alumina BOND / CFC -
DM-PLOT MS 5A Molecular sieve 5A GS-Molsieve, HP-PLOT Molesieve, - Rt-Msieve 5A Molsieve 5A
CP-Molesieve 5A
M PL ivinylben ene CP PoraPL , - Rt Supel PL
CP Pora ond
M PL S Porous divinyl ben ene S - Rt S -
homopolymer
DM-PLOT S ivinylben ene vinylpyridine CP-PoraPLOT S - Rt-S-BOND -
DM-PLOT U ivinylben ene ethylene HP-PLOT U, CP-PoraPLOT U, - Rt-U-BOND -
glycol / dimethylacrylate CP-PoraBond U
DM-624 6% Cyanopropylphenyl HP-1301, HP-624, DB-1301, DB-624, BP-624 Rtx-1301, Rtx-624 SPB-1301
94% Dimethyl polysiloxane CP-1301, VF-624ms, VF-1301ms
DM-624MS 6% Cyanopropylphenyl HP-624, DB-624, VF-624ms BP-624 Rxi-624Sil MS -
94% Dimethyl arylene polysiloxane
DM-FAMEWAX Polyethylene glycol - - FAMEWAX Omegawax
DM-5 Amine 5% Diphenyl CP-Sil 8 CB - Rtx-5 Amine -
95% Dimethyl polysiloxane
DM-35 Amine 35% Diphenyl - - Rtx-35 Amine -
65% Dimethyl polysiloxane
DM-Wax Amine Polyethylene glycol CAM, CP-Wax 51 - Stabilwax-DB Carbowax Amine
DM-TVOC 100% Dimethyl polysiloxane - - - -
DM-PONA 100% Dimethyl polysiloxane HP-PONA, DB-Petro, CP-Sil PONA CB BP1-PONA Rtx-DHA Petrocol DH
DM-TCEP 1,2,3-tris [2-cyanoethoxy]propane CP-TCEP - Rt-TCEP TCEP
DM-2887 100% Dimethyl polysiloxane DB-2887 - Rtx-2887 Petrocol 2887,
DM-2887 Metal Petrocol EX2887
DM-1HT SimDist Metal 100% Dimethyl polysiloxane DB-HT Sim Dis, CP-SimDist - MXT-1HT SimDist -
DM-1 SimDist Metal CP-SimDist - MXT-1HT SimDist -
DM-500 SimDist Metal Carborane siloxane polymer - - MXT-500 SimDist -
DM-BDTG Metal - - MXT-Biodiesel TG -
DM-Volatile Amine CP-VolAmine - Rtx-Volatile Amine -
DM-PAH 50% Methyl - - - -
50% Phenyl polysiloxane

www.dikmatech.com 91
 GC Guard Columns

Guard Columns / Transfer Lines (Intermediate Polarity Deactivated)

• Use in a wide variety of applications
• llow most common solvents

Ordering Information
5m 5 m (6/pk) 10 m 30 m
ID (mm) OD (mm) MAOT (ºC) Cat. No. Cat. No. Cat. No. Cat. No.
0.05 0.363 ± 0.012 325 7001
0.10 0.363 ± 0.012 325 7002
0.15 0.363 ± 0.012 325 7003
0.18 0.37 ± 0.04 325 7004
0.25 0.37 ± 0.04 325 7005 7061 7015 7064
GC Columns

0.28 0.37 ± 0.04 325 7006

0.32 0.45 ± 0.04 325 7007 7062 7017 7065
0.45 0.69 ± 0.04 325 7008
0.53 0.69 ± 0.05 325 7009 7063 7019 7066

Guard Columns / Transfer Lines (Polar Deactivated)

• Provide optimum wettability for polar compounds
• Minimi e pea splitting and pea tailing when using polar solvents such as water or methanol
• Polyethylene glycol deactivation used for M Wax, M and M

Ordering Information
5m 10 m 30 m
ID (mm) OD (mm) MAOT (ºC) Cat. No. Cat. No. Cat. No.
0.25 0.37 ± 0.04 280 7011 7014 7010
0.32 0.45 ± 0.04 280 7012 7016 7020
0.53 0.69 ± 0.05 280 7013 7018 7030

Guard Columns / Transfer Lines (Water Resistant Deactivated)

• High density surface deactivation and excellent water resistance
• Use for purge trap system, headspace in ection, gas concentration analysis and hydrated sample test
• nertness and water resistance tube connection

Ordering Information
5m 5 m (6/pk) 10 m 30 m
ID (mm) OD (mm) MAOT (ºC) Cat. No. Cat. No. Cat. No. Cat. No.
0.05 0.363 ± 0.012 325 7021
0.10 0.363 ± 0.012 325 7022
0.15 0.363 ± 0.012 325 7023
0.18 0.37 ± 0.04 325 7024
0.25 0.37 ± 0.04 325 7025 7031 7034 7037
0.32 0.45 ± 0.04 325 7027 7032 7035 7038
0.53 0.69 ± 0.05 325 7029 7033 7036 7039

Guard Columns / Transfer Lines (Base Deactivated)

• Excellent inertness for basic compounds
• Use for M mine, M mine, M Wax mine, M olatile mine
• atch test with basic compounds

Ordering Information
5m 5 m (6/pk)
ID (mm) OD (mm) MAOT (ºC) Cat. No. Cat. No.
0.25 0.37 ± 0.04 315 7041 7044
0.32 0.45 ± 0.04 315 7042 7045
0.53 0.69 ± 0.05 315 7043 7046

92 www.dikmatech.com
 DM-1 / DM-1MS

DM-1 / DM-1MS
• imethyl polysiloxane
• eneral purpose column of non polar phase
• Long lifetime
Application Chromatogram
• emperature range C to C
Sample / Compound Page
• onded and cross lin ed phase, solvent rinsable
Air Sample TO-14 183
• M MS is a low bleed column, use for MS s
• Similar to , SP , HP , etc Citronella Java Oil 233
• E uivalent to USP , , phases Fatty Acids (Free) 228
Flavor Volatiles 231
DM-1MS column exhibits ultra-low bleed that has excellent inertness for Fragrance 234
active compounds and improves detection performance for MSDs, ECDs Gasoline Aromatics 208

GC Columns
and NPDs. Hydrocarbons, C7 - C42 207
Oxygenates MTBE 203
Petroleum Oxygenates 202 203
Sulfide 204
Sulfur in Gasoline 204
Solvents 220, 221 223, 225
Sulfur in Naphtha 204
USP Solvents 220

DM-1 Ordering Information

15 m 30 m 50 m 60 m
ID (mm) df (µm) MAOT (ºC) Cat. No. Cat. No. Cat. No. Cat. No.
0.25 0.10 -60 to 330 / 350 7119
0.25 -60 to 330 / 350 7121 7172 7122
0.50 -60 to 330 / 350 7123 7174 7124
1.00 -60 to 330 / 340 7125 7176 7126
0.32 0.25 -60 to 330 / 350 7131 7182 7132
0.50 -60 to 330 / 350 7133 7184 7134
1.00 -60 to 320 / 340 7135 7186 7136
1.50 -60 to 310 / 330 7137 7138
3.00 -60 to 280 / 300 7141 7142
4.00 -60 to 280 / 300 7143
5.00 -60 to 260 / 280 7139 7140
0.53 0.50 -60 to 310 / 330 7147 7148
1.00 -60 to 310 / 330 7109 7149 7150
1.50 -60 to 310 / 330 7110 7151 7152
3.00 -60 to 270 / 290 7112 7155 7156
5.00 -60 to 270 / 290 7113 7157 7198 7158
7.00 -60 to 270 / 290 7159 7160

DM-1MS Ordering Information

30 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
0.25 0.25 -60 to 330 / 350 8121
0.32 0.25 -60 to 330 / 350 8131

www.dikmatech.com 93
 DM-5 / DM-5MS

DM-5 / DM-5MS
• onded and cross lin ed diphenyl dimethyl polysiloxane
• eneral purpose column with low polarity phase
• emperature range C to C
• Solvent rinsable
• M MS is a low bleed column, use for MS s
• Similar to , SP , HP , etc
• E uivalent to USP , phases Application Chromatogram
Sample / Compound Page
DM-5 column has a slightly higher polarity compared to DM-1, resulting in a
Alcohols 215
better selectivity for aromatic compounds. DM-5 column exhibits excellent
asic rugs Underivati ed 236
reproducibility, high column efficiency, and low bleed.
en idines Phenols EP 190
GC Columns

Butyl Tins 194

DM-5MS column exhibits ultra-low bleed with excellent inertness for active
Chlorinated Hydrocarbons (EPA 612) 189
compounds and improves detection performance for MSDs, ECDs and
Food Packaging Volatiles 234
NPDs.
Glycols / Alcohols 215
Nitrogen-Containing Herbicides 192
Organochlorine Pesticides 191, 193
PAEs 195
PAHs (EPA 610) 186
Solvents 227
Steroids, Anabolic 238

DM-5 Ordering Information

15 m 30 m 50 m 60 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No. Cat. No. Cat. No.
0.25 0.10 -60 to 330 / 350 7219
0.25 -60 to 330 / 350 7221 7272 7222
0.50 -60 to 330 / 350 7223 7274 7224
1.00 -60 to 320 / 340 7225 7276 7226
0.32 0.25 -60 to 330 / 350 7231 7282 7232
0.50 -60 to 330 / 350 7233 7284 7234
1.00 -60 to 330 / 350 7235 7286 7236
1.50 -60 to 310 / 330 7237 7238
3.00 -60 to 280 / 300 7241 7242
5.00 -60 to 260 / 280 7239
0.53 0.50 -60 to 310 / 330 7247 7248
1.00 -60 to 310 / 330 7209 7249
1.50 -60 to 310 / 330 7210 7251
3.00 -60 to 270 / 290 7212 7255
5.00 -60 to 270 / 290 7213 7257 7298 7258

DM-5MS Ordering Information

30 m 50 m 60 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No. Cat. No.
0.25 0.10 -60 to 330 / 350 8219 8220
0.25 -60 to 330 / 350 8221 8272 8222
0.50 -60 to 330 / 350 8223
0.32 0.10 -60 to 330 / 350 8229 8230
0.25 -60 to 330 / 350 8231 8282 8232
0.50 -60 to 330 / 350 8233
*The listed temperature limits are for 15 m and 30 m columns. Longer columns may have lower temperature limits.

94 www.dikmatech.com
 DM-5MS / LB

DM-5MS / LB
• Cross lin ed diphenyl phenyl arylene dimethyl polysiloxane
• ery low bleed
• mproves the resolution between en o b fluoranthene and
en o fluoranthene
• Similar to MS

DM-5MS / LB (low bleed) column is coated with a 5% diphenyl / 95%

phenyl arylene dimethyl polysiloxane phase, which can inhibit the
formation of ring-shaped fragments of siloxane skeleton, thereby
reducing column bleed and increasing the thermal stabilty. The stationary
phase has better stability; and will not exhibit oxidative degradation when

GC Columns
there is trace oxygen in the carrier gas. Application Chromatogram
Sample / Compound Page
DM-5MS / LB column is similar to DM-5MS. The DM-5MS / LB has good Phenols (EPA 528) 187
sensitivity and peak symmetry for strong polar and basic compounds. PAHs (EPA 610) 185
We recommend DM-5MS / LB column for analysis of semi-volatile Semi-volatile Organic Compounds 188
compounds such as PAHs and PCBs. Volatile Organic Compounds (EPA 526) 187

PAHs
Column: DM-5MS / LB
1. Naphthalene 9. en o a anthracene 30 m x 0.25 mm x 0.50 µm
2. Acenaphthylene 10. , en phenanthrene Cat. No.: 8723
3. Acenaphthene 11. en o b fluoranthene Index: CER00549
4. Fluorene 12. en o fluoranthene Oven Temp.: 40 ºC (hold 1 min) to 220 ºC at 20 ºC/min
5. Phenanthrene 13. en o a pyrene to 310 ºC at 4 ºC/min (hold 5 min)
6. Anthracene 14. Indeno[1,2,3-cd]pyrene
Carrier Gas: H2, 40 cm/sec
7. Fluoranthene 15. iben o a,h anthracene
Sample: PAHs standard
8. Pyrene 16. en o ghi perylene
Injection: Splitless, hold 1 min, 1.0 µL, 300 ºC
Detector: FID, 310 ºC

DM-5MS / LB Ordering Information

30 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
0.25 0.10 -60 to 330 / 350 8719
0.25 -60 to 330 / 350 8721
0.50 -60 to 330 / 350 8723
0.32 0.10 -60 to 330 / 350 8729
0.25 -60 to 330 / 350 8731
0.50 -60 to 330 / 350 8733

www.dikmatech.com 95
 DM-1HT / DM-5HT

DM-1HT
• imethyl polysiloxane
• High temperature resistant application
• emperature range C to C

DM-1HT Ordering Information

15 m 30 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No.
0.25 0.10 -60 to 400 8841 8842
0.25 -60 to 400 8843
0.32 0.10 -60 to 400 8844 8845
0.25 -60 to 400 8846
GC Columns

0.53 0.15 -60 to 400 8847

*Column is capable of going up to 430 ºC, but it will reduce column lifetime.

DM-5HT
• Low polarity phase, bonded and cross lin ed diphenyl dimethyl polysiloxane
• longer lifetime from designed fused silica tubing
• High temperature resistant application
• emperature range C to C
• Similar to ht, F ht

DM-5HT Ordering Information

15 m 30 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No.
0.25 0.10 -60 to 400 8848 8849
0.25 -60 to 400 8850
0.32 0.10 -60 to 400 8851 8852
0.25 -60 to 400 8853
0.53 0.15 -60 to 400 8854
*Column is capable of going up to 430 ºC, but it will reduce column lifetime.

Bleed Profiles of DM-5HT

Column: DM-5HT
30 m x 0.25 mm x 0.10 µm
Cat. No.: 8849
Index: CGN1144
Carrier Gas: He, 38 cm/sec
Oven Temp.: 110 ºC (hold 8 min) to 380 ºC (hold 10 min)
at 30 ºC/min to 400 ºC (hold 10 min) at 30 ºC/min
Detector: FID, 400 ºC
Injection: Split, 250 ºC, 1.0 µL
Instrument: HP5890 GC

96 www.dikmatech.com
 DM-35 / DM-35MS

DM-35
• onded and cross lin ed diphenyl dimethyl polysiloxane
• eneral purpose column of mid polarity phase for pesticides, herbicides,
pharmacenticals, sterols, etc.
• emperature range C to C
• Solvent rinsable
• Similar to , SP , HP , SP , etc
• E uivalent to USP phase

DM-35MS
• Bonded and cross-linked 35% diphenyl / 65% dimethyl arylene polysiloxane

GC Columns
• Special selectivity and excellent inertness for substituted polar compounds
• emperature range C to C
• Ultra low bleed for MS s and EC s analysis
• Similar to ms, F ms, P

Application Chromatogram
Sample / Compound Page
cidic eutral rugs Underivati ed 237
asic rugs Underivati ed 236
Chlorinated Hydrocarbons (EPA 612) 189
Chlorophenoxyacid Herbicides (EPA 615) 194
Endocrine Disruptors Butyl Tins (Hexyl Derivatives) 195
Nitrogen-Containing Herbicides 192
Organochlorine Pesticides (EPA 8081) 193
Organophosphorus Pesticides (EPA 8140 / 8141 / 8141A ) 191

DM-35 Ordering Information

15 m 30 m 60 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No. Cat. No.
0.25 0.25 40 to 320 7921 7922
0.50 40 to 310 7923 7924
0.32 0.25 40 to 320 7931 7932
0.50 40 to 310 7933 7934
0.53 1.00 40 to 290 7910 7951

DM-35MS Ordering Information

30 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
0.25 0.25 50 to 340 / 360 8101
0.32 0.25 50 to 340 / 360 8102
*The listed temperature limits are for 15 m and 30 m columns. Longer columns may have lower temperature limits.

www.dikmatech.com 97
 DM-1701

DM-1701
• Cross lin ed cyanopropylphenyl dimethyl polysiloxane
• eneral purpose column of mid polarity phase
• emperature range C to C
• onded and cross lin ed phase, solvent rinsable
• Similar to , HP , SP
• E uivalent to USP phase

DM-1701 is one of the most popular stationary phases. The mix of cyano
and phenyl functional groups increases polarity and offers a different
elution order compared to DM-1 or DM-5 column. DM-1701 column
exhibits low bleed, high inertness and thermal stability because the
GC Columns

polymer is characteri ed, and can be used for EC s, P s and MS s

Application Chromatogram
Sample / Compound Page
Acrylic Esters 219
Formaldehyde 217
Fragrance 234
Organochlorine Pesticides (EPA 8081) 193
Styrene Impurities 219

DM-1701 Ordering Information

15 m 30 m 50 m 60 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No. Cat. No. Cat. No.
0.25 0.25 -20 to 280 7321 7322
0.50 -20 to 270 / 280 7325 7326
1.00 -20 to 260 / 280 7323 7324
0.32 0.25 -20 to 280 7331 7382 7332
0.50 -20 to 270 / 280 7335 7336
1.00 -20 to 260 / 280 7333 7384 7334
0.53 0.50 -20 to 260 / 270 7347 7348
1.00 -20 to 250 / 270 7310 7351 7352
1.50 -20 to 240 / 260 7353 7354
3.00 -20 to 230 / 250 7355 7356
*The listed temperature limits are for 15 m and 30 m columns. Longer columns may have lower temperature limits.

98 www.dikmatech.com
 DM-17 / DM-17MS

DM-17
• onded and cross lin ed diphenyl dimethyl polysiloxane
• eneral purpose column of mid-polarity phase for pesticides,
herbicides, sterols, etc.
• emperature range C to C
• Solvent rinsable
• Similar to , HP , HP , etc

DM-17MS
• Bonded and cross-linked 50% diphenyl / 50% dimethyl arylene polysiloxane
• Excellent inertness and selectivity for active environmental compounds

GC Columns
• emperature range C to C
• Ultra low bleed
• Similar to ms, F ms, P
• E uivalent to USP phase

Application Chromatogram
Sample / Compound Page
BHA / BHT 234
Chlorophenoxyacid Herbicides (EPA 515.1) 194
Organochlorine Pesticides (EPA 8081) 193
PAEs (EPA 8060) 189
Phenols (EPA 604) 190
ria ine Herbicides EP 194

DM-17 Ordering Information

15 m 30 m 60 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No. Cat. No.
0.25 0.25 40 to 280 / 320 7421 7422
0.50 40 to 280 / 320 7423 7424
0.32 0.25 40 to 280 / 320 7431 7432
0.50 40 to 280 / 320 7433 7434
0.53 1.00 40 to 280 / 320 7410 7451

DM-17MS Ordering Information

15 m 30 m 60 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No. Cat. No.
0.25 0.25 40 to 340 / 360 8831 8832 8833
0.32 0.25 40 to 340 / 360 8834 8835
*The listed temperature limits are for 15 m and 30 m columns. Longer columns may have lower temperature limits.

www.dikmatech.com 99
 DM-200 / DM-200MS

DM-200 / DM-200MS
• 100% Trifluoropropylmethyl polysiloxane
• General purpose column of mid-polarity phase
• Temperature range: -20 ºC to 340 ºC
• Bonded and cross-linked phase, solvent rinsable
• Similar to DB-200, DB-210, etc.
• Equivalent to USP G6 phase

Interaction between trifluoropropylmethyl phase and molecules with lone Application Chromatogram
pair electrons or electron-rich molecules is easier, due to electrophilicity of Sample / Compound Page
the fluorine. DM-200 column has accomplished many difficult separations romatics en ene oluene ylene 209
that are not possible on other bonded stationary phases, such as PH, CN Basic Drugs 236
GC Columns

and WAX phase. The trifluoropropyl stationary phase can change elution
Chlorinated Hydrocarbons (EPA 612) 189
orders of compounds. The DM-200 column can make a qualitative analysis
Explosives 195
of phenols, nitrosamines, orgaochlorine pesticides, and chlorhydrocarbons
Glycols 215
and chlorophenoxy herbicides in coordination with the DM-5 column.
Nitrosamines 190
PAHs (EPA 610) 186
DM-200 column offers low bleed, superb inertness, and excellent thermal
Silanes 219
stability, even with sensitive detectors, such as ECDs, NPDs and MSDs.
Solvents 220, 222, 224, 226
USP Solvents 220

DM-200 Ordering Information

15 m 30 m 60 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No. Cat. No.
0.25 0.25 -20 to 320 / 340 8321 8322
0.50 -20 to 310 / 330 8323 8324
1.00 -20 to 290 / 310 8325 8326
0.32 0.25 -20 to 320 / 340 8331 8332
0.50 -20 to 310 / 330 8333 8334
1.00 -20 to 290 / 310 8335 8336
1.50 -20 to 280 / 300 8337 8338
0.53 0.50 -20 to 300 / 320 8347 8348
1.00 -20 to 290 / 310 8310 8351 8352
1.50 -20 to 280 / 300 8353 8354
3.00 -20 to 260 / 280 8355 8356

DM-200 MS Ordering Information

30 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
0.25 0.25 -20 to 320 / 340 8103
0.32 0.25 -20 to 320 / 340 8104
*The listed temperature limits are for 15 m and 30 m columns. Longer columns may have lower temperature limits.

100 www.dikmatech.com
 DM-225

DM-225
• Cross lin ed cyanopropylmethyl phenylmethyl polysiloxane
• eneral purpose column of polar phase, for F MEs, carbohydrates,
sterols and flavor compounds
• emperature range C to C
• Similar to , HP
• E uivalent to USP , phases

he stationary phase of M is less polar than that of W column

containing polyethylene glycol, but can be used for many of the same
applications

GC Columns
n most cases, the cyanopropyl siloxane polymer is not fully compatible
with a Carbowax deactivation layer M polymer has solved this
problem because of the uni ue polymer synthesis technology and pro
prietary siloxane deactivation technology, and provides a C thermal
stability advantage over other columns

Application Chromatogram
Sample / Compound Page
eutral Sterols
Sugars lditol cetates

DM-225 Ordering Information

15 m 30 m 60 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No. Cat. No.
to
to
to
to
to
he listed temperature limits are for m and m columns Longer columns may have lower temperature limits

www.dikmatech.com 101
 DM-Wax

DM-Wax
• onded and cross lin ed polyethylene glycol
• eneral purpose column of polar phase
• Resistant to oxidation
• emperature range C to C
• Solvent rinsable
• Similar to HP Wax, CP W C , etc
• E uivalent to USP , , , and phases
GC Columns

DM-Wax vs. DM-InertWax

Column Features Benefits
M Wax • Wide chemical compatibility acidic, basic and neutral samples • eneral purpose column
• Low bleed at elevated temperatures • est choice for MS use
• High inertness
• High stability and ruggedness
M nertWax • Wide operating temperature range • naly e low boiling point analytes
• Lowest operating temperature limit
• est inertness

Application Chromatogram
Sample / Compound Page
ldehydes
lcohols
lcohols ldehydes
mines lcohols Chlorides
romatics ,
Concentrated Li uors
Esters
Flavor olatiles
lycols
etones
Solvents , ,
Styrene mpurities
Peppermint il
Petroleum xygenates
PUF nimal Source

DM-Wax Ordering Information

15 m 30 m 50 m 60 m
ID (mm) df (µm) MAOT (ºC) Cat. No. Cat. No. Cat. No. Cat. No.
to
to
to
to
to
to
to
to

102 www.dikmatech.com
 DM-InertWax

DM-InertWax
• onded and cross lin ed polyethylene glycol
• eneral purpose column of polar phase for analysis of solvents,
such as F MEs, E , and flavor volatiles
• emperature range C to C
• Similar to Wax, HP Wax, etc
• E uivalent to USP , , , and phases

GC Columns
Application Chromatogram
Sample / Compound Page
ldehydes
F MEs

DM-InertWax Ordering Information

30 m 60 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No.
to
to
to
to
to
he listed temperature limits are for m columns Longer columns may have lower temperature limits

www.dikmatech.com 103
 DM-FFAP

DM-FFAP
• itroterephthalic acid modified polyethylene glycol
• esigned for analysis of underivati ed free acids
• Resistant to oxidation
• emperature range C to C
• Similar to FF P, HP FF P, u ol, etc
• E uivalent to USP , phases

M FF P column is used to analy e acidic compounds including phenol,

derivati ed or underivati ed free acids, organic acids, flavor compounds
and solvents
GC Columns

Application Chromatogram
Sample / Compound Page
lcoholic Standard cids and Esters
Fatty cids Free

DM-FFAP Ordering Information

15 m 30 m 50 m 60 m
ID (mm) df (µm) MAOT (ºC) Cat. No. Cat. No. Cat. No. Cat. No.
to
to
to
to
to
to
to
to

104 www.dikmatech.com
 DM-2330

DM-2330
• iscyanopropyl phenylcyanopropyl polysiloxane
• eneral purpose highly polar phase for cis trans F MEs and dioxin
isomers
• emperature range C to C
• Similar to SP , SP , SP , etc
• E uivalent to USP and phases

M is one of the most polar capillary column stationary phases

his column offers high selectivity for cis trans isomers with con ugated
double bonds due to cyano groups on both sides of the polymer bac
bone

GC Columns
n order to overcome the poor column efficiencies, high bleed and short
column lifetime of highly polar columns, we have developed an advanced
surface treatment technology that is compatible with the M phase
ur improved polymer exhibits better column efficiency and lower bleed

Since the stationary phase of M is not bonded, it should not be

solvent rinsed

Application Chromatogram
Sample / Compound Page
ioxins
PUF nimal Source
Suars lditol cetate

DM-2330 Ordering Information

30 m 60 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No.
to
to
to
to
he listed temperature limits are for m columns Longer columns may have lower temperature limits

www.dikmatech.com 105
 DM-2560

DM-2560
• iscyanopropyl polysiloxane
• Specially designed for cis trans F MEs
• emperature range C to C
• Similar to SP , HP , Silar C, CP Sil F ME, and CP Sil
• Since the stationary phase of M is not bonded, it should not be solvent rinsed

Application Chromatogram
Sample / Compound Page
GC Columns

F MEs cis trans somers

cis / trans FAMEs

C methyl stearate
Column M
C methyl petroselaidate trans
mx mm x m C methyl elaidate trans
Cat o 8858 C methyl transvaccenate trans
ndex CFR C methyl petroselinate cis
ven emp C hold min to C hold min , C min C methyl oleate cis
Carries as H, mL min C methyl vaccenate cis
C methyl linoleate cis ,
Sample mg mL cis trans F MEs Mix, in dichloromethane
n ection Split, , L, C
etector F , C

DM-2560 Ordering Information

100 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
to

106 www.dikmatech.com
 DM-PLOT Alumina

Column Phase Cross Reference

DikmaCap™ Phase Agilent Restek Supelco
S lumina, HP PL S, CP l
M PL lumina luminum oxide
PL
luminum oxide S lumina, HP PL S,
M PL lumina aS Rt lumina aS lumina Sulfate PL
a S deactvation CP l a S PL
luminum oxide S lumina C , HP PL l C,
M PL lumina C Rt lumina C lumina Chloride PL
C deactvation CP l C PL
M PL CFC Rt lumina CFC
M PL MS Molecular sieve HP PL Molesieve, CP Molesieve Rt Msieve Molsieve
M PL CP PoraPL , CP Pora ond Rt Supel PL
M PL S Porous homopolymer S Rt S

GC Columns
M PL S vinylpyridine CP PoraPL S Rt S
HP PL U, CP PoraPL U,
M PL U ethylene glycol dimethylacrylate Rt U
CP Pora ond U

DM-PLOT Alumina ( Al2O3 )

• Retention index for unsaturated hydrocarbons is higher than that of al ane
hydrocarbon Selectivity of M PL lumina column is tested using
retention indices for unsaturated hydrocarbons
• i ma has developed a special procedure to reduce the activity of
alumina to the lowest level he column sensitivity for unsaturated
compounds such as al enes, al ynes and dienes is also verified
toensure a linear and uantitative chromatographic analysis for these
compounds
• Every M PL lumina column is tested with a hydrocarbon standard
to ensure proper phase thic ness and inertness
• Strong bonding avoids particle generation
• he phase can be regenerated by water flushing after contamination

Selectivity Sensitivity
Selectivity of M PL lumina columns are measured using retention reasonable deactivation treatment can reduce the activity of alumina
indices for acetylene and propadiene he retention property is higher phase to the lowest level and improves the selectivity of column he
with increasing compounds unsaturation and decreasing volatility inertness of alumina phase ensures a linear response which is the base
of uantitative analysis i ma has developed special deactivated proce
For saturated substances, the volatility decides the retention strength of dures to M PL lumina to ensure high inertness and linear response
compounds he volatility is stronger with less retention index ll al ane to unsaturated and saturated hydrocarbons he sensitivity of M PL
isomers have wea er retention strengths and stronger volatility compared lumina is four times more than that of other PL columns on the mar
with n al anes containing same number of carbon atoms Similarly, the et see able
volatility is decreased and retention index is increased as the number of
carbon atoms is increased Reproducibility
Every M PL lumina column is tested with gas standard C C to
For unsaturated hydrocarbons, the retention index is decided by the
confirm proper phase thic ness and deactivation degree, ensuring maxi
degree of unsaturation polarity Retention properties are higher with
mum reproducibility
stronger degree of unsaturation n general, hydrocarbons with a higher
degree of unsaturation have higher polarity due to the electrons

Table 1 The Retention Index and Sensitivity of DM-PLOT Application Chromatogram

Alumina to Unsaturated Hydrocarbons Sample / Compound Page
Ethylene Acetylene Propylene Allene , utadiene Purity
Retention ndex Hydrocarbons
Ratio of Pea Height Propylene Purity
Refinery as

www.dikmatech.com 107
 DM-PLOT Alumina / Na2SO4

DM-PLOT Alumina / Na2SO4

• utanes impurities in acetylene propadiene elute before acetylene
propadiene
• est separation for butene isomers impurities in butene streams
• Propylene elutes after cyclopropane impurity in propylene
• Similar to S lumina, HP PL S, lumina Sulfate PL , lumina,
and CP l a S PL

Application Chromatogram
Sample / Compound Page
GC Columns

Refinery as

Refinery Gas
Column M PL lumina aS
Methane utene
mx mm x m
Ethane sobutylene
Sample Refinery gas
Ethylene cis utene
Cat o 8806 Propane sopentane
ndex CSR Propylene n Pentane
ven emp C hold min to C hold min at C min sobutane , utadiene
Carrier as He, constant pressure psi, Pa n utane trans Pentene
cm sec C Propadiene Methyl butene
cetylene Pentene
n ection Split, L, C
trans utene cis Pentene
Split ent Flow Rate mL min
Hexanes
etector F , C
Ma eup as N

DM-PLOT Alumina / Na2SO4 Ordering Information

30 m 50 m
ID (mm) df (µm) MAOT (ºC) Cat. No. Cat. No.
to
to
to

108 www.dikmatech.com
 DM-PLOT Alumina / KCI

DM-PLOT Alumina / KCl

• C hydrocarbons impurities in butane isobutane elute after acetylene
• , utadiene elutes after methyl acetylene impurity in , butadiene
• Similar to S lumine C and CP l C PL

Application Chromatogram
Sample / Compound Page

GC Columns
utane Lighter Fluid

Butane Lighter Fluid

Column M PL lumina Cl
mx mm x m
Cat o 8813
ndex CSR
ven emp C hold min to C hold min at C min Methane
Carrier as H , constant pressure psi, Pa cm sec at C Ethane
Sample utane lighter fluid Propane
n ection alve, L, C sobutane
etector F , C n utane
trans utene
utene
sobutylene

DM-PLOT Alumina / KCI Ordering Information

30 m 50 m
ID (mm) df (µm) MAOT (ºC) Cat. No. Cat. No.
to
to
to

www.dikmatech.com 109
 DM-PLOT MS 5A

DM-PLOT MS 5A
• Separation for permanent gases
• Stationary phase bonded without particles loss

M PL MS column is used for separation of r and other

permanent gases Special procedures ensure high column efficiency and
integrity of the porous layer coating his column has special selectivity to
certain compounds by controlling the pore si e of particles dditionally,
our spcial immobili ation process ensures that the stationary phase
particles adheres to the tubing

he advanced molecular sieve M PL MS column can separate

GC Columns

r and H He at or above ambient temperature his column is also

an ideal choice for separation of permanent gases in refined or natural
gases

Application Chromatogram
Sample / Compound Page
Permanent ases

Permanent Gases
Column M PL MS
mx mm x m
Cat o 8823
ndex CSR
ven emp C Hydrogen ppm
Carrier as He, cm sec rgon ppm
n ection Sample Loop, mL xygen ppm
etector alco, H

DM-PLOT MS 5A Ordering Information

30 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
to
to

110 www.dikmatech.com
 DM-PLOT Q / QS / S / U

DM-PLOT Q / QS / S / U
• Separation for gases and volatile organic compounds
• Stationary phase bonded without particles loss

We have developed a uni ue polymer synthesis technology and coating

process for the manufacture of porous polymer PL columns he
selectivity of stationary phase is similar to the phase of Porapa and
HayeSep

he porous polymer PL column is not sensitive to water, so this

column can be used for analysis of water containing samples

GC Columns
he polarity and selectivity of the stationary phase is changed by
incorporating polar groups on PS he non polar phase of M
PL column is M PL S is the mid polarity PL column
with high vinyl pyridine on

he stationary phase of M PL S is porous divinylben ene

homopolymer, which has a polarity between M PL and M PL
S due to intermediate polarity PL column incorporation of low vinyl
pyridine his column is used for separation of ethane, ethylene and
acetylene to baseline

M PL U is a polar PL column incorporating divinylben ene

ethylene glycol dimethylacrylate, and can be used for the analysis of Application Chromatogram
polar and non polar compounds Sample / Compound Page
lcohols
ll PL columns have wide application range PL columns can Hydrocarbon ases , ,
analy e permanent gases below room temperature norganic gases atural as
such as C , hydrocarbons and polar and non polar solvents can be Polar Solvents
easily separated on PL columns Permanent ases ,

DM-PLOT Q / QS / S / U Ordering Information

30 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
DM-PLOT Q to
to
to
DM-PLOT QS to
to
to
DM-PLOT S to
to
to
DM-PLOT U to
to
to

www.dikmatech.com 111
 DM-PLOT CFC

DM-PLOT CFC
• mproved inertness for halogenated compounds
• Highly selective alumina based column
• High retention and capacity for CFCs
• Specially designed for CFCs separation

luminum oxide is an ideal absorbent for retaining halogenated compounds

especially CFCs Freon products t has high selectivity for separating CFC
isomers at above ambient temperatures

M PL CFC column can reduce the reactivity of alumina due to the

deactivation process Even though there is still some residual mono or
GC Columns

di substituted CFCs, the ma ority of these compounds can be accurately

uantified in impurity analysis

Application Chromatogram
Sample / Compound Page
mpurity nalysis of , , , etrafluoroethane

Impurity Analysis of 1,1,1,2-Tetrafluoroethane

Column M PL CFC
mx mm x m
Cat o 8859
ndex C R
Sample , , , etrafluoroethane Chloropentafluoroethane CFC
ichlorodifluoromethane CFC
n ection Split, L
Chlorodifluoromethane CFC
ven emp C hold min to C hold min at C min
, , , etrafluoroethane CFC a
Carrier as He
etector F

DM-PLOT CFC Ordering Information

30 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
to

112 www.dikmatech.com
 DM-PONA

DM-PONA
• imethyl polysiloxane
• on polar phase
• Specially designed for analysis of complex hydrocarbon compounds
• Exceeds S M and C S method guidelines
• emperature range C to C
• Similar to Petrocol H, petro and HP P
• Solvent rinsable

MP is a non polar column for analysis of complex hydrocarbon

compounds ur rigorous C method exceeds the S M method guide
lines for resolution and retention time

GC Columns
Application Chromatogram
Sample / Compound Page
etailed Hydrocarbons nalysis

Detailed Hydrocarbons Analysis

Column MP
mx mm x m
Cat o 7805 Propane n Heptane n onane
ndex CSR sobutane Methanol oluene , , rimethylben ene
ven emp C hold min to C hold min at C min to n utane , imethylhexane , , rimethylben ene
C hold min at C min to C hold min at C min iso Pentane n ctane n ecane
Carrier as He, cm sec, C n Pentane Ethylben ene n Undecane
Sample Unleaded gasolines, L Methylpentane m ylene aphthalene
n Hexane p ylene n odecane
n ection Split, , C
en ene , imethylheptane Methylnaphthalene
etector F , x FS, C
Methylhexane o ylene n ridecane

DM-PONA Ordering Information

50 m 100 m
ID (mm) df (µm) MAOT (ºC) Cat. No. Cat. No.
to
to

www.dikmatech.com 113
 DM-TCEP

DM-TCEP
• , , ris cyanoethoxy propane
• Highly polar phase
• eneral purpose column, ideal for aromatics and oxygenates in gasoline
• emperature range C to C
• Similar to CP CEP

Most gasolines contain aliphatic hydrocarbons up to C o separate aro

matics and oxygenates in gasoline effectively, it is desirable to elute ben ene
after C and toluene after C he strong polar M CEP stationary phase
offers a retention index for ben ene greater than , ppm and can sepa
rate alcohols and aromatics from the aliphatic constituents in gasoline
GC Columns

M CEP column has the same high polarity as pac ed columns, which is a
column used for analysis of petroleum oxygenates listed in S M with
higher efficiency

Application Chromatogram
Sample / Compound Page
romatics
Petroleum xygenates

Petroleum Oxygenates
Column M CEP
mx mm x m
Cat o 7809 Methyl tert butyl ether
ndex CSR n Undecane
ven emp C hold min to C hold min at C min tert utanol
Methanol
Carrier as He, cm sec, C
sopropyl alcohol
Sample L, ppm
Ethanol
n ection Split, mL min, C n odecane
etector F , x FS, C n ridecane
n utanol

DM-TCEP Ordering Information

60 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
to

114 www.dikmatech.com
 DM Series SimDist Metal

DM-1HT SimDist Metal

• Special purpose column, ideal for high temperature simulated distillation
• Reliably meets all S M , , and specifications
• imethyl polysiloxane phase
• Sulfinert treated high elasticity stainless steel tubing
• Stable up to C

M H Sim ist Metal meets S M , and

specifications for high temperature simulated distillation Highly robust
phase provides an accurate retention time boiling point curve, and
exhibits excellent pea shape and low bleed even at C M H
Hydrocarbons, C44-C100
Sim ist Metal offers a higher maximum operating temperature compared

GC Columns
Column M H Sim ist Metal
with M H Sim ist Metal C vs C
mx mm x m
Cat o 8871
ndex CSR
ven emp C to C at C min
Carrier as He
Sample C C , in CS
n ection P , L
Flow Rate mL min
etector F , C

DM-1 / DM-500 SimDist Metal

• Special purpose column, ideal for high temperature simulated distillation
• M Sim ist Metal phase offers true methyl silicone polarity
• M Sim ist Metal phase is a carborane siloxane polymer
• Sulfinert treated high elasticity stainless steel tubing
• Stable up to C

Application Chromatogram
Sample / Compound Page
leed Profile
Hydrocarbons, C C
Hydrocarbons, C C
Hydrocarbons, C C

DM Series SimDist Metal (Sulfinert Treated Stainless Steel) Ordering Information

5m 6m
Phase ID (mm) df (µm) MAOT (ºC) Cat. No. Cat. No.
M H Sim ist Metal to
to
M Sim ist Metal to
M Sim ist Metal to

www.dikmatech.com 115
 DM-2887 / DM-2887 Metal

DM-2887 / 2887 Metal

• imethyl polysiloxane
• Special purpose column, ideal for simulated distillation
• Stable up to C
• Similar to , Petrocol E

M column s stationary phase, film thic ness, and dimension

have been optimi ed to exceed the asymmetry factor and resolution
re uirements specified in S M method Each column is
individually tested with hydrocarbon mixtures to guarantee low bleed and
reproducibility
GC Columns

Application Chromatogram
Sample / Compound Page
Simulated istillation

Simulated Distillation
C C
Column M
C C
mx mm x m C C
Cat o 7808 C C
ndex CSR C C
ven emp C to C hold min at C min C C
Carrier as N, cm sec C C
C C
Sample wt hydrocarbons
C
in standard CS solvent, L
C
n ection irect, C

DM-2887 (Fused Silica) Ordering Information

10 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
to

DM-2887 Metal (Sulfinert-Treated Stainless Steel) Ordering Information

10 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
to

116 www.dikmatech.com
 DM-BDTG Metal

DM-BDTG Metal
• For biological diesel oil analysis
• Reduces analysis time and optimi es mono ,di and triglyceride pea s
• Stable up to C
• ntegra ap built in retention gap eliminates column coupling completely

Application Chromatogram
Sample / Compound Page
lycerin in iodiesel S M

GC Columns
Glycerin in Biodiesel (ASTM D6584)
Column M Metal Monoglycerides Monoglycerides iglycerides riglycerides
mx mm x m
with m ntegra ap, total length m
Cat o 8864
ndex CSR
ven emp C hold min to C at C min to
C at C min to C hold min
at C min
Carrier as H , mL min
Sample iodiesel in n hexane
ricaprin S
n ection L cold on column
etector F , C

lycerin
utanetriol S

DM-BDTG Metal Ordering Information

ID (mm) df (µm) MAOT (ºC) Length Cat. No.
to m with m ntegra ap total length m

www.dikmatech.com 117
 DM-Volatile Amine

DM-Volatile Amine
• Special selectivity for baseline resolution of all volatile amines
• Excellent inertness assures sensitivity and accuracy for volatile amines such as free ammonia
• Highly robust phase allows repeated water in ections, increases longer column lifetime
• irect replacement for CP olamine, thic film CP Sil

he M olatile mine column was optimi ed for the separation of volatile amines even when the
sample contains high precentages of water he uni ue base deactivation creates an exceptionally
inert surface for these sensitive compounds, resulting in highly symmetric pea s which allow low
detection limits

oth m and m columns are available to ensure the separation for most of amine samples
GC Columns

ue to the high temperature stability up to C, it ensures elution of amines up to C and allows

contaminations to be removed by ba ing out the column

Application Chromatogram
Sample / Compound Page
Short Chain mines in Water

Short Chain Amines in Water

Column M olatile mine
pA
mx mm
Cat o 8857 225
ndex C
ven emp C hold min to C at C min hold min 200 2

Carrier as H , mL min, cm sec C

Sample , ppm Short chain amines in water 175

n ection Split, , L, C
5
etector F , C 150

125
Methanol
imethylamine 100
rimethylamine
Methylethylamine IS
75
imethylethylamine
iethylamine
50
iethylmethylamine
riethylamine 6
7 8
1 4
25 3
S sopropylamine
0
0 5 10 15 20min.

DM-Volatile Amine Ordering Information

30 m 60 m
ID (mm) MAOT (ºC) Cat. No. Cat. No.
to

118 www.dikmatech.com
 DM-5 Amine

DM-5 Amine
• onded and cross lin ed diphenyl dimethyl polysiloxane
• Low polarity phase
• Specially designed for amines and other basic compounds
• Stable up to C
• Solvent rinsable
• Similar to P

ypical C methods for analysis of basic compounds re uire

derivati ation to avoid pea tailing he M mine column has a
special tubing surface which is chemically altered to reduce tailing of
basic compounds, thereby eliminating the need for column priming

GC Columns
he M mine column is ideal for analysis of basic compounds
including al ylamines, diamines, triamines, ethanolamines, nitrogen Amines / Phenols
heterocyclic compounds, neutral compounds, and adsorptive Column M mine
compounds with oxygen groups susceptible to hydrogen bonding, or mx mm x m iethylamine
even wea ly acidic compounds such as phenols Cat o 7817 Pyridine
ndex CCR Morpholine
Every M mine column is tested to ensure that it meets the Phenol
ven emp C to C at C min
re uirements for analy ing amines with low ppm levels, and to ensure niline
Carrier as H, cm sec, C
low bleed at maximum operating temperature Chlorophenol
Sample mines phenols in water, L, ng iethylenetriamine
n ection Split, , C ctylamine
etector F , x FS, C Methyl
pyrrolidinone
itrophenol
, imethylaniline
icotine
itroaniline

Application Chromatogram
Sample / Compound Page
mines Phenols
ntihistamines
Ethylenediamines
Sympathomimetic mines rugs

DM-5 Amine Ordering Information

30 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
to
to
to
to
to
to

www.dikmatech.com 119
 DM-35 Amine

DM-35 Amine
• onded and cross lin ed diphenyl dimethyl polysiloxane
• Mid polarity phase
• ase deactivated
• Specially designed for amines and other basic compounds
• Stable up to C
• Solvent rinsable

ypical C methods for analysis of basic compounds re uire derivati ation to

avoid pea tailing he M mine column has a special tubing surface which
is chemically altered to reduce tailing of basic compounds, thereby eliminating the
need for column priming
GC Columns

he M mine column is ideal for analysis of basic compounds including

al ylamines, diamines, triamines, ethanolamines, nitrogen heterocyclic
compounds, neutral compounds and adsorptive compounds with oxygen groups Ethanolamines
susceptible to hydrogen bonding, or even wea ly acidic compounds such as Column M mine
phenols mx mm x m
Cat o 7823
Every M mine column is tested to ensure that it meets the re uirements
ndex CCR
for analy ing amines with low ppm levels, and to ensure low bleed at maximum
ven emp C hold min to C at C min
operating temperature
Carrier as He, cm sec constant pressure
Sample g mL Ethanolamine standard in water, L
n ection Split, , C
Monoethanolamine
etector F , C
iethanolamine
riethylene glycol monomethyl ether
riethanolamine

Application Chromatogram
Sample / Compound Page
Cold Medicine
Ethanolamines
Primary mines
Sympathomimetic mines rugs

DM-35 Amine Ordering Information

30 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
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 DM-Wax Amine

DM-Wax Amine
• polyethylene glycol
• ase deactivated
• Specially designed for amines and other basic compounds
• oes not re uire derivati ation or column priming
• Stable up to C
• Similar to C M, Carbowax mine, CP Wax

M Wax mine column can reduce adsorption and improve sensitivity

for many basic compounds without analyte derivati ation or column
priming he M Wax mine column can analy e al ylamines, diamines,
triamines, ethanolamines and nitrogen heterocyclic compounds We

GC Columns
recommend use of M Wax mine combined with M mine columns
when separating oxygenates because the M Wax mine has wea
adsorption of some compounds at less than ppm concentrations
Primary Amines
Column M Wax mine
mx mm x m
Cat o 7833
ndex CCR
ven emp C
Carrier as H, cm sec
Sample mines in water, L
n ection irect, L, C
etector F , x FS, C

rimethylamine
imethylamine
Application Chromatogram
Ethylamine
Sample / Compound Page Methylamine
mines Low MW sopropylamine
Hexamethylenediamine n Propylamine
itrosamines tert utylamine
Primary mines Low MW iethylamine
sec utylamine

DM-Wax Amine Ordering Information

30 m 60 m
ID (mm) df (µm) MAOT (ºC) Cat. No. Cat. No.
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 DM-624 / DM-624MS

DM-624
• Cyanopropylphenyl dimethyl polysiloxane
• Recommended in US EP methods for volatile organic pollutants
• deal for analy ing residual solvents in drugs
• Stable up to C
• Solvent rinsable
• Similar to HP , HP , , , etc
Application Chromatogram
• E uivalent to USP phase
Sample / Compound Page
EP Class and Class Solvents
DM-624MS rganic olatile mpurities
• Cyanopropylphenyl dimethyl arylene polysiloxane Primary, Secondary and ertiary mines
• High inertness and low bleed Residual Solvents
GC Columns

• Highly selective for residual solvents

olatile rganic Compounds EP
• Stable up to C
• Similar to , HP , F ms, etc

ertiary
amine
Primary, Secondary and Tertiary Amines Secondary
Column M MS amine
mx mm x m
Cat o 8838
ndex CPR
ven emp C hold min to C hold min at C min
Carrier as He, cm sec Primary
amine
Sample Primary, secondary and tertiary amines in MS , g mL
n ection Split, , L, C
etector F , C High activity,
low inertness
sopropylamine
iethylamine
riethylamine

DM-624 Ordering Information

30 m 60 m 75 m 105 m
ID (mm) df (µm) MAOT (ºC) Cat. No. Cat. No. Cat. No. Cat. No.
to
to
to

DM-624MS Ordering Information

20 m 30 m 60 m
ID (mm) df (µm) MAOT (ºC) Cat. No. Cat. No. Cat. No.
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 DM-TVOC

DM-TVOC
• imethyl polysiloxane
• Specially designed for analysis of Cs
• Meets specifications
• Low baseline noise when adopting programmed temperature
• Low bleed
• onded and cross lin ed phase, solvent rinsable

GC Columns
Application Chromatogram
Sample / Compound Page
Cs

TVOCs
Column M C
mx mm x m
Methanol
Cat o 7831
en ene
oluene ndex CE
utyl acetate ven emp C hold min to C at C min
Ethylben ene Carrier as N
p ylene n ection Split, , C, L
m ylene etector F , C
inyl ben ene
o ylene
Undecane
mpurity
mpurity

DM-TVOC Ordering Information

50 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
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www.dikmatech.com 123
 DM-PAH

DM-PAH
• Methyl phenyl polysiloxane
• Specially designed for analysis of P Hs
• Stable up to C
• Used for C MS and EC s
• onded and cross lin ed phase, solvent rinsable

he M P H phase has excellent inertness and selectivity for P Hs

E uivalent to USP phase, M P H can separate EU P Hs including
fluoranthene
GC Columns

Application Chromatogram
Sample / Compound Page
P Hs

PAH-Mix 27
Column MP H
mx mm x m
Cat o 8862
ndex CER
ven emp C hold min to C at C min
to C hold min , C min
Carrier as He, mL min 7
8
Sample EP P Hs in dichloromethane solution, ppm
n ection Splitless hold min , L, C 16
etector F , C
6
45
Ma eup as mL min
2
aphthalene en o fluoranthene 3
14 15
Methylnaphthalene en o fluoranthene 1

Methylnaphthalene en o a pyrene
cenaphthylene Methylcholanthrene
cenaphthene iben o a,h acridine 11.8 12.0 12.2 12.4
Fluorene iben o a, acridine 9 26.226.4 26.6 26.827.0 27.227.427.6 27.828.0 28.228.4
Phenanthrene ndeno , , cd pyrene 10

nthracene iben o a,h anthracene 12/13

21/22
Fluoranthene en o ghi perylene 11

Pyrene H iben o c,g carba ole 17

18 20 23 24
en o a anthracene iben o a,e pyrene 19

Chrysene iben o a,i pyrene 25

riphenylene iben o a,h pyrene
en o b fluoranthene 2627

5 10 15 20 25 30 35 40 min.

DM-PAH Ordering Information

30 m 60 m
ID (mm) df (µm) MAOT (ºC)* Cat. No. Cat. No.
to
he listed temperature limits are for m columns Longer columns may have lower temperature limits

124 www.dikmatech.com
 DM-FAMEWAX

DM-FAMEWAX
• Polyethylene glycol
• Specially designed for analysis of F MEs
• ested with a F ME mixture
• Stable up to C
• Similar to megawax

When M F MEW is used for separation of unsaturated F MEs, the

baseline resolution is achieved in less time

GC Columns
Application Chromatogram
Sample / Compound Page
F MEs lac Currant Seed il
F MEs Flax Seed il
F MEs Marine il Standard

FAMEs (Marine Oil Standard)

C C
Column M F MEW
C C n
mx mm x m
C C n
Cat o 7813 C C n
ndex CFR C C n
ven emp C to C hold min at C min C C n
Carrier as H, cm sec C C n
Sample mg mL F MEs, L C C n
C C S
n ection Split, , mm , C
C oleate C n
etector F , C
C vaccenate C n
C n cis C n
C n C
C n
C n

DM-FAMEWAX Ordering Information

30 m
ID (mm) df (µm) MAOT (ºC) Cat. No.
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