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This document contains the answers, hints, and solutions for the Physics and Chemistry sections of the FIITJEE All India Test Series for JEE (Advanced) 2024, specifically for Full Test XI, Paper 1. It includes detailed solutions for various physics problems, covering topics such as mechanics, optics, and electromagnetism, as well as chemistry problems involving chemical reactions and electrochemistry. The test date is set for May 19, 2024.

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0% found this document useful (0 votes)
15 views

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This document contains the answers, hints, and solutions for the Physics and Chemistry sections of the FIITJEE All India Test Series for JEE (Advanced) 2024, specifically for Full Test XI, Paper 1. It includes detailed solutions for various physics problems, covering topics such as mechanics, optics, and electromagnetism, as well as chemistry problems involving chemical reactions and electrochemistry. The test date is set for May 19, 2024.

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FIITJEE

ALL INDIA TEST SERIES


JEE (Advanced)-2024
FULL TEST – XI
PAPER –1
TEST DATE: 19-05-2024

ANSWERS, HINTS & SOLUTIONS


Physics PART – I

SECTION – A

1. A, B, D
0.5  0.56  0.57  0.54  0.59
Sol. Tm   0.55 sec
5
Tm  0.03
Tm
 5.45%
Tm

2. A, B, D
Sol. At equation
A0 v 02
kx 0 
2d2
Now, small shift ‘x’ has been given them
A0 v 02
Frestoring   k(x 0  x)
2(d  x)
Md3
T  2
kd3  A0 v 02

3. A, C
Sol. Increase in length of A is x1
Increase in length of B is x2
Compression in spring x = x1 + x2
Spring force = kx
L A T0  x1
Strain in rod A =
L
LB T0  x 2
Strain in rod B =
L

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024

YA A L A T0  x1 
Force on A  FA 
L
YB A LB T0  x 2 
FB 
L
FA = FB = kx (equal stress)
LT0 ( A  B )
x 
 kL  1 1 
1    
 A  YA YB  

4. D
3 2 t = t0
t0 O
Sol. Given  2  30  t 0
320
80
t0  sec 3 2
3 h t0
3200 2
h m
3
v = 3t0 = 80 m/s t=0

5. A
Sol. Height of water lands are 0.75 m and 0.25 m (for resonance)
v1 A
Av 2  av 2
v 2  2gH H
 dH 
a 2gH  A   
 dt 
 t  66 sec
a
v2

6. A
Sol. Use concept of TIR
c
A 

 
B c

7. B
Sol. Smallest main scale division = 0.05 cm
Diamter = Main scale reading + Vernier coincidence L.C.
= 5.10 + 24  0.001 = 5.124 cm

8. A
Sol. For central maxima optical path difference is zero.

9. C
Sol. Use Doppler’s effect

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024

10. D
Sol. The resultant dipole moment has magnitude
R 3R
( 3P)2  P2  2P at an angle
 3R R  A  2 , 2 
  , D  
3P
1 2 2 
  tan  60 with positive direction 
P 2p
Diameter AB is along net dipole moment and 60
diameter CD is normal to net dipole momet.
R 3R 
 Potential at A  ,
 2 2  C  3R R
  B  , 
 R 3R  2 2 
  ,  
 2 2  R/2

 3R R   3R R 
Potential is zero at C  ,   and D   , 
 2 
2  2 2 
 
1 4p R 3R   R 3R 
Magnitude of electric field is at  ,  and B   ,  
40 R3 2 2   2 2 

1 2p  3R R   3R R 
Magnitude of electric field is at C  ,   and D   , 
40 R3 2  2 2 
 2 

11. D
Sol. In photoelectric effect
T = h  
For A, TA 4.25 A
For B, TB 4.70 B
TB = TA  1.5
 A h / 2mTA 1 TB
  
B h / 2mTB 2 TA
TA = 2eV, TB = 0.5 eV, A = 2.25 eV, B = 4.20 eV

SECTION – B

12. 13
Sol. C1C2  42  32  2  4  3cos 60  13 F
F
4cm
3cm
30 30
F
C1 C2 120 F
F
120
120
F

13. 1
Sol. Use concept of ampere’s law

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024

14. 1
1 
Sol. mv 20  eV
2
eE edt C.M.
At instant t = t, acceleration of e  
M M v0
2Ma2
Pitch =  9 mm B
4eBv

15. 1
Sol. T1 cos30  T2 sin30  mg
mv 2
T1 sin30  T2 cos 30  30
r
T1
3mv 2
T2  mg 
r 30
gr T2
vmin   1 m/s 30
3
r

16. 16
mv 20 v0 v0/3 T
Sol. 3T  60
3 3 B T + 2T
mv 20 v0/3 v0 2v 0
T v0
9 C 3
v0/3 3
3
4v02  18 8
rC  
9  3v 02 3

17. 2
Sol. d  RdER sin 
2 Ring (m, R)
2 2 RdE

   0R E sin d
0
d

Sheet 

2
 1  cos 2  
2
  0R E   d 
 2  0
 = 0 R2E fs
fs = ma …(i) Rough surface
0 R2E  fsR  mR2 
0 RE  fs  ma …(ii)
Solving equations (i) and (ii), we get
0 RE  2ma
0 RE 0 R    
a   E  
2m 2m 20  20 
0 R
a
4m 0

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024

Chemistry PART – II

SECTION – A

18. A, C
Sol. Balanced chemical equation
4Au  8KCN  O2  2H2 O  4K  Au  CN2   4KOH
Weight of Au in 1 kg sample = 1.97 g
1.97
Moles   102
197
 Moles of KCN required  2  10 2
Weight of KCN required  2  102  65
= 1.3 g.

19. A, B, C
NC OH HOOC OH

Sol. A: C , B=
Ph CH3 Ph CH3
COOH
COOH
C: , D = Ph C CH2 Br
Ph
H
COOH COOH O
E: , F=
Ph CH CH2 OH Ph CH C H
O
G:
Ph CH2 C H

20. B, D
Sol. At anode
Ni  s   Ni2   2e
At cathode
Ni2   2e   Ni  s 
 Mass of Ni electrode (cathode) increases.
 Number of equivalent of Ni2  formed = number of equivalents of Ni2  lost.
 No change in concentration of Ni2  in the electrolytic solution.

21. B
Sol. I and III are correct.

22. B
Sol. H2 O2  H2O
O 2  g  colourless O2     Blue
Ca NO3  2  CaO  NO2  O2

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024

23. D
Sol.

will not be stabilized by resonance.

O
O

24. B
Sol. 
C3H7NH2  HCl  C3H7 NH3 Cl
Intial 2mmol 2mmol 
at equivalencepoint 0 0 2mmol
1  2 
pH  7  pK b  log  
2  40  
6

25. B
Sol. Cr 2  HS   d4  t 32g e1g
Mn3 LS   d4  t 42g eog
Fe 2 HS   d6  t 2g
4
e2g
Ni4 LS   d6  t 62g eog

26. D

27. C
Sol. N2 O5  H2 O  HNO3
N2 O3  H2 O  HNO2
Cl2O7  H2O  HClO4
Cl2 O  H2 O 
 HClO

28. C
Sol. 4
O
O O
F F

Xe
Xe F

O O
F F O
O
F F F F

Xe Xe F

F F F F

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024

SECTION – B

29. 9375
960  103
Sol. Energy required for dissociation of N2 per molecule   16  1019 J / molecule
6  1023
Since each N-atom has 2 eV extra energy after photochemical dissociation.
 Energy required for dissociation  16  10 19  2  1.6  10 19
 19.2  10 19 J
hC
 19.2  10 19    9375  1011 m.

x  9375

30. 6
Sol.
Br


 



Br

B   C
A

O O

 

O O
F E D

1. O3  excess 
2. H2 O2

O
C  6CO 2
2CH3 CH3

31. 2000
1 N 
Sol. 500  n  o 
av  Nt 
 
1  No  2
500  n  
N
av  o   av
 
 8 

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024

1
av 
250
1 1
av        
t  t
1 1 1
 
250 t  400
2000
t  years
3
 x  2000
32. 3
Sol. PbS, CuS, CuO – Black
Sb3S2 – Orange
CdS – Yellow
Cu2O – Red
33. 1155
Sol. From the given data if is clear that reaction follows first order kinetics
t1/2  50 min
Partial pressure of X(g) remaining after 200 min
4
1
 4  t1/2   600     37.5 mm Hg
2
2X  g  2Y  g  3Z  g  4W  s 

Initial 600 0 0 
3
t  200 min 600  P  37.5 P P
2
 P  562.5
Total pressure after 200 min
3
= 600  P  P  P
2
3
 600   562.5
2
= 1443.75 mm Hg.
4
Ptotal  1155
5

34. 3
Sol. B3N3H4 X2 has 4-isomer.
X X X
BH X
B X B B
HN N HN NH HN N HN N

HB BH HB B HB BH HB BH
NH NH X N N

X X
Borazon is crystalline form of boron nitride.

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024

Mathematics PART – III

SECTION – A

35. A, C, D
x2 y2 M(0, b)
Sol. 2
 2  1 let c 2  a2  b2  c  a 2  b 2
a b
FA = a – c  FB = a + c  FM = a = FN
Case-I:
If A, B are the left and figure vertices B(–a, 0) F(c, 0) A(a, 0)
respectively
Then, a + c = 3, a – c = 2 N(0, –b)
|AB| = 2a = 5
2
According b = (a + e)(a – c) = 6
4x2 y 2
So, then equation of ellipse is  1
25 6
Case-II:
Let A is left vertex and B is the top or bottom vertex, then a + c = 3, a = 2 and c = 1
Hence, b2 = a2 – c2 = 3
x2 y2
So, AB  a 2  b 2  7 the corresponds of ellipse  1
4 3
Case-III:
If A is the top or bottom vertex and B is the right vertex, then a = 3, a – c = 2, c = 1
b2 = a2 – c2 = 8
AB  a 2  b 2  17

36. A, B
Sol. Equation of circle is (x – 1)2 + (y – r)2 = r2 y
2
y2  y 2  2
Put x  ;   1   y  r   r 2 (1, r)
4  4 
2

 r
 y2  4  x
32y (1, 0)
By the given condition equation has just one positive
solution of which corresponds to the unique common point
between circle and parabola. We shall consider the
minimum value of
2

f y 
 y2  4 
 y  0
32y
3
4 4 4 4
Using AM·GM y2 + 4 = y 2     4 y2  
3 3 3 3
3
1 4 4 3
f 4   16  y 2   
32y 3 9
4 3 4
So, f(y) takes the minimum value if and only if y 2 
9 3
2 3 4 3
 y we get, r 
3 9

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024

4 3 1 2 3
So, r  is consistent with the given condition at this point  ,  is a unique common
9 3 3 
point between circle and parabola

37. A, B, C, D
Sol. f(x) is S.D. in (0, 3]
 S.I. in [3, 9]
 S.D. in [9, ) with f(3) = 0, f(9) = 1
 a  (0, 3), b  (3, 9), c  (9, )
Also, f(a) = f(b) = f(c)  (0, 1)
As f(a) = f(b), then 1 – log3 a = log3 b – 1
 log3 a + log3 b = 2  ab = 9 and abc = 9c
Since, 0  f  c   4  c  1  c  (9, 16)
abc = 9c  (81, 144)

38. B
Sol. Use AM  GM
(1 + 2a)(2 + 2b)(2a + b)  8 2a  4b  2ab  32ab
So, equally condition must be satisfied this means 2a = b = 1, so we have only one solution
Alternate solution:
2 2 2
(1 + 2a)(2 + 2b)(2a + b) = 32ab  b  2a  1  2a  b  1   2a  b   0
1 
Since, a, b > 0  2a – 1 = b – 1 = 2a – b = 0  (a, b) =  , 1
2 

39. D
1 3 i
Sol. The roots of z2 + z + 1 = 0 ; z  
2
  1  3 i     1  3 i    1  3 i   1  3 i 
So, z 2  z  1   z    z     z     z  4
  2   2   2   2 
1  3 1  3
Now let z = a + ib (we are trying to maximize b)  a  b  i a   b  i  4
2  2  2  2 
Since we are trying to maximize b, we want the real parts of the components to be as small as
1
possible which we can do by setting a  
2
3 3 3 19 19
This leaves b  b  4  b2   4  b2   b
2 2 4 4 2

40. B
Sol. These are 102 = 100 equally likely selection for array (a, b), let us consider the number of
2
selections say N that a + b is divisible by 3
If a is divisible by 3, then b is also divisible by 3. In this case, there are 3 selection for a, b
respectively, then the number of selection for (a, b) is 32 = 9
If a is not divisible by 3, then a2 – 1 is divisible by 3 and hence b + 1 is also divisible by 3, in this
37
case a has 7 selection and b has 4. So, that 28 outcomes probability =
100

41. D
x2 y2
Sol.   1 (a > b > 0)
a2 b1

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024

|AB| = 2a = 4, a  a 2  b 2  AF  2  3  a = 2, b = 1, |EF| = 2 a2  b 2  2 3
 |PE| + |PF| = 2a = 4 and |PE|·|PF| = 2
Then |PE|2 + |PF|2 = (|PE| + |PF|)2 – 2|PE|·|PF| = 12 = |EF|2
1
i.e., EPF is right angle PEF  PE  PF  1
2

42. D
Sol. Total number is 4  4! = 96
Permutation (2, 0, 1, 9, 2019)(2019, 2, 0, 1, 9)
Correspondence to the same number 20, 192019, while other are different
So, 96 – 1 = 95

43. B
Sol. (P) Let x = sin 
 /2  /2
sin2   ln  sin   cos    1  cos 2   
 d     ln sin   d  1  ln 4 
0
cos  0
2  8
 1 1
 sin 1 
x sin x  2  52
(Q)  dx  10  dx  10    
0 1  x
2
0 1  x2  8  4
3
3
(R)  f  x  dx = 
2
3
20 2
x  x 
(S)  2 sin dx = 10 2  sin   dx
0
2 0
 2 

44. D
Sol. (P) f is differential in [0, 5] f(0) = 4, f(5) = –1
f x 4
 gx   , g 0   4
x 1 1
1
 g 5  
6
g 5   g 0  5
By LMVT g  c   
50 6
(Q) By LMVT
f  5   f 1 0  24
f c   
5 1 4
c  24
 
25  c 2 4
(R) By LMVT on [1, 6]
f  6   f 1
f  c  
6 1
 f(c)  2  f(6)  8
(S) f(x) and g(x) are differentiable for x  [0, 1], f(0) = 2, g(0) = 0, f(1) = 6
 f(c) – 2g(c) = 0 for some c  (0, 1)
 f(0) – 2g(0) = f(1) – 2g(1)
 2 – 2  0 = 6 – 2g(1)
 g(1) = 2

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024

45. B
Sol. (P) Use n Cr  nCr 1  n 1
Cr

SECTION – B

46. 8321
12 12
  2  2k  2k     1  k  
2
Sol. 1
k 0 k 0
12
   1  i  k   1  i  k 
k 0
th
We consider the polynomial x13  1  0 whose roots are the 13 root of unity
Let 0 , 1, 2 , ....., 12 are the roots of this equation
 x13  1   x  0  x  1  x  2  x  3  .....  x  12 
Put x = 1 + i and 1 – i


12
  1  i  k   1  i  k    i
2e 4  k

 2 e
i

4  k 
k 0

  13   13 
   2 e
i
4  1
  2 e
i
4 13
i

13  13
i
 1  2 2  e 4  1 2 2  e 4  1
13 

13

 213  1  2 2  2cos  213  1  27  8321
4

47. 18
Sol. If we use the product rule to calculate fn"  x  , the result is a sum of terms of two types, terms
where two distinct factors cos(m 1 x) and cos(m 2 x) have each been differentiated once, and terms
where a single factors cos(mx) has been differentiated twice. When we calculate at x = 0, all
terms of first type vanish since sin(0) = 0, while term of the second type involving (cos mx)
becomes (–m2), thus
n
n  n  1 2n  1
fn"  0     m2 
m 1 6
n n  1 2n  1

The function g  n   is increasing for n  N and satisfy g(17) = 1785 and g(18) =
6
2109
So, n = 18
48. 1
Sol. For log7x 2023  log289x 2023  log2023 x 2023
 log2023 7x  log2023 289x  log2023 2023x
Let log2023 x  a
We get,  log2023 7  a log2023 289  a   1  a
 a2   log2023 7  log2023 289  a  log2023 7  log2023 289  1  a
 a 2  log2023 7  log2023 289  1  0  a1 + a2 = 0
log2023 x1  log2023 x 2  0  x1·x2 = 1

49. 5
Sol. Let the common difference = d
We know that a1 + a2 = ak (k is some positive integer)

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AITS-FT-XI (Paper-1)-PCM(Sol.)-JEE(Advanced)/2024

 2a1 + d = a1 + (k – 1)d i.e. a1 = (k – 2)d


a
 d 1 ,k  2
k2
n 1
Hence, an = a1 + (n – 1)d = a1   a1
k2
So, for any positive integer n1
n n  1  n  n  1 
a1 + a2 + ....., an = a1  n   d = a1    n  1  k  2   d
2  2 
The above is really a term in {an} therefore, we only need to consider the number of positive
a1
integer k such that is integer
k  2 
Note that 2019 is a product of primes 3 and 673, then it is easy to find that the values of k – 2 are
–1, 1, 3, 673, 2019 which corresponds to 5 AP

50. 4
Sol. We have equation of circle (x – (r + 1))2 + y2 = r2
 (a – r – 1)2 + b2 = r2  r2 – (a – r – 1)2 = b2
(r + a – r – 1)(r – a + r + 1) = b2  (a – 1)(2r – (a – 1)) = b2
2r(a – 1) – (a – 1)2 = b2  4a  2ra – 2r – (a2 – 2a + 1) – 4a  0
2ra – 2r – a2 + 2a – 1 – 4a  0  –a2 – 2a – 2r + 2ar – 1  0
a2 + 2a + 2r – 2ar + 1  0  a2 – 2a(r – 1) + 2r + 1  0
This equation has solution (2(r – 1))2 – 4(2r + 1)  0
4r(r – 4)  0  r  4, (a, b) =  3, 2 3  satisfy the given condition when r  4
Minimum value of r = 4

51. 51
n n r
Sol. x  2  
y  1   n Cr  x nr  2 y  1 
r 0
4
So, coefficient of xn  4 is n C4  xn 4   2 y  1
   
 1 4  n C4  n n  1 n  2 n  3 ..... (1)
24
n 1
Coefficient of xy, n Cn1x  2 y  1
n3
n
Cn1  n1C2 4  1 = (–1)n – 3 2n(n – 1)(n – 2) ..... (2)
From equation (1) and (2), we get n = 51

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