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Exemple_6

The document presents data on two constituents, A and B, including their properties such as vapor pressure and activity coefficients at various temperatures and compositions. It includes calculations for partial pressures and activity coefficients using the provided formulas. Additionally, it features graphical representations of the relationship between temperature, composition, and activity coefficients.

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omarstudent203
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12 views7 pages

Exemple_6

The document presents data on two constituents, A and B, including their properties such as vapor pressure and activity coefficients at various temperatures and compositions. It includes calculations for partial pressures and activity coefficients using the provided formulas. Additionally, it features graphical representations of the relationship between temperature, composition, and activity coefficients.

Uploaded by

omarstudent203
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
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Constiuant_1 Constituant_2

A 8.07131 8.021
B 1730.63 1936.01
C 233.426 258.431

P (mmHg) 760

x T (°C) Pvap_1 Pvap_2 log10(Gam_1)


0 118.21 1411.47 760.00 0.5203

0.1 106.79 964.74 524.85 0.46991843


0.2 100.78 781.49 427.89 0.41660454
0.3 97.33 690.08 379.36 0.36041468
0.4 95.37 642.26 353.93 0.3015956
0.5 94.36 618.71 341.38 0.2407207
0.6 93.94 609.30 336.36 0.17892389
0.7 93.85 607.09 335.19 0.11831018
0.8 93.86 607.33 335.31 0.0626979
0.9 94.26 616.61 340.26 0.01901004
1 100.00 760.00 416.49 0

x 0 0.1 0.2 0.3


y 0 0.3746 0.5367 0.6246
T (°C) 118.21 106.79 100.78 97.33

118.00

113.00

108.00

103.00

98.00

93.00
0 0.2 0.4 0.6 0.8 1 1.2
98.00

93.00
0 0.2 0.4 0.6 0.8 1 1.2
Coef_Activité
A12 0.5203
A21 1.1066

𝑷_𝒄𝒂𝒍=𝒙_𝟏 𝜸_𝟏 𝑷_(𝒗𝒂𝒑−𝟏)+ 𝒙_𝟐 𝜸_𝟐 𝑷_(𝒗𝒂𝒑−𝟐)

log10(Gam_2) Gam_1 Gam_2 Pcal


0 3.314 1.000 760.00

0.00272772520618 2.951 1.006 760.00


0.01224241711013 2.610 1.029 760.00
0.03112519397628 2.293 1.074 760.00
0.06302395408322 2.003 1.156 760.00
0.11318180074343 1.741 1.298 760.00
0.18928405041523 1.510 1.546 760.00
0.30285785075539 1.313 2.008 760.00
0.47166773382181 1.155 2.963 760.00
0.72398776379898 1.045 5.296 760.00
1.1066 1.000 12.782 760.00

0.4 0.5 0.6 0.7


0.6769 0.7085 0.7263 0.7343
95.37 94.36 93.94 93.85

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

1 1.2 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.2

0.1

1 1.2 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
𝜸_𝟐 𝑷_(𝒗𝒂𝒑−𝟐)

〖𝒍𝒐𝒈〗 _𝟏𝟎⁡〖𝜸 _𝟏 〗 = 𝑨_𝟏𝟐 ((𝑨_𝟐𝟏


𝒙_𝟐)/(𝑨_𝟏𝟐 𝒙_𝟏 + 𝑨_𝟐𝟏 𝒙_𝟐 ))^𝟐
y
0.0000

0.3746

〖𝒍𝒐𝒈〗 _𝟏𝟎⁡〖𝜸 _𝟐 〗 = 𝑨_𝟐𝟏 ((𝑨_𝟏𝟐


0.5367
0.6246

𝒙_𝟏)/(𝑨_𝟏𝟐 𝒙_𝟏 + 𝑨_𝟐𝟏 𝒙_𝟐 ))^𝟐


0.6769
0.7085
0.7263
0.7343
0.7386
0.7629
1.0000

0.8 0.9 1
0.7386 0.7629 1
93.86 94.26 100.00

.7 0.8 0.9 1
.7 0.8 0.9 1
_𝟏𝟐 ((𝑨_𝟐𝟏
𝟐𝟏 𝒙_𝟐 ))^𝟐

_𝟐𝟏 ((𝑨_𝟏𝟐
𝟐𝟏 𝒙_𝟐 ))^𝟐

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