at certain constant temperature. When liquid evaporates and vapour goes up and strikes on the wall of the container they have a tendency to condense (i.e. back to liquid form). This process continues and stops at certain stage due to equilibrium it attains (because of the constant temperature). This pressure of vapour at this stage is called vapour pressure. Boiling point • The boiling point of a substance is the temperature at which the vapour pressure of the liquid equals the environmental pressure surrounding the liquid.
• Boiling point depends upon the environmental pressure.
• A liquid in a vacuum environment has lower boiling point
than a liquid in a high atmospheric pressure.
• Boiling point varies from substance to substance.
• For example, boiling point of water is 212°F @ 1bar
atmospheric pressure and boiling point of refrigerant R134a is -15.3°F @ 14.5psi atmospheric pressure. Ex
• 14.7 psi (atm pressure) = kPa
• 420.6 psi (absolute pressure) = psi(g) • 5 pa = N/m2 • 43.5 psi (absolute pressure) = kPa • Absolute Pressure - Atm Pressure = Thermodynamic properties which are relevant to refrigeration and air-conditioning
• Temperature • Pressure • Volume • Density • Specific heat • Enthalpy • Entropy What is Enthalpy and Entropy?