SAFETY DATA SHEET

Revision Date: 06-Aug-2020

Issuing Date: 06-Mar-2017
Product Name: BTD60BK Revision Number: 3
Safety data sheet number: BHK168
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Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product Name BTD60BK

Product Form Mixture

Safety data sheet number BHK168

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses Water based ink for inkjet printing machine

Uses advised against No information available

1.3. Details of the supplier of the safety data sheet

Manufacturer Brother Industries, Ltd.

15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
Telephone (for information): +81-52-824-2735

Importer (Europe)
Brother International Europe Ltd.
1 Tame Street, Audenshaw, Manchester M34 5JE, UK
Brother International (Nederland) B.V.
Zanderij 25, 1185 ZM Amstelveen, The Netherlands
Telephone (for information): +44-161-330-6531

For further information, please contact

E-mail address [email protected]

1.4. Emergency telephone number

Emergency Telephone CHEMTREC +1-703-527-3887 (International)

For France only:

Antipoison Center telephone number: ORFILA +33-1-45-425-959

Section 2: Hazard(s) identification

2.1. Classification of the substance or mixture
Regulation (EC) No 1272/2008
This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [GHS]

2.2. Label elements

Regulation (EC) No 1272/2008
This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [GHS]

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 SAFETY DATA SHEET

Revision Date: 06-Aug-2020

Issuing Date: 06-Mar-2017
Product Name: BTD60BK Revision Number: 3
Safety data sheet number: BHK168
_____________________________________________________________________________________________

EUH208 - Contains 1,2-Benzisothiazolin-3-one May produce an allergic reaction.

2.3. Other hazards

This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This product contains no substance considered to be very persistent nor very bioaccumulating (vPvB).

Section 3: Composition/information on ingredients

3.1 Substances

Not applicable

3.2 Mixtures

Chemical name CAS No EC No EC Index No Weight-% Classification REACH

according to Registration
Regulation (EC) Number
No. 1272/2008
[CLP]
Water 7732-18-5 231-791-2 - 60-70 Not classified Not applicable
Glycerol 56-81-5 200-289-5 - 15-25 Not classified Not applicable
Triethylene glycol, 143-22-6 205-592-6 603-183-00-0 1-5 Eye Dam. 1 01-2119475107-
monobutyl ether (H318) 38-XXXX
Triethanolamine 102-71-6 203-049-8 - 1-5 Not classified Registered
1,2-Benzisothiazolin-3-one 2634-33-5 220-120-9 613-088-00-6 <0.05 Acute Tox. 4 Not applicable
(H302)
Skin Irrit. 2
(H315)
Eye Dam. 1
(H318)
Skin Sens. 1
(H317)
Aquatic Acute 1
(H400)
** CONFIDENTIAL

Full text of H- and EUH-phrases: see section 16

Section 4: First aid measures

4.1. Description of first aid measures

General advice If symptoms persist, call a physician.

Inhalation IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Get immediate medical advice/attention.

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 SAFETY DATA SHEET

Revision Date: 06-Aug-2020

Issuing Date: 06-Mar-2017
Product Name: BTD60BK Revision Number: 3
Safety data sheet number: BHK168
_____________________________________________________________________________________________

Eye contact In case of eye contact, immediately flush eyes with plenty of water for at least 15 minutes.
Get immediate medical advice/attention.

Skin contact: Wash off immediately with soap and plenty of water. If skin irritation persists, call a
physician.

Ingestion Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of
water to drink.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms Inhalation ( Vapor / Mist ) : No specific effects and/or symptoms have been reported or
known For large quantities: May cause irritation to the respiratory system. Increased
difficulty in breathing. Sneezing. Coughing

4.3. Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

Section 5: Firefighting measures

5.1. Extinguishing media

Suitable Extinguishing Media Dry chemical, CO2, water spray or regular foam

Unsuitable extinguishing media None

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the Thermal decomposition can lead to release of irritating and toxic gases and vapors
chemical Carbon monoxide , Carbon dioxide (CO2) , Nitrogen oxides (NOx) , Oxides of sulfur

5.3. Advice for firefighters

Special protective equipment for Wear self contained breathing apparatus for fire fighting if necessary.
fire-fighters

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

For non-emergency personnel Avoid contact with skin, eyes or clothing

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions Prevent entry into waterways, sewers, basements or confined areas.

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Revision Date: 06-Aug-2020

Issuing Date: 06-Mar-2017
Product Name: BTD60BK Revision Number: 3
Safety data sheet number: BHK168
_____________________________________________________________________________________________

Environmental precautions Prevent substance entering sewers. Washings must be prevented from entering surface
water drains.

6.3. Methods and material for containment and cleaning up

Methods for containment Absorb with earth, sand or other non-combustible material and transfer to containers for
later disposal.

Methods for cleaning up Wipe up with absorbent towel Wash with water to remove remaining traces of ink.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

Section 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling Avoid contact with skin, eyes or clothing.

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Keep out of the reach of children. Keep cool. Protect from sunlight.

7.3. Specific end use(s)

Specific use(s) Water based ink for inkjet printing machine

Section 8: Exposure controls and personal protection

8.1. Control parameters

Exposure Limits .

Chemical name European Union United Kingdom France Spain Germany

Glycerol - TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 200 mg/m3
56-81-5 STEL: 30 mg/m3
Triethanolamine - - - TWA: 5 mg/m3 -
102-71-6
Chemical name Italy Portugal Netherlands Finland Denmark
Glycerol - TWA: 10 mg/m3 - TWA: 20 mg/m3 -
56-81-5
Triethanolamine - TWA: 5 mg/m3 - TWA: 5 mg/m3 TWA: 0.5 ppm
102-71-6 TWA: 3.1 mg/m3
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Revision Date: 06-Aug-2020

Issuing Date: 06-Mar-2017
Product Name: BTD60BK Revision Number: 3
Safety data sheet number: BHK168
_____________________________________________________________________________________________

Chemical name Austria Switzerland Poland Norway Ireland

Glycerol - TWA: 50 mg/m3 TWA: 10 mg/m3 - TWA: 10 mg/m3
56-81-5 STEL: 100 mg/m3 STEL: 30 mg/m3
Triethanolamine TWA: 0.8 ppm TWA: 5 mg/m3 - TWA: 5 mg/m3 TWA: 5 mg/m3
102-71-6 TWA: 5 mg/m3 STEL: 10 mg/m3 STEL: 10 mg/m3 STEL: 15 mg/m3
STEL 1.6 ppm
STEL 10 mg/m3

Derived No Effect Level (DNEL) No information available.

Predicted No Effect Concentration No information available.

(PNEC)

8.2. Exposure controls

Appropriate engineering controls Good general ventilation should be sufficient under normal use.

Personal protective equipment Not normally required. For use other than in normal operating procedures (such as in the
event of large spill), the following should be applied:

Eye/face protection Safety goggles.

Hand protection Protective gloves.

Skin and body protection Apron, Boots

Respiratory protection Use appropriate respiratory protection.

Environmental exposure controls Avoid release to the environment.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance
Physical state Liquid
Color black
Odor Slight
Odor threshold No information available

Property Values Remarks • Method

pH 7 - 9
Melting point / freezing point < -5 °C
Boiling point / boiling range > 100 °C
Flash point > 93.3 °C Tag Closed Cup, Cleveland Open Cup,
Evaporation rate No data available None known
Flammability (solid, gas) No data available None known,
Flammability Limit in Air None known
Upper flammability limit: No data available
Lower flammability limit: No data available
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Revision Date: 06-Aug-2020

Issuing Date: 06-Mar-2017
Product Name: BTD60BK Revision Number: 3
Safety data sheet number: BHK168
_____________________________________________________________________________________________

Vapor pressure No data available None known

Vapor density No data available None known
Relative density 1.0 - 1.1 (H2O=1)
Water solubility Soluble in water
Solubility(ies) No data available None known
Partition coefficient No data available None known
Autoignition temperature > 400 °C
Decomposition temperature No data available None known
Kinematic viscosity No data available None known
Dynamic viscosity 1 - 5 mPa s
Explosive properties No information available
Oxidizing properties No information available

9.2. Other information

No information available

Section 10: Stability and reactivity

10.1. Reactivity

None.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

None under normal processing.

10.4. Conditions to avoid

Keep away from heat. Keep away from water or moist air.

10.5. Incompatible materials

Acids, Bases, Oxidizing agent, Reducing agent

10.6. Hazardous decomposition products

Carbon monoxide, Carbon dioxide (CO2), Nitrogen oxides (NOx), Oxides of sulfur

Section 11: Toxicological information

11.1. Information on toxicological effects

Product Information

Inhalation No information available

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Revision Date: 06-Aug-2020

Issuing Date: 06-Mar-2017
Product Name: BTD60BK Revision Number: 3
Safety data sheet number: BHK168
_____________________________________________________________________________________________

Eye contact No information available

Skin contact: No information available

Ingestion Acute LD50 > 2000 mg/kg (OECD 420 method)

The following values are calculated based on chapter 3.1 of the GHS document

ATEmix (dermal) 28,600.00 mg/kg

Skin corrosion/irritation Non-irritant (OECD 404 method)

Serious eye damage/eye irritation Non-irritant (OECD 405 method)

Respiratory or skin sensitization Respiratory sensitization : No information available

It is not a skin sensitizer (OECD 406 method)

Germ cell mutagenicity AMES test : Negative (OECD 471 method)

Carcinogenicity Ingredients of this product have not been classified as carcinogens according to IARC
monographs, NTP and OSHA

Reproductive toxicity No information available.

STOT - single exposure No information available.

STOT - repeated exposure No information available

Aspiration hazard No information available.

Potential health effects Eye : May cause slight irritation

Skin : Prolonged exposure may cause skin irritation
Ingestion : Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea
Inhalation : Not an expected route of exposure Over exposure may cause respiratory
irritation.

Section 12: Ecological information

12.1. Toxicity

Ecotoxicity

Contains 0 % of components with unknown hazards to the aquatic environment

Chemical name Algae/aquatic plants Fish Toxicity to Crustacea

microorganisms
Glycerol - 51 - 57: 96 h - 500: 24 h Daphnia magna
Oncorhynchus mykiss mg/L EC50
mL/L LC50 static

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Revision Date: 06-Aug-2020

Issuing Date: 06-Mar-2017
Product Name: BTD60BK Revision Number: 3
Safety data sheet number: BHK168
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Triethylene glycol, 500: 72 h Desmodesmus 2400: 96 h Pimephales - 500: 48 h Daphnia magna

monobutyl ether subspicatus mg/L EC50 promelas mg/L LC50 mg/L EC50
static 2400: 96 h
Pimephales promelas
mg/L LC50 2200 - 4600:
96 h Leuciscus idus mg/L
LC50 static
Triethanolamine 216: 72 h Desmodesmus 10600 - 13000: 96 h - 1386: 24 h Daphnia
subspicatus mg/L EC50 Pimephales promelas magna mg/L EC50
169: 96 h Desmodesmus mg/L LC50 flow-through
subspicatus mg/L EC50 1000: 96 h Pimephales
promelas mg/L LC50
static 450 - 1000: 96 h
Lepomis macrochirus
mg/L LC50 static

12.2. Persistence and degradability

No information available.

12.3. Bioaccumulative potential

There is no data for this product.

Component Information
Chemical name Partition coefficient
Glycerol -1.76
Triethylene glycol, monobutyl ether 0.51
Triethanolamine -2.53
1,2-Benzisothiazolin-3-one 1.3

12.4. Mobility in soil

No information available.

12.5. Results of PBT and vPvB assessment

This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This product contains no substance considered to be very persistent nor very bioaccumulating (vPvB).

12.6. Other adverse effects

No information available.

Section 13: Disposal considerations

13.1. Waste treatment methods

Dispose in accordance with federal, state and local regulations.

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Revision Date: 06-Aug-2020

Issuing Date: 06-Mar-2017
Product Name: BTD60BK Revision Number: 3
Safety data sheet number: BHK168
_____________________________________________________________________________________________

Section 14: Transport information

IMDG
14.1 UN/ID no Not regulated
14.2 Proper shipping name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing group Not regulated
14.5 Marine pollutant Not applicable
14.6 Special Provisions None
14.7 Transport in bulk according toNot applicable
Annex II of MARPOL 73/78 and the
IBC Code

RID
14.1 UN/ID no Not regulated
14.2 Proper shipping name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing group Not regulated
14.5 Environmental hazard Not applicable
14.6 Special Provisions None

ADR
14.1 UN/ID no Not regulated
14.2 Proper shipping name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing group Not regulated
14.5 Environmental hazard Not applicable
14.6 Special Provisions None

IATA
14.1 UN/ID no Not regulated
14.2 Proper shipping name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing group Not regulated
14.5 Environmental hazard Not applicable
14.6 Special Provisions None

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU-Regulations
* Contains no substances listed in REACH Regulation (EC) No.1907/2006 ANNEX XVII.
* Contains no substance listed in REACH Regulation (EC) No.1907/2006 Candidate List for Authorization.
* Contains no substances listed in REACH Regulation (EC) No.1907/2006 ANNEX XIV.

National Regulations
No information available

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Revision Date: 06-Aug-2020

Issuing Date: 06-Mar-2017
Product Name: BTD60BK Revision Number: 3
Safety data sheet number: BHK168
_____________________________________________________________________________________________

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

Section 16: Other information

Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3

H302 - Harmful if swallowed
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H400 - Very toxic to aquatic life

Legend
SVHC: Substances of Very High Concern for Authorization:
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
Ceiling Ceiling Limit Value ** Trade secret

Key literature references and sources for data

No information available

Issuing Date 06-Mar-2017

Revision Note
Importer information has been changed.

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer
The information relates only to this product. It may not be valid, if used in combination with any other materials or in any
other process, and it is based on our best knowledge as of the date of preparation (revision).

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