(1001CJA106216240183) Test Pattern

CLASSROOM CONTACT PROGRAMME JEE (Advanced)

FULL SYLLABUS
(Academic Session : 2024 - 2025)
19-03-2025

JEE(Main+Advanced) : LEADER COURSE SPECIAL BATCH (SCORE-II)

ANSWER KEY PAPER (OPTIONAL)
PART-1 : PHYSICS
Q. 1 2 3 4 5 6
SECTION-I
A. D A,B B,C B,D A,C A,C
Q. 1 2 3 4 5 6
SECTION-II
A. 3.33 1.04 to 1.06 1.50 88.00 to 91.00 0.14 to 0.15 2.45 to 2.47
Q. 1 2 3 4 5 6
SECTION-III
A. 4 8 6 7 4 8

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6
SECTION-I
A. A,B,C,D A,B,C B,C,D A,B,C,D A,B,C,D B,D
Q. 1 2 3 4 5 6
SECTION-II
A. 3.00 23.30 99.98 1.25 10.00 2.00
Q. 1 2 3 4 5 6
SECTION-III
A. 5 3 4 5 5 6

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6
SECTION-I
A. A,B A,B,D A,B,C B,C A,C A,C,D
Q. 1 2 3 4 5 6
SECTION-II
A. 6.25 9.00 4.80 3.60 1.41 1.25
Q. 1 2 3 4 5 6
SECTION-III
A. 2 0 4 1 1 5

HINT – SHEET

PART-1 : PHYSICS PART-1 : PHYSICS

SECTION-I SECTION-III

4. Ans ( B,D ) 2. Ans ( 8 )

Spectrum peaks are due to characterstic X-rays,
which depend on target, where as lmin is a property
of accelerating voltage.

g
2g – T = 2a ; T – g = a ⇒ a =
3
The velocity of 1 kg at the instant of 2 kg falling
down a height h is
1001CJA106216240183 HS-1/6
 Target : JEE(Main + Advanced) 2025/19-03-2025

v20 = 0 + 2ah or v0 = √
2gh
↑ PART-2 : CHEMISTRY
3
From this moment, 1 kg moves upward as a free SECTION-II
body till its speed becomes zero and then comes 2. Ans ( 23.30 )
down. The string is not in taut condition during the P4 + 8SOCl2 → 4P Cl3 + 2S2 Cl2 + 4SO2 (A)
speed changes from v0 to zero and from zero to v0. 0.1 0.6 − 0.3

Hence 0 = v0 – gt or t = v0
−1
2MnO4 + 5SO2 + 2H2 O → 2Mn + 5SO4 2− + 4H +2+

g 0.2 0.3 − 0.3

String is not taut during Δ t = 2t SO4 2−

+ Ba 2+
→ BaSO4
0.3 0.3
2v0 2h √ 8h √ nh
= = 2√ = =
g 3g 3g 3g ⇒ x = 0.3 × [137 + 32 + 64] = 69.9g
∴n=8
3. Ans ( 99.98 )
PART-2 : CHEMISTRY
[Ag+] for pptn of I – =
SECTION-I

2. Ans ( A,B,C ) ksp (AgI)

[I − ]
=
10−17
0.1
= 10−−16 M
pH = 3 ⇒ [H+] = 10 – 3 M
let the degree of dissociation be α [Ag+] for pptn of Br – =
10−3
⇒α= = 0.1 ⇒ % α = 10 ksp (AgBr) 10−13 1
0.01 = = × 10−12 M
⇒ π (osmotic pressure) = (1.1) (0.01)RT = 0.011 RT [Br− ] 0.2 2
⇒ i = 1 + (h − 1)α = 1.1
⇒ [I – ] when AgBr starts precipitating =
HA = H+ + A –
ksp (AgI) 10−17
= × 2 = 2 × 10−5
Kb of at 25°C [Ag + ] 10 −12

5. Ans ( A,B,C,D ) ⇒ % [I – ] remaining in solution =

, , & Will 10−−5

2× × 100 for precipitation of AgBr
0.1

not give SN2 reaction with ⇒ % [I – ] precipitated = 100 – 0.02 = 99.98

phthalimidate ion so (A), (B), (C), (D) can not be
prepared by gabriel phthalimide reaction. 4. Ans ( 1.25 )
6. Ans ( B,D ) T1 V1γ−1 = T2 V2γ−1

T1 = T, T2 = T
2
V1 = V and V = 5.66 V
T
T V γ−1 = (5.66V )γ−1 Pv = nRT
2
γ –1
2 = (5.66)
γ = 1.4
∣ P 2 V2 − P 1 V1 ∣ nRT 1
|w| = ∣ ∣ = = P V = 1.25P V
∣ γ−1 ∣ 2(γ − 1) 0.8

HS-2/6 1001CJA106216240183
 Leader Course/Special Batch(Score-II)/19-03-2025
5. Ans ( 10.00 ) 5. Ans ( 5 )
(i), (iii), (iv), (vi), (vii) statements are correct.

PART-3 : MATHEMATICS
SECTION-I

1. Ans ( A,B )
f(n + 2) – f(n + 1) = (n + 2)!

= (n + 2) [f(n + 1) – f(x)]

f(n + 2) = (n + 3) f(n +1) – (n + 2) f(n)

f(n) = n + 3, h(n) = – (n + 2)
6. Ans ( 2.00 )
2. Ans ( A,B,D )
n+xn
1 1
(1 + ) = e ⇒ x + xn =
n ln(1 + 1
)
n

1
xn = − x, Let n + 1 =u
ln(1 + 1
)
n
n

1 1 1
xn = lim ( − ) =
u→1 ℓnu u − 1 2

1
f(x) = ∑ x2r + ∑ + 2n
x2r
1
x2 (1 − x2n ) 1 1− x2n
= + + 2n
1 − x2 1
x2 1 −
x2
PART-2 : CHEMISTRY
1
SECTION-III (f(x) − 2n) (1 − x2 ) = (1 − x2n ) (x2 + )
x2n
1. Ans ( 5 )
HA + NaOH → NaA lim(f(n) − 2n)x−2n−2 (1 − x2 ) for x ≠ ±1
g(n) = n→∞
Moles = 50 × 10 – 1 × 10 – 3 ⎧ −1 IF |x| > 1
⎪
⎪
NaA + HCl → HA + NaCl ⎪
⎪
⎪

= ⎨ −∞ IF |x| < 1
5 × 10 – 3 25 × 10 – 1 × 10 – 3 ⎪
⎪
⎪
⎪
⎩
⎪

moles 2 HA = 2.5 × 10 – 3 0 If x= ±1

moles 2 NaA = 2.5 × 10 – 3 has non removable infintie type discontinuity at

[salt]
P H = P ka + log
[Acid]
x = ±1
⇒ PH = pka = 5

1001CJA106216240183 HS-3/6
 Target : JEE(Main + Advanced) 2025/19-03-2025
3. Ans ( A,B,C ) 5. Ans ( A,C )
n
∫ cos2n+1 xdx = ∫ (1 − sin2 x) . cos xdx logx < 0 on (0, 1) and > 0 for x > 1 for x > 32,
1
n
C0 cos x − n C1 sin2 x cos x+. . .) dx
log n > 1 (Rejected)
=∫ ( 5 2
1 2
sin x n sin3 x n sin5 x sin5 π x = 0 at x = 0, , ,...
= − C1 . + C2 . ...... 5 5
1 3 5
for n < 1, logx lies in ( – 1, 0) in the interval
a1 + a2 + a3 +. . . . . = 1 + 3 + 5+. . . . +2n + 1
1 2 3 4
( , ),( , )
5 5 5 5
= (n + 1)2 ⇒ λ = 1
1 < x < 32, LHS lies in (0, 1) in interval
dx x3 + 1 − x3
∫ =∫ dx
(x3 + 1)2 (x3 + 1) 6 7 8 9 158 159
x ∈ ( , ),( , )...( , )
5 5 5 5 5 5
dx −x. x2
=∫ +∫ dx
x3 + 1 (x3 + 1) Hence equation has roots
dx 1 3x2 1 2 3 4
= ∫ − ∫ x. dx x = 1, two roots each in , ) , ( , ) two
3
x +1 3 (x3 + 1) (
5 5 4 5
dx 1 −1 −1 6 7 8 9 158 159
=∫ − [x. −∫ dx] each in ( , ),( , )....( , )
x3 +1 3 3
x +1 3
x +1 5 5 5 5 5 5

2 dx 1 x 2 1 total = 159
= ∫ + A= ,B =
3 x3 +1 3 x3 + 1 3 3

4. Ans ( B,C ) 6. Ans ( A,C,D )

4 25
2023
1 1 1 1 1
Domain of f(x) is [ , ) integers 2, 3, 4, 5, 6
∑ f (r) = 1 + (1 + ) + (1 + + ) +. . . (1 + +. . . ) 3 4
r=1
2 2 3 2 2023
x−1 y+2 z−4
1 1 1
Line L = = = = r (let) at xy
= 2023 × 1 + 2022 × + 2021 × +.....+ 2 3 6
2 3 2023 −2
plane, z = 0 r=
1 1 1
3
= 2023 × 1 + (2023 − 1) + (2023 − 2) +. . . (2023 − 2022)
2 3 2023 1 7 7
A (− , −4, 0) , B ( 0, − , 1) , C ( , 0, −8)
3 2 3
1 1 1 1 2 2022
= 2023 (1 + + +. . . ) − ( + +. . . )
2 3 2023 2 3 2023 1 ¯¯ ¯ ¯ 28
V = [abc] =
6 9
1 1 1
= 2023f (2023) − [1 − + 1 − +. . .1 − ]
2 3 2023 ∑∑ Δi Δj = Δ1 (h2 + h3 + h4)+..... min value
1 1 1
= 2023f (2023) − [2022] + ( + +. . . . )
2 3 2023 = 12. Δ .h (AM ⩾ GM)

= 2023 f(2023) – 2022 + f(2023) – 1 = = 12 × 3. 28 = 112 = λ

9

= 2024 f(2023) – 2023

HS-4/6 1001CJA106216240183
 Leader Course/Special Batch(Score-II)/19-03-2025
PART-3 : MATHEMATICS 6. Ans ( 1.25 )
mC n
2 + C2 1
SECTION-II m+n C
⇒ Solving (m - n)2 = m + n
=
2 2
1. Ans ( 6.25 ) Put N = m + n, larger of m, n is N + N
2
√

195 (n + 3)! 195 (n + 3)(n + 2)

an = n
− = − N must be largest square ⩽ 1991 = 442
4 . n! n!(n + 1)! 4n! n!
an > 0 means possible values of m = 990, 946
195
− (n + 3)(n + 2) > 0 ⇒ n = 4
4
also b1 = 1, b2 = 3, b3 = 9, b4 = 3 ..... b13 = 3
b = 25 PART-3 : MATHEMATICS
b 25 SECTION-III
= = 6.25
a 4
1. Ans ( 2 )
2. Ans ( 9.00 ) sin θ + cos θ = csin θ cos θ
(h, k) is mid point of PT then c2sin2 θ cos2 θ = 1 + 2sin θ cos θ
at2 2at + at take sin2 θ = t, c2t2 – 4t – 4 = 0, t ∈ [ – 1 ,1 ]
h= ; k=
2 2
4k2 Hence k = 8
⇒ 2h = a.
⇒ 2y2 = 9ax
9a2
2. Ans ( 0 )
7 12
a=2 A2 = [ ] , A2 − 4A + I = 0
y2 = 9x 4 7
4
L.R = 9
a = – 4, b = 1, x3 cos xdx = 0
3. Ans ( 4.80 )
∫

−4
line passes (17, 76) then it will pass (17 - x, 92) a + 4b
=
and 17 − x , 84
( )
4a − b
2 m = 1, n = 4
x 2 2025
3−x=2+ ⇒x= 4 16
2 3
16 [ ] = null matrix
slope = 2 = −24 −1 −4
−3
4. Ans ( 3.60 ) 3. Ans ( 4 )
2
Let n2 = t and make it 4 degree equation in t. 5x2 + 9y2 = 45 a = 3, b = √ 5, c= , end of LR
3
t4 – (84 + x2 + y2 + z2 + w2)t3 +....... = 0 where 5
is ( 2, )
3
t = 4, 16, 36, 64
9
Hence 84 + x2 + y2 + z2 + w2 = 120 tangent 2x + 3y = 9, meets at (
2
, 0) (0,3)
5. Ans ( 1.41 ) area = 1 9
4. . .3 = 27
2 2
6 6 6
10 = 2 .5 x2 y 2 x2 y 2
∑ log(2m .5n ) excluding m = n = 6 Let E2 & E3 2 + 2 = 1, 2 + 2 = 1
a b b c
0 ⩽ m, n 6 ⩽ Required area = πab − πbc
= (7(1 + 2+ ... +6) -6) (log2 + log5)
= 141 b2 = a2 (1 – e2), c2 = b2(1 – e2) ⇒ a – c = ae2
4
Area = πb(a − c) = πabe2 = 9 × =4
9
1001CJA106216240183 HS-5/6
 Target : JEE(Main + Advanced) 2025/19-03-2025
4. Ans ( 1 ) 6. Ans ( 5 )
Differentiable wrt x, and y constant b must be integer, b2 − 24b ⩾ 0, b (b – 24) perfect

f ′ (x + f(y) + xf(y))(1 + f(y)) = f ′ (x) + yf ′ (x)

square b = 0, 24 can work.
now Differentiable wrt y
Now put B = b – 24, b < 24 and put B = – b for b < 0
f ′ (x + f(y) + xf(y))(1 + x)f ′ (y) = 1 + f(x)
(1 + y)f ′ (y) 1 + f(x) If d = GCD (B, B + 24), d must be 1, 2, 3, 4, 6, 8, 12,
= = λ ⇒ λ = ±1
1 + f(y) (1 + x)f ′ (x)
f ′ (x) (B + 24)
1 24 and B/d and are squares.
=± , Integerate f(x) = d
1 + f(x) 1+x
b = 125 x = −25, 30
c(1 + x)±+1 − 1
b = −8 x = −4, 12
put x = y = 0, f(f(0)) = f(0)
b = −3 x = −3, 6
f(0) = c – 1 hence f(c – 1) = c – 1
b = −1 x = −2, 3
c = 0, 1 (taking + sign)
b=0 x=0
where c = 1 (taking – sign) b = 24 x = −12, −12

wherec = 0, f(x) = – 1, when c = 1, f(x) = 1 + x – 1 b = 25 x = −15, −10

=x b = 27 x = −18, −9
1 −x b = 32 x = −24, −8
and f(x) = −1=
1+x 1+x
1 b = 49 x = −42, −7
1 + f(x) =
1+x
1
1 + f(2024) =
2025
Ans = 1
5. Ans ( 1 )
w10 = x120 y120 z120 = w5w3.z120

⇒ w = z60

|w| = |z|60 = 230 = (7 + 1)10

HS-6/6 1001CJA106216240183