7 C 309 Fef
7 C 309 Fef
VISION
1
Laguna University shall be a socially responsive
educational institution of choice providing holistically
developed individuals in the Asia-Pacific Region.
MISSION
Laguna University is committed to produce academically
prepared and technically skilled individuals who are
socially and morally upright citizens.
VISION
The Department of Mechanical Engineering of Laguna
University is envisioned to be the provincial college of
choice producing well-equipped mechanical engineers who
specializes on energy management.
2
Table of Contents
3
Course Code: ME 204
Course Requirements:
Computation of Grades:
MIDTERM GRADE = 30%(Prelim Grade) + 70 %[60% Class Standing) + 40% (Midterm exam)] =
30%(Midterm Grade) + 70 %[60% (Class Standing) + 40% (Final exam)]
FINAL GRADE
4
MODULE 1
FUELS AND COMBUSTION
Introduction
Fuel is any substance or combustible material that by rapid oxidation or burning produces
heat and light. An example of a fuel is coal or gasoline. A fuel is composed of chemical elements
which, in rapid chemical union with oxygen, produce combustion. Fossil fuels are fuels that originate
from the earth as a result of the slow decomposition and chemical conversion of organic material.
The basic forms of fossils are solid (coal), liquid (oil), and natural gas. Synthetic fuels or synfuels, the
new combustible-fuel-options, are liquid or gaseous fuels derived largely from coal, oil shale, and tar
sands (Francisco, 2014).
Learning Outcomes
1. Define what fuels is, and determine the different classification of Fuels;
1
Lesson 1. Classification of Fuels
1. Solid Fuels
a. Natural solid fuels. Ex. Coal, wood, bagasse
b. Prepared or manmade. Ex. Charcoal, coke, briquette fuels
2. Liquid Fuels
a. Hydrocarbon (Cn Hm )
i. Gasoline – Octane, C8 H18
ii. Diesel – Hexadecadene, C16 H32
iii. Fuel oil – Dodecane, C12 H26
b. Alcohol (Cx Hy Oz )
i. Ethyl alcohol
ii. Methyl alcohol
c. Alcogas (70% alcohol and 30% ethanol)
d. Methanol (Liquid Coal)
3. Gaseous Fuels
a. Natural Gas Derivatives
i. Methane, CH4
ii. Propane, C3 H8
iii. Ethane, C2 H6
iv. Acetylene, C2 H2
b. Liquid Petroleum Gas (LPG)
c. Biogas (Animal waste gas)
Crude Oil
Crude oil is the term used from the raw petroleum as it comes from the oil wells (Francisco,
2014).
1. Paraffin Base
2. Napthenic Base
2
3. Mixed Base
1. Natural gas
The gaseous hydrocarbons are usually associated with liquid petroleum, either
standing above the liquid in the earth or dissolved in it.
2. Gasoline
Liquid petroleum fuel intended for use in spar-ignition engines. Specific gravity is 0.70
to 0.78
3. Kerosene
The next fraction heavier than gasoline
Intended for use in lamps, heaters, stoves, and similar appliances
Excellent fuel for compression-ignition engines and for aircraft gas turbines
Specific gravity is 0.78 to 0.85
4. Distillate
Slightly heavier than kerosene
Obtained from some Western United States crude by distillation at atmospheric
pressure
Substantially the same uses as a kerosene
5. Diesel Fuel
Petroleum fractions that lie between kerosene and lubricating oils
It covers a wide range of specific gravity
Composition is controlled to make them suitable for use in various types of CI engines.
6. Fuel oils
Covers a wide range of specific gravity
Distillation is similar to that of Diesel oils
Its compositions do not require such accurate control as in Diesel oils for it is used in
continuous burners.
7. Lubricating oils
Made up in part from heavy distillates of petroleum and in part from residual oil, that is,
oils remaining after distillation. Tar and asphalt are solid or semi-solid products that
remain undistilled.
3
Compositions of Petroleum Products from Francisco (2014)
The common or main compositions of petroleum products are carbon and hydrogen
Hydrocarbon is the combination of carbon and hydrogen
The general formula is Cn Hm , where n = 1 to 26 and m = 2 to 54
Lesson 2. Hydrocarbons
Cracking is the process of splitting hydrocarbon molecules into smaller molecules. It is used
to obtain lighter hydrocarbons (such as used in gasoline) from heavy hydrocarbons (say,
Crude oil)
o Ex. Alkane molecules crack into a smaller member of the alkane subfamily and a
member of the alkene subfamily.
Cracking can proceed under the influence of high temperatures (thermal cracking) or
catalysts (catalytic cracking or “cat cracking”).
Catalytic Cracking also produces gasoline with better antiknock properties than does
thermal cracking.
4
Gaseous Fuels
1. Natural Gas
Obtained from oil wells
It is called a casing-head gas
Usually treated for gasoline recovery
It is delivered into the pipeline system to be used as fuel
2. Coke-oven Gas
Obtained as a by-product when making coke
Its analysis depends into the pipeline system to be used as fuel
Coke; typically used in blast furnaces, is produced by heating coal in the
absence of oxygen. The heavy hydrocarbons crack, leaving only a
carbonaceous residue containing ash and sulfur. Coke burns smokelessly.
Breeze is coke smaller than 5/8 inch (16 mm). it is not suitable for use in blast
furnaces, but steam boilers can be adapted to use it. Char is produced from coal
in 900 °F (500°C) carbonization process.
3. Blast-Furnace Gas
A by-product of melting iron ore
4. Produces Gas
5. Sewage-Sludge Gas
Obtained from sewage disposal plants
5
Lesson 3. Properties of Diesel Engine
Density – the mass per unit volume of the fuel, in kg/li, kg/m3 , or lb/Ft 3
𝒎
𝝆=
𝑽
𝟏𝟒𝟎
°𝐁𝐚𝐮𝐦𝐞 = 𝟏𝟓.𝟔 °𝐂
− 𝟏𝟑𝟎
𝐒𝐆 𝐚𝐭 ( )
𝟏𝟓.𝟔 °𝐂
𝟏𝟒𝟏. 𝟓
°𝐀𝐏𝐈 = 𝟏𝟓.𝟔 °𝐂
− 𝟏𝟑𝟏. 𝟓
𝐒𝐆 𝐚𝐭 (𝟏𝟓.𝟔 °𝐂)
Coefficient of Volumetric Expansion – a coefficient used in oil purchasing and storage, since
oil is bought by volume usually expressed in terms of 42-gallons barrels.
𝐕𝐭 = 𝐕𝐨 [𝟏 + 𝟎. 𝟎𝟎𝟎𝟕(𝐭 − 𝐭 𝐨 )] → 𝐒𝐈 𝐔𝐧𝐢𝐭
6
t = temperature, °F
Vo = volume at a temperature t o , (usually 15.6 °F), m3 , li
Coefficient = 0.0007/°C
Solution:
𝟏𝟒𝟏.𝟓
For SG at 60°F, °API = 𝟏𝟓.𝟔 °𝐂 − 131.5
𝐒𝐆 𝐚𝐭 ( )
𝟏𝟓.𝟔 °𝐂
60 °F 141.5 141.5
SG at ( )= = = 𝟎. 𝟖𝟖𝟕
60 °F °API + 131.5 28 + 131.5
60 °F
ρ60°F = ρwater@60°F (Sg @ 60 °F) = 62.4(0.887) = 𝟓𝟓. 𝟑𝟓 𝐥𝐛/ f𝐭 𝟑
55.35
ρ40°F = 0.992 = 𝟓𝟓. 𝟖 𝐥𝐛/f𝐭 𝟑
t = 40 °F = 4.44°C
m m
Vt = Vo [1 + 0.0007(t − t o )] → = [1 + 0.0007(t − t o )]
ρt ρo
ρo 0.887 𝐤𝐠
ρt = = = 𝟎. 𝟖𝟗𝟒
[1 + 0.0007(t − t o )] [1 + 0.0007(4.44 − 15.6)] 𝐥𝐢
7
Viscosity – property of Diesel fuel used to measure its resistance to flow. It is a fair indication
of how the oil will atomize and how it will affect the injection pump.
o Absolute viscosity, µ
µ
o Kinematic Viscosity – the ratio of absolute viscosity to that of the density, v =
ρ
Heating Value – refers to the heat content of the fuel in a unit mass. The heating value of a
liquid fuel is ranging from 18 000 to 19 500 Btu/lb. An instrument or apparatus used to
determine the heating value of a fuel is known as Bomb or Sergent Calorimeter. Heating
value is also called as Calorific Value.
Higher Heating Value (HHV) is the heating value obtained when the moisture or water
ASME formula:
8
Sherman and Knoff Formula:
Flash Point and Fire Point – the temperature at which oil vapor flashes or burns steadily;
used in relation to ignition and storage hazards of oil.
Pour point – the lowest temperature at which oil flows; used in pumping and flow of oils. It is
more important to the fuel for mobile engines whose fuel tanks are generally exposed and
unheated that for stationary units.
Color is sometime specified on the basis that good color indicates clean fresh stock of
satisfactory volatility.
Purity. Although oils is a relatively pure fuel it may contain some sediment and water, ash, or
sulfur, all of which are undesirable impurities and are limited to low permissible amounts in
specifications. Sediment and water are determined by eluting the fuel with benzol and
centrifuging. They are reported together, sometimes by the number B.S. and W., meaning
bottom sediment and water.
Sulfur Content – in weight percentage; useful with reference to corrosion of plant equipment.
Specific Heat – varies with temperature but for usual values is about 0.4 to 0.5 Btu/lb-F; used
in heating problems.
Carbon Residue – test indicating carbon forming characteristics of oil; used in oil burning.
9
Coal from Francisco (2014)
Coal – is a solid fuel which is a mixture of carbon, hydrogen, oxygen, nitrogen, sulfur, ash,
and moisture. It is believed that the coal once existed primarily as vegetable matter.
Coal is a general term that encompasses a large number of solid organic minerals with widely
differing compositions of properties, although all are essentially rich in amorphous (without
Coal has these components distributed throughout its mass: a) coal substance, b) mineral
The mineral matter to some extent was in the original vegetable fibers. Water, which
percolated through the peat, bogs and coal seams, contained dissolved salts and deposited
most of the mineral content of the coal.
The moisture content of coals, of ten called “mechanical moisture”, means water retained by
coal.
There are many ways of classifying coal according to its chemical and physical properties.
The most accepted system is that one used by the American Society for Testing and
Materials (ASTM), which classifies coals by grade or rank according to the degree of
metamorphism (change in form and structure under the influences of heat, pressure, and
water), ranging from the lowest state (lignite) to the highest (anthracite)
These classifications are briefly described below in descending order:
1. Anthracite coal
10
Contains a high content, 86% to 98% by mass, of fixed carbon on a dry, mineral-
Non-coking
Note:
into diamond, imperfectly into graphite and is amorphous (having no regular structure,
non-crystalline) in anthracite and charcoal.
o The anthracite rank of coal is subdivided into three groupings, in descending of fixed-
carbon percent, as follows:
Metha-anthracite, greater than 90%
Anthracite, 92 % to 98%
Semi-anthracite, 86% to 92%
2. Semi-anthracite coal
Less luster
11
3. Semi-bituminous coal
4. Bituminous coal
Low grade bituminous coal which has lost the woody, structural appearance of
lignites
Disintegrates when exposed to the air and requires careful attention during
storage
6. Lignites coal
The transition state between peat and the sub-bituminous grade
Have a woody or offer a claylike appearance
With low heating value
Contains 30 to 45 % moisture
12
o It is a heterogeneous material consisting of decomposed plant matter
1. Coal substance – part of coal consisting of organic compounds of carbon, hydrogen, and
wood.
3. Moisture Content – referred to as mechanical moisture and means water as such retained by
the coal.
1. Heating Value or Calorific Value – the equivalent heat content in a unit mass fuel; determined
O2
HHV = 33 820C + 144212 (H2 − ) + 9304S → kJ/kg
8
O2
HHV = 14544C + 62028 (H2 − 8
) + 4050S → Btu/lb
LHV = HHV – QL
13
mH2 = mass of original hydrogen per unit mass of fuel, known from ultimate
analysis.
hfg = latent heat of vaporization of water vapor at its partial pressure in the
combustion products, Btu/lbm H2 O or kJ/kg H2 O
4. Coking – refers to the ability of the coal, when heated, to evolve volatile matter
5. Caking
6. Free-burning
7. Friability
8. Clinkering
Note:
o Coke is the solid substance remaining after the partial burning of coal in an even or
14
Lesson 5. Coal Analysis
According to Francisco (2014) there are two types of coal analysis: proximate and ultimate, both
o “Dry Mineral-Matter-Free Basis”, circumvents the problem of the ash contents not
being the same as the mineral matter in coal.
This is the easier of the two types of coal analysis and the one which, supplied readily
It determines the mass percentages of fixed carbon, volatile matter, moisture, and ash.
original sample and the sum of volatile matter, moisture, and ash.
o It is that portion of coal, other than water vapor, which is driven off when the sample is
heated in the pre absence of oxygen in a standard test (up to 1750 °F for 7 minutes)
15
o It consists of hydrocarbon and other gases that result from distillation and
decomposition.
o this does not account for all the water present, which includes combined water and
water of hydration
o there are several other terms for moisture in coal. One, inherent moisture, is that,
existing in the natural state of coal and considered to be part of the deposit, excluding
surface water.
o It forms oxides which combine with water to form acids. These cause corrosion
problem in the back end of steam generators if the gases are cooled below the dew
point, as well as environmental problems.
It is a special type of gravimetric analysis in which the constituents are reported by atomic
In this analysis, combined hydrogen from moisture in the fuel is added to hydrogen from
16
It is an analysis showing the chemical elements of coals such as carbon, hydrogen,
oxygen, nitrogen, sulfur, ash, and moisture. Elements are presented in percentage by
weight.
C – Carbon
H – Hydrogen
O – Oxygen
N – Nitrogen
S - Sulfur
A – Ash
W – Moisture
C + H + O + N + S + A + W = 100%
C+ H + O + N + S + A = 100 %
C+ H + O + N = 100 %
Note:
o The first basis, as fired, is of most use to the power-plant operator because it shows
the constituents of the fuel in the same condition as it was weighed and supplied to the
furnace.
o The remaining methods are used primarily for comparing coals from various sources.
17
remaining constituents by one minus the decimal equivalent of the moisture. A similar
C = 80.50 % S = 1.20 %
H = 4.10 % A = 5.30 %
O = 3.00 % W = 4.40 %
N = 1.50 %
Solution:
Dry-basis Analysis:
80.50 4.10
C = 0.956 = 84.20 % H = 0.956 = 4.30 %
3.00 1.50
O= = 3.10 % N= = 1.60 %
0.956 0.956
1.20 5.30
S = 0.956 = 1.30 % A = 0.956 = 5.50 %
Then the sum of the components:
C+ H + O + N + S + A = 100 %
18
80.50 4.10
𝐶 = 0.903 = 89.20 % 𝐻 = 0.903 = 4.50 %
3.00 1.50
𝑂 = 0.903 = 3.30 % 𝑁= 0.903
= 1.70 %
1.20
𝑆= = 1.30 %
0.903
C+ H + O + N + S = 100%
2. Convert the ultimate analysis of coal shown in the table below to a) an ultimate analysis showing
the amount of moisture (“as-received”), b) moisture-free basis, c) moisture and ash-basis, and d)
moisture, ash, and sulfur-free basis. Determine the heating value in each case.
Total = 100 %
𝑂2
HHV = 14600C + 62000(𝐻2 − ) + 4050𝑆
8
0.0886
HHV = 14600(0.6623)+6200(0.0425 − ) + 4050(0.0075)
8
19
HHV = 11648.305 Btu/lb
HV = 12 909.165 Btu/lb
66.23 81.16 %
C=
0.816
4.25 5.21 %
H2 =
0.816
8.86 10.86 %
O2 =
0.816
1.51 1.85 %
N2 =
0.816
20
0.75 0.92 %
S=
0.816
TOTAL 100.00 %
O2
HV = 14600C + 62000 (H2 − 8
) + 4050S
0.1086
HV = 14600(0.8116) + 62000 (0.0521 − 8
) + 4050(0.0092)
HV = 14 275.17 Btu/lb
66.23 81.92 %
C=
0.8085
4.25 5.26 %
H2 =
0.8085
8.86 10.96 %
O2 =
0.8085
1.51 1.87 %
N2 =
0.8085
TOTAL 100.00 %
HV = 14 372.12 Btu/lb
21
Lesson6.Combustion
Combustion is the rapid chemical union with oxygen of an element in which the exothermic
heat of reaction is sufficiently great and the rate of reaction is sufficiently fast that useful
quantities of heat are liberated at elevated temperature.
Combustion is synonymous with oxidation and is the union of oxygen with a combustible
material.
1. Components By Weight
𝐍𝟐 = 𝟕𝟔. 𝟗 % 𝐚𝐧𝐝 𝐎𝟐 = 𝟐𝟑. 𝟏 %
2. Components By Volume
𝐍𝟐 = 𝟕𝟗 % 𝐚𝐧𝐝 𝐎𝟐 = 𝟐𝟏 %
3. Air Gas Constant
R = 0.28708 kJ/kg-°K
4. Molecular Weight or Mass
MW = 28.95 kg/kgmol = 28.95 lb/pmol
The following equations are the combustion chemistry of combustible components of the fuel.
Analysis by weight
12 kg C + 32 kg O2 = 44 kg CO2
8 11
1 kg C + ( ) kg O2 = ( ) kg CO2
3 3
Oxygen required for 1 kg C
8
Woc = 3 kg C/ kgO2
Molal Analysis
1 mole C + 1 mole O2 = 1 mole CO2
22
2. Combustion of Hydrogen, 2H2 + O2 = 2H2 O
Analysis by weight
4 kg H2 + 32 kg O2 = 36 kg H2 O
1 kg H2 + 8 kg O2 = 9 kg H2 O
Oxygen required for 1 kg H2
WOH2 = 8 kg H2 /kg O2
Molal Analysis
2 moles H2 + 1 mole O2 = 2 moles H2 O
1
1 mole H2 + mole O2 = 1 mole H2 O
2
3. Combustion of Sulfur, S + O2 = SO2
Analysis by Weight
32 kg S + 32 kg O2 = 64 kg SO2
1 kg S + 1 kg O2 = 2 kg SO2
Oxygen required for 1kg sulfur
WOS =1 kg S/ kg O2
Molal Analysis
1 mole S + 1 mole O2 = 1 mole SO2
4. Incomplete Combustion of Carbon, 2 C + O2 = 2 CO
Analysis by Weight
24 kg C + 32 kg O2 = 56 kg CO
4 7
1 kg C + ( ) kg O2 = ( ) kg CO
3 4
4
WOC = kg C/kg O2
3
Molal Analysis
2 moles C + 1 mole O2 = 2 moles CO
1 mole C + ½ mole O2 = 1 mole CO
8 O2
Wo = 3 C + 8 (H2 − 8
)+S → kg O2 / kg fuel
Where,
23
C = fuel carbon content, kg/kg fuel
𝟖 𝐎
𝐖𝐨
𝐂+𝟖(𝐇𝟐 − 𝟐 )+𝐒
𝐖𝐚 = 𝟎.𝟐𝟑𝟏 =𝟑 𝟎.𝟐𝟑𝟏
𝟖
Equation by Vopat
O2
Wa = 11.5 C + 34.5 (H2 − ) + 4.32S
8
Equation by Potter
O2
Wa = 11.53 C + 34.36 (H2 − ) + 4.32S
8
Equation Used by Subaran
O2
Wa = 11.44 C + 34.32 (H2 − ) + 4.29S
8
8 11
Relative Weight: 1 kg + 3 kg O2 + 8.77 kg N2 = 3
kg CO2 + 8.77 kg N2
8
Theoretical Air/ Fuel Ratio: A : F = + 8.77 = 11.45 kg air/ kg fuel
3
24
1 Deduce the combustion equations for a) complete combustion of 1 kg and 1 m3 ethylene, C2 H4 , in
Solution:
Carbon, 2 = b
Oxygen, 2a = 2b + c; a = b + c/2 = 2 + 1 = 3
Hydrogen, 4 = 2c; c = 2
By Volume,
Analysis by Weight,
Relative Weight,
25
b. Consider the Actual Combustion with e = 25 %
Weight Analysis,
The composition of the products depends on the kind of fuel used, the A/F ratio, and the
conditions of combustion. The products usually contain carbon dioxide (CO2 ), carbon
monoxide (CO), oxygen, nitrogen, free carbon, fly ash, steam, sulfur dioxide, and unburned
carbons.
Considering the Cn Hm
Atom balance,
Carbon: n = b; b = n
Oxygen: 2a = 2b + c; a = n + 0.25m
26
Substituting the coefficients,
32(1+e)(n+0.25m)+(1+e)(3.76)(n+0.25m)(28)
Waa = 12n+m
[32+3.76(28)](1+e)(n+0.25m)
Waa = 12n+m
100n
CO2 =
n + e(n + 0.25m) + 3.76(1 + e)(n + 0.25m)
100
𝐶𝑂2 = 𝑚 𝑚
1 + 𝑒 (1 + 0.25 𝑛 ) + 3.76(1 + 𝑒) (1 + 0.25 𝑛 )
H2 m m 12H2
= ; =
C 12n n C
27
100
CO2 = 12H2 12H2
1 + [1 + 0.25 ( C
)] + 3.76(1 + e) [1 + 0.25 (
C
)]
100 100
CO2 = 12H2
= 3H2
1 + [e + 3.76(1 + e)] [1 + 0.25 ( C
)] 1 + (3.76 + 4.76e) (1 + C
)
100 100
CO2 = 3H2 3H2
= H2 3H2
1 + 3.76 (1 + C
) + 4.76e (1 +
C
) 1 + (3.76 + 11.28 C
) + 4.76e (1 +
C
)
H2 3H2 100
1 + [3.76 + 11.28 ( )] + 4.76e (1 + )=
C C CO2
3H2 100 H2
4.76e (1 + )= − [3.76 + 11.28 ( )] − 1
C CO2 C
H2 H2
100 − CO2 − (3.76 + 11.28 ) CO2 100 − [1 + [3.76 + 11.28 C
]] CO2
C
e= 3H2
= H2
4.76e (1 + C
) CO2 (4.76 + 14.28
C
) CO2
H2
100 − (4.76 + 11.28 C
) CO2
e= H2
(4.76 + 14.28 ) CO2
C
H2
100 − (4.76 + 11.28 C
) CO2
e= H2
→ By Maleev
(4.76 + 14.28 ) CO2
C
H2
137.6(n + 0.25m)(1 + e) 137.6 (1 + 0.25 C ) (1 + e)
Waa = = H
12n + m 12 + 2
C
m 12H2
But, =
n C
12H2 3H2
137.6 [1 + 0.25 ( C
)] (1 + e) 137.6 (1 + C
) (1 + e)
Waa = 12H2 = H2
12 + C
12 (1 + )
C
28
𝟑𝐇𝟐
𝟏𝟏. 𝟓𝟑 (𝟏 + 𝐂
) (𝟏 + 𝐞)
𝐖𝐚𝐚 = 𝐇𝟐
(𝟏 + )
𝐂
1. An analysis of exhaust gases shows the products to consist of the following percentages vy
volume: 𝐶𝑂2 = 12.1, 𝑂2 = 0.30, CO = 3.3, 𝐻2 = 1.3, 𝐶𝐻4 = 0.30, 𝑁2 = 82.7. Assuming the fuel to be a
pure hydrocarbon of the form Cn Hm , a) find the values of n and m; b) Balance the combustion
equation; and c) Determine the air-fuel ratio.
Solution:
Where, a = moles of oxygen in air supplied; b = moles of water vapor in the products
Calculate:
Solution:
29
MW = 16CH4 + 30C2 H6 + 28N2 + 44CO2
MW = 16(0.598) + 30(0.376) + 28(0.022) + 44(0.004) = 21.64 kg/kgmol fuel
b) Gravimetric analysis by component
TOTAL 100
d) Solving for the actual air required per kg fuel
(1 + e)Wa (1 + e) 8 O2
Waa = = [ C + 8 (H2 − ) + S]
0.231 0.231 3 8
kg
ma = (Waa )mF = (24.12)(50) = 1206
min
30
Solving for the volumetric rate of air required
ma R a Ta 1206(0.28708)(15.56 + 273)
Va = = = 985.71 m3 /min
Pa 101.325
O2 − 0.5CO
Excess Air, e = (100%)
0.26N2 − (O2 − 0.5CO)
4CO2 + O2 + 700 3 5
Wdg = (Cab + S) + S
3(CO2 + CO) 8 8
Assignment1
31
Summary
Combustion is the rapidchemical union with oxygen of an element whose heat of reaction is
sufficiently great and rate of reaction is fast enough that quantities of heat are liberated at
elevated temperature.
Straight oils are oils produced entirely from the crude chosen entirely through elimination of
undesired constituents by refining process.
Additive oils are oils produced by adding to straight mineral oils; certain oil are soluble
compounds that enhance the lubricating oil properties for use in Diesel engines.
Proximate analysis – composition of fuel that gives on mass basis the relative amount of
volatile matter, fixed carbon, moisture and ash.
Fuel is any substance or combustible material that by rapid oxidation or burning produces
heat and light. An example of a fuel is coal or gasoline. A fuel is composed of chemical
elements which, in rapid chemical union with oxygen, produce combustion. Fossil fuels are
fuels that originate from the earth as a result of the slow decomposition and chemical
conversion of organic material. The basic forms of fossils are solid (coal), liquid (oil), and
natural gas. Synthetic fuels or synfuels, the new combustible-fuel-options, are liquid or
gaseous fuels derived largely from coal, oil shale, and tar sands (Fossil Fuel, n.d).
Reference
Francisco, Jose R. (2014). Lecture Notes in Industrial Plant Design, Lesson 8: Fuels and
Combustion, p.g 125 to p.g 151.
32
MODULE 2
STEAM GENERATING UNIT
Introduction
Learning Objectives
33
Lesson 1.Types of Boiler
1. Fire-tube boilers – are those having the heat gases of combustion inside the tubes. Limited
only to a working pressure of 1.7 Mpag.
a. Horizontal-Return-Tubular (HRT) Boiler
b. Packaged Fire-Tube Boiler
c. Vertical Tubular Boiler
2. Water-Tube-Boilers – are those having the hot gases of combustion outside the tubes.
a. Horizontal Straight-Tube Boiler
b. Central Station Steam Generators
c. Marine Steam Generators
d. Forced-circulation Steam Boilers
o Dryness Factor (or fraction) or Quality of steam – refers to the amount of steam in the
mixture of water and steam at the riser.
o Top Dryness Factor – applies to the mixture leaving the tubes.
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Lesson 2. Boiler Ratings and Performance
According to Francisco (2014) Boiler rating and performance can be evaluated by:
Boiler Hp = equivalent to the generation of 34.5 lb/hr (15.44 kg/hr) from water at 212 °F (100 °C)
to saturated steam also at 212 °F (100 °C).
Energy of Evaporation
lb Btu
Energy of Evaporation = (34.5)(hfg @ 212 °F) = (34.5 hr) (970.3 lb
) ≈ 33 500 Btu/hr
kg kJ
Energy of Evaporation = (15.46)(hfg @ 100 °C) = (15.646 hr ) (2257 kg ) ≈ 35 314 kJ/hr
Btu
Where, hfg = enthalpy of evaportion at 212 °F (100 °C) = 970.3 lb
= 2257 kJ/kg
Boiler Horsepower, Bo Hp
ms (h2 − h1 ) ms (h2 − h1 )
Bo. Hp = =
35 314 33 500
35
(F. E. )(ms ) Eq. Evap. (F. E. )(ms ) Eq. Evap.
Dev. Bo. Hp = = = =
15.646 15.646 34.5 34.5
Where, ∑ ms (∆h) = total heat transfer to cycle fluid in steam generator (boiler, superheater,
heater, Economizer, reheater), kJ/hr, Btu/hr.
Percent Rating
Dev. Bo. Hp
Percent Rating =
Rated Bo. Hp
where, Steam Generated = kg/hr of steam at a given pressure and temperature and feed water
temperature.
Boiler Performance – the measure of boiler heat output, QB , in kJ/hr or Btu/hr
a) QB = Based on the flow diagram
b) QB = mF (HHV)EB
c) QB = (Dev. Bo. Hp)( 35 314) or QB = (Dev. Bo. Hp)(33 500)
d) QB = (Eq. Evap.)(2257) or QB = (Eq. Evap.)(970.3)
% Rating % Rating
e) QB = (Rated Bo. Hp. ) ( 100 %
) (35 314) or QB = (Rating Bo. HP) (
100%
) (33 500)
EB = boiler efficiency
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QB ′ ∑ ms (∆h)
ƞB = (100%) = (100%)
mF (HHV) mF (HHV)
Where, QB ′ = heat absorbed by the boiler fluid less the amount of heat used for the boiler
auxiliaries.
Grate Efficiency
The fuel supplied to a furnace when completely burned releases its heating value. The
energy primarily changes the feedwater pumped to the boiler into steam. All the heating value does
not go to this useful purpose. These are some losses in the form of incomplete combustion, of flue
gases leaving at high temperature, and of radiated and convected heat from the outside of the steam
generator. An energy balance shows the distribution of the heating value of the fuel to the formation
of steam and to the various losses (Francisco, 2014).
37
Useful Energy from Francisco (2014)
Where, Q1 = energy absorbed by the boiler fluid or the useful energy, kJ/kg fuel, Btu/lb fuel
hg2 = enthalpy of steam leaving the boiler, kJ/kg, Btu/lb
hf1 = enthalpy of feed water, kJ,kg, Btu/lb
hf2 = enthalpy of water at boiler pressure, kJ/kg, Btu/lb
hg4 = enthalpy of reheat steam leaving the steam generator, kJ/kg, Btu/lb
hg3 = enthalpy of reheat steam entering the steam generator, kJ/kg, Btu/lb
Ws = mass of steam from feedwater per unit mass fuel, kg/kg fuel, lb/lb fuel
Wr = mass of reheated steam per unit mass fuel, kg/kg fuel, lb/lb fuel
WB = mass of blowdown per unit mass fuel (often negligible), kg/kg fuel, lb/lb fuel
1. Energy Loss due to mechanical moisture in fuel (or energy loss due to evaporating and
superheating moisture in fuel)
English Units:
Q2 = W(1066 + 0.5t g − t a ) when t g > 575 °𝐹
Q2 = W(1089 + 0.46t g − t a ) when t g < 575 °𝐹
SI Units:
Q2 = W(2479.81 + 20.935t g − 4.187t a ) when t g > 302 °𝐶
Q2 = W(2533.31 + 1.92602t g − 4.187t a ) when t g < 302 °𝐶
Where, Q2 = energy loss due to moisture content of the fuel as fired, kJ/kg fuel, Btu/lb fuel
W = moisture content of the fuel, kg/kg fuel, lb/lb fuel
t g = temperature of flue gas after passing all heat-transfer surfaces, °C, °F
t a = temperature of air entering for combustion to the furnace or air heater, if the latter
is used, °C, °F
2. Energy loss due to moisture from hydrogen in the fuel (or energy loss due to evaporating and
superheating moisture formed by combustion of hydrogen)
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English Units:
Q3 = 9H2 (1066 + 0.5t g − t a ) when t g > 575 °𝐹
Q3 = 9H2 (1089 + 0.46t g − t a ) when t g < 575 °𝐹
SI Units:
Q3 = 9H2 (2479.81 + 20.935t g − 4.187t a ) when t g > 302 °𝐶
Q3 = 9H2 (2533.31 + 1.92602t g − 4.187t a ) when t g < 302 °𝐶
English Units:
Q4 = 0.47 WAV (t g − t a )
SI Units:
Q4 = 1.96789WAV (t g − t a )
Where, WAV = mass of moisture content n supp air per unit mass fuel, kg/kg fuel, lb/lb fuel
WAV = (1 + e)Wa (g)
Wa = theoretical air-fuel ratio, kg/kg fuel, lb/lb fuel
g = humidity ratio of supply air, kg/kg d.a. ,lb/lbd.a.
3. Energy Loss due to dry flue-gas sensible heat
English Units:
Q5 = WDG cp (t g − t a ) = 0.24WDG (t g − t a )
SI Units:
Q5 = WDG cp (t g − t a ) = 1.005WDG (t g − t a )
Where, WDG = mass of dry flue gas per unit mass fuel, kg/kg fuel, lb/lb fuel
English Units:
39
28 CO
Q6 = ( ) (10187)
44CO2 + 28CO + 28N2 + 32O2
CO
Q6 = 10160Ci = 10160Cab ( )
CO2 + CO
SI Units:
28 CO
Q6 = ( ) (4380)
44CO2 + 28CO + 28N2 + 32O2
CO
Q6 = 23 631Ci = 23 631Cab ( )
CO2 + CO
Note: CO and CO2 in the second equation must be an Orsat analysis (% by Volume)
English Units:
Q7 = 14 600 (C − Cab )
Q7 = Wr (HHV)r
SI Units:
Q7 = 33 964 (C − Cab )
Q7 = Wr (HHV)r
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Assignment 2
2. A steam boiler has an actual evaporation rate of 8.23 kg/kg coal fired. Coal as fired
contains 2 % moisture. Dry coal contains 5 % ash and has a heating value of 29 776 kJ/kg.
During the test 12 % of coal fired is delivered from the ashpit as refuse. The steam leaving the
boiler is saturated at a pressure of 0.70 MPaa and the temperature of feed water is 49 °C.
Determine a) the boiler efficiency; b) the boiler-furnace efficiency; c) the grate efficiency.
41
4. A condenser receives 11 338 kg of steam per hour at 89 % dryness factor. Steam
temperature in the condenser is 33 °C and free air at 101.325 kPaa and 15.56 °C leaks into
the condenser at the rate of 0.51 𝑚 3/min. Determine the pressure in the condenser.
Summary
Reference
Francisco, Jose R. (2014). Lecture Notes in Industrial Plant Design, Lesson 9: Steam Generators
p.g 152 to p.g 161.
42
MODULE 3
MECHANICAL DRYERS
Introduction
Drying is the process of removing moisture in varying amounts from solid or semi-fluid materials.
This process may be accomplished by pressure, suction, decantation, or evaporation (Francisco,
2014).
Learning Objectives
43
Lesson 1. Mechanical Dryer
1. Application of heat to the material and/or to the air mixture which carries away the moisture.
2. Means for removing the water vapor, steam, or mixture
3. Conveying the material in its wet, semi-dried, dried condition into, through, and out of the
apparatus, allowing the material the proper time for contact with the heating and moisture-
removing elements.
44
Six Commercial Types of Dryers and Three Materials Suitable for Each Dryers from Francisco (2014):
1. Rotary Dryer
Materials: copra, sand, wood chips
2. Compartment Batch Dryer
Materials: wood, enamel wares, foodstuffs
3. Centrifugal Dryer
Materials: sugar, fertilizer, salt
4. Hearth Dryer
Materials: copra, enamel wares, chalk
5. Tower Dryer
Materials: palay, wheat, grains
6. Infrared Ray Dryer
Materials: air conditioners, cars, refrigerators
Hygroscopic Materials are those substances which are particularly variable in the moisture content
that they can possess at different times (Francisco, 2014).
Bone-Dry Weight (BDW) or Dry Bone Weight is the final constant weight reached by a hygroscopic
substance after being dried out (Francisco, 2014).
Regain is the hygroscopic moisture content of a substance expressed as a percentage of the dry-bone
-weight of the material (Francisco, 2014).
𝐖𝐞𝐢𝐠𝐡𝐭 𝐨𝐟 𝐌𝐨𝐢𝐬𝐭𝐮𝐫𝐞
𝐑𝐞𝐠𝐚𝐢𝐧 =
𝐁𝐨𝐧𝐞 − 𝐝𝐫𝐲 − 𝐖𝐞𝐢𝐠𝐡𝐭
Moisture Content is usually expressed as a percentage of the gross weight of the body, and may refer
to both hygroscopic and purely substance moisture (Francisco, 2014).
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𝐖𝐞𝐢𝐠𝐡𝐭 𝐨𝐟 𝐌𝐨𝐢𝐬𝐭𝐮𝐫𝐞
𝐌𝐨𝐢𝐬𝐭𝐮𝐫𝐞 𝐂𝐨𝐧𝐭𝐞𝐧𝐭 =
𝐆𝐫𝐨𝐬𝐬 𝐖𝐞𝐢𝐠𝐡𝐭
Gross Weight:
Figure 3.1 below illustrates the schematic diagram of a dryer with conditioned air that passed through
a CDA and re-heater (Francisco, 2014).
Figure 3.2 below illustrates the different drying processes in the psychrometric chart (Francisco, 2014).
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Figure 3.2. Psychrometric Chart of Drying Processes from Francisco (2014)
1. Copra enters a dryer, containing 60 % water and 40 % solids, and leaves with 5 % water and 95 %
solids. Find the mass of water removed on each: a) kilogram of original product; b) kilogram of final
product; and c) kilogram of Bone-dry material.
Required:
Solution:
47
MC1 = moisture content of the original or wet product
For the mass of water removed, MV = MG2 − MG1 = 2.375 − 1.00 = 𝟏. 𝟑𝟕𝟓 𝐤𝐠
1.0 1.0
MG2 = = = 1.053 kg
1 − MC2 0.95
For the weight of water removed, MV = MG2 − MG1 = 2.5 − 1.053 = 𝟏. 𝟒𝟒𝟕 𝐤𝐠
2. A tower-type moisture dryer is to deliver 1000 kg/hr of cassava flour with 2 % residual moisture of
20 % in the feed. The air to be heated in the heating chamber is a mixture of fresh air at 33 °C DB and
60 % RH, and hot humid air from dryer at 49 °C DB and 60 % RH. The mixture at 38 °C and 65 % RH
is heated by a steam coil to 93 °C. The dryer is properly insulated so that moisture absorption can be
considered adiabatic. Compute:
48
a. Required flow of heated air mixture to dryer;
b. Capacity of forced draft fan on dryer
c. Heat in kcal/hr for heating the air mixture in the heating chamber
d. Percentage by weight of fresh air in the mixture.
Required:
49
Figure 3.5 Temperature from Francisco (2014)
Solution:
Figure 3.6 Drying System mass flow rate from Francisco (2014)
ma + ma (W3 ) + m5 = ma + ma (W4 ) + m6
m2 − m6
ma (W3 ) + m5 = ma (W4 ) + m6 → ma (W4 − W3 ) = m5 − m6 ma =
W4 − W3
50
Then, BDM = m6 − 0.02 m6 = m6 (1 − 0.02) = 0.98 m6 = 0.98 (1000)
pv4 7.0494
Then, W4 = ( ) = (0.622) ( )
pt − pv4 101.325 − 7.0494
= 0.0465 kg/kg da
m5 − m6 1225 − 1000
therefore, ma = = = 11842.11 kg/hr ma = 3.29 kg/s
W4 − W3 0.0465 − 0.0275
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b. For the capacity of the forced-draft fan, Q3 = ma (v3 )
W3 (pt ) 0.0275 (101.325)
where, pv3 = = = 4.2901 kPaa
W3 + 0.622 0.0275 + 0.622
c. For the heat added to the heating chamber, consider the heating chamber
d. For the % by weight of fresh air in the mixture, consider junction 1-4-2
By energy balance, m1 h1 + m4 h4 = m2 h2
52
Where, m4 = m2 − m1
m1 h1 + (m2 − m1 )h4 = m2 h2 → m1 h1 + m2 h4 − m1 h4 = m2 h2
m1 (h1 − h4 ) = m2 (h2 − h4 )
m h2−h4
Then, % by weight of m1 = m1 (100 %) = h1−h4
(100 %)
2
108.64 − 169.715
% by weight of m1 = (100 %) = 69.61 %
81.98 − 169715
#3. Wet material containing 215 % moisture (dry basis) is to be dried at the rate of 1.5 kg/s in a
continuous dryer to give a product containing 5 % moisture (wet basis). The drying medium consist
of air heated to 373 K and containing water vapor equivalent to a partial pressure of 1.40 kPaa. The
air leaves the dryer at 310 K and 70 % RH. Calculate how much air will be required to remove the
moisture.
Required:
Solution:
Solving for the mass of the material leaving the dryer, m4 = BDM + 0.05 m3
53
BDM 0.476
m4 = = = kg/s
0.95 0.95
ma + ma (W1 ) + m3 = ma + ma (W3 ) + m4
m3 − m4
ma (W2 − W1 ) = m3 − m4 ; → ma =
W2 − W1
Assignment 3
1. A dryer is to deliver 0.30 kg/s of cassava with 2 % moisture and 20 % moisture in the feed.
Determine the mass of air required if the change in humidity ratio is 0.0165 kg/kg da.
2. A certain material enters dryer containing 60 % water and leaves with 5 % water. Find the
mass of the final product if the original product is 1 kg/s.
3. Copra enters a dryer containing 60 % water and 40 % solids and leaves with 5 % water and
95 % solids. Find the weight of water removed based on a kg of original product.
4. A rotary dryer fired with bunker oil of 10 000 kcal/kg higher heating value is to produce 20
metric tons/hr of dried sand with 0.5 % moisture from a wet feed containing 7 % moisture,
specific heat of sand is 0.21 Btu/lb-°F. Temperature of wet sand is 30 °C and temperature of
dried product is 115 °C.
a. Calculate the weight of the wet feed
b. Calculate the weight of water to be removed in kg/hr
c. Calculate the heat required
d. Calculate the liters of bunker oil per hour if specific gravity of bunker oils is 0.90 and
dryer efficiency is 60 %.
Summary
54
Drying is the process of removing moisture in varying amounts from solid or semi-fluid
materials. This process may be accomplished by pressure, suction, decantation, or
evaporation (Francisco, 2014).
Dryer is machine or equipment used for drying process.
Evaporation is the main principle of the term drying process. In drying process, not only
the surface liquid is removed or reduced but also removes internal moisture and in many
cases water in chemical combination.
Inherent moisture and bed moisture are the terms used for describing the moisture in the
mass that is not on the surface of the material.
Chemically combined water is that water occurring when a chemical component of the
material changes its chemical composition by heat or other means.
Reference
Francisco, Jose R. (2014). Lecture Notes in Industrial Plant Design, Lesson 6: Mechanical
Dryers, p.g 90 to p.g 100.
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