Structure of an Atom
Structure of an Atom
----
6. Bohr's frequency rule: 10. de Broglie equation:
\= 6E _ E 2 - E,
>.. - ~ =.!!.
h h mv p
E = Energy of lo" er energy state p mv - Momentum of particle
£ 2 = Energy of higher energy state 11. Heisenberg' s uncertainty principle:
7. Energy of an electron (E.,) in the nth orbtt of h
~6p, 2' -
hydrogen-like species: 47t
t:.x = Uncertainty m position,
E.,--218x 10
18
(!:J J 6p, = Uncertainty in momentum
h
Z = Atomic number 6x x 6(mv, ) .!: - (·: p = mvx)
4it
2
Radtus of Bohr's orbit (r) = 52.9 x ~ pm h
8. 6xxm x6v, .!:-
z 4it
9. Energy difference for an electronte transition in 12. Maximum number of electrons in each principal
hydrogen atom: shell:
2n2 electrons
Af: = 2.18 x 10-tB [-In/ __n,2
I ] J n = Principal quantum number
13. Maximum number of electrons in each subshell:
nr = n1 = Lower energy level 2(2/ + I) electrons
n, = n2 = Higher energy level I = Azimuthal quantum number
4.2 Atomic number and atomic mass number 4.3 Isotopes, isobars and isotones
I. What is the number of nucleons present in an 1. Which among the following statements is TRUE
atom having 29 electrons and 34 neutrons in it? regarding isobars? [2022)
[2022) (A) These have different atomic numbers.
(A) 29 (B) 05 (B) These have same chemical properties.
(C) 63 (D) 34 (C) These are of same elements.
(D) These occupy same positions in the
2. Match the following pairs. [2022) modem periodic table.
Species Number of electrons 2. Which among the following statements is TRUE
I. o2- a. 18 about isotones? [2022)
II . Li2+ b. 2 (A) These are nuclides having the same number
10 of neutrons but different number of protons
111. He C.
Ca++
and hence different mass numbers.
IV. d.
(B) These occupy same positions in the
(A) i - a, ii - b, iii - d, iv - c
modem periodic table.
(B) i - c, ii - d, iii - b, iv - a
(C) These have same chemical properties.
(C) i - d, ii - a, iii - c, iv - b (D) These have different number of neutrons
(D) i - b, ii - c, iii - a, iv - d and same number of protons.
3. What is the representation of element (X) 3. Which of the following statements is NOT
having mass number 40 containing 22 neutrons? TRUE about isotones? [2023)
[2024) (A) These are the atoms of same elements.
(A) :x (B) :x (C) :x (D) :x (B) These are the atoms having different
number of electrons.
4. What is the representation of an element having (C) These atoms have same number of
mass number of 40 and 21 neutrons in it? [2024J neutrons.
(A) ~x ~x ~x ___
___________
(B):x __________ ____ _
(C) (D) .,:_
(D) These atoms have different mass number.
19
MHT-CET: Chemistry (PSP) C,
4. Which of the following pair of nuclidcs is 1111 5. ·r he wavelength of a i;pcctral line 1)f
~xomplc of isotones'l 120231 4 6 () nm Wh,11 rs the frequcucy of cac ru 1n
•"K PCCtral fin
(A) :;c1, :~c1 (H) 40
11 Ar, 1q 1
IIC 1113 (A) 4.5 x to" llz (B) 6S IC po111
(C) t!C 119
6 • 5 (D) h ' l
3 109 11
( C) x l IJ.,
x z (I>) 5•() y I(I14 If,
s. Identify correct stntcmcnt ,q;ording i!;otopcs
from following. I20241
,,. What is the wavelength for a wave
frequency 50 llz'? h4v 11J'
(A) They have same numher of neutrons.
(A) 1.6 x I({' m 120211
(8) They have different numhcr of protons. (B) 6x 10 2 rn
11
(C) They contnin same number of protons. (C') 6 X 10 m (D) 15xl(,2rn
(D) They ha, e same mass number . 7. All fndia radio broadcasts on a frequency
6. Which of the following statements is correct 1200 kllz Calculate wavclcn,,th 0
regarding isobars? 120241 electromagnetic radiation ° 1202;
(A) These have same number of neutrons. (A) 200 m (B) 225 m I
(B) n,cse arc the atoms of different clements. (C) 250 m (D) 275 m
(C') n,csc h:lvc same atomic number,
8. Which from following coloured light has the
(D) These have different mass number.
lowest energy?
4.4 120231
Drawbacks of Rutherford atomic model (A) Red (8) Violet
1. (C) Yellow (D) Blue
Which of the following statements is NOT
TRUE about Rutherford atomic model? (2023] 9. Calculate the frequency of blue light having
(A) Each atom consists of massive, +vely wavelength 440 nm. f20231
charged centre. 14 14
(A) 6.82 x 10 Hz (B) 7.5 x 10 Hz
(B) The electrons are revolving continuously 14
(C) 4.0 x 10 Hz (D) 5.26 x 10 14 Hz
around the nucleus.
10. Which from following coloured light has the
(C) This model does not describe the
distribution of electrons around the nucleus. highest energy? 120231
(D) This model describes the energies of (A) Red (B) Blue
electrons. (C) Yellow (D) Violet
4.5 Developments leading to the Bohr's atomic 11. Which of the following electromagnetic
model radiations possesses lowest energy? f2023)
(A) Radio waves (B) Microwaves
1. What is wave number of a radiation having
(C) Infrared (D) Ultraviolet
frequency 4 x I 011 kHz? (2021)
2.33 x 106 m-• 12. What is the frequency of red light having wave
(A) (B) 3.33 X 106 m - l
(C) 1.2 x 106 m-• (D) 1.33 X 106 m - l length 750 nm? (20241
14
(A) 3.0xl0 Hz (8) 4.0xl014 Hz
2. The wavelength of blue light is 480 nm. What is 14
(C) 7.5xl0 Hz (D) 9.0,1014 Hz
frequency of this light? [2021)
9
(A) 5.25 x 10 Hz (B) 2.25 x 1014 Hz 13. Calculate wavelength for e!l]ission of a photon
14
(C) 6.25 X 10 Hz (D) 4.8 X 109 Hz having wave number 11516 cm 1• 120241
3. What is the frequency of yellow light having (A) 4.34 x 10-5cm (B) 8.68 x 10 scm
wavelength 580 nm? 12021] (C) 6.42 x 10- 5cm (D) 2.16 x JO 5cm
(A) 193 x 10-9Hz (B) 517 x 10-14 Hz 14. Calculate wavelength for emission of a photon
(C) 5.17 x 1014 Hz (D) 580 x 10-9 Hz having wave number 23032 cm 1• f2024l
4. What is the value of frequency of radiation (A) 2.llx10-5 cm (B) 4.34,10.,cm
when transition occurs between two stationary (C) 6.4tx!0 5
cm (D) 8.54xl0 5 cm
states that differ in energy by AB? (2021)
v= 21t 15. Calculate wavelength of violet light having
(A) (B) v=~
b ~E frequency 7.50 x 1014 Hz. (20241
(C) v=~ (A) 300 nm (B) 400 nm
(D) v=~
b 27t (C) 750 nm (0) 550 nm
20
MHT·CET: Chemistry (PSP) . +
C,
late radius of third 0rb1t of He . 12023 I 26.
15. Calc:u Cnlculntc the wnvenumhc1 or the photon cm·
(A) 52.9 pm (B) I 05.8 pm
· from the orlm· ol· n 2 ton'hcd
during 1ra11sitton
(C) 238.1 pm (D) 423.2 pm in hydrogen atom. fR11 I0%77 cm 1 l2oi 1 1
24. What is the wave number of photon emitted 32. Which of the following equations gives angular
during transition from orbit n = 3 to n = 1 in momentum of an electron in a stationary orbit?
hydrogen atom? [RH = 109677 cm- 1] (2023) [2024, 2023, 20211
(A) 97612 .53 cm- 1 (B) 82257 .75 cm-1 (A) 2n
mvr= -xn
(C) 102822 .18 cm- 1 (D) 105289.92 cm-1 h
25. (B) h
mvr= nx-
Calculate the shortest wavenumber in hydrogen
2n
spectrum ofLyman series. (RH = 109677 cm- 1)
(C) mvh=nx..!...
(A) 12064.5 cm-1 12023) 2n
(B) 82257 .8 cm- I
(C) 6854.8 cm-I (D)
(D) · 4387.l cm- 1 mv= (hxr)
~ n
u
33. Whatisth;;; - ~ -fi - - - . - - - - - -
.
he11um .
ton? ms O rst orbit of monopositive
C,41 • Chapter 4: Structure of Atom
23
MHT CET Ch mlstrv ( !;p)
, th 11\I , p11 IH
0
le 7. Wl111 h of the f o II owin1,c, pt inciplcs decides
•
lhai
I, ~ \\ t\ . I t.rm ittco111modate
r111 w !11111 • , max11nurnI two
40 to k• mn, II\!' ",th 20221
~l(•\;IIOIIS \1/ i'h
I Ol)l)OSIIC flPIIIS!
•
(,t,, 10 ~Js)
'(h (J\) tic Broglie hypothe~tR.
j20241
P,1uli's exclusion p1 mc:1ple .
\I ti 1111 l
(Hl oo' n ,1111 (II)
(C) l lcisc11bcrg unccr tntn.
· typrtnciplt,;
ll}) ' , nm (D) i\ufhnu principle
l I
1f Cllll tOfl
8. Wh ,1 ,s totn I nu mbcr of unpaired
fi electrons
.
1 , h ~ f\ t 111 ,isthlc . h , eel electronic con 1gurat1on of
120241 (llC'it.:lll Ill O scrv ' 12022
(Bl I )m:111 c, (Z 2•1)'l .3 6 (D) 5 I
(A) (HJ (C)
(()) B,111 r
9. Whul is the mnn ber of electrons·r present
. in
4. Qua t m mt'fhnnlcnl modl.'I of ,tom · 11 11, f I oxidation state 1 its atomic
d-subsh~ ~ ' f2022J
tll'l'lll\lI!'> (
l ur, I\ the- S, me orh1111 me
120211
number 1s 24 /
(8) 5
(A) 2
(C} 3 (D) 7
-n:z
(A) 2 (B) 3 (D) E=-R"
(C) 5 (D) 6
25
MHT-CET: Chemistry (PSP)
. orrect statem
0 (A) 4s (8) 3s
31. Which of rhc following is c duality ent of (C) 4p (D) 2p
regarding wa,c Part1clc ? [2024I
clectromagneuc radiation. 35. Identify the orbital having lowest ener
be explained by
(A) Black body rad1auon can following. gy fr~~
\\ a, c nature of light. he (A) 2p (B) 3s 120111
(B) Photoelectnc efficc t cou Id no1 (C) 3d (D) 4p
ex lamed by \\a\e nature o'.hght. .
(Cl \\~en light interacts with matter it 36. Which of the following orbitals is repr
beha-.e~ as an electromagnetic wave. by n = 3 and / = 2? ese~1.,"IJ
(D) \\ hen light propagates, it behaves as a (A) 3s (8) 3p (C) 3d (D) 120241
tream of particles called photons. 3f
37. Identify the orbital having highest energy fr%
t:. h rrect increasing order of energy of following.
32. ldenth) t e co 120241 1
orbitals. (A) 2p (B) 3s 2024
I
(A) 4f <6p< 6d {B) 6p<6 d<4f (C) 3d (D) 4p
(Cl 4f <6d <- 6p (D) 6d<4 f<6p 38. What is the total number of orbitals present
10
33 _ \\ hich from folio,\ ing sets of quantum numbers N shell? l2024]
represents highest energy of an electron? (A) I (B) 4
[2024] (C) 9 (D) 16
(A) (B) (3,2,1,+½) 39. Which of the following species contain
20 electrons? (20241
(A) K+
C') (D) (s,o,o,+½) (C) Mg
(B) Ca
(D) Cl
34. Which of the following orbitals have same value
of (n + /) as that of3d orbital? (2024)
5
~ C and ~Bare isotones.
V =~= 3.0 X 10 8 ms I = 250 m
• (q
r,...._..:: •;- --- -- - - - - - - - -~ - - - - - - A. 1200 kHz x IOOO Hz x ~
I kHz . I Hz