Lecture Notes
Lecture Notes
SCIENCE
Formation of Elements
Found in the Universe
The Universe and the Solar
System
•With regards to the formation of
the universe, science already
has an existing theory for that.
BIG BANG THEORY
•In 1929,
astronomers
Edwin Hubble
proved that the
“nebulae” were
distant galaxies.
• Hubble deduced that galaxies
have been moving away from
one another since the big bang.
• This shows that the universe is
expanding.
GEORGE GAMOW
1. Scandium
2. V
3. 26
4. Cu
5. Co
6. 37
7. K
8. P
9. Si
10. Y
Drill no.2
Elements
Symbol Name Atomic no. (Z)
1. Sc Scandium 21
2. V Vanadium 23
3. Fe Iron 26
4. Cu Copper 29
5. Co Cobalt 27
6. Rb Rubidium 37
7. K Potassium 19
8. P Phosphorus 15
9. Si Silicon 14
10. Y Yttrium 39
The idea of the
Atom
Models of the Atom
a Historical Perspective
Early Greek Philosophers Theories
water
Democritus
Atomos
=
atom
Alchemy
•A pseudoscience
•Some alchemists
were mystics and
some were serious
scientists
•Discovered several
elements
John Dalton
• 1800 –Dalton put together many observations
and results of several experiments and
formulated the “ Atomic Theory”.
• All matter is made of atoms.
• Atoms of an element are
identical/alike.
• Atoms are rearranged in reactions.
• Atoms of different elements combine
in constant ratios to form compounds
John Dalton
• All matter is made of atoms.
• Atoms of an element are identical.
• Atoms of different elements combine
in constant ratios to form compounds.
• Atoms are rearranged in reactions.
2. Conservation of mass
One view of atomic structure in early 20th century was that an electron (e-)
traveled about the nucleus in an orbit.
Atomic Spectra and Bohr
1. Louie de Broglie
2. Erwin Schrodinger
3. Werner Karl Heisenberg
Heisenberg Uncertainty
Principle
16
E.g. Oxygen: 8 O
• These values are given on the periodic table.
• For now, round the mass # to a whole number.
• These numbers tell you a lot about atoms.
# of protons = # of electrons = atomic number
# of neutrons = mass number – atomic number
• Calculate # of e–, n0, p+ for Ca, Ar, and Br.
Atomic Mass p+ n0 e–
Ca 20 40 20 20 20
Ar 18 40 18 22 18
Br 35 80 35 45 35
Ions
• The atomic number, or the number of protons,
distinguishes one element from others.
3 4 5 6 7 8 9 10
2 Li Be B C N O F Ne
10.811 12.001 14.007 15.999 18.998 20.180
6.941 9.012
11 12 13 14 15 16 17 18
3 Na Mg 3 4 5 6 7 8 9 10 11 12 Al Si P S Cl Ar How many
periods
22.990 24.305 26.982 28.086 30.974 32.066 35.453 39.948
4 19
K
20
Ca
21
Sc
22
Ti
23
V
24
Cr
25
Mn
26
Fe
27
Co
28
Ni
29
Cu
30
Zn
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr (rows)
are on the
44.956 54.938
39.098 40.078 47.87 50.942 51.996 55.845 58.933 58.69 63.546 65.39 69.723 72.61 74.922 78.96 79.904 83.80
5
37 38 39 40 41 42 43 45 46 47 48 49 50 51 52 53 54
Periodic
44
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Table
85.468 87.62
88.906
91.224 92.906 95.94 (98) 102.906 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29
101.07
6 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Of
Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.905 137.327 174.967
178.49 180.95 183.84 186.207 190.23 192.217 195.078 196.967 200.59 204.383 207.2 208.980 (209) (210) (222) Elements?
7 87 88 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
Fr Ra Lr Rf Db Sg Bh Hs Mt Ds Rg Uub
(285)
Uut Uuq Uup Uuh
(292)
Uus Uuo
(262) (284) (289) (288)
(261) (262) (266) (264) (269) (268) (269) (272)
(223) (226)
57 58 59 60 61 62 63 64 65 66 67 68 69 70
Lanthanides La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
144.24 150.36 168.934
138.906 140.116 140.908 (145) 151.964 157.25 158.925 162.50 164.930 167.26 173.04
3 4 Periodic Table 5 6 7 8 9 10
2 Li Be Of Elements? B C N O F Ne
10.811 12.001 14.007 15.999 18.998 20.180
6.941 9.012
11 12 13 14 15 16 17 18
3 Na Mg 3 4 5 6 7 8 9 10 11 12 Al Si P S Cl Ar
22.990 24.305 26.982 28.086 30.974 32.066 35.453 39.948
4 19
K
20
Ca
21
Sc
22
Ti
23
V
24
Cr
25
Mn
26
Fe
27
Co
28
Ni
29
Cu
30
Zn
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
44.956 54.938
39.098 40.078 47.87 50.942 51.996 55.845 58.933 58.69 63.546 65.39 69.723 72.61 74.922 78.96 79.904 83.80
5
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.468 87.62
88.906
91.224 92.906 95.94 (98) 102.906 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29
101.07
6 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.905 137.327 174.967 180.95 186.207 192.217 195.078 196.967 204.383 208.980
178.49 183.84 190.23 200.59 207.2 (209) (210) (222)
7 87 88 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
Fr Ra Lr Rf Db Sg Bh Hs Mt Ds Rg Uub
(285)
Uut Uuq Uup Uuh
(292)
Uus Uuo
(262) (284) (289) (288)
(261) (262) (266) (264) (269) (268) (269) (272)
(223) (226)
57 58 59 60 61 62 63 64 65 66 67 68 69 70
Lanthanides La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
144.24 150.36 168.934
138.906 140.116 140.908 (145) 151.964 157.25 158.925 162.50 164.930 167.26 173.04
1 Transition Metals 18
1 2
1 H 2 13 14 15 16 17 He
1.008 4.003
3 4 5 6 7 8 9 10
2 Li Be B C N O F Ne
10.811 12.001 14.007 15.999 18.998 20.180
6.941 9.012
11 12 13 14 15 16 17 18
3 Na Mg 3 4 5 6 7 8 9 10 11 12 Al Si P S Cl Ar
22.990 24.305 26.982 28.086 30.974 32.066 35.453 39.948
4 19
K
20
Ca
21
Sc
22
Ti
23
V
24
Cr
25
Mn
26
Fe
27
Co
28
Ni
29
Cu
30
Zn
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
44.956 54.938
39.098 40.078 47.87 50.942 51.996 55.845 58.933 58.69 63.546 65.39 69.723 72.61 74.922 78.96 79.904 83.80
5
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.468 87.62
88.906
91.224 92.906 95.94 (98) 102.906 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29
101.07
6 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.905 137.327 174.967 180.95 186.207 192.217 195.078 196.967 204.383 208.980
178.49 183.84 190.23 200.59 207.2 (209) (210) (222)
7 87 88 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
Fr Ra Lr Rf Db Sg Bh Hs Mt Ds Rg Uub
(285)
Uut Uuq Uup Uuh
(292)
Uus Uuo
(262) (284) (289) (288)
(261) (262) (266) (264) (269) (268) (269) (272)
(223) (226)
57 58 59 60 61 62 63 64 65 66 67 68 69 70
Lanthanides La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
144.24 150.36 168.934
138.906 140.116 140.908 (145) 151.964 157.25 158.925 162.50 164.930 167.26 173.04
1 Using this
Classas a guide,
Color color 18
1 code your periodic table to
Metal
2
1 H 2 show the three classes. Start
Non-Metal 13 14 15 16 17 He
1.008 4.003
3 4 by highlighting
Metalloid
the “zig-zag.” 5 6 7 8 9 10
2 Li Be B C N O F Ne
10.811 12.001 14.007 15.999 18.998 20.180
6.941 9.012
11 12 13 14 15 16 17 18
3 Na Mg 3 4 5 6 7 8 9 10 11 12 Al Si P S Cl Ar
22.990 24.305 26.982 28.086 30.974 32.066 35.453 39.948
4 19
K
20
Ca
21
Sc
22
Ti
23
V
24
Cr
25
Mn
26
Fe
27
Co
28
Ni
29
Cu
30
Zn
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
44.956 54.938
39.098 40.078 47.87 50.942 51.996 55.845 58.933 58.69 63.546 65.39 69.723 72.61 74.922 78.96 79.904 83.80
5
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.468 87.62
88.906
91.224 92.906 95.94 (98) 102.906 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29
101.07
6 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.905 137.327 174.967 180.95 186.207 192.217 195.078 196.967 204.383 208.980
178.49 183.84 190.23 200.59 207.2 (209) (210) (222)
7 87 88 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
Fr Ra Lr Rf Db Sg Bh Hs Mt Ds Rg Uub
(285)
Uut Uuq Uup Uuh
(292)
Uus Uuo
(262) (284) (289) (288)
(261) (262) (266) (264) (269) (268) (269) (272)
(223) (226)
57 58 59 60 61 62 63 64 65 66 67 68 69 70
Lanthanides La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
144.24 150.36 168.934
138.906 140.116 140.908 (145) 151.964 157.25 158.925 162.50 164.930 167.26 173.04
Location
• Found on the left of the 79
Au
zigzag line/staircase on 196.967
Physical Properties
• ductile, good conductors,
malleable, shiny, most are Image taken from:
http://chemistry.about.com/od/periodictableelements/ig/E
solid @ room lement-Photo-Gallery.--98/Sodium.htm
temperature
What
@ room
metal
temperature?
is not a solid
-
Notice: only 1 Na
electron in outer
22.990
level
+ -
-
+ + -
- -
+
- -
+++
-
++ +
-
+ + -
4
++ +
Be
9.012 Notice: only
2 electrons -
in outer level - -
-
Non-Metals
Location
• Most found to the right of
the zigzag line/staircase on
the periodic table 17
Cl
Chemical Properties
35.453
Physical Properties
• not ductile or malleable, not
shiny, poor conductors, most
16
S
are solid, but some are gas
32.066
- - O
Notice: 2
15.999 -
electrons in
-
+
outer level – + -
++ +
- + + + - FULL
+ +
- 2
-
He
- 4.003
- - -
-
Notice: 6
electrons in +++
outer level – + + +
Notice: 7
-
almost full
++ +
electrons in
- outer level –
9 - -
almost full
F
18.998
-
Metalloids
Location
• Border the zigzag
line/staircase on the 14
periodic table Si
28.086
Chemical Properties
• Most atoms have ½ (≈) Image taken from:
complete set of electrons http://library.thinkquest.org/C0113863/bios.shtml
in outer level
Physical Properties
• have properties of both
metals and non-metals
5
B
10.811
Molecules of compounds
are formed by chemical
bonds.
Polar Covalent Bond
F- fluoride O- oxide
Cl- chloride S- sulfide
Br- bromide N- nitride
I- iodide P- phosphide
H- hydride C- carbide
Practice
Name the following ionic compounds:
• NaO
• CsBr
• K2S
Naming Covalent Compounds
(Non-metals with Non-metals)
•Name the
second
non-metal using •Examples:
the correct CO2
prefix and an
-ide ending Carbon
Dioxide
You try . . .
Cl2O
You try . . .
Cl2O
Dichlorine
monoxide
CO Carbon Monoxide
PCl3 Phosphorus
Trichloride
CI4 Carbon
Tetraiodide
Name the following covalent compounds:
1. H2O
2. NH3
3. SO2
4. CO
5. N2O4
6. SO3
7. P2O5
8. OF2
9. BF6
10.BI3
Name and draw Lewis diagram of the
following compounds:
1. H2O
2. NH3
3. H2Se
4. CS2
5. KCl
Drawing Lewis Structures
Writing Lewis Dot Structures
Lewis Dot Structures
Example:
H has 1 valence electron
F has 8 valence electrons
Carbon has 4 valence electrons
PRACTICE:
What is the Lewis electron dot diagram for
each element?
•Ca
•O
•P
•Cl
•S
•Be
What is the Lewis electron dot diagram for
each element?
1. Rb
2. Mg
3. Kr
4. As
5. Al
6. Sn
7. Br
Drawing Lewis Diagrams for Compounds
1. H2O
2. CO2
3. PCl3
4. CS2
5. KCl
Name then draw the Lewis diagram of
the following compounds:
1. SO2
2. NH3
3. H2Se
4. HF
5. CH4
Formation of Cations
Cl + 1e- → Cl -
What is the Lewis electron dot diagram for each
ion?
• Ca2+
• O2−
Solution
•Having lost its two original valence
electrons, the Lewis electron dot diagram is
just Ca2+.
Ca2+
•The O2− ion has gained two electrons in its
valence shell, so its Lewis electron dot
diagram is as follows:
SUMMARY
• a) CH2ClF b) SO2
Cl
H C F O S O
• c) H SO42- d) H3PO4
O O
O S O H O P O H
O O
H
Molecular Geometry
Molecular Geometry
Intermolecular Forces:
(inter = between) between molecules
and the temperature (kinetic energy) of the molecules.
What determines if a
substance is a solid,
liquid, or gas?
4
0
4
1
Phase changes:
• dispersion forces,
• dipole-dipole interactions,
• hydrogen bonds,
• Ion-dipole interaction
Dipole - Dipole Interactions
Forces that act between polar molecules.
Hydrogen Bonding
Occurs only between molecules that contain
hydrogen.
5
1 Hydrogen bonding is a weak to moderate
attractive force that exists between a hydrogen
atom covalently bonded to a very small and
highly electronegative atom and a lone pair of
electrons on another small, electronegative
atom (F, O, or N).
5
2
Dispersion Forces
2. Ring:
3. Branched Chain:
Macromolecule
Large molecules that make up living things. They are
large chains of smaller molecules. It means “giant
molecule”.
http://t2.gstatic.com/images?q=tbn:55aWKrNBBIHHfM:http://chsweb.lr.k12.nj.us/mstanley/outlines/organicAP/glucose.gif
Monomers
All macro organic molecules are made up of
smaller subunits called monomers. This is just
the base unit that repeats over and again. The
monomers can be identical or different.
Polymers
Organic macromolecules are made up of
repeating monomers.These chains of monomers
are called polymers.
4 Groups of Biological Macromolecules
1. Carbohydrates
2. Proteins
3. Lipids
4. Nucleic Acids
Carbohydrates
*Carbohydrates are composed of C, H, and O.
*Ratio: 1C:2H:1O
*Function:
1. Main source of energy.
2. Plants and some animals use it for
structural purposes.
GLUCOSE!
Fructose
Carbohydrates
Two monomers of monosaccharides together are
called disaccharides. Maltose is a examples of a
disaccharide.
MALTOSE
Carbohydrates
A polysaccharide is a long chain of monosacchrides
Joined together.
Examples of polysacchrides:
1.glycogen:stored energy
2.Starch: plant stored energy
3.Cellulose: cell walls
STARCH!!!
Lipids
DEFINE: Large groups of organic compounds
not soluble in water.
Mostly made up of C and H with very little O.
Functions:
1.Store energy for long term.
2.Waterproof covering
come from the word
“lipos” which means
“greasy”
Non-polar in nature or
insoluble in water.
4 main categories of Lipids
1. Fats
2. Oils
3. Waxes
4. steroids FAT!!!
Lipids
Saturated vs. Unsaturated
Saturated means that all the carbon bonds are taken.
They are solid at room temperature and bad for you.
Unsaturated means that there is at least one double
bond with the carbon. They are liquid at room temp.
and are better for you.
Lipids
All lipids are not soluble in water. That is why
they are placed together.
Trans fat
Valine
proteins in the human diet
proteins in the human diet
Histidine
proteins in the human diet
Isoleucine
Other Examples of Proteins
1. Hemoglobin in blood
2. Collagen
3. Enzymes
4. insulin
Protein Deficiency and
Dietary Imbalance
• fatigue
• insulin resistance
• hair loss
• loss of hair pigment
• loss of muscle mass
• low body temperature
• hormonal irregularities
• loss of skin elasticity
• Kwashiorkor
Excessive Protein Intake
•Liver dysfunction
•Loss of bone density
Proteins and Amino acid formation
Proteins are made up of monomers of amino
acids help together by peptide bonds.
3 parts of an amino acid:
1.Amino group
2.Carboxyl group
3.R group
The R – Group(functional group)
Functional Groups
• Most of the useful behavior of organic
compounds comes from functional groups
attached to the carbons. A functional group is a
special cluster of atoms that performs a useful
function.
Nucleic acid
Example:
Making Orange Juice
What is a Chemical Change?
Example:
Baking a
Cake
5 Signs of a Chemical Change
1. Color Change
2. Precipitation
Precipitation
•Precipitation – the solid that forms from
a solution during a chemical reaction.
3. Gas Production
4. Temperature Change
5 Signs of a Chemical Change
release
input
change in color change in odor production of new input or release difficult to reverse
gases or vapor of energy
Chemical or Physical Change?
•Cutting paper?
•Physical
Chemical or Physical Change?
•Ice melting?
•Physical
Chemical or Physical Change?
•Toast burning?
•Chemical
Chemical or Physical Change?
•Sawing wood?
•Physical
Chemical or Physical Change?
•Metal rusting?
•Chemical
What is a chemical equation?
Reactant Product
Reaction symbol
Subscripts and Coefficients
•2H2 + O2 → 2H2O
Characteristics of Chemical Equations
(g)
Showing Phases in
Chemical Equations
Solid Phase – the substance is relatively rigid and has a definite volume
and shape. NaCl(s)
Liquid Phase – the substance has a definite volume, but is able to change
shape by flowing. H2O(l)
Reactants Product
1 carbon atom 1 carbon atom
2 oxygen atoms 2 oxygen atoms
Balancing Chemical Equations
1 carbon 1 carbon
atom atom
4 hydrogen 2 hydrogen
atoms atoms
A Balanced Equation
⚫ CH4 + 2O2 → CO2 + 2H2O
1 carbon 1 carbon
atom atom
4 hydrogen 4 hydrogen
atoms atoms
Unbalanced and Balanced Equations
Cl Cl H H
Cl H
H Cl Cl Cl
Cl
H
H
H 2 1 H 2 2
Cl 2 1 Cl 2 2
Balancing Chemical Equations
2 Na + H2O → 2 NaOH + H2
Answer:
2 Na + 2 H2O → 2 NaOH + H2