NEET SET - A

Prof Santosh Yadav’s

ACE CHEMISTRY PRIVATE TUITIONS
MCQ Test – 87 XI + XII Entire Chemistry
Time: 60 min. STD: XII
Marks: 180 Negative Marking) Date: 19/03/2025

Physical constants: [R = 8.314 JK–1 mol–1 = 0.082 lit-atm K–1 mol–1  2 cal K–1mol–1]
[F = 96500 C, Kf (H2O) = 1.86oC, Kb (H2O) = 0.512o C]
Atomic Mass: H = 1, C = 12, N = 14, O = 16, Na = 23, Cl = 35.5, S = 32, K = 39,
Ca = 40, Ni = 58.5, Cu = 63.5, Zn = 65, Ag = 108]

ALL THE QUESTIONS ARE COMPULSORY. 51] [A] ⎯⎯⎯⎯

Reduction
→ [B] ⎯⎯⎯
HNO2
→ CH3CH2OH
46] 0.05 mol of NaOH is added to 5 litres of The compound [A] is
water. What will be the pH of the solution? 1) CH3CH2CN 2) CH3NO2
1) 12 2)7 3) CH3NC 4) CH3CN
3) 2 4) 10
52] Which belongs to actinide series?
47] Which alkene on ozonolysis gives 1) Ce 2) Cf
CH3CH2CHO and CH3COCH3? 3) Ca 4) Cs
1) CH3CH2CH = C(CH3)2
2) CH3CH2CH = CHCH2CH3 53] Select the rate law that correspond to data
3) CH3CH2CH = CHCH3 shown for the following reaction
4) (CH3)2C = CHCH3 A + B ⎯⎯ → Products
48] Which one of the following can exhibit
cis–trans isomerism? Exp. [A] [B] Initial rate
1 0.012 0.035 0.1
1) CH3 − CHCl − COOH
2 0.024 0.070 0.8
2) H − C  C − Cl 3 0.024 0.035 0.1
3) Cl − CH =CHCl 4 0.012 0.070 0.8
4) ClCH 2 − CH 2Cl 1) rate = k[B]3 2) rate = k[B]4
49] The solubility of a saturated solution of 3) rate = k[A] [B]3 4) rate = k[A]2 [B]2
calcium 54] Which substance is acting as a reduction agent
fluoride is 2  10–4 mol/L. in the reaction?
Its solubility product is 2MnO−4 + 16H + + 10Fe 2+ ⎯⎯
→ 2Mn 2+ + 10Fe3+ + 8H 2O
1) 12  10–2 1) H2O 2) H+
2) 14  10–4 3) Fe2+ 4) MnO2–
3) 22  10–11
4) 32  10–12 55] Among H2O, H2S, H2Se and H2Te the one with
the highest boiling point is
50] How many chain isomers could be obtained 1) H2O, because of hydrogen bonding
from the alkane, C6H14 2) H2Te because of higher molecular mass
1) Four 2) Five 3) H2S because of hydrogen bonding
3) Six 4) Seven 4) H2Se because of lower molecular mass

Ace Chemistry Private Tuitions Prof Santosh Yadav

 NEET SET - A
56] Match List-I with List-II together to give diethyl ether. A, B and C are in
List-I List-II the order of _____.
(A) Glucose + HI (p) Gluconic acid 1) C2H5OH, C2H6, C2H5Cl
(B) Glucose + Br2 water (q) Glucose 2) C2H5OH, C2H5Cl, C2H5ONa
pentaacetate 3) C5H5Cl, C2H6, C2H5OH
(C) Glucose + acetic (r) Saccharic acid 4) C2H5OH, C2H5ONa, C2H5Cl
anhydride
(D) Glucose + HNO3 (s) Hexane 61] Given that
Choose the CORRECT answer from the C(s) + O2(g) ⎯⎯
→ CO2(g) , Ho = −x kJ
options given below:
1) (A) - (s), (B) - (p), (C) - (q), (D) - (r)
2CO(g) + O2(g) ⎯⎯
→ 2CO2(g) , Ho = −y kJ
2) (A) - (s), (B) - (r), (C) - (q), (D) - (p)
3) (A) - (r), (B) - (p), (C) - (s), (D) - (q) The enthalpy of formation of carbon monoxide
4) (A) - (p), (B) –(r), (C) – (s), (D) - (q) will be
1) y – 2x 2) 2x – y
57] The CORRECT configuration of f-block y − 2x 2x − y
3) 4)
element is 2 2
1) (n − 2) f 1−14 (n − 1)d 0−1 ns2 62] The increasing order of atomic radii of the
2) (n − 1) f 1−14 (n − 1)d 0−1 ns2 following group 13 elements is
1) Al > Ga > In > Tl
3) (n − 3) f 1−14 (n − 2)d 0−1 (n − 1) ns 2 2) Ga < Al < In < Tl
4) (n − 2) f 0−1 (n − 1)d 0−1 ns 2 3) Al < In < Ga < Tl
4) Al < Ga < Tl < In
58] Which one of the following statement is
FALSE ? 63] The coordination number and oxidation state
1) The correct order of osmotic pressure for of Cr in K3[Cr(C2O4)3] are respectively
0.01 M aqueous solution of each 1) 3 and + 3 2) 3 and 0
compound is 3) 6 and + 3 4) 4 and + 2
BaCl2 > KCl > CH3COOH > Sucrose.
2) The osmotic pressure () of a solution is 64] How many among the following are p-block
elements? Xe, Sr, Sn, Be, Te, Ga, Cs, Bi.
given by the equation  = MRT where M
1) 2 2) 3
is the molarity of the solution
3) 4 4) 5
3) Raoult’s law states that the vapour
pressure of a component over a solution is 65] Benzoic acid gives benzene on being heated
proportional to its mole fraction. with ‘X’ and phenol gives benzene on being
4) Two sucrose solutions of same molality heated with ‘Y’. Therefore, ‘X’ and ‘Y’ are
prepared in different solvents will have the respectively
same freezing point depression. 1) sodalime and copper
2) Zn dust and NaOH
59] Chemical formula for iron (III) 3) Zn dust and sodalime
hexacyanoferrate (II) is 4) sodalime and zinc dust
1) Fe[Fe(CN)6]
2) Fe3[Fe(CN)6] 66] Wurtz-Fitting reaction uses the reactants
3) Fe3[Fe(CN)6]4 in dry ether solution.
4) Fe4[Fe(CN)6]3 1) alkyl halide + sodium metal
2) aryl halide + alkyl halide + sodium metal
60] The compound A on treatment with Na gives 3) aryl halide + sodium metal
B, and with PCl5 gives C. B and C react 4) aryl halide + alkyl halide

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 NEET SET - A
67] Which of the following possess a sp-carbon in 1) 1/10 2) 1/8
its structure? 3) 8 4) 16
1) CH 2 = CCl − CH = CH 2
73] According to MOT, the species O +2 possesses
2) CCl2 = CCl2
1) bond order of 2.5
3) CH 2 = C = CH 2
2) three unpaired electrons
4) CH 2 = CH − CH = CH 2 3) diamagnetic character
4) stability lower than O2
68] In sodium fusion test of organic compounds,
74] The element with the atomic number 118, will
the nitrogen of the organic compound is
be
converted into
1) alkali 2) noble gas
1) sodamide 2) sodium cyanide
3) lanthanide 4) transition element
3) sodium nitrite 4) sodium nitrate
75] The offensive smell produced in carbylamine
69] Which of the following reagent is used for the reaction is due to the formation of
separation of acetaldehyde from acetophenone? 1) nitrile 2) chloro compound
1) NH2OH 2) NaOI 3) nitrosoamine 4) isocyanide.
3) Tollen’s reagent 4) C6H5NHNH2
70] Among the given pairs, in which pair second 76] Liquid benzene (C6H6) burns in oxygen
compound is more acidic than first? according to the equation
1) BrCH2NO2 and CH3CH3 2C6H6(l) + 15O2(g) ⎯⎯ → 12CO2(g) + 6H2O(g)
O O How many litres of O2 at STP are needed to
2) complete the combustion of 39 g of liquid
CH 3 − CCH 2CN and CH 3 − C− CH 3 benzene? (Mol mass. of O2 = 32, C6H6 = 78)
OH OH 1) 74 L 2) 11.2 L
3) 22.4 L 4) 84 L
3) & 77] The rate constants for forward and backward
reaction of hydrolysis of ester are 1.1  10–2
CH 3 − C = O and 1.5  10–3 per minute. Equilibrium
OH OH constant
for the reaction
& CH3COOC2H5 + H+ CH3COOH +
4) C2H5OH is
1) 4.33 2) 5.33
CH 3 3) 6.33 4) 7.33
71] The CORRECT order of strengths of the
78] During preparation of Mohr's salt equimolar
carboxylic acids is _______.
mixture of ____ is dissolved in water. Which
one of the following should be filled in blank?
1) FeSO4 + (NH4)2SO4
2) FeSO4.6H2O + Al2 (SO4)3
1) II > I > III 2) I > II > III 3) FeSO4 + (NH4) HSO4
3) II > III > I 4) III > II > I 4) Fe2(SO)3 + (NH4)2SO4

72] The rate of a gaseous reaction is given by the 79] Which of the following is a basic amino acid?
expression k[A][B]. If the volume of the 1) Alanine 2) Tyrosine
reaction vessel is suddenly reduced to 1/4th of 3) Lysine 4) Serine
the initial volume, the reaction rate
relating to original rate will be
Ace Chemistry Private Tuitions Prof Santosh Yadav
 NEET SET - A
80] Consider the following compounds − +
3) C H 2 = CH − CH = O
− +
4) C H 2 = CH − C H = O

84] Cyclic hydrocarbon ‘A’ has all the carbon

and hydrogen atoms in a single plane. All the
Hyperconjugation occurs in: carbon-carbon bonds have the same length,
1) II only 2) III only 0 0
3) I and III 4) I only less than 1.54 A , but more than 1.34 A . The
C−C−C bond angle will be
81] Cu2+ + 2e–  Cu; log [Cu2+] v/s. Ered graph is 1) 10928 2) 100
of the type as shown in figure where OA = 3) 180 4) 120
0.34 V. Then electrode potential of the half
cell of 85] An organic compound ‘A’ on reduction gives
Cu | Cu 2+ (0.1M) will be compound ‘B’ which on reaction with
chloroform and potassium hydroxide forms
A ‘C’. The compound C on catalytic reduction
E red
gives N-methylaniline. The compound, ‘A’ is
1) nitrobenzene
O 2) nitromethane
log [Cu 2+ ]
3) methylamine
0.0591
1) −0.34 + V 4) aniline
2
2) 0.34 + 0.0591 V 86] A 5A current is passed through a solution of
3) 0.34 V zinc sulphate for 40 mins. The amount of zinc
4) 0.34 – 0.0591 V deposited at the cathode is
1) 40.65 g 2) 0.4065 g
82] The correct decreasing order of energy for the 3) 4.065 g 4) 65.04 g
orbitals having, following set of quantum
number. 87] Match Column- I with Column-II.
(A) n = 3, l = 0, m = 0 (B) n = 4, l = 0, m = 0 Column -I Column- II
−
(C) n = 3, l = 1, m = 0 (D) n = 3, l = 2, m = 1 (A) ArN C l ⎯⎯
+
2 → ArOH (p) HBF4 / NaNO2
1) (D) > (B) > (C) > (A) (B) ArN +2 C l − ⎯⎯
→ ArNO 2 (q) H2O
2) (B) > (D) > (C) > (A)
(C) ArN +2 C l − ⎯⎯
→ ArH (r) HBF4 /
3) (C) > (B) > (D) > (A)
4) (B) > (C) > (D) > (A) (D) ArN +2 C l − ⎯⎯
→ ArF (s) CH3CH2OH
1) A-(q), B-(p), C-(s), D-(r)
83] Polarisation of electrons in acrolein may be 2) A-(s), B-(p), C-(q), D-(r)
written as 3) A-(q), B-(s), C-(p), D-(r)
+ −
1) C H 2 = CH − CH = O 4) A-(q), B-(s), C-(r), D-(p)
+ −
2) C H 2 − C H − CH = O

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 NEET SET - A
88] An electrochemical cell is shown below 90] The indicator used in the titration of acetic acid
Pt, H2 (1atm)  HCl (0.1 M)  CH3COOH with sodium hydroxide for quantitative
estimation is
(0.1 M)  H2 (1 atm), Pt.
1) phenolphthalein
The emf of the cell will NOT be zero, because 2) methyl orange
1) emf depends on molarities of acids used 3) methyl red
2) pH of 0.1 M HCl and 0.1 M CH3COOH is 4) a mixture of methyl red and methyl orange.
not same
3) the temperature is constant
4) acids used in two compartments are different

89] The Cl −C−Cl angle in

1, 1, 2, 2-tetrachloroethene and
tetrachloromethane will be about
1) 120 and 10928 2) 90 and 109.5
3) 109.5 and 90 4) 109.5 and 120

TYPES OF MISTAKES
1. Factual Mistake No of Q Standard fact given in NCERT Textbook in Q. No
Sentences, Table, Graphs.
2. Analysis Mistake Not a standard fact, but analysis of the concept
(Conceptual Mistake)
3. Marking Mistake Marked wrongly in Answer copy. CORRECT
on Question paper.
4. Reading Mistake Question wrongly read or read in hurry,
important key word missed.
5. Time deficient Mistake No time available to read the question.
6. Formula Mistake Formula forgotten
7. Numerical approach Formula known. Not able to use it properly.
8. Calculation Mistake –

Ace Chemistry Private Tuitions Prof Santosh Yadav