L2
L2
oleophobic oleophilic.
oleophobic impurities include: soluble in crude oil and include:
(insoluble in crude oil) a) Sulphur compounds
a) salts-mainly chlorides and sulphates of b) Organometallic compounds
sodium, calcium and magnesium. containing Ni,V,Fe,As,etc
b) sediments-such as silt, sand drilling mud, iron c) Naphthenic acids
oxide, iron sulphide,etc. d) Nitrogen compounds
c) water-presents as soluble, emulsified and /or
finely dispersed water.
these impurities must be removed to avoid problems in subsequent processing operations. several
problems which can be caused by oleophobic impurities include:
1) corrosion in the atmospheric distillation overhead system caused by HCL, which is liberated due to
hydrolysis/ dissociation of chloride salts.
2) erosion of crude oil pumps, pipelines and valves by suspended matter.
3) plugging of equipment and fouling of heat-transfer surfaces
4) product degradation, like high ash content in fuel oil
Asaad Salim.
Degassing Process:
Two – Phase Gas – Oil Separation:
High pressure crude oils containing large amount of free dissolved gas flow from the wellhead into the flow
line, which routes the mixture to the(GOSP).
This is usually done by admitting the well fluid into a gas – oil separator plant (GOSP) through which the
pressure of the gas – oil mixture is successively reduced to atmospheric pressure in a few stages.
In the separator, crude oil separates out, settles, and collects in the lower part of the vessel. Gas goes out the
top of the separators to a gas collection system, a vapor recovery unit (VRU), or a gas flow line.
Crude oil, on the other hand, goes out the bottom and is routed to other stages of separation, if necessary,
and then to the stock tank Volatile components, either sent to consumer centers as natural gas or used
repressurize the oilfield.
Desalting is carried out by mixing the crude oil with from 3 to 10 vol% water at temperatures from 200
to 300°F (90 to 150°C). Both the ratio of the water to oil and the temperature of operation are functions
of the density of the oil.