Experiment 3
Experiment 3
Bsmt 1e
Precipitation of 3 mL of unknown + 1 mL 5M
Practice Unknown NH4Cl + 5M NH4OH dropwise 1 mL (NH4)2CO3, mix, and stand
Group IV until basic + 3 drops in excess. for 5 mins then centrifuge
1 mL = Mg(NO3)2 + Na(NO3)2 + Ca(NO3)2 Heat almost to boiling.
+
Wash ppt w/ 2
10 mL distilled H2O Decant the Cloudiness?
mL H2O and supernatant Test for completeness of ppt,
discard washings liquid + treat add few drops of (NH4)2CO2
Yes. Stir and No. Test again for
with B-3C completeness of
warm the soln.
the centrifuge. precipitation
Test for Barium Test for
Ion Strontium Ion
Test for Calcium Test for
6M HAc dropwise or 10 drops to Adjust volume of soln. B-2 to 2 mL
Observe the liquid if it is
ppt until solid dissolved + 10
yellow before decanting
by evaporation of dilution Ion Magnesium Ion
drops of 3M NH4Ac + 2 mL H2O
Filtered B-3 soln,. add 10 drop Centrifuge C soln. add 5 drops
Centrifuge and discard
0.2M (NH4)2C2O4 15M NH4OH & 20 drops 0.5 M
supernatant liquid
If yellow supernatant liquid,
Na2HPO4. Mix and stand for 10 min
Boil solution + 1 drop of 1M Add 15 drops of triethanolamine
K2CrO4 decant and treat with B-2
(TEA), stir and boil. Centrifuge