ppp
ppp
SECTION – A
1. A, B, D
0.5 0.56 0.57 0.54 0.59
Sol. Tm 0.55 sec
5
Tm 0.03
Tm
5.45%
Tm
2. A, B, D
Sol. At equation
A0 v 02
kx 0
2d2
Now, small shift ‘x’ has been given them
A0 v 02
Frestoring k(x 0 x)
2(d x)
Md3
T 2
kd3 A0 v 02
3. A, C
Sol. Increase in length of A is x1
Increase in length of B is x2
Compression in spring x = x1 + x2
Spring force = kx
L A T0 x1
Strain in rod A =
L
LB T0 x 2
Strain in rod B =
L
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2
AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024
YA A L A T0 x1
Force on A FA
L
YB A LB T0 x 2
FB
L
FA = FB = kx (equal stress)
LT0 ( A B )
x
kL 1 1
1
A YA YB
4. D
3 2 t = t0
t0 O
Sol. Given 2 30 t 0
320
80
t0 sec 3 2
3 h t0
3200 2
h m
3
v = 3t0 = 80 m/s t=0
5. A
Sol. Height of water lands are 0.75 m and 0.25 m (for resonance)
v1 A
Av 2 av 2
v 2 2gH H
dH
a 2gH A
dt
t 66 sec
a
v2
6. A
Sol. Use concept of TIR
c
A
B c
7. B
Sol. Smallest main scale division = 0.05 cm
Diamter = Main scale reading + Vernier coincidence L.C.
= 5.10 + 24 0.001 = 5.124 cm
8. A
Sol. For central maxima optical path difference is zero.
9. C
Sol. Use Doppler’s effect
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3
AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024
10. D
Sol. The resultant dipole moment has magnitude
R 3R
( 3P)2 P2 2P at an angle
3R R A 2 , 2
, D
3P
1 2 2
tan 60 with positive direction
P 2p
Diameter AB is along net dipole moment and 60
diameter CD is normal to net dipole momet.
R 3R
Potential at A ,
2 2 C 3R R
B ,
R 3R 2 2
,
2 2 R/2
3R R 3R R
Potential is zero at C , and D ,
2
2 2 2
1 4p R 3R R 3R
Magnitude of electric field is at , and B ,
40 R3 2 2 2 2
1 2p 3R R 3R R
Magnitude of electric field is at C , and D ,
40 R3 2 2 2
2
11. D
Sol. In photoelectric effect
T = h
For A, TA 4.25 A
For B, TB 4.70 B
TB = TA 1.5
A h / 2mTA 1 TB
B h / 2mTB 2 TA
TA = 2eV, TB = 0.5 eV, A = 2.25 eV, B = 4.20 eV
SECTION – B
12. 13
Sol. C1C2 42 32 2 4 3cos 60 13 F
F
4cm
3cm
30 30
F
C1 C2 120 F
F
120
120
F
13. 1
Sol. Use concept of ampere’s law
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4
AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024
14. 1
1
Sol. mv 20 eV
2
eE edt C.M.
At instant t = t, acceleration of e
M M v0
2Ma2
Pitch = 9 mm B
4eBv
15. 1
Sol. T1 cos30 T2 sin30 mg
mv 2
T1 sin30 T2 cos 30 30
r
T1
3mv 2
T2 mg
r 30
gr T2
vmin 1 m/s 30
3
r
16. 16
mv 20 v0 v0/3 T
Sol. 3T 60
3 3 B T + 2T
mv 20 v0/3 v0 2v 0
T v0
9 C 3
v0/3 3
3
4v02 18 8
rC
9 3v 02 3
17. 2
Sol. d RdER sin
2 Ring (m, R)
2 2 RdE
0R E sin d
0
d
Sheet
2
1 cos 2
2
0R E d
2 0
= 0 R2E fs
fs = ma …(i) Rough surface
0 R2E fsR mR2
0 RE fs ma …(ii)
Solving equations (i) and (ii), we get
0 RE 2ma
0 RE 0 R
a E
2m 2m 20 20
0 R
a
4m 0
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5
AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024
Chemistry PART – II
SECTION – A
18. A, C
Sol. Balanced chemical equation
4Au 8KCN O2 2H2 O 4K Au CN2 4KOH
Weight of Au in 1 kg sample = 1.97 g
1.97
Moles 102
197
Moles of KCN required 2 10 2
Weight of KCN required 2 102 65
= 1.3 g.
19. A, B, C
NC OH HOOC OH
Sol. A: C , B=
Ph CH3 Ph CH3
COOH
COOH
C: , D = Ph C CH2 Br
Ph
H
COOH COOH O
E: , F=
Ph CH CH2 OH Ph CH C H
O
G:
Ph CH2 C H
20. B, D
Sol. At anode
Ni s Ni2 2e
At cathode
Ni2 2e Ni s
Mass of Ni electrode (cathode) increases.
Number of equivalent of Ni2 formed = number of equivalents of Ni2 lost.
No change in concentration of Ni2 in the electrolytic solution.
21. B
Sol. I and III are correct.
22. B
Sol. H2 O2 H2O
O 2 g colourless O2 Blue
Ca NO3 2 CaO NO2 O2
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024
23. D
Sol.
O
O
24. B
Sol.
C3H7NH2 HCl C3H7 NH3 Cl
Intial 2mmol 2mmol
at equivalencepoint 0 0 2mmol
1 2
pH 7 pK b log
2 40
6
25. B
Sol. Cr 2 HS d4 t 32g e1g
Mn3 LS d4 t 42g eog
Fe 2 HS d6 t 2g
4
e2g
Ni4 LS d6 t 62g eog
26. D
27. C
Sol. N2 O5 H2 O HNO3
N2 O3 H2 O HNO2
Cl2O7 H2O HClO4
Cl2 O H2 O
HClO
28. C
Sol. 4
O
O O
F F
Xe
Xe F
O O
F F O
O
F F F F
Xe Xe F
F F F F
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024
SECTION – B
29. 9375
960 103
Sol. Energy required for dissociation of N2 per molecule 16 1019 J / molecule
6 1023
Since each N-atom has 2 eV extra energy after photochemical dissociation.
Energy required for dissociation 16 10 19 2 1.6 10 19
19.2 10 19 J
hC
19.2 10 19 9375 1011 m.
x 9375
30. 6
Sol.
Br
Br
B C
A
O O
O O
F E D
1. O3 excess
2. H2 O2
O
C 6CO 2
2CH3 CH3
31. 2000
1 N
Sol. 500 n o
av Nt
1 No 2
500 n
N
av o av
8
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024
1
av
250
1 1
av
t t
1 1 1
250 t 400
2000
t years
3
x 2000
32. 3
Sol. PbS, CuS, CuO – Black
Sb3S2 – Orange
CdS – Yellow
Cu2O – Red
33. 1155
Sol. From the given data if is clear that reaction follows first order kinetics
t1/2 50 min
Partial pressure of X(g) remaining after 200 min
4
1
4 t1/2 600 37.5 mm Hg
2
2X g 2Y g 3Z g 4W s
Initial 600 0 0
3
t 200 min 600 P 37.5 P P
2
P 562.5
Total pressure after 200 min
3
= 600 P P P
2
3
600 562.5
2
= 1443.75 mm Hg.
4
Ptotal 1155
5
34. 3
Sol. B3N3H4 X2 has 4-isomer.
X X X
BH X
B X B B
HN N HN NH HN N HN N
HB BH HB B HB BH HB BH
NH NH X N N
X X
Borazon is crystalline form of boron nitride.
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024
SECTION – A
35. A, C, D
x2 y2 M(0, b)
Sol. 2
2 1 let c 2 a2 b2 c a 2 b 2
a b
FA = a – c FB = a + c FM = a = FN
Case-I:
If A, B are the left and figure vertices B(–a, 0) F(c, 0) A(a, 0)
respectively
Then, a + c = 3, a – c = 2 N(0, –b)
|AB| = 2a = 5
2
According b = (a + e)(a – c) = 6
4x2 y 2
So, then equation of ellipse is 1
25 6
Case-II:
Let A is left vertex and B is the top or bottom vertex, then a + c = 3, a = 2 and c = 1
Hence, b2 = a2 – c2 = 3
x2 y2
So, AB a 2 b 2 7 the corresponds of ellipse 1
4 3
Case-III:
If A is the top or bottom vertex and B is the right vertex, then a = 3, a – c = 2, c = 1
b2 = a2 – c2 = 8
AB a 2 b 2 17
36. A, B
Sol. Equation of circle is (x – 1)2 + (y – r)2 = r2 y
2
y2 y 2 2
Put x ; 1 y r r 2 (1, r)
4 4
2
r
y2 4 x
32y (1, 0)
By the given condition equation has just one positive
solution of which corresponds to the unique common point
between circle and parabola. We shall consider the
minimum value of
2
f y
y2 4
y 0
32y
3
4 4 4 4
Using AM·GM y2 + 4 = y 2 4 y2
3 3 3 3
3
1 4 4 3
f 4 16 y 2
32y 3 9
4 3 4
So, f(y) takes the minimum value if and only if y 2
9 3
2 3 4 3
y we get, r
3 9
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024
4 3 1 2 3
So, r is consistent with the given condition at this point , is a unique common
9 3 3
point between circle and parabola
37. A, B, C, D
Sol. f(x) is S.D. in (0, 3]
S.I. in [3, 9]
S.D. in [9, ) with f(3) = 0, f(9) = 1
a (0, 3), b (3, 9), c (9, )
Also, f(a) = f(b) = f(c) (0, 1)
As f(a) = f(b), then 1 – log3 a = log3 b – 1
log3 a + log3 b = 2 ab = 9 and abc = 9c
Since, 0 f c 4 c 1 c (9, 16)
abc = 9c (81, 144)
38. B
Sol. Use AM GM
(1 + 2a)(2 + 2b)(2a + b) 8 2a 4b 2ab 32ab
So, equally condition must be satisfied this means 2a = b = 1, so we have only one solution
Alternate solution:
2 2 2
(1 + 2a)(2 + 2b)(2a + b) = 32ab b 2a 1 2a b 1 2a b 0
1
Since, a, b > 0 2a – 1 = b – 1 = 2a – b = 0 (a, b) = , 1
2
39. D
1 3 i
Sol. The roots of z2 + z + 1 = 0 ; z
2
1 3 i 1 3 i 1 3 i 1 3 i
So, z 2 z 1 z z z z 4
2 2 2 2
1 3 1 3
Now let z = a + ib (we are trying to maximize b) a b i a b i 4
2 2 2 2
Since we are trying to maximize b, we want the real parts of the components to be as small as
1
possible which we can do by setting a
2
3 3 3 19 19
This leaves b b 4 b2 4 b2 b
2 2 4 4 2
40. B
Sol. These are 102 = 100 equally likely selection for array (a, b), let us consider the number of
2
selections say N that a + b is divisible by 3
If a is divisible by 3, then b is also divisible by 3. In this case, there are 3 selection for a, b
respectively, then the number of selection for (a, b) is 32 = 9
If a is not divisible by 3, then a2 – 1 is divisible by 3 and hence b + 1 is also divisible by 3, in this
37
case a has 7 selection and b has 4. So, that 28 outcomes probability =
100
41. D
x2 y2
Sol. 1 (a > b > 0)
a2 b1
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024
|AB| = 2a = 4, a a 2 b 2 AF 2 3 a = 2, b = 1, |EF| = 2 a2 b 2 2 3
|PE| + |PF| = 2a = 4 and |PE|·|PF| = 2
Then |PE|2 + |PF|2 = (|PE| + |PF|)2 – 2|PE|·|PF| = 12 = |EF|2
1
i.e., EPF is right angle PEF PE PF 1
2
42. D
Sol. Total number is 4 4! = 96
Permutation (2, 0, 1, 9, 2019)(2019, 2, 0, 1, 9)
Correspondence to the same number 20, 192019, while other are different
So, 96 – 1 = 95
43. B
Sol. (P) Let x = sin
/2 /2
sin2 ln sin cos 1 cos 2
d ln sin d 1 ln 4
0
cos 0
2 8
1 1
sin 1
x sin x 2 52
(Q) dx 10 dx 10
0 1 x
2
0 1 x2 8 4
3
3
(R) f x dx =
2
3
20 2
x x
(S) 2 sin dx = 10 2 sin dx
0
2 0
2
44. D
Sol. (P) f is differential in [0, 5] f(0) = 4, f(5) = –1
f x 4
gx , g 0 4
x 1 1
1
g 5
6
g 5 g 0 5
By LMVT g c
50 6
(Q) By LMVT
f 5 f 1 0 24
f c
5 1 4
c 24
25 c 2 4
(R) By LMVT on [1, 6]
f 6 f 1
f c
6 1
f(c) 2 f(6) 8
(S) f(x) and g(x) are differentiable for x [0, 1], f(0) = 2, g(0) = 0, f(1) = 6
f(c) – 2g(c) = 0 for some c (0, 1)
f(0) – 2g(0) = f(1) – 2g(1)
2 – 2 0 = 6 – 2g(1)
g(1) = 2
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024
45. B
Sol. (P) Use n Cr nCr 1 n 1
Cr
SECTION – B
46. 8321
12 12
2 2k 2k 1 k
2
Sol. 1
k 0 k 0
12
1 i k 1 i k
k 0
th
We consider the polynomial x13 1 0 whose roots are the 13 root of unity
Let 0 , 1, 2 , ....., 12 are the roots of this equation
x13 1 x 0 x 1 x 2 x 3 ..... x 12
Put x = 1 + i and 1 – i
12
1 i k 1 i k i
2e 4 k
2 e
i
4 k
k 0
13 13
2 e
i
4 1
2 e
i
4 13
i
13 13
i
1 2 2 e 4 1 2 2 e 4 1
13
13
213 1 2 2 2cos 213 1 27 8321
4
47. 18
Sol. If we use the product rule to calculate fn" x , the result is a sum of terms of two types, terms
where two distinct factors cos(m 1 x) and cos(m 2 x) have each been differentiated once, and terms
where a single factors cos(mx) has been differentiated twice. When we calculate at x = 0, all
terms of first type vanish since sin(0) = 0, while term of the second type involving (cos mx)
becomes (–m2), thus
n
n n 1 2n 1
fn" 0 m2
m 1 6
n n 1 2n 1
The function g n is increasing for n N and satisfy g(17) = 1785 and g(18) =
6
2109
So, n = 18
48. 1
Sol. For log7x 2023 log289x 2023 log2023 x 2023
log2023 7x log2023 289x log2023 2023x
Let log2023 x a
We get, log2023 7 a log2023 289 a 1 a
a2 log2023 7 log2023 289 a log2023 7 log2023 289 1 a
a 2 log2023 7 log2023 289 1 0 a1 + a2 = 0
log2023 x1 log2023 x 2 0 x1·x2 = 1
49. 5
Sol. Let the common difference = d
We know that a1 + a2 = ak (k is some positive integer)
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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024
50. 4
Sol. We have equation of circle (x – (r + 1))2 + y2 = r2
(a – r – 1)2 + b2 = r2 r2 – (a – r – 1)2 = b2
(r + a – r – 1)(r – a + r + 1) = b2 (a – 1)(2r – (a – 1)) = b2
2r(a – 1) – (a – 1)2 = b2 4a 2ra – 2r – (a2 – 2a + 1) – 4a 0
2ra – 2r – a2 + 2a – 1 – 4a 0 –a2 – 2a – 2r + 2ar – 1 0
a2 + 2a + 2r – 2ar + 1 0 a2 – 2a(r – 1) + 2r + 1 0
This equation has solution (2(r – 1))2 – 4(2r + 1) 0
4r(r – 4) 0 r 4, (a, b) = 3, 2 3 satisfy the given condition when r 4
Minimum value of r = 4
51. 51
n n r
Sol. x 2
y 1 n Cr x nr 2 y 1
r 0
4
So, coefficient of xn 4 is n C4 xn 4 2 y 1
1 4 n C4 n n 1 n 2 n 3 ..... (1)
24
n 1
Coefficient of xy, n Cn1x 2 y 1
n3
n
Cn1 n1C2 4 1 = (–1)n – 3 2n(n – 1)(n – 2) ..... (2)
From equation (1) and (2), we get n = 51
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