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Aakash RM AIATS 04 - Repeater - V3 - Solutions - 2021 - 22

The document contains the answers and hints for Test - 4 (Code-F) of the All India Aakash Test Series for NEET-2022, conducted on March 6, 2022. It includes a list of answers for 200 questions along with hints and solutions for selected physics problems. The document is structured to assist students in reviewing their performance and understanding key concepts in preparation for the NEET exam.

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0% found this document useful (0 votes)
10 views19 pages

Aakash RM AIATS 04 - Repeater - V3 - Solutions - 2021 - 22

The document contains the answers and hints for Test - 4 (Code-F) of the All India Aakash Test Series for NEET-2022, conducted on March 6, 2022. It includes a list of answers for 200 questions along with hints and solutions for selected physics problems. The document is structured to assist students in reviewing their performance and understanding key concepts in preparation for the NEET exam.

Uploaded by

shitisking
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Test - 4 (Code-F)_(Answers) All India Aakash Test Series for NEET-2022

All India Aakash Test Series for NEET-2022

TEST - 4 (Code-F)
Test Date : 06/03/2022

ANSWERS
1. (4) 41. (3) 81. (3) 121. (1) 161. (1)
2. (3) 42. (4) 82. (4) 122. (3) 162. (4)
3. (2) 43. (3) 83. (3) 123. (1) 163. (4)
4. (2) 44. (3) 84. (4) 124. (3) 164. (3)
5. (3) 45. (4) 85. (3) 125. (3) 165. (2)
6. (4) 46. (3) 86. (3) 126. (4) 166. (2)
7. (2) 47. (2) 87. (1) 127. (1) 167. (3)
8. (4) 48. (4) 88. (3) 128. (2) 168. (2)
9. (3) 49. (3) 89. (2) 129. (4) 169. (4)
10. (4) 50. (1) 90. (2) 130. (2) 170. (1)
11. (4) 51. (1) 91. (3) 131. (2) 171. (4)
12. (2) 52. (2) 92. (3) 132. (3) 172. (4)
13. (2) 53. (2) 93. (2) 133. (3) 173. (3)
14. (4) 54. (2) 94. (3) 134. (1) 174. (1)
15. (3) 55. (3) 95. (4) 135. (2) 175. (2)
16. (3) 56. (3) 96. (3) 136. (4) 176. (3)
17. (4) 57. (3) 97. (3) 137. (3) 177. (2)
18. (4) 58. (3) 98. (1) 138. (4) 178. (4)
19. (3) 59. (4) 99. (4) 139. (3) 179. (1)
20. (2) 60. (2) 100. (2) 140. (2) 180. (3)
21. (2) 61. (3) 101. (3) 141. (4) 181. (2)
22. (4) 62. (1) 102. (1) 142. (2) 182. (2)
23. (1) 63. (4) 103. (3) 143. (4) 183. (4)
24. (4) 64. (2) 104. (4) 144. (3) 184. (3)
25. (2) 65. (2) 105. (4) 145. (4) 185. (2)
26. (2) 66. (1) 106. (2) 146. (1) 186. (3)
27. (3) 67. (2) 107. (1) 147. (1) 187. (1)
28. (3) 68. (3) 108. (4) 148. (3) 188. (1)
29. (2) 69. (4) 109. (4) 149. (1) 189. (2)
30. (3) 70. (4) 110. (1) 150. (4) 190. (4)
31. (1) 71. (4) 111. (1) 151. (4) 191. (3)
32. (1) 72. (3) 112. (4) 152. (1) 192. (4)
33. (2) 73. (1) 113. (2) 153. (3) 193. (3)
34. (3) 74. (2) 114. (2) 154. (1) 194. (3)
35. (4) 75. (2) 115. (4) 155. (2) 195. (2)
36. (2) 76. (2) 116. (1) 156. (2) 196. (4)
37. (4) 77. (3) 117. (2) 157. (4) 197. (1)
38. (4) 78. (1) 118. (3) 158. (3) 198. (4)
39. (3) 79. (1) 119. (4) 159. (2) 199. (1)
40. (1) 80. (2) 120. (2) 160. (3) 200. (2)

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All India Aakash Test Series for NEET-2022 Test - 4 (Code-F)_(Hints & Solutions)

HINTS & SOLUTIONS


[PHYSICS]
SECTION-A 1 / P1 T2 273 + 140
= =
1. Answer (4) 2 / P2 T1 273 + 20

R X 413 293
Hint : CProcess = CV +  =  X = X
1− N X  293 413
3R R 3R R 5R 6. Answer (4)
Sol. : CProcess = + = − =
2 1− 5 2 4 4
Hint : U = nCVT
2. Answer (3)
Sol. : Utotal = U1 + U2
Hint and Sol. : PV = nRT
= n1CV T + n2CV T
PV m 1 2
 = nR = R
T M
5 3 15 18
PV  R  = 3  RT + 6  RT = RT + RT
Here =   m, equation of straight line 2 2 2 2
T M 
33
 Slope is different for different gases. U total = RT
2
3. Answer (2)
7. Answer (2)
Hint : PV = nRT
Hint : CP – CV = R
12
Sol. : Initially PV = R  500 …(i)
M CV 2 2
Sol. : =  CV = CP
P (12 − x ) CP 3 3
Finally V = R  300 …(ii)
3 M
2
On solving I and II Now CP − CP = R  CP = 3R
3
12  5
 3=  3(12 − x ) = 20 8. Answer (4)
(12 − x )  3
Hint : fbeat = |f1 – f2|
16
 16 = 3 x  x = g
3 Sol. : f1 = f2
4. Answer (2)  330 − v   330 + v 
   175 =   165
3RT  330 − 10   330 
Hint : v rms =
M (330 − v ) (330 + v )33
 35 =
v He 40 320 330
Sol. : = = 10 = 3.16
v Ar 4  330 × 35 – 35v = 330 × 32 + 32v
5. Answer (3)  990 = 67v
Hint : Use ideal gas equation PV = nRT
990
Sol. : PV = nRT v= m/s  14.8 m/s
67
m
PV = RT 9. Answer (3)
M
Hint and Sol. : Speed depends on elastic and
PV RT  M  1
=  =   inertial properties of medium.
m M P RT P T
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Test - 4 (Code-F)_(Hints & Solutions) All India Aakash Test Series for NEET-2022

10. Answer (4) 1 3T 1 T


Now f  = = =f
Pv 2L  2L r 2
Hint : For open organ pipe fo = 9r 2 
2L 3
(2P − 1)v Hence f = f
For closed organ pipe fc =
4L 15. Answer (3)
fo P v 4L Hint and Sol. : Frequency of standing wave in
Sol. : Required ratio X = =
fc 2L(2P − 1) v string closed at both end is

2P nv 10  20
= f = = = 5 Hz
(2P − 1) 2L 2  20
16. Answer (3)
X P
Hence, =
2 (2P − 1) Hint : For cylindrical tube open at both ends

11. Answer (4) v


f =
Hint and Sol. : According to first condition 2L
fA = 257 Hz or 263 Hz for cylindrical tube closed at one end
According to second condition v
f =
fA = 263 Hz or 277 Hz 4L
Hence frequency of source A should be 263 Hz. v v 2
Sol. : f  = = f
12. Answer (2)  3L  3L 3
4 
0.61V  4 
Hint : Reverberation time, T =
aS 2
Hence f  = f
V 3
Sol. : T  , where V = volume, S = surface area
S 17. Answer (4)
T1 V1 S2 V 9S 1 RT
=  =  = Hint : Speed of sound in air v =
T2 V2 S1 27V S 3 M

Here T2 = 3T1 = 3 seconds v1 T1


Sol. : =
13. Answer (2) v2 T2
Hint : Due to a point source
v (273 + 27)k
1  =  T = 1200 K
I 2v T
r2
= 927°C
2
I1 r22 r   25  18. Answer (4)
Sol. : = = 2 = 
I2 r12 r
 1 9 
 v  v0 
Hint : Doppler’s effect f  = f0 
I1 25  v  v 
Hence =  s 
I2 9
8 8  340 + u 
Sol. :  =    = 
14. Answer (4) 7 7  340 − u 
1 T 1 T  340 × 8 – 8u = 340 × 7 + 7u
Hint : Frequency f = =
2L  2L r 2
 340 = 15u
 340 68
Sol. :  = , T  = 3T and r  = 3r  u= = m/s
3 15 3

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All India Aakash Test Series for NEET-2022 Test - 4 (Code-F)_(Hints & Solutions)

19. Answer (3) 26. Answer (2)


Hint and Sol. : Both light and sound represent the Hint and Sol. : Mach number is the ratio of velocity
phenomenon of interference. of an object to the velocity of sound.
20. Answer (2) Light waves are transverse in nature.
Hint and Sol. : In stationary wave, strain is 27. Answer (3)
maximum at node points. Hint : fbeat = |f2 – f1|
21. Answer (2) Sol. : 1 = 2f1 = 300 
Hint : fbeat = |f2 – f1|  f1 = 150 Hz
Sol. : Increase in tension increases the frequency
2 = 2f2 = 306
of sound produced by the string. As the increase in
tension produces fewer beats per second, the  f2 = 153 Hz
frequency of string is 378 Hz. Beat frequency = 3 beats/s
22. Answer (4) Hence 180 beats/min.

T 28. Answer (3)


Hint : Speed of wave on string v =
 2
Hint :  = x

0.07
Sol. :  = and tension T = 154 N
5.5 v 300 1
Sol. : v = f    = = = m
f 600 2
154  5.5
v= = 110 m/s 2    1 
0.07 Now,  = x  x = = 
 2 2 6  2
23. Answer (1)
1
Hint and Sol. : Resultant amplitude of first and = m = 0.041m
third wave is = 16 – 13 = 3 mm. 24
29. Answer (2)
Now, this wave has a phase difference of /2 with
second wave. I
Hint : T = 2
Hence resultant amplitude mgr

Anet = (3)2 + (4)2 = 5 mm Sol. : Here, dcos45° =


d
2
24. Answer (4)
Hint : v = f md 2
I = mr2 =
2
5
Sol. : From the given figure, = 40 cm
2 md 2 2
So T = 2
  = 16 cm 2  mgd

v 480 d
Now f = = = 3000 Hz = 2
 16  10−2 2g
25. Answer (2) 30. Answer (3)
Hint : Speed v = /k Hint : Equation of SHM is
Sol. : From the equation given,  = 7 and k = X = Asin(t + )
0.04
2 2
7 7  22  100 Sol. : Here A = 10,  = = =
Hence, speed v = = T 2
0.04 47
A 
= 550 m/s. at t = 0 x = =
2 6
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Test - 4 (Code-F)_(Hints & Solutions) All India Aakash Test Series for NEET-2022

So equation will be 35. Answer (4)


  Hint : Equation of a particle performing SHM is
x = 10sin  t + 
 6 y = Asin(t + )
31. Answer (1) Sol. : x = Psint + Qcost
1
Hint : Kinetic energy K = mv 2   Q 
2 x = P 2 + Q 2 sin t + tan−1   
  P 
1
Sol. : K = m2 ( A2 − x 2 ) Hence, it is SHM of amplitude
2
A A = P 2 + Q2
at x =
2
SECTION-B
1  A  2
K= m2  A2 −  36. Answer (2)
2  4 
I
3 Hint : 2 = 2
= K mgR g
4 max

Hence
K
=
K
=
3 2mR 2
Sol. :  2 = 2
Kmax K total 4 mgR g
32. Answer (1) On comparing  = 2R
m
Hint : T = 2 37. Answer (4)
keff
3
Sol. : Here keff = k1 + k2 Hint : oscillation  x = 0 to x = A and x = A to
8
= 2k + 3k A
x=
= 5k 2
m Sol. : Total time is
So, Time period T = 2
5k T = T1 + T2
33. Answer (2) T T 5T
= + =
Hint : Time required to travel from 4 6 12
A T 38. Answer (4)
x = 0 to x = is
2 12 Hint and Sol. : Sound wave travelling from guitar
Sol. : Required time in air is longitudinal and progressive.
t = t1 + t2 39. Answer (3)
T T T Hint : Work done = Area under P–V curve on
= + =
12 12 6 volume axis.
T Sol. : WorkTotal = WA→B + WB→C + WC→A
t=
6 15 = 10 × 3 + 0 + WC→A
34. Answer (3) Hence WC→A = –15 J
Hint and Sol. : y = Asin(2mt + ) 40. Answer (1)
= Asin Hint : Change in internal energy doesn’t depend
Phase at any time ‘t’ is on process. It only depends on change in
 = (2mt + ) temperature.

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All India Aakash Test Series for NEET-2022 Test - 4 (Code-F)_(Hints & Solutions)

Sol. : For adiabatic process U = – 200 J 1 T T 3


Sol. : = 1− 2  2 =
Which remains same for other processes also, as 4 T1 T1 4
temperature change is same.
T2 − 43 1 3 43
Let ‘C’ be the heat capacity of 2nd process then 2 = 1 −  = 1− +
T1 3 4 T1
–8·C = dU + dw
43 1 1
–8·C = – 200 + 36 = – 164  = −
T1 3 4
164
C= = 20.5 J/K  T1 = 516 K
8
and Hence, T2 = 387 K
41. Answer (3)
45. Answer (4)
Hint and Sol. :
Hint : Work done = Area of loop
nR T
⚫ Work done in adiabatic process W =  5V   7P0 
1−  Sol. : W =   0  
 2   2 
⚫ Q = nCT
35
= P0V0
⚫ Work done depends on path followed while 4
internal energy depends on initial and final
46. Answer (3)
states.
work done
42. Answer (4) Hint : Efficiency of heat engine  =
heat absorbed
Hint : Internal energy of the gas remains constant.
227 + 273 Work
Sol. : T1 = T2 Sol. :  = 1 − =
327 + 273 5  104 J
P1V1 = P2V2
1
P·V = P·2V  Work = 5  104  J
6
P = P/2, Hence P = P/2 = 0.83 × 104 J
43. Answer (3) 47. Answer (2)
Hint : For adiabatic process PV = constant Hint : PV = nRT
Sol. : PV4/3 =K PV
1 1
P2V2
Sol. : =
4 T T
ln P + lnV = ln K
3 80
= PV
1 1
= P2 · V
100 1
P 4 V
 + =0
P 3 V 100  20 
 P2 = P1 =  1 + P
80  80  1
 P 4 V 
  =−   100
 P 3 V   P − P1 
  2  100 = 25%
 P 
V 3 3 9  1 
 100  = −   = − %
V 4 4 16 48. Answer (4)
9 Hint : Heat is absorbed from the source in process
Hence percentage decrement in volume is % AB and BC.
16
3 PV 5 6P V
44. Answer (3) Sol. : Q = n  R  0 0 + n  R  0 0
2 nR 2 nR
T2
Hint : Efficiency  = 1 − 3 30 33P0V0
T1 = P0V0 + P0V0 = = 16.5 P0V0
2 2 2

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Test - 4 (Code-F)_(Hints & Solutions) All India Aakash Test Series for NEET-2022

49. Answer (3) 50. Answer (1)



Hint : Use PV = constant Hint : PV = nRT

Sol. : PV
1 1
= P2V2
nRT
Sol. : P =
P 1V17/5 = P2 (32V1 )7/5 V
P1 Slope of P-T graph is inversely proportional to V
P1 = P2 128  P2 = ( P1 = P)
128
Hence V2 < V1.
P
 P2 =
128

[CHEMISTRY]
SECTION-A

51. Answer (1) Sol.: Due to + R effect of – OH group, has


Hint: Hydroboration oxidation gives anti
Markovnikov addition of water.
(i) B H highest electron density in benzene ring, so will
Sol.: CH3 CH2CH = CH2 ⎯⎯⎯⎯⎯⎯

2 6

(ii) OH /H2O2 give fastest rate of electrophilic aromatic
CH3CH2CH2CH2OH substitution.
(Major )
55. Answer (3)
52. Answer (2) Hint: FeBr3 is a lewis acid.
Hint: 1° radical gives dimerization as major product +
during Kolbe's electrolysis. Sol.: FeBr3 + Br2 ⎯⎯→ FeBr4− + B r
(Electrophile )
Sol.: CH3CH2COO–Na+ ⎯→CH3CH2COO– + Na+

56. Answer (3)
Anode: 2CH3CH2COO ⎯⎯→

2CH3 CH2 + 2CO2 + 2e− Hint: Isohexane:


Sol.:
CH3 CH2 + CH3 CH2 ⎯⎯→ CH3CH2CH2CH3

1
Cathode: H2O + e− ⎯⎯→ H2 + OH−
2
53. Answer (2)
Hint: Anti form has least van der Waals as well as
torsional strains among all conformers.

57. Answer (3)


Sol.: is antiform and it has least Hint: Sodium reacts with acidic hydrogen and
gives H2 gas. Terminal alkyne contains acidic
hydrogen.
strains so will be most stable. Na
Sol.: CH3CH2CH2C  CH ⎯⎯⎯

54. Answer (2)
s r 1
Hint: Ring of highest electron density will give CH3CH2CH2C  CNa+ H2 (g)
fastest rate of electrophilic aromatic substitution. 2

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All India Aakash Test Series for NEET-2022 Test - 4 (Code-F)_(Hints & Solutions)

58. Answer (3) 64. Answer (2)


Hint: Alkenes and alkynes decolourise bromine Hint: Paper chromatography, is a type of partition
water. chromatography.
Sol.: Benzene due to aromatic nature is stable so Sol.: • Commonly used adsorbents during
does not decolourise bromine water. adsorption chromatography are silica gel
59. Answer (4) and alumina.
Hint: With increase of % s character of carbon • Column chromatography is an example
atom, acidic nature of hydrogen attached with it of adsorption chromatography in which
increases. most readily adsorbed substances are
Sol.: HC  CH, contains sp hybridised carbon, retained near the top and other comes
hence it will contain most acidic hydrogen. down to various distances in the column.
60. Answer (2) 65. Answer (2)
Hint: H2, Pd/C, quinoline as well as Na/liq NH3 Hint: C3H8O may be an alcohol or ether.
reduce alkynes into alkenes.
Sol.: C3H8O : CH3CH2CH2OH, ,
Sol.: ⚫ H2, Pd/C, quinoline converts alkynes into
cis-alkene.
CH3OCH2CH3
66. Answer (1)
80 mass of AgBr  100
Hint: % of Br = 
188 mass of compound
⚫ Na/liq NH3 converts alkynes into trans
alkenes Sol.:  188 g AgBr contains 80 g bromine
61. Answer (3)
80  0.15
Hint: Cyclic complete conjugated systems having  0.15 g AgBr contains g bromine
188
(4n + 2) electrons are aromatic in nature.
80  0.15  100
Sol.: contains 6 electrons, so aromatic in so % bromine = = 31.9 %
188  0.2
67. Answer (2)
nature.
Hint: When both nitrogen and sulphur are present
62. Answer (1)
in organic compounds, sodium thiocyanate is
Hint: Fuming sulphuric acid or oleum is used as a formed.
reagent for sulphonation of aromatic compounds.
Sol.: Na + C + N + S ⎯→ NaSCN
Sol.: 2H2SO4 H3O+ + SO3 + HSO4−
Electrophile Fe3+ + SCN− ⎯⎯→ [Fe(SCN)]2+
(Blood red)
63. Answer (4)
68. Answer (3)
Hint: Symmetrical alkanes with even number of
carbon atoms can be produced in good yield by Hint: Only sigma bonds and lone pairs of electron
Wurtz reaction. are considered in hybridization.
Sol. : • n-hexane contains six carbon atoms sp3 sp2 sp sp2 sp3 sp2 sp2
which can be prepared in good yield by Sol.: CH3 − CH = C = CH− CH2 − CH = CH2
1 2 3 4 5 6 7
the following way.
Na/Ether 69. Answer (4)
2CH3 CH2CH2 − Br ⎯⎯⎯⎯ ⎯→
Hint: Each successive condensation and
CH3CH2CH2CH2CH2CH3 vaporization unit in the fractionating column is
(n-hexane ) called a theoretical plate.

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Test - 4 (Code-F)_(Hints & Solutions) All India Aakash Test Series for NEET-2022

Sol.: Steam → Used to separate those Sol.: • Cu(250°C) – Controlled oxidation (e.g.:
distillation substances which are CH4 into CH3OH)
steam volatile and
immiscible with water

Distillation → Used for very high boiling • + ZnO


under reduced points liquids and those
pressure which decompose at or • Baeyer’s reagent (dil. KMnO4):
below their boiling points

70. Answer (4)


Hint: Metamerism arises due to different alkyl
chains on either sides of polyfunctional groups or 76. Answer (2)
atoms. Hint: % N in the organic compound
Sol.: CH3CH2OCH2CH3 and CH3OCH2CH2CH3 are
1.4  meq of acid
related as metamers. =
wt. of organic compound
71. Answer (4)
Sol.: % N in the organic compound
Hint: Cyclic polymerisation of ethyne take place
Sol.: 1.4  20  0.5
=
0.6
= 23.33%
77. Answer (3)
72. Answer (3)
Hint: –R effect is observed when the transfer of
Hint: Alc. KOH is used for elimination while aq. electrons is towards the atom or substituent group
KOH is used for substitution. attached to the conjugated system.
Sol.: Reactions 1, 2 and 4 are examples of
Sol.: – R effect groups: – COOH, – CHO, – CN,
addition reactions.
– NO2
73. Answer (1)
+ R effect groups: – OH, – OCH3, – NH2,
Hint: Compounds in which all carbon atoms are
– NHCH3, NHCOCH3
sp2 hybridised will be coplanar.
78. Answer (1)
Sol.: In , all the carbon Hint: Neutral resonating structure having highest
number of covalent bonds is most stable.
atoms are sp2 hybridised, so it will be coplanar.
74. Answer (2) Sol.: Negative charge on oxygen atom is more
stable than carbon.
Hint: Resonance increases the stability of
carbocation. So, the correct order of stability : I > II > III
Sol.: Due to presence of conjugation in 79. Answer (1)

CH3 − CH − OCH3 , it is most stable. Hint: Acid and its derivative groups have higher
priority during IUPAC naming of polyfunctional
groups.
75. Answer (2) Sol.: Correct order of priority of functional groups:
Hint: Cr2O3 or V2O5: Aromatization catalyst.

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80. Answer (2) 85. Answer (3)


Hint: More substituted carbon gets lower number. Hint: Carbon is tetravalent while nitrogen is
trivalent.

Sol.:
Sol.: , contains, 3-bonds.

3-Ethyl-1, 1-dimethylcyclohexane. SECTION-B


81. Answer (3) 86. Answer (3)
Hint: Isobutyl group has atleast one 3° carbon Hint: Bridgehead carbon cannot be sp2 hybridized.
atom.
Sol.: ⚫

Sol.: ⚫ : isobutyl group.


tert-butyl group
87. Answer (1)
⚫ CH3CH2CH2CH2 – : n-butyl group Hint: Chloroform (B.P. 334 K) and Aniline
82. Answer (4) (B.P. 457 K).
Hint: Anisole has ether as functional group. Sol.: Due to high boiling point difference,
Sol.: C6H5OCH3: Anisole components of mixture of chloroform and aniline
can be separated by distillation technique.
CH3COCH3: Acetone
88. Answer (3)
C6H5COCH3: Acetophenone
C6H5OC6H5: Diphenyl ether Hint: CO2(g) being acidic can absorb in aq.
solution of KOH.
83. Answer (3)
 y
Sol.: • CxHyNz +  2x +  CuO ⎯⎯→
 2
Hint:
y z  y
xCO2 + H2O + N2 +  2x +  Cu
2 2  2
• Traces of nitrogen oxides formed, (if
Sol.: contains four -bonds and six
any) are reduced to nitrogen by passing
the gaseous mixture over a heated
hydrogen atoms. copper gauze.
84. Answer (4) 89. Answer (2)
Hint: In Heterocylic compound, atoms other than Hint: Naphthalene is an aromatic compound
carbon are also present in the ring. having two rings fused together.
Sol.: Tetrahydrofuran(THF) is heterocyclic since it Sol.:
contains oxygen atom in the ring other than carbon
atoms. • : Naphthalene, contains 10

electrons

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Sol.: (CH3)3C – C(CH3)3 molecule has only one


type of H-atoms so will give only
1 monohalogenated product.
• : 1,2-Dimethylbenzene
93. Answer (2)
(o-xylene) Hint: Vicinal dibromide undergoes
dehydrohalogenation on treatment with alc. KOH.
• : 1,2-Dibromoethane is a Sol.:
vicinal dichloride
+s s + •
• NaC  CNa : Disodium ethynide
90. Answer (2)
Hint: In the presence of excess electrophilic •
reagent (i.e., Cl2/Anhy. AlCl3) substitution reaction
occurs to replace hydrogen atoms with chlorine
atoms.
Sol.:

• 94. Answer (3)


Hint: In symmetrical alkenes, Markovnikov’s rule is
not observed.
Sol.: CH3CH=CHCH3 is a symmetrical molecule,
so, during addition of HBr in it, Markovnikov’s rule
is not observed.
• 95. Answer (4)
Hint: In the presence of Cl2/h, toluene gives free
radical substitution reaction.
(Benzene hexachloride (BHC))
Sol.:
91. Answer (3)
Hint: Electrophilic addition reaction take place.
Sol.:

96. Answer (3)


Hint: Correct order of bond energies of HX is:
HI < HBr < HCl
Sol.: • Addition of hydrogen halides is an
example of electrophilic addition reaction
in which reactivity depends on bond
92. Answer (3) energy.
Hint: Hydrocarbons having only one type of • Due to least bond energy of HI, it can
H-atom will give only one monobrominated release electrophile (H+) most easily
product. hence shows highest reactivity.

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97. Answer (3) 99. Answer (4)


Hint: If both the groups or atoms attached to Hint: Sodium salt of carboxylic acids on heating
doubly bonded carbon atoms are different then with soda lime gives alkanes containing one
carbon atom less than the carboxylic acid.
alkene can show geometrical isomerism.
NaOH+ CaO
Sol.: CH3 CH2CH2CH2COONa ⎯⎯⎯⎯⎯→

Sol.: Molecule , does not show
CH3CH2CH2CH3 + Na2CO3
geometrical isomerism 100. Answer (2)
98. Answer (1) Hint: In reductive ozonolysis, cleavage of ‘C=C’
take place and converts into carbonyl group.
Hint: As the molar mass of alkanes increases,
Sol.:
boiling point increases.

Sol.: Propane <2-methylpropane < Pentane

B.P.: 230.9 K 261.0 K 309 K ( CH3 )2C = O + HCHO + OHCCH2CH2CHO

[BOTANY]
SECTION-A 105. Answer (4)
Hint : Glycolysis occurs in all organisms aerobes
101. Answer (3)
as well as anaerobes.
Hint : In TCA cycle at a single step, CO2 is
Sol. : Glycolysis is partial oxidation of glucose and
released along with NADH + H+ synthesis
occurs in cytoplasm.

Sol. : -KGA Succinyl CoA 106. Answer (2)


Hint : Net gain of ATP in both types of
fermentation is 2 ATP.
Oxalo succinic acid -KGA
Sol. : There is release of CO2 in alcoholic
Malic acid fermentation only not in lactic acid fermentation.
107. Answer (1)
Reaction ‘c’ is not part of TCA cycle. It is link
reaction. Hint : Cyclic photophosphorylation involves only
one photosystem.
102. Answer (1)
Sol. : Cyclic photophosphorylation lacks PS II,
Hint : Link reaction occurs when pyruvic acid
photolysis of water and evolution of oxygen. It
enters in mitochondria.
occurs mostly in stroma lamellae.
Sol. : Link reaction occurs in mitochondrial matrix.
108. Answer (4)
103. Answer (3)
Hint : C4 plants does not show dual activity of
Hint : Two H+ are required to reduce NAD+ into RuBisCO.
NADH + H+.
Sol. : Photorespiration is absent in C4 plants.
Sol. : 1 PGAL removes 2H+ and reduces NAD+ to
109. Answer (4)
NADH + H+. So 2 PGAL will remove 4H+.
Hint : Sugarcane is a C4 plant while rice is C3
104. Answer (4)
plant.
Hint : There are two substrate level
Sol. : For the synthesis of one glucose molecule:
phosphorylation reactions in pay off phase of
glycolysis. In sugarcane, ATP required = 30

Sol. : At two steps, total 4 ATPs are formed. NADPH2 required = 12

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In rice, 117. Answer (2)


ATP required = 18 Sol. : Jan Ingenhousz showed that in presence of
NADPH2 required = 12 sunlight only green parts of plant release oxygen.

So, additional ATP required in C4 plant = 30 – 18 = 118. Answer (3)


12 Hint : Calcium is an immobile element.

And additional NADPH2 required in C4 plant = 0 Sol. : Being immobile deficiency of Ca appear first
in younger tissue. Mn toxicity reduces uptake of Mg
110. Answer (1)
and Fe.
Hint : Photorespiration involves chloroplast,
119. Answer (4)
mitochondria and peroxisome.
Sol. : Necrosis is caused by deficiency of Ca, Cu,
Sol. : Peroxisome is single membrane bound
K, Mg.
whereas chloroplast and mitochondria are double
membrane bound. 120. Answer (2)
Hint : The given process is reductive amination
111. Answer (1)
Sol. : Reductive amination process occurs in
Sol. : Maize, Sorghum, Sugarcane etc. show
plants and is catalysed by glutamate
Kranz anatomy
dehydrogenase.
112. Answer (4)
121. Answer (1)
Hint : C4 pathway was discovered in plants of dry
Hint : Leghaemoglobin imparts pink colour to
tropical area.
nodules
Sol. : C4 pathway is more efficient pathway than C3
Sol. : Nitrogenase is found in prokaryotes only.
pathway
122. Answer (3)
113. Answer (2)
Hint : Frankia, Rhizobium and Nostoc are
Hint : RuBP is primary acceptor of CO2 of C3 cycle.
symbiotic N2 fixer.
Sol. : RuBP is a five carbon ketose sugar and is Sol. : Pseudomonas denitrificans is denitrifying
substrate for RuBisCO. bacteria.
114. Answer (2) 123. Answer (1)
Hint : The primary acceptor of electrons transfers Hint : Magnesium acts as an activator of various
its electrons to a H+ carrier. enzymes of respiratory and photosynthetic
Sol. : Phaeophytin is primary acceptor of electrons pathway.
and it transfer electrons to PQ which is a H+ carrier Sol. : Nitrogenase requires Mo as an activator.
too. Phaeophytin is situated towards outer side of
124. Answer (3)
membrane.
Hint : Essential elements are very specific.
115. Answer (4)
Sol. : Disorders caused by essential elements are
Hint : PS II is found in grana lamellae only. specific and corrected by availability of that
Sol. : The reaction centre of photosystem II is P680. element only.
116. Answer (1) 125. Answer (3)
Hint : This pigment is main photosynthetic Hint : Some macronutrients are classified as
pigment. critical elements.
Sol. : Chlorophyll a appears blue green in Sol. : Zn is a micronutrient and act as an activator
chromatogram. of alcohol dehydrogenase.

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126. Answer (4) 135. Answer (2)


Hint : Inorganic minerals are mainly transported Hint : Transpiration pull is negative hydrostatic
via xylem pressure
Sol. : Phloem sap mainly contains organic Sol. : Root pressure is positive hydrostatic
materials. pressure

127. Answer (1) SECTION-B


Sol. : Girdling experiment proved that food is 136. Answer (4)
translocated via phloem.
Hint : Nitrocystis converts nitrite to nitrate.
128. Answer (2)
Sol. : Pseudomonas denitrificans and Thiobacillus
Hint : Cells of this layer adjust quantity and type of denitrificans reduce nitrate present in the soil into
solutes that reach the xylem. gaseous nitrogen. This process is called
Sol. : Endodermis is known as control point. denitrification.

129. Answer (4) 137. Answer (3)

Hint : Rate of photosynthesis is affected by Hint : TCA cycle yield 6NADH2, 2FADH2 and 2ATP
chlorophyll content from one glucose molecule.

Sol. : Chlorophyll content of leaf affects Sol. : 6 NADH2 ⎯→ 18 ATP


photosynthesis not the rate of transpiration. 2 FADH2 ⎯→ 4 ATP
130. Answer (2) Total 22 ATP
Hint : Loss of water in the form of liquid droplet is 138. Answer (4)
due to positive hydrostatic pressure. Hint : Light reaction involves absorption of light
Sol. : Root pressure is responsible for guttation from source and convert it into chemical energy.

131. Answer (2) Sol. : Light reaction involves light absorption, water
splitting which leads to release of O2 and formation
Hint : Dry woods also show imbibition.
of high energy intermediate, ATP and NADPH.
Sol. : Facilitated diffusion is selective in nature.
139. Answer (3)
Living as well as dead cells/structures show
Hint : IAA and IBA are produced by plants
imbibition.
Sol. : 2,4-D and NAA are produced artificially and
132. Answer (3)
extensively used in agriculture and horticulture.
Hint : A fully turgid cell does not absorb water
140. Answer (2)
further.
Hint : Hypertonic solution has more solute
Sol. : In a fully turgid cell  S =  P or OP = TP
concentration.
So, DPD will be zero. Sol. : Water will move from high water potential to
133. Answer (3) low water potential. Cell will shrink as water will
move out of the cell.
Hint : Porins allow passage of small proteins
141. Answer (4)
Sol. : Porins are found in outer membrane in
plastids and it is found in prokaryotes as well. Hint : Day neutral plants does not show any
correlation between exposure of light duration and
134. Answer (1)
flowering
Hint : Simple diffusion is a random process Sol. : Henbane being LDP require long
Sol. : Simple diffusion is non selective in nature photoperiods for flowering

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142. Answer (2) 147. Answer (1)


Sol. : Vernalisation refers to cold treatment for Hint : The hormone that delays senescence can
promotion of flowering. also increase shelf life.
143. Answer (4) Sol. : Cytokinins are applied to increase shelf life
Hint : ABA is also called stress hormone of cut plant parts.
Sol. : ABA induces dormancy of buds and seeds. 148. Answer (3)
144. Answer (3) Hint : Adenine derivative hormone promotes cell
Hint : Gibberellin is used to increase sugarcane division.
yield. Sol. : Cytokinins are adenine derivatives.
Sol. : Gibberellin is terpene derivative and it was
149. Answer (1)
first extracted from rice plant, infected with
bakanae disease. Hint : Difference in shape of leaves can be
observed present in air and water.
145. Answer (4)
Hint : ABA induces seed dormancy. Sol. : Buttercup shows environmental heterophylly.
Rest all show developmental heterophylly.
Sol. : ABA and gibberellin act antagonistically as
gibberellin induces seed germination. 150. Answer (4)
146. Answer (1) Hint : Sigmoid curve shows accelerated as well as
Hint : 2,4-D is used as weedicide. stationary growth phases.

Sol. : 2,4-D is indole compound that is artificially Sol. : S-shaped curve shows geometrical growth
synthesised. Ethylene is fruit ripening agent. which occurs under limited resources supply.

[ZOOLOGY]
SECTION-A 154. Answer (1)
Hint : Found in aquatic invertebrates
151. Answer (4)
Sol. : Statocyst is considered as a balancing
Hint : Air sacs are avascular. organ. Both prawn (aquatic arthropod) and
Sol. : In birds, avascular air sacs are not directly cuttlefish (aquatic mollusc) have statocyst as
involved in gaseous exchange. They supplement balancing organ.
respiration. 155. Answer (2)

152. Answer (1) Hint : Anterior part of genital pouch in female is


called genital chamber.
Hint : Crocodiles are poikilothermous.
Sol. : Anterior part of genital pouch is called genital
Sol. : Birds and mammals are homoiothermous chamber which has spermathecal pore, female
animals having double circulation. Crocodiles have gonopore and openings of ducts collaterial glands.
double circulation but they are cold blooded Genital pouch is present in both male and female
animals. cockroach. Each ovary of cockroach is formed by 8
ovarioles.
153. Answer (3)
156. Answer (2)
Hint : In Latin, reptum refers to creep or crawl.
Hint : Tracheoles is the site of diffusion of gases.
Sol. : Class ‘Reptilia’ is called so, on the basis of Sol. : Respiratory system of cockroach consists of
creeping mode of locomotion of its members. Class a network of trachea which further divide to form
Mammalia name is derived from ‘mamma’ which tracheoles. Gaseous exchange takes place in the
means mammary gland. region of tracheoles by simple diffusion.

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157. Answer (4) in annelids and vertebrates. Presence of crop and


Hint : Triangular shaped muscles gizzard in alimentary canal is a common feature of
both insects and birds.
Sol. : Alary muscles are in 12 pairs, found attached
with tergites and dorsal diaphragm. Their 164. Answer (3)
contraction and relaxation helps in circulation of Hint : It is present in birds and mammals.
haemolymph.
Sol. : Four chambered heart is present in
158. Answer (3)
mammals, birds, crocodiles, alligators etc. So, four
Hint : Arthrodial membrane chambered heart is not an exclusive feature of
Sol. : The body of cockroach is divided into head, mammals.
thorax and abdomen. In each segment, hardened
165. Answer (2)
plates are present as exoskeleton which are joined
together by arthrodial membrane. Head is freely Hint : Pila is commonly known as apple snail.
movable due to flexible neck. Sol. : Pearl oyster is common name given to
159. Answer (2) Pinctada. Pila has asymmetrical body due to
Hint : Midgut is also known as mesenteron. torsion. Ascaris (roundworm) is an aschelminth and
Sol. : In cockroaches, excretion is performed by Octopus (devil fish) is a mollusc.
Malpighian tubules which are present at the 166. Answer (2)
junction of midgut and hindgut.
Hint : Parasitic form having structures for
160. Answer (3)
anchorage
Hint : Most of the cartilaginous fishes are
viviparous. Sol. : Ancylostoma duodenale is commonly known
as hookworm. It is placed in the phylum
Sol. : Scoliodon is commonly called dog fish. It is a
marine cartilaginous fish having placoid scales. Aschelminthes and has hooks for attachment
Most of the cartilaginous fishes are viviparous and within intestinal mucosa.
bony fishes are oviparous. Cuttlefish is a false fish 167. Answer (3)
placed in phylum Mollusca. Magur and rohu are
Hint : Medusa is sexually reproducing form.
fresh water bony fishes.
161. Answer (1) Sol. : Polyp reproduces asexually to form umbrella
shaped medusa. Gonads are formed in medusa,
Hint : Pneumatic bones
which reproduce sexually to form polyp form. This
Sol. : In Aves, long bones of the body contain
alternation of generation is called metagenesis.
cavities filled with air. These bones are called
pneumatic bones which are present in birds. Spread of cancer is called metastasis and
mutagenesis is a cause of cancer due to genetic
162. Answer (4)
mutation.
Hint : Identify a mammal that can echo-locate
168. Answer (2)
Sol. : Delphinus is an aquatic mammal and
commonly known as Dolphin. Elephas is the Hint : Digestive tract has both mouth and anus.
largest living terrestrial animal. Balaenoptera is Sol. : Animals placed in phylum Aschelminthes are
commonly known as blue whale.
commonly known as roundworms because their
163. Answer (4) body is circular in cross-section. They have
Hint : Insects have double, ventral, solid nerve complete digestive tract having separate mouth
cord. and anus with well developed muscular pharynx.
Sol. : Heart is dorsal in non-chordates and ventral Aschelminths have internal fertilisation and
in chordates. Closed type of circulation is present development occurs with or without larval stages.
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169. Answer (4) 175. Answer (2)


Hint : Vector for chikungunya Hint : Presence of organ level of organisation
Sol. : Aedes (mosquito) is an insect placed in Sol. : Fasciola is a flatworm having organ level of
phylum Arthropoda. It is a unisexual animal having body organisation. Loose cell agregate body plan
separate male and female sex organs with sexual and cellular level of body organisation is
dimorphism. characteristic feature of sponges. Limulus is an
170. Answer (1) arthropod having organ-system level of body
Hint : Mammals are warm-blooded animals. organisation.
Sol. : Fishes, amphibians and reptiles are 176. Answer (3)
poikilothermous animals whereas birds and
Hint : Function of ciliated comb plates
mammals are homeothermous animals.
Sol. : Presence of radial symmetry, both
171. Answer (4)
extracellular and intracellular digestion, and larval
Hint : Cyclostomes are also chordates. stages during embryonic development are common
Sol. : Cyclostomes are the most primitive extant features present in both ctenophores and
vertebrates in which mouth is circular and without coelenterates. Tentacles are locomotory structures
jaws. Petromyzon belongs to class Cyclostomata in coelenterates and ciliated comb plates are
which migrates to fresh water for spawning.
locomotory structures in ctenophores.
172. Answer (4)
177. Answer (2)
Hint : 2nd largest phylum
Hint : Identify cnidarians
Sol. : Phylum Mollusca includes soft bodied
Sol. : Cnidoblasts are specialized cells found in
animals enclosed within calcareous exoskeleton;
anal styles are unjointed appendages in members of phylum Coelenterata. They also have
arthropods; roundworms can be parasitic or free- tentacles for locomotion, food capturing, offence
living forms; presence of water-vascular system is and defence. Molluscs, ctenophores and
the most distinctive feature of echinoderms. echinoderms lack cnidoblasts.
173. Answer (3) 178. Answer (4)
Hint : Flatworms are acoelomates. Hint : Choanocytes
Sol. : Platyhelminths are bilaterally symmetrical, Sol. : Most of the porifers are asymmetrical but
triploblastic and acoelomates, e.g., Taenia and some show radial symmetry. Platyhelminths are
Fasciola. Roundworms are triploblastic triploblastic acoelomates. In hemichordates, body
pseudocoelomates and annelids are triploblastic is differentiated into proboscis, collar and trunk.
coelomates. Hydra and Obelia are diploblastic
acoelomates. 179. Answer (1)

174. Answer (1) Hint : Biradial symmetry is present in ctenophores.

Hint : Presence of water-vascular system Sol. : Pleurobrachia and Beroe are members of
phylum Ctenophora having statocyst as the
Sol. : Radial symmetry is present in both
echinoderms and coelenterates and also present in balancing organ, biradial symmetry and only sexual
some porifers. In echinoderms, larva shows mode of reproduction. Echinoderms exhibit
bilateral symmetry which is a more advanced pentamerous radial symmetry and most of the
character than radial symmetry. Most of the sponges are asymmetrical. Hydra and Obelia have
molluscs show bilateral symmetry in both larval radial symmetry and can perform both sexual and
and adult forms of life. asexual reproduction.

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180. Answer (3) SECTION-B


Hint : Collar cells are present in sponges.
186. Answer (3)
Sol. : Bungarus is a venomous snake having
Hint : Animal which has a dorsoventrally flattened
scales and creeping mode of locomotion.
body
Ctenoplana is placed in phylum Ctenophora
showing bioluminescence. Pterophyllum is a bony Sol. : Ascaris is an endoparasitic roundworm
fish and Euspongia is a bath sponge. having muscular pharynx. Laccifer is an arthropod
having jointed legs. Planaria is a flatworm in which
181. Answer (2)
segmentation is absent. Euspongia is a bath
Hint : Type of circulation in arthropods sponge found in marine water.
Sol. : In arthropods, open type of circulation is 187. Answer (1)
present having poorly developed blood vessels Hint : Larval stages are different from adult stage.
without blood capillaries. The blood is pumped out
Sol. : The skeleton forming cells of sponges are
of the heart and the tissues are directly bathed in it.
called scleroblasts which synthesize spicules and
In closed type circulation, the blood circulates
spongin fibres. In animals, larval stages are
through blood vessels of varying diameter.
morphologicaly dissimilar in comparision to adult
182. Answer (2) stage.
Hint : Different levels of organisation in animals 188. Answer (1)
Sol. : All members of kingdom Animalia are Hint : Helps in movability of head.
multicellular but have different levels of body Sol. : Head of cockroach is connected with thorax
organisation. Sponges have loose cell aggregate by a short extension of prothorax called neck.
body plan with some division of labour among
189. Answer (2)
cells. Cells are organised to form tissues and
tissues are organised to form organs. Hint : Doliolum is a chordate.

183. Answer (4) Sol. : In chordates, nerve cord is even dorsal to


notochord. Nerve cord of chordates is single,
Hint : Increase in cell number hollow and dorsal in position.
Sol. : Two types of cell division i.e., mitosis and 190. Answer (4)
meiosis occur in all animals. Animals are classified
Hint : Dorso-ventrally flattened body
on the basis of level of organisation, body plan,
types of coelom, germ layers, digestive and Sol. : Platyhelminths are considered as the first
reproductive system etc. triploblastic acoelomates. So, mesoderm first
evolved in this phylum.
184. Answer (3)
191. Answer (3)
Hint : Rasping organ in molluscs
Hint : Hemichordates have notochord-like
Sol. : Radula is a rasping organ present in most of structure.
the molluscs. Operculum is a gill cover found in
Sol. : Torpedo – Electric organ
bony fishes. Parapodia are locomotory structures
in certain annelids. Trygon – Poison sting

185. Answer (2) Saccoglossus – Stomochord present

Hint : Segmented animals Bombyx mori – Silkworm


192. Answer (4)
Sol. : In animals having metameric segmentation,
the body is externally and internally divided into Hint : Larval stage is present in life.
segments with a serial repetition of at least some Sol. : Balanoglossus is bilaterally symmetrical,
organs. Metameric segmentation first evolved in triploblastic and coelomate. Body is divisible into
the members of phylum Annelida and also found in proboscis, collar and trunk. Fertilization is external
arthropods and chordates. and development is indirect through a larval stage.

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193. Answer (3) 197. Answer (1)


Hint : Bony fishes exhibit external fertilization. Hint : Commonly known as sea horse
Sol. : Carcharodon is a cartilaginous fish and Sol. : Exocoetus (flying fish) and Hippocampus
shows internal fertilization. Crocodile is a reptile (sea horse) are marine bony fishes. Betta,
and Aptenodytes is a bird. Both of these have Pterophyllum and Catla are fresh water bony
internal fertilisation and external development. fishes.
Clarias is a bony fish which shows external
198. Answer (4)
fertilization.
Hint : Osteichthyes are bony fishes.
194. Answer (3)
Hint : Vertebrata is a sub-phylum. Sol. : Cyclostomes are anadromous and spend
most of their life in marine water. They migrate to
Sol. : Sub-phylum Vertebrata is divided into two
fresh water for spawning and die after sometime.
divisions : Agnatha and gnathostomata. Animals
Larva after metamorphosis, returns to the ocean.
which are placed in division Agantha lack jaws and
are placed in class Cyclostomata, e.g., lamprey They have cartilaginous vertebral column.
and hagfish. 199. Answer (1)
195. Answer (2) Hint : Neck is absent in amphibians.
Hint : Calcareous ossicles form endoskeleton in Sol. : Rana is an amphibian in which body is
echinoderms. divisible into head and trunk. A tympanum
Sol. : Echinoderms are spiny bodied, having represents the ear. Upper eyelids are almost
endoskeleton formed by calcareous ossicles. immovable and lower eyelids are movable in frog.
Branchiostoma is placed in Cephalochordata, in Rattus (rat) is a mammal, Struthio (ostrich) is a bird
which notochord persists throughout life. In and Clarias (magur) is a fish.
molluscs, feather-like gills are present in mantle
200. Answer (2)
cavity. Locusta is a gregarious pest.
196. Answer (4) Hint : Limbs which are used for swimming by
aquatic birds.
Hint : Structures which participate in respiration.
Sol. : In birds, forelimbs are modified into wings for
Sol. : In chordates, pharynx is perforated by gill
flying and hindlimbs are modified for walking,
slits which are absent in non-chordates. Nerve
cord, heart and germ layers are present in both swimming or clasping the tree branches (perching
chordates and non-chordates. mechanism in birds).

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