Cryogenic Engineering

Lecture 2: Properties of cryogenic fluids

Prof. Dipanshu Bansal

Department of Mechanical Engineering

1
 Outline of the Lecture
• What is Cryogenics?

• The Chronology of Cryogenic Technology

• Definitions and different temperature Scales

• T – s diagram of a Cryogenic Fluid

• Properties of the Cryogenic Fluids

2
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 The Chronology
Year Event
1877 Cailletet and Pictet liquefied Oxygen.
1879 Linde founded the Linde Eismaschinen AG.
1892 Dewar developed a vacuum insulated vessel
for cryogenic fluid storage.
1895 Onnes established Leiden Laboratory.
1902 Claude established l’Air Liquide and
developed air-liquefaction system.
1908 Onnes liquefied helium (Nobel prize in 1913)
1911 Onnes discovered superconductivity in solid
Hg at 4.2 K

Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay 4

 The Chronology
Year Event
1926 Goddard test fired the first cryogenically
propelled rocket.
1934 Kapitza designed the first expansion engine.
1952 National Institute of Standards & Technology
(NIST), USA, Cryogenic Engineering
Laboratory established.
1966 Development of Dilution refrigerator.
1975 Record high superconducting transition
temperature (23 K) achieved.
1994 Matsubara developed a 4 K cryocooler

Prof. 5
Prof. M
MDD Atrey,
Atrey, Department
Department of
of Mechanical
Mechanical Engineering,
Engineering, IIT
IIT Bombay
Bombay
 Temperature

Kelvin Celsius Rankine Fahrenheit

(K) (°C) (°R) (°F)
0 -273.15 0 -459.67
273.15 0 491.67 32
373.15 100 671.67 212

Increment
• 1 K = 1°C = 1.8°R = 1.8°F

7
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
Chronology of Temperature Scales
• 1724 – Fahrenheit scale

• 1742 – Centigrade scale (Reverse order)

• 1744 – Centigrade scale (Changed to existing order)

• 1848 – Kelvin scale

• 1859 – Rankine scale

• 1948 – Centigrade to Celsius

Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay

Chronology of Temperature Scales
• 1724
– Dutch-German-Polish physicist, engineer, and glass blower,
Daniel Gabriel Fahrenheit(1686–1736) invents Fahrenheit
scale.

• 1742
– Swedish astronomer Anders Celsius(1701–1744) invents
Centigrade scale but in reverse order, i.e., boiling point
of water = 0 0C
freezing point of water = 100 0C

Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay

Chronology of Temperature Scales
• 1744
– Coincident with the death of Celsius, Swedish botanist
Carolus Linnaeus(1707–1778) reverses Celsius's scale.
Independently few others are also credited for the same.

• 1848
– Glasgow University engineer and physicist Lord Kelvin
(William Thomson)(1824–1907), recognizes the need for
an absolute thermometric scale, so he proposes the Kelvin
scale which uses degree Celsius for its unit increment.

Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay

Chronology of Temperature Scales
• 1859
– Glasgow University engineer and physicist William John Macquorn
Rankine(1820–1872) proposes the Rankine thermodynamic (absolute)
temperature scale.
1 0R = 1 0F

• 1948
– 9th CGPM (Conférence générale des poids et mesures) and the CIPM
(Comité international des poids et mesures) formally replaces "degree
Centigrade“ with "degree Celsius“.
Reason:- Centigrade was also the Spanish and French
language name for a unit of angular measurement and had a similar
connotation in other languages.

Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay

 Temperature
The Kelvin Temperature Scale
• K = C + 273 (Note it is Kelvin, but not
degree Kelvin).

Room Temperature ~ 300 K

Cryogen Temp Cost
(K) (Rs/Lit)
LN2 77.36 25
LH2 20.39
LHe 4.2 4000
12
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Cryogen
Cryogen
• Fluid with normal boiling point less than 123 K.

Cryogen Boiling Point Triple Point

(K) (K)
Methane, CH4 111.67 90.69
Oxygen, O2 90.19 54.36
Argon, Ar 87.30 83.81
Air(N2+O2+Ar) 78.6 59.75

13
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Cryogen (contd..)

Cryogen Boiling Point Triple Point

(K) (K)
Nitrogen, N2 77.36 63.15
Normal H2 20.39 13.96
He4 4.230 -
He3 3.191 -

14
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 T – s diagram of a cryogen
300 K, 1atm A

Absolute Temperature

B Isobar

C Critical Point

Liquid
Normal F
Boiling Point E Vapor
L+V
Entropy
15
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Properties of few Cryogens

Sat. Liq. at 1atm LHe 4 LH2 LN2 LAir LOX

Normal
Boiling K 4.214 20.27 77.36 78.8 90.18
Point
Critical
MPa 0.229 1.315 3.39 3.92 5.08
Pressure
Density kg/m3 124.8 70.79 807.3 874 1141
Latent
kJ/kg 20.90 443 199.3 205 213
Heat

16
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 T – s diagram of Helium

Critical Pt.
2.29 atm,
5.2 K

T – s chart for He – 4
1 atm, 4.2 K •Pressure (P) – atm
•Density – gm/mol-lit
•Temp (T) – K
•Enthalpy (h) – J/gm-
mol
•Entropy (s) – J/g-mol-K

17
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 T – s diagram of Nitrogen
T – s chart for N2
•Pressure (P) – atm
•Density – gm/mol-lit
•Temp (T) – K
•Enthalpy (h) – J/gm-
mol
•Entropy (s) – J/g-mol-K

Critical Pt.
33.9 atm,
126 K

1 atm,
77.36 K

18
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Cryogenic Fluids
Hydrogen, Helium
• They fall in special class. These gases are dealt in
next lecture.

Liquid Methane
• It boils at 111.7 K.

• It can be used as rocket fuel.

• In the form of Compressed natural gas (CNG).

19
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Cryogenic Fluids
Liquid Neon
• It is a clear, colorless liquid with boiling point at
27.1 K.

• Neon is commonly used in neon advertising.

• Liquid neon is commercially used as cryogenic

refrigerant.

• It is compact, inert and less expensive as

compared to liquid helium.
20
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Cryogenic Fluids
Liquid Nitrogen (LN2)
• Boils at 77.36 K and freezes at 63.2 K.

• Resembles water in appearance - 807 kg/m3

(water – 1000 kg/m3).

• Exists in 2 stable isotopes - N14 & N15 in ratio of

10000 : 38.

• Heat of vaporization is 199.3kJ (water -

2257kJ/kg) and it is produced by distillation of
liquid air.
21
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Cryogenic Fluids
Liquid Nitrogen (LN2)
• Nitrogen is primarily used to provide an inert
atmosphere in chemical and metallurgical
industries.

• It is also used as a liquid to provide refrigeration.

• Food preservation, blood, cells preservation.

• High temperature superconductivity.

22
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Cryogenic Fluids
Liquid Oxygen (LOX)
• Blue in color – due to long chains of O4.

• Boils at 90.18 K and freezes at 54.4 K.

• Has a density of 1141kg/m3 (water – 1000

kg/m3).

• O2 is slightly magnetic and exists in 3 stable

isotopes - O16, O17, O18 in ratio of (10000 : 4
: 20).

23
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Cryogenic Fluids
Liquid Oxygen (LOX)
• Because of the unique properties of oxygen,
there is no substitute for oxygen in any of its
uses – widely used in industries and for medical
purpose.

• It is largely used in iron and steel manufacturing

industry.

• Oxidizer propellant for spacecraft rocket

applications.

24
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Cryogenic Fluids
Liquid Argon
• It is a colorless, inert and non toxic gas.

• It boils at 87.3 K and freezes at 83.8 K.

• It has a density of 1394 kg/m3 (water – 1000

kg/m3).

• Exists in 3 stable isotopes – Ar35, Ar38, Ar40 and

in a ratio of (338 : 63 : 100000).

25
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Cryogenic Fluids
Liquid Argon
• The property of inertness of argon is used to
purge moulds in casting industry.

• It is used in Argon-oxygen decarburization (AOD)

process in stainless steel industry.

• It offers inert atmosphere for welding stainless

steel, aluminum, titanium etc.

26
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Cryogenic Fluids
Liquid Air
• For practical purpose, it is considered as a mixture
of 78% N2 + 21% O2 + 1% Ar + others.

• It has a boiling point of 78.9 K and 874 kg/m3 as

density (water density - 1000 kg/m3).

• Liquid air was earlier used as precoolant for low

temperature applications.

• Liquid air is primarily used in production of pure

nitrogen, oxygen, and rare gases.
27
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay
 Thank You!

32
Prof. M D Atrey, Department of Mechanical Engineering, IIT Bombay