Control No.

ZN2GA1E-01

Instruction Manual
of
Absorption Unit GA-210

MITSUBISHI CHEMICAL ANALYTECH

Introduction

Thank you for purchasing our Absorption Unit Model GA-210.

To use the unit efficiently and safely, read this manual and fully understand the functions and the
operation methods before use.
To use Model GA-210 correctly and safely, appoint supervisors and operators before use.
Also read the operation manual for measurement operations using the complete system.

Before the use

(1) Do not reprint this manual wholly or partially without permission.

(2) The contents may be changed without notice.

(3) Though this manual was prepared carefully, contact local distributor when mistakes, omissions,
and missing pages are found. The system program windows in this manual may be different
depending on the version of the software.

(4) For any circumstances resulting from usage of results of the unit, we do not take any responsibility
regardless of (3).

(5) Assign specific operators and supervisors when using this unit.

(6) Follow the contents in this manual. When troubles or damages occur by neglecting the contents in
this manual, we do not guarantee units even within the guarantee term.

MITSUBISHI CHEMICAL ANALYTECH has the copyrights of this manual and the unit software.
Microsoft and Windows are registered trademarks of Microsoft Corporations of America and other
countries.
Other company and product names are their trademarks and registered trademarks.
 SAFETY PRECAUTIONS

SAFETY PRECAUTIONS
Read this instruction manual with care before use.
Keep the manual at hand when operating the unit.
When the unit is operated without following this manual description, security can not be assured.
If any questions, errors, and omissions are found, contact local distributor.

WARNING
Information under this sign explains critical operations which contain risk of death or
serious casualties.

CAUTION
Information under this sign explains critical operations which contain risk of human
casualties or damages to surrounding objects.

POINT
Information under this sign explains important and useful information for utilizing the
unit.

Labels

The following labels are attached to this unit. Always follow the instructions in the labels.

Caution labels Attached places

At gas connection part of
GA-210 rear

1
SAFETY PRECAUTIONS

Read the following cautions carefully to use the unit correctly and safely.

Installation

When installing the units, observe the following precautions.

CAUTION
Install the unit in a place where temperature is 15 to 35 degrees Celsius.
Failure to do so can lead to a fire or unstable operation.

CAUTION
Install the unit in a place free from direct sunlight.
Failure to do so can lead to a fire.

CAUTION
Install the unit in a place free from strong vibration or continuous weak vibration.
Failure to do so can lead to unstable operation.

CAUTION
Install the unit in a place free from strong electromagnetic field.
Failure to do so can lead to unstable operation.

CAUTION
Install the unit in a place where humidity is 80% or less.
Failure to do so can lead to a fire or cause electric shock.

CAUTION
Install the unit in a place free from corrosive gas.
Failure to do so can lead to deterioration of the unit.

CAUTION
Install the unit in a place free from much dust.
Failure to do so can lead to a fire or cause electric shock.

CAUTION
Install the unit in a place where fire is not used.
Failure to do so can lead to a fire.

2
 SAFETY PRECAUTIONS

CAUTION
Install the unit on a flat surface to avoid displacement of the unit.

During Usage

WARNING
Avoid direct exposure of the unit to combustibles and combustible gases.
The unit is equipped with a high-temperature furnace.
Contact with combustible gases or spilling combustible fluids near the unit can lead to
fire.

WARNING
Always check for gas leaks before using the unit.
When organic matter suddenly mixes with oxygen or air at high temperature, explosive
combustion can occur.
As a result, glass parts such as pyrolysis tubes and trap columns can break and lead to
human casualties.
To prevent explosive combustion, samples are vaporized slowly in argon gas and
mixed with oxygen and combusted.
Before use, always check gas piping looseness, O-ring deterioration, septum
displacement, etc. which could lead to gas leakage.

CAUTION
Appoint specific supervisors and operators for this unit.

CAUTION
Check for proper gas flow before injecting a sample.

CAUTION
Do not touch the power plug with wet hands.
Failure to do so can lead to electric shock.

CAUTION
Do not modify or damage the power cable. Do not place heavy objects on the cable.
Do not heat the cable.

3
SAFETY PRECAUTIONS

CAUTION
Check that the earth terminal is properly connected.
Failure to do so can lead to electric shock.

CAUTION
Do not remove the covers of units except for our servicemen.
Electric shock or fire can be caused.

CAUTION
When handling chemicals, put on safety glasses and gloves to protect skin and eyes.
Do not inhale chemical vapor.

Maintenance and Inspection

CAUTION
Check units every day before use.
Failure to check can lead to reduced performance of the units, and even to serious
accidents.

4
 Table of Contents

Table of Contents
Section 1: Names and Functions of GA-210 Units
1-1. GA-210 Unit Front Names and Functions 1-1
1-2. GA-210 Unit Rear Names and Functions 1-3
1-3. GA-210 Rear Signal Terminals 1-4
1-4. GA-210 Absorption Part Names and Functions 1-5
1-5. GA-210 Absorption Part Line Names and Functions 1-6
1-6. GA-210 Operation Panel Names and Functions 1-7
Section 2: Parts Check
2-1. Parts for GA-210 2-1
2-2. Absorption Tube 2-2
2-3. Attachment Set for High Concentration 2-3
2-4. Parts for Horizontal Furnace 2-3
2-4-1. Set for AQF Horizontal Furnace 2-3
2-4-2. Pyrolysis Tube Set for AQF Horizontal Furnace 2-4
Section 3: Installation
3-1. Installation Conditions 3-1
3-2. Installation Space and Positions 3-2
3-2-1. Installation Space 3-2
3-2-2. Installation Positions 3-2
3-3. Power Preparation 3-2
3-3-1. Power 3-2
3-3-2. Grounding 3-2
3-4. Assembly of GA-210 Absorption Part 3-3
3-5. Syringe Setting 3-6
3-6. GA-210 Line Connection 3-7
3-6-1. Connection of Humidification Water and Argon Lines 3-7
3-6-2. Line Connection of Absorption Solution, Washing Solution, and Drain 3-9
3-6-3. Line Connection to the Branch Tube of Pyrolysis Tube 3-10
3-6-4. Line Connection of GA-210 and Ion Chromatography Unit 3-11
3-7. Cable Connection 3-12
3-7-1. Communication Cable Connection 3-12
3-7-2. Signal Cable Connection 3-12
3-7-3. Cooling Fan Signal Cable Connection 3-12
3-7-4. Power Cable Connection 3-12
3-8. Connection of High Concentration Kit (Optional) 3-12
3-8-1. Absorption Tube Connection 3-12
3-9. Measuring Tube Connection 3-12

1
Table of Contents

3-10. Operation Check 3-13

3-10-1. Check of Absorption Tube Sensor 3-13
3-10-2. Check of Washing Water Supply 3-13
3-10-3. Check of Syringe Pump Supply 3-14
3-10-4. Check of Absorption Solution Aspiration 3-14
3-10-5. Check of External Solution Aspiration 3-15
3-10-6. Check of Humidification Water and Ar Gas Supply 3-16
Section 4: GA-210 Functions
4-1. GA-210 Start 4-1
4-2. Water Supply Pump Switch 4-1
4-3. Service Panel 4-2
4-3-1. Service Panel Functions 4-2
4-3-2. Constant Volume Function Sensor Check and Constant Volume Mode 4-4
4-4. Skip IC Time 4-6
4-5. Options 4-6
4-5-1. Setting of Pump Automatic Turn-On 4-6
4-5-2. Setting of Collection Function 4-7
4-6. GA-210 Parameters and Operation Sequences 4-9
4-6-1. Setting of GA-210 Parameters 4-9
4-6-2. GA-210 and Automatic Measurement 4-12
4-6-3. GA-210 Sequences 4-13
4-6-3-1. Flow and Settings of Absorption Solution Setting Sequence 4-14
4-6-3-2. Flow and Settings of Absorption Solution Injection Sequence 4-15
4-6-3-3. Flow and Settings of External Solution Injection Sequence 4-16
4-6-3-4. Flow and Settings of Absorption Solution Collection Sequence 4-17
4-6-3-5. Flow and Settings of “Wash All” Sequence 4-18
4-6-3-6. Flow and Settings of End Processing Sequence 4-19
4-6-3-7. Flow and Settings of Volume Calibration Sequence 4-20

Section 5: Troubleshooting
5-1. No Power to the Unit 5-1
5-2. No Gas Flow 5-1
5-3. No (or very weak) Response in Ion Chromatography 5-2
5-4. Unstable Measurement Values 5-2
5-5. Water Leakage inside the Unit 5-3
5-6. Decrease of Water Supply Volume (or Pump Stop) 5-5
5-7. No Collection of Absorption Solution / Standard Solution 5-5
and No Chromatography Peak

2
 Table of Contents

Section 6: Error Messages and Measures 6-1

Section 7: Maintenance and Inspection
7-1. Inspection 7-1
7-1-1. Daily Inspection 7-1
7-1-2. Periodical Inspection 7-3
7-3. Storage of the Unit 7-4
Section 8: Specifications 8-1
Section 9: Consumables
9-1. GA-210 9-1
9-2. Optional Parts 9-2
9-3. Parts Pictures 9-2

3
Table of Contents

4
 Section 1: Names and Functions of GA-210 Unit

Section 1: Names and Functions of GA-210 Unit

1-1. GA-210 Unit Front Names and Functions

1
3 10

5 9

7
Fig. 1-1. GA-210 Unit Front
Table 1-1. GA-210 Unit Front Names and Functions
No. Names Functions
1 Power switch GA-210 power switch
2 Power lamp This is ON when power switch is ON.
3 Operation panel For manual operation of GA-210
Refer to “1-6. GA-210 Operation Panel Names and
Functions” for details.
4 Bottle tray Place an absorption solution bottle and a washing
solution bottle.
5 Injector The six-way valve to collect absorption solution or
external solution from GA-210 and send it to other units.
6 Peristaltic pump The solution in the absorption tube is drained or taken
out.
7 Syringe pump Absorption solution is injected into the absorption tube.
The buret moves up and down. Put the attached cover in
the front. Do not place objects below the syringe pump.

1-1
Section 1: Names and Functions of GA-210 Unit

No. Names Functions

8 Absorption tube Absorption solution is injected and combustion gas is
absorbed. Refer to “1-4. GA-210 Absorption Part Names
and Functions”.
9 Cooling fan For cooling the pyrolysis tube outlet
It works with the ON and OFF of the electric furnace.
Light is ON during operation.
10 Partition For the reception of the fan wind for cooling the
pyrolysis tube outlet

1-2
 Section 1: Names and Functions of GA-210 Unit

1-2. GA-210 Unit Rear Names and Functions

2
4

5 6 7

10
11 1

Fig. 1-2. GA-210 Unit Rear

Table 1-2. GA-210 Unit Rear Names and Functions

No. Names Indications Functions
1 Power connector a.c. POWER AC100 to 240 power can be used.
2 Main power switch MAIN POWER Earth leakage breaker
It should be ON at all times.
3 Signal connector COOLING FAN For the fan to cool the pyrolysis tube outlet
for cooling fan
4 Signal connector SELECTOR For connecting ES-210 (external solution
for external solution injector, optional unit)
injector
5 Function setting FUNCTION For setting optional functions
switch
(in the blank panel)
6 Signal connector MAIN UNIT For connecting GA-210 to the electric furnace
(HF-210)
Connect with a RS-232C crossing cable.

1-3
Section 1: Names and Functions of GA-210 Unit
No. Names Indications Functions
7 Signal terminal Upper 1 to 8 For connecting GA-210 to the ion
Lower 1 to 8 chromatography unit
Refer to “1-3. GA-210 Rear Signal Terminals”
for details.
8 Ar gas inlet for Ar IN The inlet connector is φ4mm metal.
humidification
9 Humidification WATER OUT φ3/2 PTFE tube is attached.
water outlet
10 Ar gas outlet Ar OUT φ4/2 PTFE tube is attached.
11 Connector for Special T-shaped connector for mixing
humidification humidification water with argon and supplying
water supply it
Two branches are φ4 and one branch is φ3.

1-3. GA-210 Rear Signal Terminals

The terminals for external input and output are in GA-210 rear. Connect contact signals if necessary.
Table 1-3. Setting of Rear Signal Terminals
Numbers Indications Description
Input side 1 COM+ Pull-up COMMON
(Upper) 2 IN1 Pump 1 stop
3 IN2 Pump 2 stop
4 IN3 Spare
5 IN4 Spare
6 5V DC 5V input
7 24V DC 24V input
8 GND Ground for input
Output 1 (red) IC START Port for connection to the ion
side 2 (black) chromatography unit which can start
(Lower) by receiving the start signal at I/O
contact.
3 OUT2 The concentration pump is on.
4
5 OUT3 Spare
6
7 OUT4 Spare
8
9 5V/24V DC output
10 GND Ground for output

* The servicemen of local distributor will set them during installation.

1-4
 Section 1: Names and Functions of GA-210 Unit

1-4. GA-210 Absorption Part Names and Functions

A. Absorption solution collecting tube
B. Absorption solution dispensing tube
C. Washing solution dispensing tube

1. Overflow tank

2. Vinyl tube for drain

3. Combustion gas inlet

4. Absorption tube

5. Liquid level sensor indicating lamp

6. Liquid level sensor

7. Combustion gas inlet

8. Drain outlet

Fig. 1-3. GA-210 Absorption Part

Table 1-4. GA-210 Absorption Part Names and Functions
No. Names Functions
A. Absorption solution For collecting absorption solution and sending to injection
collecting tube valve.
B. Absorption solution For dispensing absorption solution.
dispensing tube
C. Washing solution For dispensing washing solution or dilution water.
dispensing tube
1 Overflow tank For washing solution overflow.
2 Vinyl tube For draining overflowed washing solution.
3 Combustion gas inlet
4 Absorption tube Absorption solution is filled and combustion gas is absorbed.
5 Liquid level sensor The lamp lights while the tube contains solution.
pilot lamp
6 Liquid level sensor The liquid level in the absorption tube is monitored.
Liquid level can be set to “HIGH”, “MIDDLE”, or “LOW”.
It is used at constant volume mode measurement.
7 Combustion gas outlet Combustion gas comes out from the tip in bubble form.
8 Drain outlet For draining absorption solution and washing solution.

1-5
Section 1: Names and Functions of GA-210 Unit

1-5. GA-210 Absorption Part Line Names and Functions

3,4 V2 P2
5
WATER Ar

WS Ar
3
4
ABS. V1 P1
9
V5

WS OUT
Absorption Washing solution 9
5 4 3
solution P5
O2
Syringe pump P6

WS IN
External solution
(Standard solution)
injection Absorption
V7
1,8 tube

OVER DRAIN
V8 1,7,8
Humidification
V3 2,6 water
6
P3 P4 V4
ABS. DRAIN

Ion chromatography SMP. DRAIN

separation column
Ion chromatography COLLECTION
pump 2
Drain

Fig. 1-4. GA-210 Absorption Part Lines

Table 1-5. Names and Functions of GA-210 Absorption Part Lines

Pump Valve
No. Names Functions
P. No. V. No.
1 IC Injection 3 3, 7, 8 Direct injection from the external line to IC
2 Collection 4 4 For collecting the absorption solution in the
absorption tube
3 Gas Line 2 2, 5 For washing gas lines with washing solution
4 Absorption Tube 1, 2 1, 2 (5) For supplying washing water to the absorption tube
5 Dispense 5 For dispensing absorption solution into the
absorption tube
6 Drain 4 (4) For draining absorption solution or washing
solution from the absorption tube
7 Absorption Tube 3 3, (7) For sucking out absorption solution from the
absorption tube
8 External 3 3, 7 For sucking solution from the external solution
absorption nozzle
9 Water Supply 6 For supplying humidification water to the pyrolysis
tube

1-6
 Section 1: Names and Functions of GA-210 Unit
1-6. GA-210 Operation Panel Names and Functions

When the key is fringed with green, press it once for one operation. Otherwise, operation is run while
the key is pressed.

1 2 3 4 5 6 7 8 9 10 11 12
Fig. 1-5. GA-210 Operation Panel
Table 1-6. GA-210 Operation Panel Names and Functions

No. Grouping Indications Names Functions

1 IC INJECT External solution Injection of external solution such as standard
(EXTERNAL) injection solution into IC (Ion Chromatograph).
Press this key during operation to suspend
Start/ End key operation.
(Operating parts: V3, V7, V8, P3)
Line 1 in “Fig. 1-4. GA-210 Absorption Part”
External solution It lights during external solution injection.
injection pilot
lamp
2 COLLECTION Collection key Absorption solution in the absorption tube can
be collected by switching the V4 valve to the
collection side.
Collection is run while this key is pressed.
(Operating parts: V4, P4)
Line 2 in “Fig. 1-4. GA-210 Absorption Part”
Collection pilot It lights during collection pump operation.
lamp
3 WATER GAS LINE Gas line washing Washing water is supplied to the gas line.
FEED
key (Operating parts: P2, V2, V5)
The line is washed by flowing washing
solution into the sample gas line between the
pyrolysis tube and the absorption tube.
Washing water flows while this key is
pressed.
Check gas flow and then press the key.
Line 3 in “Fig. 1-4. GA-210 Absorption Part”
Gas line washing It lights during gas line washing.
pilot lamp

1-7
Section 1: Names and Functions of GA-210 Unit

No. Grouping Indications Names Functions

4 WATER ABSORPTION Key for water Washing water is supplied into the absorption
FEED
TUBE injection to the tube. Washing water flows while this key is
absorption pressed.
tube (Operating parts: P1, P2, V1, V2, (V5) )
Line 4 in “Fig. 1-4. GA-210 Absorption Part”
Water It lights during water injection.
injection pilot
lamp
5 DISPENSE Absorption By one press, absorption solution of one
solution stroke (5ml) is dispensed. (Operating part: P5)
dispense key Line 5 in “Fig. 1-5. GA-210 Absorption Part
Lines”
The operation continues by pressing this key
continuously. The continuous operation is 4
times at most.
Absorption It lights during absorption solution dispense.
solution
dispense pilot
lamp
6 DRAIN Absorption The solution in the absorption tube is drained
tube drain key while this key is pressed.
(Operating parts: P4, (V4) )
Line 6 in “Fig. 1-5. GA-210 Absorption Part
Lines”
Absorption It lights during drain.
tube drain pilot
lamp
7 ASPIRATE ABSORPTION Absorption Absorption solution is aspirated from an
TUBE solution absorption tube.
aspiration key (Operating parts: P3, V3, V7)
Line 7 in “Fig. 1-5. GA-210 Absorption Part
Lines”
Absorption It lights during absorption solution aspiration.
solution
aspiration pilot
lamp
8 EXTERNAL External line External solution is aspirated from the
aspiration key external line.
The line for [IC INJECT] key also can be
washed. (Operating parts: P3, V3, V7)
Line 8 in “Fig. 1-5. GA-210 Absorption Part
Lines”
External line It lights during the aspiration of the external
aspiration pilot line solution.
lamp

1-8
 Section 1: Names and Functions of GA-210 Unit

No. Grouping Indications Names Functions

9 ASPIRATE VALVE Inject valve key The six-way valve is changed to the load side
or the injection side. (Operating part: V8)
INJECT Injection pilot It lights while the six-way valve is at the
lamp injector side.
LOAD Load pilot lamp It lights while the six-way valve is at the load
side.
10 WATER FLOW Flow rate change Water supply This key contains the
SUPPLY
RATE key volume can be full operation mode of
changed. forcible water supply
(Input range: 1 to 9)at pump start (used
1= About 0.05ml/min during installation).
2= About 0.10ml/min Press [FLOW RATE]
4= About 0.20ml/min key long. “F” is
displayed in the
11 Flow rate indicator “0” is displayed
indicator during the
during stop.
full operation mode.
Otherwise, “1” to 9”
Press the key again to
are displayed.
release the mode. Refer
to “3-10-6. Check of
Humidification Water
and Ar Gas Supply”.
12 WATER ON/OFF Water supply Water supply on/off is changed.
SUPPLY
on/off key (Operating part: P6)
Switching can be done also from PC software.
* Do not press this key while the flange joint is
connected to the branch tube of the pyrolysis
tube and the furnace temperature is not raised.
Humidification water will accumulate in the
pyrolysis tube.
Water supply pilot It lights during water supply.
lamp

1-9
Section 1: Names and Functions of GA-210 Unit

1-10
 Section 2: Parts Check

Section 2: Parts Check

Table 2-1 shows GA-210 parts list.
When initially opening the package, check that all listed parts are included.
For consumables, refer to “Section 9: Consumables”.

2-1. Parts for GA-210

Table 2-1. GA-210 Parts List

Parts names Quantity Check Remarks
No.
column
1 GA-210 1 pc
®
2 Syringe 5ml cavro 1 pc
3 Syringe cover 1 pc
4 Inline filter 1 pc
5 Connector EASYFITT 2 pcs/set
6-way valve 2pcs
6 Hexagonal nut (HEX FITT #9003) 6 pcs/set
IC 4pcs
7 1/16” Connector (#9005) 2 pcs IC
 6/3 Reducer inlet connector 2 pcs Straight, U-shaped tube
8 inlet and outlet
(30-6RU3-T-S)
 6/3 Reducer elbow connector Elbow, absorption tube
9 2 pcs inlet and outlet
(30-6RUE3-S)
10 Vinyl tube 1.6m 1 pc Overflow drain
11 PEEK tube blue 1/16” × 0.01” 3m 1 pc To IC
1 pc From absorption tube to
12 PTFE tube 3/2 0.5m U-shaped tube
13 PTFE tube 4/2 0.7m 1 pc Ar line
1 pc From WS to the branch
14 PTFE tube 4/2 1.2m tube of the inner
pyrolysis tube inlet
15 Polyethylene tank 4L (For drain) 1 pc
Polyethylene tank 2L 1 pc Two holes in the cap
16
(For washing water)
Polyethylene tank 500ml 1 pc Two holes in the cap
17
(For absorption solution)
Polyethylene tank 250ml 1 pc Two holes in the cap
18
(For humidification water)
19 PP tube L-16L 1 pc Nozzle holder

2-1
Section 2: Parts Check
Parts names Quantity Check Remarks
No.
column
2 pcs For binding lines
20 Magnet for binding lines For the tube for
absorption solution
collection line
21 Tube cutter 1 pc
22 Signal cable red and black 1.5m 1 pc For IC connection
23 RS-232C cable, 9-pin, cross 1 pc
Three-way connector (4TTT-S 1 pc
24
with a stainless tube)
25 Plastic bag 1 set
26 Air removal syringe 1 pc For maintenance
4 Nut 1 set For Ar gas line
27 (with front and rear ferrules and
inserts)
28 4/2 Insert 2 pcs/set
Plastic connector 1 set
29
(Z union, TZ3-00 nut ferrule 4/4/3)
GA-210 instruction manual 1 pc
30
(This manual)
31 AQF-2100H operation manual 1 pc
32 Power cable 2.0m 1 pc Packed in separate box.

2-2. Absorption Tube

The following parts are optional and may not be included in the package depending on the purchased
configuration.
Table 2-2. Absorption Tube Parts List
Parts names Quantity Check Remarks
No.
column
1 Absorption tube 10ml 1 pc

2-2
 Section 2: Parts Check

2-3. Attachment Set for High Concentration

The following parts are optional and may not be included in the package depending on the purchased
configuration.
Table 2-3. Parts List of Attachment Set for High Concentration
Parts names Quantity Check Remarks
No.
column
1 Absorption tube 20ml 1 pc
2 Sample loop 20μl 1 pc

2-4. Parts for Horizontal Furnace

2-4-1. Set for AQF Horizontal Furnace

The following parts are optional and may not be included in the package depending on the purchased
configuration.
Table 2-4. Parts List of Set for AQF Horizontal Furnace
Parts names Quantity Check Remarks
No.
column
1 Cooling fan 1 pc For U-shaped tube
2 Partition 1 pc For U-shaped tube
3 Spring for pyrolysis tube 2 pcs/set
4 Ball joint with U-shaped tube (Quartz) 1 pc
For branch tube of outer
5 Female ball joint, elbow, 12.5 1 pc
pyrolysis tube
For branch tube of outer
6 6/4 Reducer connector (30-6RU4-S) 2 pcs
pyrolysis tube
2 pcs For branch tube of inner
pyrolysis tube
7 Clip 12for ball joint
For branch tube of outer
pyrolysis tube
Flange joint 17.5 x 22 1 pc
8
(with O-ring and connector)
Thermal cover (stainless, round-type) 1/set
9
for pyrolysis tube inlet
10 Thermal ring for pyrolysis tube outlet 1 pc
Heat shield plate (stainless) for 1/set
11
pyrolysis tube outlet
12 Gastight microsyringe 50μl (1705-N) 1 pc

2-3
Section 2: Parts Check

2-4-2. Pyrolysis Tube Set for AQF Horizontal Furnace

The following parts are optional and may not be included in the package depending on the purchased
configuration.
Table 2-5. Parts List of Pyrolysis Tube Set for AQF Horizontal Furnace
Parts names Quantity Check Remarks
No.
column
1 Outer pyrolysis tube 1 pc
2 Inner pyrolysis tube (flange joint) 1 pc

2-4
 Section 3: Installation

Section 3: Installation
Necessary space, power, and gas lines for GA-210 installation are described in this section.

3-1. Installation Conditions

Install GA-210 based on the following conditions for long-term stable use.
Refer to “SAFETY PRECAUTIONS” in this manual for details.

• Room temperature is 15 to 35 degrees Celsius. Temperature fluctuation is small.

• No direct exposure of the unit to wind from air conditioners.
• Free from direct sunlight.
• No strong vibration and continuous weak vibration.
• No strong electromagnetic field.
• Humidity is under 80%. (No condensation).
• No corrosive gas.
• Free from much dust.
• Fire must not be used.
• No flammable materials.
• The surface for installation is flat and stable.

If troubles or damages are caused by negligence of the above conditions, we can not guarantee units
even within the guarantee term.

3-1
Section 3: Installation

3-2. Installation Space and Positions

3-2-1. Installation Space

Space needed to install GA-210 is as follows. Depending on the system configuration, check and
prepare enough space for the complete system.
• Bench size: Width 250mm × Depth 430mm
• Bench withstand load: About 22kg

3-2-2. Installation Positions

Install GA-210 to the left of the electric furnace while allowing about 20cm space.
Set attached partition and fan between the electric furnace and GA-210.
By referring to the following figure, set them to surround the outlet of the pyrolysis tube.
Surround the U-shaped tube with the partition to cool the tube efficiently.

Top side view Partition

Electric
furnace side
GA-210 side

Cooling fan
Power lamp

Fig. 3-1. Setting Positions of Partition and Fan

3-3. Power Preparation

3-3-1. Power

GA-210 consumption power is 50VA.

Voltage fluctuation range should be within ±10%.
When voltage fluctuation is over 10%, use a voltage stabilizer.

3-3-2. Grounding

GA-210 power cable is 3-line type including a grounding line.

Insert power cables into 3-line type power outlets and ground them stably.
If the power outlets are 2-line type, always ground them from the earth terminals of power cables.

3-2
 Section 3: Installation

3-4. Assembly of GA-210 Absorption Part

Set the overflow tank to the absorption tube, fix to GA-210, and then connect lines.
After the assembly, check the line condition and sensor reaction by referring to “3-10-1. Check of
Absorption Tube Sensor”.
(1) Remove the overflow tank from the unit and remove the vinyl chloride pipe for transportation.
(2) Place the O-ring to the overflow tank and screw in the O-ring holder lightly.
(3) Insert the absorption tube into the overflow tank. Position the tube so that the marks of the
absorption tube and the overflow tank are at the same level.
(4) Place the drain outlet of the overflow tank and the combustion gas inlet of the absorption tube on
the right side, and then fully tighten the O-ring holder.
Overflow tank
(1) (2) (3) (4)

Drain outlet

O-ring Marks
O-ring holder

Absorption tube Combustion gas inlet

Vinyl chloride pipe

for transportation

Combustion gas inlet

Fig. 3-2. Assembly of GA-210 Absorption Part

(5) Put following three lines through the holes of the overflow tank cap, and then place the cap on the
overflow tank so that all three lines are placed inside the absorption tube.
• A. Absorption solution collecting tube (green) Peek 1/16, Nut φ1/16 (#9734, with a #9706
ferrule)
• B. Absorption solution dispensing tube φ3/2, Hexagonal nut φ3 (#9731, with a #9704 ferrule)
• C. Washing solution dispensing tube φ3/2, Hexagonal nut φ3 (#9731, with a #9704 ferrule)

3-3
Section 3: Installation

(6) Fix the absorption tube to the absorption tube holder and fix it with holding plates and knurled
screws. Squeeze the fixing levers of the sensor (upper corners) and push it down to the bottom
(LOW level).

(7) Make sure that the absorption solution collecting tube (green) is passing the FRONT side of the
combustion gas blowing tube, and adjust the tip position so that it is 2mm from the bottom of the
absorption tube. (If the green tube is set BEHIND the combustion gas tube, the liquid level sensor
may operate improperly.)
(8) Set a φ6/3 reducer elbow joint upward to the combustion gas inlet of the absorption tube and
connect a PTFE tube. Put the free end of the connected PTFE tube through the tube outlet at the
middle of GA-210 right side.
(The destination is the U-shaped tube, to be connected to the end further from the ball joint)
To prevent flow back of solution, refer to the following figure and make sure to set the PTFE tube
in an upward position.
(9) Set a φ6/3 reducer elbow joint to the absorption tube drain outlet and connect a PTFE tube.
(The destination is the bottom of the peristaltic pump.)
(10) Put the vinyl tube through the opening on the right side middle of GA-210, and connect to the
overflow tank.

3-4
 Section 3: Installation

A. Absorption solution collecting tube

The tube outlet of GA-210 right middle
B. Absorption solution dispensing tube
C. Washing solution dispensing tube
(5) (6) (8) (10)

Cap

Combustion
gas inlet

Set “C.
washing
solution
Knurled screw injection
tube” to
1cm
below the
sensor. Vinyl tube

Absorption φ 6/3 Reducer elbow

tube joint
exhaust (9)

(7)
PTFE tube for exhaust
Set “A. Absorption
solution collecting
tube” to the front of
the combustion gas Set the absorption solution collecting tube
tube to be 2mm (green) to the FRONT side of the
above the bottom. combustion gas blowing tube and adjust the
tip position so that it is 2mm from the
bottom of the absorption tube.
Refer to “3-10-1. Check of Absorption Tube
Sensor”.

Fig. 3-3. Assembly of GA-210 Absorption Part

(11) Connect the other end of the absorption solution dispensing tube to the right outlet of the syringe
pump with a φ3 nut blue (P306, with a ferrule P343).

Make sure that the absorption solution collecting tube (green) is passing the FRONT side of the
combustion gas blowing tube, and adjust the tip position so that it is 2mm from the bottom of the
absorption tube. (If the green tube is set BEHIND the combustion gas tube, the liquid level sensor
may operate.)

3-5
Section 3: Installation

3-5. Syringe Setting

Set the syringe to the plunger drive to dispense absorption solution into the absorption tube.

(1) Turn OFF the GA-210 power switch. Remove the syringe pump cover.
(2) Lower the plunger to the lowest position by hand.
(3) Place the plunger ball to the reception position while the plunger is fully inserted in the syringe.
(4) Raise the syringe.
(5) Screw the syringe to the top valve hole. Turn further 1/4 turn to fix.
(6) Set the syringe pump cover.

(2), (3) (4), (5)

Valve × × × ×

(5)

Syringe

(2) (4)

(3)
Plunger

Ball reception position Plunger drive

Fig. 3-4. Syringe Assembly

3-6
 Section 3: Installation

3-6. GA-210 Line Connection

When cutting tubes, always use the attached tube cutter and make sure cut surface is flat. When the
surface is not straight or rough, liquid/gas may leak. After the cut, check that the inner diameter is not
reduced.

3-6-1. Connection of Humidification Water and Argon Lines

To supply water (ultrapure water) with argon gas into a pyrolysis tube, connect the horizontal furnace
(HF-210) and GA-210. Refer to “HF-210 Instruction Manual” for the line connection to the
horizontal furnace (Dotted line part).
(1) Connect the reducer attached to HF-210 to the outlet of the gas purification filter which the utility
Ar gas line is connected.
(2) Connect the stainless tube of the three-way connector (4TTT-S) to (1) reducer to branch the line.
Connect one side of the branched line to HF-210.
(3) Connect a φ4/2 PTFE tube, 0.7m to the other side and connect it to “Ar IN” of GA-210 rear.

CAUTION
Always connect lines with two spanners.
Use ferrules and inserts to connect PTFE tubes.

(3) φ4/2 PTFE tube

A
(2) Three-way connector
(with a stainless tube,
4TTT-S) Ar IN
A
(1) φ4/3 Reducer

HF-210 rear GA-210 rear

Ar gas
O2 gas
A details

Insert Front ferrule Rear ferrule Nut PTFE tube

Fig. 3-5. GA-210 Gas Line Connection

3-7
Section 3: Installation

(4) When not using absorption solution for another analysis, bind the PTFE tube with “Collection”
tag to GA-210 inside top, stick it with a magnet for binding lines, and pass the tip from the center
hole of the overflow tank to prevent the tube removal from the cap.
When using absorption solution for another analysis, pass the PTFE tube with “Collection” tag
from GA-210 right outlet to the outside and fix the tip to the tube holder of the door inside or a
container. Container should be prepared by end user.
(5) Put out the PTFE tube with “WS IN” tag from GA-210 right outlet to the outside, pass it through
the hole of the cap of the polyethylene bottle (0.25L) for water supply, and fix it to prevent the
removal from the bottle.

(6) Connect the PTFE tube with “Ar OUT” tag from GA-210 rear to φ4 part of the three-way
connector (Z union).

(7) Connect the PTFE tube with “WATER OUT” tag from GA-210 rear to φ3 part of the three-way
connector (Z union).

(8) Connect the PTFE tube with “WS Ar” tag to the remaining φ4 part of the three-way connector
(Z union) and pass it behind the electric furnace to reach the right side of the furnace. Set the
flange joint (with an O-ring) to the tip.

(9) Pour pure water up to the half of the nozzle holder and set it inside the GA-210 front door.
Insert the external solution aspiration nozzle (green PEEK tube) into this holder.

Magnet for binding lines

(4) [COLLECTION] PTFE tube φ3/2
GA-210 (9) External solution (standard solution)
aspiration nozzle, PEEK tube, Green

(7) [WATER OUT] PTFE tube φ3/2

(8) [WS Ar] PTFE tube φ4/2

Flange joint
(with O-ring)
A
A A

(6) [Ar OUT] PTFE tube φ4/2

(5) [WS IN] PTFE tube φ3/2

A details
Polyethylene
Holder for external bottle 0.25L
solution (standard
solution) aspiration for humidification
nozzle water
PTFE tube Sleeve Nut

Fig. 3-6. GA-210 Water Line Connection

3-8
 Section 3: Installation

3-6-2. Line Connection of Absorption Solution, Washing Solution, and Drain

(1) Put out the PTFE tube with “Water” tag from GA-210 right outlet to the outside, pass it through
the hole of the cap of the polyethylene bottle for washing water (2L), and fix it to prevent the
removal from the bottle.
(2) Set the PTFE tube with “ABS.” tag to the left of the syringe pump with a φ3 nut blue (P306, with
a ferrule P343). Put out the opposite tip from GA-210 left outlet to the outside, pass it through the
hole of the cap of the polyethylene bottle for absorption solution (0.5L), and fix it to prevent the
removal from the bottle.
(3) Put out the PTFE tube with “WASH” tag from GA-210 right outlet to the outside and connect it to
the inlet connector of the U-shaped tube (ball joint side).
(4) Put out 2 PTFE tubes with “ABS. DRAIN” and “SMP. DRAIN” tags from the right bottom of
GA-210 and put them into a drain tank.

CAUTION
Drain from the overflow tank is done by natural flow caused by gravity. When the tip
of the vinyl tube is dipped in the solution in the drain tank, normal flow can not be
assured, and solution can overflow inside the unit. Make sure to set the vinyl tube so
that the tip is always higher than solution level.
(5) Put the vinyl tube for drain with “OVER DRAIN” tag into the drain tank. Fix the tip so that the tip
does not fall out of the tank, and tip does not touch the liquid surface inside the tank.
(2) [ABS.] PTFE tube φ3/2 (1) [WATER] PTFE tube φ3/2
Washing solution

Absorption
solution
(3) [WASH] PTFE tube φ3/2

To an absorption tube
GA-210 φ6/3 Inlet connector
(30-6RU3-T-S)

Ball joint with a

U-shaped tube

Ball joint clip

(long) φ18

(5) [OVER DRAIN]

(4) [SMP. DRAIN] Vinyl tube φ9/7
PTFE tube φ3/2
To a drain tank (4) [ABS. DRAIN] PTFE tube φ3/2
Fig. 3-7. GA-210 Line Connection of Absorption Solution, Washing Solution, and Drain

3-9
Section 3: Installation

3-6-3. Line Connection to the Branch Tube of Pyrolysis Tube

Line connection when using an automatic boat controller such as ABC (ABC-210 or ASC-240S) is
described.
(1) Ar gas line connection for each accessory is described.
• For ABC-210, set the attached φ6/4 reducer joint (30-6RU4E-S) to the Ar gas line from
GAS-OUT INNER TUBE of HF-210 rear and connect it to ABC-210 guide tube (right end).
• For ASC-240S, set the attached insert to the Ar gas line from GAS-OUT INNER TUBE of
HF-210 rear and set it to ASC-240S rear Ar IN with a nut and a ferrule.
(2) Put an O-ring A into the left of the sample introduction box, set an O-ring holder B (8mm in
thickness), and tighten it lightly.
(3) Insert a pyrolysis tube C slowly and deeply into the O-ring holder. Turn the holder to fix the tube
lightly. Turn the pyrolysis tube so that the branch tubes come to the bottom side.
(4) Connect the flange joint of the PTFE tube with “WS Ar” tag from GA-210 rear to the branch tube
of the pyrolysis tube (ABC or ASC side).
(5) Set the attached φ6/4 reducer joint (30-6RU4-S) and the ball joint (female, elbow, φ12.5) to the O2
gas line from GAS-OUT OUTER TUBE of HF-210 rear and connect it to the branch tube of the
pyrolysis tube (electric furnace side).
(6) Tighten the O-ring holder B manually to fix it.
* Open the introduction box cover and check that there are no gap between the pyrolysis tube and the
box. After the check, shut the introduction box cover.
(7) Take the thermal cover (stainless, round) for pyrolysis tube inlet, put it over the pyrolysis tube,
and push it to the electric furnace side.

（7）

C B A
（5）

（4）

Fig. 3-8. Line Connection of ABC-210 or ASC-240S Branch Tube

3-10
 Section 3: Installation

3-6-4. Line Connection of GA-210 and Ion Chromatography Unit

Connect GA-210 sample injector and ion chromatography unit lines.

Always use the attached tube cutter when cutting the PEEK tube (blue).

(1) Connect the inline filter to GA-210 sample injector with the attached PEEK tube (blue).
Use connectors (φ12, EASYFITT) for the both ends. Use a hexagonal nut (HEX FITT #9003,
black) for the injector.
(2) Connect the sample injector of the ion chromatography unit to the inline filter with the attached
PEEK tube (blue).
(3) Connect a joint (1/16 ” connector (#9005)) to the tube from the ion chromatography unit pump
and connect the joint to GA-210 sample injector with the attached PEEK tube (blue).
Ion chromatography unit
(3)
Joint (1/16 ” connector (#9005))

GA-210

Pump

Guide column

Analysis column
Eluent
Injector
4 3
Absorption solution
From IC and standard solution
5 2
Detector
6 1
Drain
Inline filter
Use connectors (φ12, EASYFITT)
Drain To IC for the both ends.
To connect the line for the injector
and IC, use a hexagonal nut (HEX
(2) FITT #9003, black).

Fig. 3-9. Connection of GA-210 and Ion Chromatography Unit Lines

3-11
Section 3: Installation

3-7. Cable Connection

3-7-1. Communication Cable Connection

Connect one of 1 to 8 “ACCESSORIES” connectors of HF-210 rear to “MAIN UNIT” connector of

GA-210 rear with the attached RS-232C cable.

3-7-2. Signal Cable Connection

Connect the signal terminal bottom 1 and 2 of GA-210 rear to IC with the attached signal cables (red
and black).
For the connection position, refer to “1-3. GA-210 Rear Signal Terminals”.

3-7-3. Cooling Fan Signal Cable Connection

Connect the signal cable for the cooling fan to the signal connector of the cooling fan of GA-210 rear.
For the connection position, refer to “1-3. GA-210 Rear Signal Terminals”.

3-7-4. Power Cable Connection

Connect a power cable to “a.c. POWER” connector of GA-210 rear.

3-8. Connection of High Concentration Kit (Optional)

When measurement concentration is 1000ppm or more, use a kit for high concentration (absorption
tube 20ml, sample loop 20μl) to measure accurately.

3-8-1. Absorption Tube Connection

Assemble the 20ml absorption tube by referring to “3-4. Assembly of GA-210 Absorption Part” and
connect it.
3-9. Measuring Tube Connection
Connect or change the measuring tube using the GA-210 operation panel by the following
procedures.
Do not conduct this operation during absorption solution preparation or combustion.
(1) Press [ABSORPTION TUBE] key of GA-210 “WATER FEED” to pour 10ml water into the
absorption tube.
(2) Press [Valve] key to switch to “Load” side.
(3) Change the measuring tube.
(4) Press [ABSORPTION TUBE] key of “ASPIRATE” to take out the water in the absorption tube.
Check that water flows through the PTFE tube with “SMP. DRAIN” tag.
(5) Press [Valve] key to switch to “Inject” side.
(6) When the ion chromatography unit are running, ion chromatography analysis starts.

3-12
 Section 3: Installation

3-10. Operation Check

The procedure for checking each part of GA-210 is described in this section.
Check operation while referring to “Section 1: Names and Functions of GA-210 Unit”.
3-10-1. Check of Absorption Tube Sensor
Check that the line of absorption tube is not in front of the sensor using GA-210 operation panel.
At installation or after absorption tube washing or changing, conduct this operation.
(1) Squeeze the fixing levers of the sensor (upper corners) and lower the sensor to the bottom (LOW
level).
(2) Turn ON GA-210 power switch.
(3) Line position check: Check that the sensor lamp if OFF when the absorption tube is empty.
If the lamp is ON, change the tube positions so that the lamp becomes OFF.
* If there is washing water in the absorption tube, press [Drain] key to drain all washing water
before check.
(4) Sensor response check: Press [Valve] key while pressing [ABSORPTION TUBE] key of
“WATER FEED”. Water injection starts with beeping sound. When washing water reaches the
sensor, injection stops (During this time, gas bubbling is stopped.). Check that solution level
reaches the sensor and the sensor lamp is on.
3-10-2. Check of Washing Water Supply
Using the GA-210 operation panel, check that the washing water is properly supplied into the
absorption tube. Check also for any leakage at connectors. At installation or when the unit is not used
for a long time, conduct this operation to fill the lines with washing water to wash and replace any old
liquids. To operate pumps, refer to “1-5. GA-210 Absorption Part Line Names and Functions” and
“1-6. GA-210 Operation Panel Names and Functions”. By this operation, air removal from the water
supply pumps (P1 and P2) to around the absorption tube and leak inspection are completed.

POINT
By water supply with [ABSORPTION TUBE] key of “WATER FEED“, 10ml
absorption tube is filled within about 20 seconds.
(1) Line washing pump (P2) check: Press [GAS LINE] key of “WATER FEED” to check that proper
amount of washing water flows into the absorption tube and no water leak from connectors. By
this operation, air removal from P2 to the absorption tube through the ball joint with U-shaped
tube and leak check are completed.
(2) Water supply (P1) check: While pressing [ABSORPTION TUBE] key of “WATER FEED”, press
[GAS LINE] key to check that proper amount of washing water flows into the absorption tube.
By this operation, air removal from P1 to the absorption tube and solution supply are completed.
(3) Water supply pumps (P1 and P2) check: Press [ABSORPTION TUBE] key of “WATER FEED”
to check that washing water flows into the absorption tube at double rate.
(4) Check of the drain from the overflow tank: Continue (3) operation, overflow the washing water of
the absorption tube from the overflow tank, and check for proper drain flow.
(5) Water leak check: Check that water does not leak from the connectors around the absorption tube.
By this operation, the inspection of leak around the absorption tube is completed.

3-13
Section 3: Installation

POINT
10ml absorption tube of full capacity should be drained by [DRAIN] key within
about 20 seconds.
(6) Pump (P4) drain check: Press [DRAIN] key to check the complete drain of the absorption tube
and the drain speed.
3-10-3. Check of Syringe Pump Supply
Check the solution supply to the absorption tube by the syringe pump using GA-210 operation panel.
At installation or when the unit is not used for a long time, conduct this operation to wash and replace
lines and syringe pump with fresh absorption solution. For pump operation, refer to “1-5. GA-210
Absorption Part Line Names and Functions” and “1-6. GA-210 Operation Panel Names and
Functions”. By this operation, the absorption solution injection pump (P5) air removal and
replacement are completed.

POINT
The times that [DISPENSE] key is pressed are memorized.
Absorption and injection are run. (Up to 4 times)
(1) Absorption solution injection pump (P5) check: Press [DISPENSE] key three times.
Absorption solution of three strokes is supplied continuously. Check that air in the line is removed
and solution enters the absorption tube.
(2) Repeat (1) operation until all air bubbles in the syringe pump glass are removed.
(3) Press [DRAIN] key to drain all absorption solution in the absorption tube.

3-10-4. Check of Absorption Solution Aspiration

Check the aspiration of absorption solution and solution supply volume by the pump using GA-210
operation panel.
At installation or when the unit is not used for a long time, conduct this operation to fill and replace
lines with fresh solution. For pump operation, refer to “1-5. GA-210 Absorption Part Line Names and
Functions” and “1-6. GA-210 Operation Panel Names and Functions”.
By this operation, air removal from the aspiration pump (P3) to the absorption solution nozzle and
drain check are completed.

POINT
By pressing continuously [ABSORPTION TUBE] key of “ASPIRATE“, 5ml
solution should be aspirated within about 25 seconds.
(1) Press [ABSORPTION TUBE] key of “WATER FEED” to accumulate washing water in the
absorption tube.
(2) Absorption solution aspiration check: Continuously press [ABSORPTION TUBE] key of
“ASPIRATE” and check the liquid flow of the PTFE tube with “SMP. DRAIN” tag.
(3) Press [DRAIN] key to drain all washing solution from the absorption tube.
(4) Solution check: Continuously press [ABSORPTION TUBE] key of “ASPIRATE” and check that
solution is not aspirated from the external solution nozzle. By this operation, washing and drain
check from the aspiration pump (P3) to absorption solution nozzle are completed.

3-14
 Section 3: Installation

3-10-5. Check of External Solution Aspiration

Check the aspiration of external solution and solution supply volume by the pump using GA-210
operation panel. At installation or when the unit is not used for a long time, conduct this operation to
wash and replace lines with fresh water. For pump operation, refer to “1-5. GA-210 Absorption Part
Line Names and Functions” and “1-6. GA-210 Operation Panel Names and Functions”.
By this operation, air removal from the aspiration pump (P3) to the external solution nozzle and drain
check are completed.

POINT
By pressing continuously [ABSORPTION TUBE] key of “ASPIRATE“, 5ml
solution should be aspirated within about 25 seconds.

(1) Place the external solution nozzle in a beaker containing pure water.
(2) External solution aspiration check: Continuously press [EXTERNAL] key of “ASPIRATE” and
check the liquid flow through the PTFE tube with “SMP. DRAIN” tag.
(3) Press [ABSORPTION TUBE] key of “WATER FEED” to accumulate washing water in the
absorption tube.
(4) Take out the external solution nozzle from the beaker, continuously press [EXTERNAL] key of
“ASPIRATE”, and check that absorption tube solution does not decrease.
When the tube is contaminated or external solution is changed, repeat operations (1) to (4).
By this operation, the washing from external solution nozzle to the aspiration pump (P3) and drain
check are completed.

3-15
Section 3: Installation

3-10-6. Check of Humidification Water and Ar Gas Supply

Check humidification water supply using GA-210 operation panel. At installation or when the unit is
not used for a long time, conduct this operation to fill the lines with humidification water and Ar gas.
Always remove the flange joint of the pyrolysis tube right at humidification water supply, and place
the tip into a beaker or hold it with tissue paper.

(1) Put the tip of the PTFE tube with “WS IN” tag into the 0.25L polyethylene bottle containing
humidification water. Check that there is enough humidification water.
(2) Remove the nut of the Z union (TZ3-00 φ4/4/3) “WATER OUT” side of GA-210 rear.
While putting the tip into a beaker or holding it with tissue paper, press [FLOW RATE] key of
“WATER SUPPLY” of GA-210 front for a long time until [F] is displayed at the water supply rate
indicator.
(3) Press [ON] key of “WATER SUPPLY” and press [OFF] key when the line of “WATER OUT” is
filled with humidification water. This takes roughly 40 seconds to 1 minute
(Operating pump: P6). When humidification water does not flow into the line tip even after one
minute, aspirate it with a syringe while pressing [ON] key.
(4) Return the line to the Z union (TZ3-00 φ4/4/3) and press [FLOW RATE] key of “WATER
SUPPLY” to return to the original water supply rate. (Standard setting is 2.)

(2)
WATER OUT
Ar OUT

(3)

Fig. 3-10. Check of Humidification Water and Ar Gas Supply

3-16
 Section 4: GA-210 Functions

Section 4: GA-210 Functions

The functions except GA-210 operation panel are described in this section.
Refer to “1-6. GA-210 Operation Panel Names and Functions” for the control functions from the
operation panel.

4-1. GA-210 Start

Start GA-210.

(1) Turn ON GA-210 power switch.

→ GA-210 power lamp lights and the syringe pump checks the home position.

4-2. Water Supply Pump Switch

The water supply pump can be switched manually from the NSX-2100 application software.
This function is not active during automatic measurement by NSX-2100 application.

(1) Click “Control”, “Accessories”, “GA-210”, and “Water Supply Pump Switch” from the menu.

(2) “Water Supply Pump Switch” window is displayed. Click [On/Off] button to check water supply
start and stop.

(3) Click [Close] button to close “Water Supply Pump Switch” window and return to the status before
opening this window.

4-1
Section 4: GA-210 Functions

4-3. Service Panel

4-3-1. Service Panel Functions

The prepared functions of the service panel can be used manually from NSX-2100 application
software.
The latest parameters are used. To change parameters, open a schedule and change GA-210
parameters. This function is unavailable during automatic measurement by NSX-2100 application.

(1) Click “Control”, “Accessories”, “GA-210”, and “Service Panel” from the menu.

(2) “GA-210 Service Panel” window is displayed.

4-2
 Section 4: GA-210 Functions

Table 4-1. Functions of GA-210 Service Panel

No. Items Contents
1 Wash All All lines and the absorption tube are washed.
Click [Wash All] button to start washing.
Click [Stop] button to stop washing.
The remaining time is displayed in the countdown bar.
2 Constant volume Use this function to obtain the liquid volume up to the
function sensor check sensor for measurements using the constant volume
mode. Refer to “4-3-2. Constant Volume Function
Sensor Check and Constant Volume Mode” for details.
3 Solvent Set Click [Solvent Set] button to prepare absorption
solution. Click [Stop] button to stop the preparation.
The remaining time is displayed in the countdown bar.

4 Absorption solution Absorption solution is injected into IC.

injection Click [Absorption solution injection] button to start
injection. Click [Stop] button to stop injection.
The remaining time is displayed in the countdown bar.
5 External solution number Use this item when optional ES-210 is connected.
Select the number of the external solution selector
nozzle to be used. When ES-210 is not connected, set 1.

6 External solution The sample selected at “External solution number” is

injection injected into IC. Click [External solution injection]
button to start injection. Click [Stop] button to stop
injection. The remaining time is displayed in the
countdown bar.

7 Stop Use this item to stop operations 1 to 6.

8 Water supply pump (P1) By clicking [ON] button, P1 pump operates and the first
digit of “Pump status” in “Status” changes from “0”
to “1”.
Click [OFF] button to stop P1 pump and return to the
original “Status”.
9 Line washing pump (P2) By clicking [ON] button, P2 pump operates and the
second digit of “Pump status” in “Status” changes
from “0” to “1”.
Click [OFF] button to stop P2 pump and return to the
original “Status”.
10 Status GA-210 current status is displayed.
This information may be used for trouble-shooting.
11 Countdown bar and Remaining operation time is displayed by seconds and
remaining time colors.

(3) Click [Close] button to close “GA-210 Service Panel” window and set all functions to the status
before opening this window.

4-3
Section 4: GA-210 Functions

4-3-2. Constant Volume Function Sensor Check and Constant Volume Mode

GA-210 service panel has [Constant volume function sensor check] button to obtain the solution
volume to the liquid level sensor. This button can not be used during automatic measurement.
For the parameters of the constant volume mode, refer to “Table 4-3. GA-210 Parameter Setting Input
Items”.

POINT
Use the constant volume mode when internal standard ion can not be used correctly.
The solution volume to the liquid level sensor is required to calculate concentration in
sample.

Constant Volume Function Sensor Check

By using the ion solution (phosphoric ion standard solution) of known concentration, obtain the each
peak area of the injection to the ion chromatography unit after the dilution to the constant volume
function sensor position and the direct injection to the ion chromatography unit. Calculate the liquid
volume to the sensor by the following formula.

Solution (ml) = 2. Peak area / 1. Peak area × Preset value of absorption solution volume (ml)

Obtain “1. Peak area” by the following procedure.

(1) Pour the ion solution of known concentration into an absorption solution bottle.
(2) Press [DISPENSE] button of GA-210 three times.
→ The contents of the syringe pump are replaced three times.
(3) Refer to “4-6-1. Setting of GA-210 Parameters” to set absorption solution volume (ml).
* Set the preset value of absorption solution volume by the absorption solution tube type and the
liquid level. Refer to the following table.

Table 4-2. Setting Examples of Absorption Solution Volume of Liquid Level Sensor Check
Absorption tube Liquid Preset values of
types Levels Liquid volume to the sensor absorption solution
volume
Low About 11ml 9ml
10ml capacity Middle About 16ml 13ml
High About 18ml 15ml
Low About 17ml 15ml
20ml capacity Middle About 25ml 23ml
High About 30ml 26ml
(4) Click “Control”, “Accessories”, “GA-210”, and “Service Panel” of the menu.
→ “GA-210 Service Panel” window is displayed.

4-4
 Section 4: GA-210 Functions

(5) Click [Constant volume function sensor check] button.

→ Drain - Washing – Setting of ion solution of known concentration (Absorption solution
volume set in GA-210 parameter) – Addition of washing water up to the optical sensor –
Injection to the ion chromatography unit
(6) Obtain the peak area by ion chromatography measurement.
(7) For multiple measurements, repeat (5) to (6).
* To obtain 2. Peak area, measure the ion solution of known concentration by the external solution
injection. Put the external solution nozzle into the ion solution of known concentration and press
[IC INJECT (EXTERNAL)] button of GA-210 operation panel. Obtain the peak area by ion
chromatography measurement.

Constant Volume Mode Use

To run combustion and absorption with the constant volume mode, make the following settings.
(1) Prepare a schedule including GA-210 by Schedule Explore.
(2) Select “Enable” of “Constant volume” in “GA” column in the step list window. (Check “GA;
Constant vol.” in “Step Editor” window.) Set the absorption tube size and the sensor position at
this time to the same values as when the “Constant volume function sensor check” was run.
(3) Refer to “4-6-1. Setting of GA-210 Parameters” and “Table 4-4. Liquid Level and Maximum
Absorption Solution Volume” to set absorption solution volume (ml).

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Section 4: GA-210 Functions

4-4. Skip IC Time

By selecting this menu, the time set at “IC Analysis Time: Min., Sec.” of “GA” column in a schedule
is cancelled and the next step can be run.
(1) Click “Control”, “Accessories”, “GA-210”, and “Skip IC Time” of the menu.

(2) The check window is displayed. Click [Yes] button to stop IC waiting time. Click [No] button to
close the check window.

4-5. Options

4-5-1. Setting of Pump Automatic Turn-On

The GA-210 is equipped with a pump to supply moisture (water) into the pyrolysis tube.
For optimal measurement, it is important to maintain appropriate amount of moisture depending on
the sample characteristic.
Moisture volume can be adjusted with [WATER SUPPLY] button of GA-210 front.
When running automatic measurement by PC control, humidification starts when the electric furnace
is hot.
Though humidification can be started manually, do not supply water into the pyrolysis tube
immediately after the unit start not to make the inside of the tube wet.
For humidification without raising the furnace temperature, remove the flange joint from the branch
tube of the pyrolysis tube, prepare a container for the humidification water from the tip, and then
supply water.

The automatic function of water supply can be changed in the NSX-2100 application software.
(1) Click “Control”, “Accessories”, “GA-210”, and “Options” of the menu.

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 Section 4: GA-210 Functions

(2) “GA-210 Option” window is displayed.

(3) When the following conditions are met while “The pump is turned on automatically.” is checked,
water supply starts automatically. (The box is not checked in factory settings.)
• Electric furnace (HF-210) temperature reaches 95% of preset temperature.
• Electric furnace (HF-210) gas flow is 44ml/min or more.
• Ar gas flow for GA-210 WS is 44ml/min or more.

4-5-2. Setting of Collection Function

The collection function is for taking out the absorption solution for purposes other than directly
injecting into IC.
The absorption solution in an absorption tube can be taken out by GA-210 front operation panel.
The default settings do not use this function, therefore change settings in NSX-2100 application
before use.
Put the line tip into a container and fix it to prevent scattering.

CAUTION
By pushing the [Collection] key of GA-210 front panel while the absorption tube
contains absorption solution and the collection function is set to ON, the solution flows
from the collection nozzle. Always make sure that the tip of the nozzle is fixed in a
container to prevent leak into the unit. When not using this function, set it to OFF.
The method of [Collection] key release in NSX-2100 application and collection is described.

(1) Click “Control”, “Accessories”, “GA-210”, and “Options” of the menu.

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Section 4: GA-210 Functions

(2) GA-210 “Option” window is displayed.

(3) Check “Use [Collection] key”.

→ Click [OK] button.
(4) Put the collection nozzle (PTFE tube with a [Collection] tag) into a container and fix it.
(5) Press [Collection] button of GA-210 front operation panel. While the key is pressed, absorption
solution is supplied from the absorption tube.

(6) When this button is pressed mistakenly, the solution runs from the collection nozzle. Handle used
collection nozzles by any of the following methods.
• Put the collection nozzle tip into the nozzle holder of GA-210 front door inside and uncheck
“Use [Collection] key”.
• Put the collection nozzle tip into a drain tank and fix it.

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 Section 4: GA-210 Functions

4-6. GA-210 Parameters and Operation Sequences

4-6-1. Setting of GA-210 Parameters

GA-210 parameters can be set only when log-in user is analyzer or higher.

(1) Open a schedule and click [Parameter] button.

(2) Click “GA-210” of the left column.
→ The following window is displayed.

(3) Click the right column to change parameters. (Gray items can not be changed.)
(4) Table 4-3 shows the input items of GA-210 parameter setting. Set each item.
(5) Click [StepList] button to save changed parameters and return to the step list.
New parameters are applied when the button is pressed. When during combustion, they are
reflected from the next combustion.

POINT
• Set GA-210 parameters while checking sequence operations.
• When the absorption tube type is changed, change the setting.
• At parameter setting, flow gas of the same volume as combustion conditions to
prevent parameter errors. Flow gas during parameter setting to prevent washing
solution from flowing into the pyrolysis tube.
• The operation command parameters changed during combustion (during sequence
operation) are reflected from the next step.

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Section 4: GA-210 Functions

Table 4-3. GA-210 Parameter Setting Input Items

Default
Values
No. Indications (units) Contents (Setting ranges)
Absorption
Tube Types
Absorption solution injection parameter
1 Absorption For a regular absorption tube, 10ml is 10 20
solution volume (ml) maximum value. For an optional
absorption tube, 20ml is maximum value.
(0.10 to 50.0)
* Set the absorption tube size in “New
Schedule” window. The selected volume is
inputted in the parameter window.
* When using the constant volume mode,
refer to “4-3-2. Constant Volume Function
Sensor Check and Constant Volume
Mode” to set absorption solution volume.
Water supply parameter
2 Water supply scale Set the water supply scale value of the 2 4
humidifier. (0 to 9)
3 Ar flow for Set Ar gas flow for humidification water. 100 100
humidification (32 to 500)
(ml/min)
Washing parameter
4 Water injection time Set the time for supplying water at 15 25
(sec) absorption tube washing. (0 to 99.9)
5 Drain time (sec) Set the time for the drain from the 10 15
absorption tube. (0 to 99.9)
6 Washing times Set the repetition time of water injection 2 2
and drain. (0 to 99)
7 Gas line washing time Set the time for supplying washing water 0.5 0.5
(sec) to the gas line for washing.
The solution used for washing the ball
joint with U-shaped tube flows into the
absorption tube from the combustion gas
inlet. (0 to 99.9)
8 Gas line washing Waiting time after gas line washing 3 3
interval (sec) Set the time necessary for the washing
solution to completely flow through the
ball joint with U-shaped tube. (0 to 99.9)
9 Gas line washing Set gas line washing times. (0 to 99) 3 3
times
10 Washing time of a Set washing time of the sample absorption 5 5
sample absorption line line. (0 to 999)
(sec)
Table 4-3. GA-210 Parameter Setting Input Items

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 Section 4: GA-210 Functions

Default
Values
No. Indications (units) Contents (Setting ranges)
Absorption
Tube Types
Gas line collection parameter
11 Syringe washing times Set times for washing the syringe pump. 3 3
(0 to 10)
12 Collection time (sec) Set the time for collecting adsorbed 0.5 0.5
material from the gas line. During this
time, washing solution passes through the
ball joint with U-shaped tube and flows
from the combustion gas inlet to the
absorption tube. (0 to 99.9)
13 Interval (sec) Waiting time after the collection of 3 3
adsorbed material from the gas line.
Set the time necessary for the washing
solution to stabilize after it passes through
the ball joint with U-shaped tube.
(0 to 99.9)
14 Times Set the times for collecting adsorbed 3 3
material from the gas line. (0 to 99)
Constant volume function parameter
15 Waiting time for Set the time necessary for the liquid 10 10
stable liquid surface surface to stabilize after the purging.
(sec) (0 to 99.9)
16 Mixing time (sec) Set the time for mixing the absorption 10 10
solution by bubbling in the absorption
tube. (0 to 99.9)
Injection parameter
17 Waiting time for Set the waiting time between turning ON 0 0
injection start (sec) the “IC START” of the rear signal terminal
and absorption solution injection into IC.
(0 to 999)
18 Sample purge (sec) Set the time for absorbing absorption 5 5
solution and replacing the line to the
injector. (0 to 999.9)
19 Sample absorption Set the time for changing the valve to the 10 10
time (sec) load side, absorbing absorption solution,
and replacing the measuring tube of the
injector. (0 to 999.9)

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Section 4: GA-210 Functions

POINT
• Refer to Table 4-4 to set the liquid level sensor position (liquid level) by the preset
absorption solution volume. When the absorption tube type is 10ml and absorption
solution volume is changed from 5ml to 10ml, change the liquid level from “Low”
to “Middle”. When using the constant volume mode, calculate the liquid volume of
“Middle” level. (Refer to “4-3-2. Constant Volume Function Sensor Check and
Constant Volume Mode”.)
• The absorption solution volume after combustion and absorption increases
depending on combustion time, line washing solution volume, and water volume
for humidification. When the absorption solution volume after combustion and
absorption is over the liquid level sensor, the error occurs. When the volume is
changed, check the sensor position.

Table 4-4. Liquid Level and Maximum Absorption Solution Volume

Absorption Liquid Maximum absorption
tube types Levels solution volume
Low 6ml
10ml capacity Middle 11ml
High 13ml
Low 12ml
20ml capacity Middle 20ml
High 22ml

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 Section 4: GA-210 Functions

4-6-2. GA-210 and Automatic Measurement

GA-210 is an absorption unit. For the combustion and absorption by AQF-2100H system, use PC and
operate the whole system by NSX-2100 application software. The classification of each operation is
as follows.
As an example of ABC-210 and ASC-240S in AQF-2100H system, the operations from preparation
to combustion and absorption is classified as follows.

Table 4-5. Operation Classification

Schedule Combustion Collection
Injection
Preparation → －Absorption (into
Step (type) (into IC)
→ container)
Set a sample
boat to the
sample
The sample boat returns to
introduction
ABC-210, ASC-240S* the sample introduction
box to
box.
introduce it
to the electric
furnace.
HF-210 Combustion
Absorption
Absorption solution
solution injection
injection Volume
calibration
Absorption
Absorption Absorption
Absorption solution Absorption
solution solution set
injection solution
injection and
Volume collection
GA-210 collection
calibration
Absorption Absorption
solution solution
collection collection
External
solution
External solution injection
injection
Volume
calibration

* For ASC-240S, the sample boat returns to the sample boat box and moves to the tray.

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Section 4: GA-210 Functions

4-6-3. GA-210 Sequences

Besides the operations described in the previous section, there are 2 additional operations; “Wash all”
and “End processing”. Total 7 types of operation sequences are prepared in GA-210.
By the combination of 14 types of packaged actions for GA-210, absorption solution preparation,
absorption, and washing are run.
Table 4-6. Operation Sequences
No. Operation sequences Operation contents
For the injection of absorption solution into the absorption
Absorption solution
1 tube
setting
This operation consists of four actions.
Absorption solution is injected from the absorption tube
Absorption solution
2 into the injector and IC is started.
injection
This operation consists of four actions.
Liquid is injected from an external solution nozzle into the
External solution
3 injector and IC is started.
injection
This operation consists of one action.
The absorption solution of the absorption tube is collected
Absorption solution from the collection nozzle to outside of GA-210.
4
collection This operation consists of three actions and a button
operation.
Absorption tube, gas line, sample absorption tube, and
5 Wash all syringe pump are washed.
This operation consists of four actions.
Absorption tube, gas line, and sample absorption tube are
6 End processing washed.
This operation consists of two actions.
Volume calibration Absorption solution is absorbed from the absorption tube
(Constant volume after constant volume operation, and is injected into the
7
function sensor injector, and IC is started.
check) This operation consists of six actions.

GA-210 parameter setting, each operation flow, and the setting are as follows.
Refer to “Fig. 1-4. GA-210 Absorption Part Lines”, “Table 1-5. Names and Functions of GA-210
Absorption Part Lines”, “Fig. 1-5. GA-210 Operation Panel”, and “Table 1-6. GA-210 Operation
Panel Names and Functions”.
As an example, the parameter values in the operation flow is using default values for a 10ml
absorption tube.

POINT
When measuring tube volume is different, sample absorption time is also different.
Sampling time setting
When an external solution bottle becomes empty during sampling, air fill flow into
lines. Air will eventually reach the IC column and may damage the column. Make
sure that enough solution is prepared, and the “Sample absorption time” (parameter
No. 19) is not too long.

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 Section 4: GA-210 Functions

4-6-3-1. Flow and Settings of Absorption Solution Setting Sequence

Absorption solution setting is operation for injecting absorption solution into an absorption tube.
Setting

Absorption solution setting Gas line washing time (Parameter No.7)

sequence For setting the time of washing the line
inside with washing solution Set it to 0.5
seconds.
Gas line washing interval (Parameter
Gas line washing
No.8) Waiting time before proceeding to
1. Gas line water injection the next step.
(Parameter No.7) Set it to 3 seconds.
2. Waiting (Parameter No.8) Gas line washing times (Parameter
No.9) For setting the times of washing
3 times repetition the line inside with washing solution
（Parameter Set it to 3 times.
No.9）

Absorption tube drain Drain time (Parameter No.5)

Time needed to drain all absorption
(Parameter No.5) solution from overflow status.
Set it to 10 seconds.

Absorption tube washing Water injection time (Parameter No.4)

Time needed to fill an empty absorption
1. Water injection tube up to overflow status by pressing the
(Parameter No.4) [ABSORPTION TUBE] key of
2. Drain (Parameter No.5) “WATER FEED”
Set it to 15 seconds.
2 times repetition Drain time (Parameter No.5)
（Parameter Time needed to drain all absorption
No.6） solution from overflow status.
Set it to 10 seconds.
Washing times (Parameter No.6)
Set the repetition times of water injection
and drain. Set it to 2 times.

Absorption solution injection

(Parameter No.1) Absorption solution volume
(Parameter No.1)
Set the appropriate volume of sample
absorption
End

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Section 4: GA-210 Functions

4-6-3-2. Flow and Settings of Absorption Solution Injection Sequence

Absorption solution injection is operation for injecting absorption solution into the measuring tube of
the injector. The parameter values in the below operation flow are default values.
Setting
Collection time (Parameter No.12)
Absorption solution injection Set the time for collecting adsorbed material
from the gas line. During this time, washing
solution passes through the ball joint with
U-shaped tube and flows into the absorption
1. Gas line collection tube from the combustion gas inlet.
(Parameter No.12) Set it to 0.5 seconds.
Interval (Parameter No.13)
2. Waiting (Parameter No. 13)
Waiting time before proceeding to the next
step. Set the time necessary for the washing
solution to stabilize after it passes through
3 times repetition
the ball joint with U-shaped tube. Set it to 3
(Parameter No.14)
seconds.
Times (Parameter No.14)
Constant volume action
Set the repetition for collecting adsorbed
1. Purge start material in the gas line. Set it to 3 times.
2. Waiting (Parameter No.15)
3. Washing water injection up to
the sensor position
4. Purge end (Parameter No.3) Only when the constant volume
operation is selected
Waiting time for stable liquid surface
(Parameter No.15)
Set the time until the liquid surface is
Mixing stable after the purge. Set it to 10 seconds.
1. Mixing time Ar flow for humidification (Parameter
(Parameter No.16) No.3) Set Ar gas flow for humidification
water. Set it to 100ml/min.

Absorption solution injection

1. 6-way valve change
(INJECT side) Mixing time (Parameter No.16)
Set the time for mixing by bubbling in the
2. Waiting 1 second (fixed)
absorption tube. Set it to 10 seconds.
3. Absorption solution collection
(Parameter No.19)
4. 6-way valve change Waiting time for injection start
(LOAD side) (Parameter No.17)
5. Waiting 1 second (fixed) Set the waiting time until the injector change
6. Absorption solution collection from external output 1 (IC START). Set it to
(Parameter No.19) 0 seconds.
7. Waiting 1 second (fixed) Sample purge time (Parameter No.18)
Set the time for flowing absorption solution
8. External output 1 ON
or external solution and replacing the line to
9. Waiting (Parameter No.17) the injector.
10. 6-way valve change Set it to 5 seconds.
(INJECT side) Sample absorption time
(Parameter No.19)
Set the time for changing the valve to the
load side, flowing absorption solution or
End external solution, and replacing the
measuring tube of the injector.
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 Section 4: GA-210 Functions

4-6-3-3. Flow and Settings of External Solution Injection Sequence

External solution injection is operation for injecting standard sample into the measuring tube of
the injector directly from an external solution injection tube.

External solution injection Setting

External solution injection

1. 6-way valve change
(INJECT side)
2. Waiting 1 second (fixed)
3. Sample absorption valve change
(External solution side) Waiting time for injection start
4. External solution selection (Parameter No.17)
valve change (if available) Set the waiting time until the injector
5. Waiting 2 seconds (fixed) change from external output 1 (IC
6. External solution collection START). Set it to 0 second.
(Parameter No.18) Sample purge time (Parameter No.18)
7. 6-way valve change Set the time for flowing absorption
(LOAD side) solution or external solution and
8. Waiting 1 second (fixed) replacing the line to the injector.
9. Absorption solution collection Set it to 5 seconds.
(Parameter No.19) Sample absorption time
10. Waiting 1 second (fixed) (Parameter No.19)
Set the time for changing the valve to the
11. External output 1 ON
load side, flowing absorption solution or
12. Waiting (Parameter No.17)
external solution, and replacing the
13. 6-way valve change measuring tube of the injector.
(INJECT side)
14. Sample absorption valve
change (Absorption tube side)

End

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Section 4: GA-210 Functions

4-6-3-4. Flow and Settings of Absorption Solution Collection Sequence

Turn this function ON before use in the PC window. Refer to “4-5-2. Setting of Collection Function”.

Setting

Collection time (Parameter No.12)

Absorption solution collection Set the time for collecting adsorbed material
in the gas line. During this time, washing
solution passes through the ball joint with
U-shaped tube and flows into the absorption
1. Gas line collection tube from the combustion gas inlet.
(Parameter No.12) Set it to 0.5 seconds.
2. Waiting (Parameter No. 13) Interval (Parameter No.13)
Waiting time before proceeding to the next
step. Set the time necessary for the washing
3 times repetition solution to stabilize after it passes through
(Parameter No.14) the ball joint with U-shaped tube. Set it to 3
seconds.
Constant volume action Times (Parameter No.14)
Set the repetition for collecting adsorbed
1. Purge start
material in the gas line. Set it to 3 times.
2. Waiting (Parameter No.15)
3. Washing water injection up to
the sensor position
Only when the constant volume
4. Purge end (Parameter No.3)
operation is selected
Waiting time for stable liquid surface
(Parameter No.15)
Set the time until the liquid surface is stable
Mixing
after the purge. Set it to 10 seconds.
1. Mixing time Ar flow for humidification (Parameter
(Parameter No.16) No.3) Set Ar gas flow for humidification
water. Set it to 100ml/min.
Sensor position
Adjust the sensor position and check
A notice is indicated in PC
constant volume.
window.
Press [COLLECTION]
key.

End Mixing time (Parameter No.16)

Set the time for mixing by bubbling in the
absorption tube.
Set it to 10 seconds.

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 Section 4: GA-210 Functions

4-6-3-5. Flow and Settings of “Wash All” Sequence

Always run “Wash All” before measurement.

Wash All sequence Setting

Drain time (Parameter No.5)

Absorption tube drain Time needed to drain all absorption
solution from overflow status.
(Parameter No.5)
Set it to 10 seconds.

Gas line washing Gas line washing time (Parameter No.7)

1. Gas line water injection For setting the time of washing the line
(Parameter No.7) inside with washing solution
2. Waiting (Parameter No.8) Set it to 0.5 seconds.
Gas line washing interval (Parameter
No.8) Waiting time before proceeding to
3 times repetition
the next step.
(Parameter No.9)
Set it to 3 seconds.
Gas line washing times (Parameter
No.9) For setting the times of washing
Syringe pump washing the line inside with washing solution
1. Syringe pump movement to the Set it to 3 times.
home position
2. Absorption solution injection
Syringe washing times
(Parameter No.11)
3 times repetition
(Parameter No.11) Set replacement times for washing the
syringe pump. Set it to 3 times.

Absorption tube drain

Drain time (Parameter No.5)
(Parameter No.5) Time needed to drain all absorption
solution from overflow status.
Set it to 10 seconds.

Absorption tube washing

Water injection time (Parameter No.4)
1. Water injection Time needed to fill an empty absorption
(Parameter No.4) tube up to overflow status by pressing the
2. Drain (Parameter No.5) [ABSORPTION TUBE] key of
“WATER FEED”
2 times repetition Set it to 15 seconds.
(Parameter No.6) Drain time (Parameter No.5)
Time needed to drain all absorption
solution from overflow status.
Set it to 10 seconds.
Continued to the next page Washing times (Parameter No.6)
Set the repetition times of water injection
and drain.
Set it to 2 times.

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Section 4: GA-210 Functions

Setting
Continued from the previous page
Water injection time (Parameter No.4)
Time needed to fill an empty absorption
tube up to overflow status by pressing the
[ABSORPTION TUBE] key of
Washing time of a sample “WATER FEED”
absorption line Set it to 15 seconds.
1. Water injection Washing time of a sample absorption
(Parameter No.4) line (Parameter No.10)
2. Absorption tube adsorption Set washing time of a sample absorption
(Parameter No.10) line.
Set it to 10 seconds.

Absorption tube drain Drain time (Parameter No.5)

Time needed to drain all absorption
(Parameter No.5)
solution from overflow status.
Set it to 10 seconds.

End

4-6-3-6. Flow and Settings of End Processing Sequence

End processing is operation for washing the absorption tube. Always run this operation before
stopping the unit.
Setting
End Processing Sequence

Drain time (Parameter No.5)

Time needed to drain all absorption
Absorption tube drain solution from overflow status.
(Parameter No.5) Set it to 10 seconds.

Water injection time (Parameter No.4)

Absorption tube washing Time needed to fill an empty absorption
1. Water injection tube up to overflow status by pressing the
(Parameter No.4) [ABSORPTION TUBE] key of
“WATER FEED”
2. Drain (Parameter No.5) Set it to 15 seconds.
Drain time (Parameter No.5)
3 times repetition Time needed to drain all absorption
(Parameter No.6) solution from overflow status.
Set it to 10 seconds.
Washing times (Parameter No.6)
End
Set the repetition times of water injection
and drain.
Set it to 3 times.

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 Section 4: GA-210 Functions

4-6-3-7. Flow and Settings of Volume Calibration Sequence

Volume calibration is the operation for checking the constant volume function sensor. Refer to “4-3-2.
Constant Volume Function Sensor Check and Constant Volume Mode”.

Volume calibration sequence

Setting

Drain time (Parameter No.5)

Time needed to drain all absorption
Absorption tube drain
solution from overflow status.
(Parameter No.5) Set it to 10 seconds.

Water injection time (Parameter No.4)

Time needed to fill an empty absorption
Absorption tube washing tube up to overflow status by pressing the
1. Water injection (Parameter No.4) [ABSORPTION TUBE] key of “WATER
FEED”
2. Drain (Parameter No.5) Set it to 15 seconds.
Drain time (Parameter No.5)
Time needed to drain all absorption
solution from overflow status.
3 times repetition Set it to 10 seconds.
(Parameter No.6) Washing times (Parameter No.6)
Set the repetition times of water injection
and drain. Set it to 3 times.

Absorption solution volume

Absorption solution injection
(Parameter No.1)
(Parameter No.1) Set the appropriate volume of sample
absorption.

Constant volume action Only when the constant volume

1. Purge start operation is selected
2. Waiting (Parameter No.15) Waiting time for stable liquid surface
3. Washing water injection up to the (Parameter No.15)
sensor position Set the time until the liquid surface is stable
4. Purge end (Parameter No.3) after the purge. Set it to 10 seconds.
Ar flow for humidification (Parameter
No.3) Set Ar gas flow for humidification
water. Set it to 100ml/min.
Sensor position
Adjust the sensor position and check
Mixing constant volume.
1. Mixing time (Parameter No.16)

Mixing time (Parameter No.16)

Set the time for mixing by bubbling in the
Continued to the next page absorption tube. Set it to 10 seconds.

4-21
Section 4: GA-210 Functions

Continued from the previous page

Setting

Absorption solution injection

1. 6-way valve change Waiting time for injection start
(INJECT side) (Parameter No.17)
2. Waiting 1 second (fixed) Set the waiting time until the injector
3. Absorption solution collection change from external output 1 (IC START).
(Parameter No.18) Set it to 0 second.
4. 6-way valve change Sample purge time (Parameter No.18)
(LOAD side) Set the time for flowing absorption solution
5. Waiting 1 second (fixed) or external solution and replacing the line to
6. Absorption solution collection the injector.
(Parameter No.19) Set it to 5 seconds.
7. Waiting 1 second (fixed) Sample absorption time
(Parameter No.19)
8. External output 1 ON Set the time for changing the valve to the
9. Waiting (Parameter No.17) load side, flowing absorption solution or
10. 6-way valve change external solution, and replacing the
(INJECT side) measuring tube of the injector.

End

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 Section 5: Troubleshooting

Section 5: Troubleshooting
This section describes GA-210 hardware and software troubleshooting.

CAUTION
Do not remove GA-210 cover except for our servicemen.
Electric shock or fire can be caused.
5-1. No Power to the Unit

Causes Countermeasures
The front power switch is not ON. Turn on the front power switch.

The rear main power switch is not Turn on the rear main power switch.
ON.
The power connector of GA-210 Connect the power connector firmly.
rear is disconnected.
The power plug is not inserted Connect the power plug firmly to the outlet.
properly into the outlet.
Power is not supplied to the Check by connecting some other electronic
outlet. instrument to the same outlet.
When it operates properly, GA-210 is broken.
Contact local distributor.

5-2. No Gas Flow

Causes Countermeasures
The gas cylinder valve is closed. Open the gas cylinder valve.
Remaining gas is insufficient. When remaining gas is low, change the cylinder.
The valve for room gas supply is Open the valve.
closed.
Line is disconnected. Connect the line firmly.
Lines are clogged. Replace any clogged parts immediately.

5-1
Section 5: Troubleshooting

5-3. No (or very weak) Response in Ion Chromatography

Causes Countermeasures
The temperature of the electric Check the following points by AQF-2100H system
furnace is not high enough. program.
(1) Is the heater switch button of the tool bar turned to
RED (ON)?.
If not, turn on the heater switch to raise heater
temperature.
(2) Are “Inlet Temp.” and “Outlet Temp.” in
“Temp./Flow” window indicating the set
temperatures?
If not, check measurement parameters.
(3) Are measurement parameters appropriate for the
sample to be measured?
If not, set proper parameters.
Refer to “4-6. GA-210 Parameters and Operation
Sequences” for GA-210 parameters.
When troubles are not solved, contact local
distributor.
Clip for ball joint is disconnected O2 line: Fix the ball joint to the branch tube of the
(inlet side). pyrolysis tube with the clip 12 (long).
Humidification/Ar line: Fix the flange joint to the
branch tube of the pyrolysis tube with the clip 12
(long).
Clip for ball joint is disconnected Fix the ball joint with U-shaped tube to the pyrolysis
(outlet side). tube outlet with the clip 18 (long).
The line to an ion chromatography Connect the line firmly.
unit is disconnected.
The sample concentration is too Increase sample volume or run repetitive combustions.
low.

5-4. Unstable Measurement Values

Causes Countermeasures
Oxygen and argon pressure and Set gas pressure as follows.
flow are improper. (1) Adjust the secondary pressure of the cylinder or the
stop valve to 0.3 ± 0.1MPa with the reducing valve.
(2) Click [Parameter] button of the schedule in NSX-
2100 application software to set the gas flow of the
electric furnace to the specified value.
Temperature setting of the electric Set proper temperature. Refer to the operation
furnace is improper. manual for the proper parameters.
Gas is leaking from pyrolysis tube Check gas leakage. Refer to ‘Gas Leak Check’ of the
connection parts. operation manual for details.

5-2
 Section 5: Troubleshooting

Causes Countermeasures
Pyrolysis tube is contaminated. Clean the contaminated pyrolysis tube:
 Brush the pyrolysis tube with detergent.
 Soak-wash in a washing solution.
In either case, rinse the pyrolysis tube with pure
water and dry thoroughly before use.
Quartz wool in the pyrolysis tube Change the quartz wool in the pyrolysis tube.
is deteriorated. Refer to ‘3-3-1. Filling of Quartz Wool’ of
the operation manual for details.

5-5. Water Leakage inside the Unit

When solution leaks, check it by the following procedure to solve the trouble.

CAUTION
When leakage is found, immediately turn OFF GA-210 power switch with dry hands
and pull out the power plug.

Causes Countermeasures
The collection nozzle protrudes When the nozzle is not in use, insert it into the hole
into the unit. of the overflow tank and wipe the unit inside.

Solution leaks from the overflow Find leakage points by the following procedures and
tank. take measures against them.
(1) Turn OFF GA-210 power switch. Check the
overflow tank surroundings to check that tubes and
connectors are not loose. When leakage points are
found, tighten them more.
(2) Check that the O-ring between the overflow tank
and the absorption tube joint is not twisted or
deteriorated.
When abnormalities are found, solve them or
change the O-ring.
(3) The drain from the overflow tank to the waste tank
is natural drop. Check that the vinyl tube for drain
from the overflow tank side is not bent.
Immersion of the vinyl tube tip into waste water
prevents the drainage.
Dispose of the waste water not to immerse the tip
into solution.
In any case, keep the unit clean by wiping the unit so
that any future leakage can be noticed immediately.

5-3
Section 5: Troubleshooting

Causes Countermeasures
Solution leaks around the (1) Turn OFF GA-210 power switch. Check the
absorption tube. absorption tube surroundings to check that tubes
and connectors are not loose. When leakage points
are found, tighten them more.
(2) Check that the O-ring between the overflow tank
and the absorption tube joint is not twisted or
deteriorated.
When abnormalities are found, solve them or
change the O-ring.
In any case, keep the unit clean by wiping the unit so
that any future leakage can be noticed immediately.
Solution leaks around the pump (1) Turn OFF GA-210 power switch. Check that tubes
for drainage. of the peristaltic pump for drainage and connectors
are not loose. When leakage points are found,
tighten them more.
(2) If leakage is coming from inside of the pump, inner
tubes of the pump may be deteriorated. Change the
peristaltic tube cassette.
In any case, keep the unit clean by wiping the unit so
that any future leakage can be noticed immediately.
Solution leaks around the syringe (1) Turn OFF GA-210 power switch. Inspect the
pump. syringe pump surroundings to check that tubes and
connectors are not loose. When leakage points are
found, tighten them more.
(2) If leakage is coming from the bottom of the syringe
buret, the piston may be deteriorated. If it still leaks
even after re-starting the unit, change the syringe
buret.
In any case, keep the unit clean by wiping the unit so
that any future leakage can be noticed immediately.
Solution leaks around the injector (1) Turn OFF GA-210 power switch. Inspect the
(6-way valve). injector (6-way valve) surroundings to check that
tubes and connectors of the measuring tube are not
loose. When leakage points are found, tighten them
more.
(2) If leakage is coming from the injector valve itself,
the seal rotor may be deteriorated. If it still leaks
even after re-starting the unit, change the seal rotor
and the face stator.
In any case, keep the unit clean by wiping the unit so
that any future leakage can be noticed immediately.

5-4
 Section 5: Troubleshooting
Causes Countermeasures
Solution leaks from the inline Turn OFF GA-210 power switch. If the inline filter is
filter. loose, tighten it. If clogging inside the filter is
suspected (i.e. increase in column pressure), change
the filter and wipe the unit inside.

5-6. Decrease of Water Supply Volume (or Pump Stop)

Causes Countermeasures
The speed of washing solution Run “3-10-2. Check of Washing Water Supply” and
accumulation in the absorption check P1 and P2 operation of water supply pumps.
tube is slower than before. When performance is poor, contact local distributor.
The drain speed from the Run “3-10-2. Check of Washing Water Supply” and
absorption tube is slower than check the drain speed.
before. When performance is poor, contact local distributor.
The aspiration speed of Run “3-10-4. Check of Absorption Solution
absorption solution is slower than Aspiration” and check the aspiration speed.
before. When performance is poor, contact local distributor.
The aspiration speed of external Run “3-10-5. Check of External Solution Aspiration”
solution is slower than before. and check the aspiration speed.
When performance is poor, contact local distributor.

5-7. No Collection of Absorption Solution / Standard Solution and No

Chromatography Peak

Causes Countermeasures
It takes more time to accumulate (1) The pump for supplying absorption solution may be
washing water in the absorption deteriorated. Check the normal injection by running
tube. “3-10-4. Check of Absorption Solution Aspiration”
or “3-10-5. Check of External Solution Aspiration”.
(2) When absorption solution or external solution is not
supplied, V7, V8, or P3 may be broken or
deteriorated. Contact local distributor.

5-5
Section 5: Troubleshooting

5-6
 Section 6: Error Messages and Measures

Section 6: Error Messages and Measures

This section describes error messages and measures displayed when troubles occur.

CAUTION
When “DANGER” or “WARNING” is displayed in the PC monitor, this
indicates risk of serious accidents.
When these messages are displayed, deal with the troubles immediately.

When errors occur, messages are displayed in the PC monitor.

Table 6-1. shows the list of error messages.
Table 6-1. Error Messages

No. Error messages Countermeasures

23 Command reception error during the A command except connection relation was
system down received during system down.
Restart the whole system. If the same error
occurs even after the restart, contact local
distributor.
24 Command reception of water supply The command of water supply pump ON
pump ON while gas is not controlled was received while gas is not controlled.
Restart the whole system. If the same error
occurs even after the restart, contact local
distributor.
50 EEPROM input and output error WIP timeout occurred during EEPROM
input and output.
(WIP timeout)
The memory control error occurred during
memory input and output.
Check the software versions of GA-210 and
PC and contact local distributor.
51 EEPROM input and output error WEL timeout occurred during EEPROM
input and output.
(WEL timeout)
The data writing error occurred during
memory input and output.
Check the software versions of GA-210 and
PC and contact local distributor.
52 EEPROM input error The identification characters input from
EEPROM are not matching.
(Different identification characters)
The identification characters input from the
memory are not matching.
Check the software versions of GA-210 and
PC and contact local distributor.

6-1
Section 6: Error Messages and Measures

No. Error messages Countermeasures

53 EEPROM input error The check sum input from EEPROM the
(Different check sum) memory is not matching.
The check sum input from the memory is not
matching.
Check the software versions of GA-210 and
PC and contact local distributor.
54 EEPROM input error The parameter input from EEPROM is
abnormal.
(Parameter error)
The parameter input from the memory is
abnormal.
Check the software versions of GA-210 and
PC and contact local distributor.
121 Irregular command An unknown command was received.
GA-210 software version may be old.
Check the software versions of GA-210 and
PC and contact local distributor.
124 Control command reception error A control command was received during
during sequence control sequence control. Restart the whole system.
When the same error is indicated even after
the restart, contact local distributor.
126 SRQ reception error during SRQ Before SRQ reply completion, SRQ command
response was received. GA-210 software version may
be old.
Check the software versions of GA-210 and
PC and contact local distributor.
142 Parameter range error Received parameters were out of the range.
GA-210 software version may be old.
Check the software versions of GA-210 and
PC and contact local distributor.
150 A syringe pump communication error No communication with the syringe pump. To
reset the pump, turn OFF GA-210 power
switch. After GA-210 restart, run reconnection
from the menu. If the same error occurs, the
pump may be broken.
Contact local distributor.
151 A syringe pump initialization error
(0x01) Syringe pump error occurred.
152 A syringe pump improper command To reset the pump, turn off GA-210 power
reception error (0x02) switch. After GA-210 restart, run reconnection
153 A syringe pump improper command from the menu. If the same error occurs, the
composition reception error (0x03) pump may be broken. Contact local
distributor.
154 A syringe pump improper command
reception order error (0x04)

6-2
 Section 6: Error Messages and Measures

No. Error messages Countermeasures

155 A syringe pump uninitialization error
(0x07)
156 A syringe pump plunger overcurrent Syringe pump error occurred.
error (0x09) To reset the pump, turn OFF GA-210 power
157 A syringe pump valve overcurrent switch. After GA-210 restart, run reconnection
error (0x0A) from the menu. If the same error occurs, the
158 A syringe pump plunger immovable pump may be broken. Contact local
error (0x0B) distributor.
159 A syringe pump command error
(0x0F)
161 Absorption tube injection timer error After water injection start, the liquid surface
sensor could not detect within the specified
time.
The following causes are expected.
• Washing water is insufficient.
• The sensor position is higher than the
preset volume.
• The preset time is short.
• P1 or P2 pump may be broken.
When pump trouble is suspected, run “3-10-2.
Check of Washing Water Supply” to check
pump operation.
When P1 or P2 pump is deteriorated or
broken, contact local distributor.
162 Absorption tube drainage timer error After drainage start, liquid surface sensor
detection continued within the specified time.
The preset time may be short or drainage pump
P4 may be deteriorated or broken.Set a longer
parameter or change the pump P4.
163 Mass flow controller connection error At initialization, the communication with a
mass flow controller failed.
To reset the mass flow controller, turn OFF
GA-210 power switch. After GA-210 restart,
run reconnection from the menu. If the same
error occurs, the mass flow controller may be
broken. Contact local distributor.
164 Mass flow controller parameter The parameter setting to a mass flow
setting error controller failed.
To reset the mass flow controller, turn OFF
GA-210 power switch. After GA-210 restart,
run reconnection from the menu. If the same
error occurs, the mass flow controller may be
broken. Contact local distributor.

6-3
Section 6: Error Messages and Measures

No. Error messages Countermeasures

165 Mass flow controller flow acquisition The flow acquisition of a mass flow controller
error failed.
To reset the mass flow controller, turn OFF
GA-210 power switch. After GA-210 restart,
run reconnection from the menu. If the same
error occurs, the mass flow controller may be
broken. Contact local distributor.
166 Mass flow controller flow control During gas control, flow was more than
error ±10 % or ± 30 ml (whichever is larger) of the
preset value for 5 seconds.
Utility gas flow fluctuation may be large or
gas residual pressure may be low.
Check the residual quantity of utility gas.
When problem can not be solved even after
flowing gas properly, check GA-210 and PC
software versions, and contact local
distributor.
167 Syringe pump check sum error The check sum of communication data from
the syringe pump is not matching.
To reset the syringe pump, turn OFF GA-210
power switch. After GA-210 restart, run
reconnection from the menu. If the same error
occurs, the syringe pump may be broken.
Contact local distributor.
168 Failure of external solution selection The external solution selection valve could not
valve change be changed within the specified time. To reset
the external solution selection valve, turn OFF
GA-210 power switch. After GA-210 restart,
run reconnection from the menu. If the same
error occurs, the valve may be broken.
Contact local distributor.
169 Hardware error of an external solution A hardware error of the external solution
selection valve selection valve was detected.
To reset the external solution selection valve,
turn OFF GA-210 power switch.
After the power-off, check the valve
connector. After GA-210 restart, run
reconnection from the menu. If the same error
occurs, the valve may be broken.
Contact local distributor.
170 Detection of external solution Cable disconnection was detected at the
selection valve disconnection change of external solution selection valve.
To reset the external solution selection valve,
turn OFF GA-210 power switch.
After the power-off, check the valve
connector. After GA-210 restart, run
reconnection from the menu. If the same error
occurs, the valve may be broken.
Contact local distributor.
6-4
 Section 6: Error Messages and Measures

No. Error messages Countermeasures

170 Detection of external solution Cable disconnection was detected at the
selection valve disconnection change of external solution selection valve.
To reset the external solution selection valve,
turn OFF GA-210 power switch.
After the power-off, check the valve
connector. After GA-210 restart, run
reconnection from the menu. If the same error
occurs, the valve may be broken.
Contact local distributor.
171 Failure of 6-way valve change The 6-way valve could not be changed within
specified time.
To reset the 6-way valve, turn OFF GA-210
power switch. After GA-210 restart, run
reconnection from the menu. If the same error
occurs, the valve may be broken.
Contact local distributor.

6-5
Section 6: Error Messages and Measures

6-6
 Section 7: Maintenance and Inspection

Section 7: Maintenance and Inspection

The maintenance and inspection to use GA-210 safely in the proper conditions are described in this
section.
7-1. Inspection

7-1-1. Daily Inspection

CAUTION
Always conduct daily inspection before measurement. Failure to check the unit can
lead not only to reduced performance of the units, but also to serious accidents.

Table 7-1. Daily Inspection Items

No. Items Contents

1 Contamination check of ball joint Check that there is no contamination from
materials such as soot.
2 Check of the syringe pump When the plunger part of a syringe pump is
contaminated, wash it.
3 Contamination check of PTFE Check that a PTFE tube is not contaminated.
tube It may be contaminated by incomplete
combustion. When it is contaminated, change it
with new one.
4 Contamination check of PTFE Check that a PTFE connector is not contaminated.
connector The inside may be contaminated by incomplete
combustion.
5 PTFE connector change When gas leaks from a PTFE connector or the
screw thread is broken, tighten it more or change
it with new one.
6 Contamination check of Check the contamination of absorption parts of
absorption parts sample gas.
7 Absorption tube change Change the absorption tube depending on sample
concentration. Remove the tube by referring to
“3-4. Assembly of GA-210 Absorption Part” and
change it with new one or one of a different size.
8 Pure water change Prepare fresh pure water every day. When
connecting tubes are contaminated, change them
with new ones.
9 Check of ion chromatography Change the inline filter in the following cases.
column pressure • When the column pressure is significantly
higher than normal
• After incomplete combustion
• When analysis with additive (such as WO3) is
run continuously.

7-1
Section 7: Maintenance and Inspection

The details of each inspection procedure are as follows.

Gas Leak Check

Check that humidification water supply gas (Ar) does not leak as follows. Refer to ‘Gas Leak Check’
of the operation manual for details.

(1) Connect the ball joint of the flow meter for gas leak check to the outlet of the pyrolysis tube.
(2) Check that the preset gas flow agrees with the indicated value of the flow meter.

Contamination Check of Ball Joint

Check that the ball joint is not contaminated with soot from incomplete combustion of sample.
When it is contaminated, wash it as follows.

(1) Wipe the contamination of a ball joint with absorbent cotton soaked in toluene.
(2) Brush the joint with detergent and rinse it with distilled water.
(3) After the washing, dry thoroughly before use.

Check of Syringe Pump

Change the syringe buret of a syringe pump with new one in the following cases.
• The syringe plunger does not move smoothly.
• Air bubbles mix from PTFE part of the plunger end or the solution leaks from the plunger
bottom.

Contamination Check of PTFE Tube

By long-term use and sample incomplete combustion, PTFE tubes can be contaminated.
Replace them with new ones.

Contamination Check of Absorption Parts

When the absorption parts are contaminated, wash them as follows.

Washing with a supersonic washing machine or a brush causes damage.
Therefore wash as follows.
(1) Prepare cleanser in a beaker. For preparation and usage, follow the contents described in the
cleanser package.

(2) Remove the absorption tube and immerse parts in the beaker. Take care not to break them. After
immersing, wash them with ultrapure water. Dry thoroughly before use. When absorption parts
contamination from incomplete combustion can not be removed, wash only the absorption tube
with organic solvents.

7-2
 Section 7: Maintenance and Inspection

CAUTION
Do not flow organic solvents such as toluene and acetone directly into GA-210 lines.
Valves inside GA-210 will break.

Fig. 7-1. Absorption Part Washing Example

7-1-2. Periodical Inspection

Table 7-2. shows the periodical inspection items.

CAUTION
Always conduct periodical inspection in the specified cycle. Failure to check the unit
can lead not only to reduced performance of the unit but also to serious accidents.

Table 7-2. Periodical Inspection Items

No. Items Contents Frequency
1 Pump operation check Check each pump operation by Every 3
referring to “3-10. Operation months
Check”.
2 Cooling fan cleaning Clean the surroundings of the Every 3
cooling fan outlet. months
3 Syringe pump plunger check Air bubbles mix from the plunger or Every 6
the solution leaks from the plunger months
bottom, change the syringe buret.
Refer to “3-5. Syringe Setting”.
4 Inline filter change Change the inline filter by referring Every 6
to “3-6-4. Line Connection of months
GA-210 and Ion Chromatography
Unit”.

7-3
Section 7: Maintenance and Inspection

7-2. Storage of the Unit

Observe the following points when GA-210 will not be used for a long time.

The cautions for storing GA-210 on a table are as follows.

• Remove the power cable and gas lines.

• Disconnect the connection cables between GA-210 and other units.

If the GA-210 is to be stored in another place, store in places with the following conditions.

• Room temperature is 45 degrees Celsius or less.

• No direct sunlight
• No strong vibration and continuous weak vibration
• No strong electromagnetic field
• Humidity is under 80%.
• No corrosive gas
• Fire must not be used.
• Free from much dust
• Flat places

7-4
 Section 8: Specifications

Section 8: Specifications

Standard Specifications

Measurement sample Solid samples, Nonaqueous liquid samples

Target substances Sulfur and halogen compounds
Analysis methods Oxidative decomposition, Gas absorption
Sample injection method Automatic injection by a sample boat (Use ABC.)
Electric furnace 100 to 1100 degrees Celsius
(By using the electric furnace from the same series)
Sample volume Solid samples: 1 to 150mg, Liquid samples: 5 to 100µl
* The volume is different depending on samples. Inject liquid
samples by a syringe.
Measuring By sample loop
Combustion time 5 to 10 minutes per sample
(The time is different depending on sample characteristics and
combustion methods.)
Absorption part Absorption tube : PYREX 10ml or 20ml
Sample injector : Ceramic sample injector
Dispenser : Syringe pump, 5ml gastight syringe
Drain pump : Peristaltic pump (Rotor pump)
Lines : PTFE tube, PEEK tube
Output Start signal (contact) to the analyzer (i.e. ion chromatography data
processing unit)
Gas Argon gas (Purity 99.98% or more, 0.3±0.1MPa)
Daily fluctuation of supply gas pressure: ± 2 % or less
Power AC 100/115/230/240V, 50/60Hz, 50VA
Dimension and weight About 250(W) 430(D) 500(H) mm, About 22kg

8-1
Section 8: Specifications

8-2
 Section 9: Consumables

Section 9: Consumables
9-1. GA-210

Table 9-1. GA-210 Consumables List

No. Parts names Parts Quantity Remarks
numbers
1 Syringe buret 5ml (Cavro®) GA1SB5 1 pc
2 Inline filter (with filter) GA1ILF 1 set
3 Replacement filter (For inline filter) GA1IFP 5 pcs/set
4 Hexagonal nut (HEX FITT, #9003) V8 (injector)
GA1NHF 10 pcs/set IC
Absorption
solution
injection
5 Hexagonal nut φ3 (#9731, with ferrule #9704) GA3N31 10 pcs/set nozzle,
washing
solution nozzle
Absorption
Hexagonal nut φ1/16 solution
6 GA3N34 10 pcs/set
(#9734, with ferrule #9706) collecting
nozzle
7 φ6/3 Reducer inlet connector (30-6RU3-T-S) VA5CNT 1 pc U-shaped tube

8 φ6/3 Reducer elbow connector (30-6RUE3-S) GA163E 1 pc Absorption tube

9 φ3/2 PTFE tube 1m TN5FTS 1 pc

10 φ4/2 PTFE tube 2m TNFT42 1 pc
11 Absorption tube 10ml GA1ABT 1 pc
12 Absorption tube 20ml GA1AB2 1 pc
13 Overflow tank (with O-ring) AQ3OFT 1 pc
14 O-ring (For overflow tank P18) TNP18 5 pcs/set
15 PP tube L-16L GT8NZ1 1 pc
Syringe pump,
16 φ3 Nut blue (P306 with ferrule P343) GA3NFB 10 pcs/set
inner valve
PEEK tube inner diameter 0.25mm blue 3m
17 GA1PTB 1 pc
φ1/16”/0.25
Outer pyrolysis tube φ30 L375 with branch tube 1 pc
18 FN2QPG
ball joint
19 Inner pyrolysis tube (Flange joint) AQ3QPN 1 pc
20 Spring for pyrolysis tube SX1QSP 2 pcs/set
21 Ball joint with U-shaped tube (Quartz) AQ3BJU 1 pc
For the branch
22 Female ball joint, elbow, φ12.5 FN2BFE 1 pc tube of an outer
pyrolysis tube

9-1
Section 9: Consumables

Parts Quantity Remarks

No. Parts names
numbers
For the branch
23 φ6/4 Connector (30-6RU4-S) QF2JGT 2 pcs/set tube of an outer
pyrolysis tube
Flange joint φ15 For the branch
24 AQ3JFL 1 pc tube of an inner
(with O-ring and connector) pyrolysis tube
25 Thermal ring for pyrolysis tube outlet AQ3RIS 1 pc
26 Seal rotor AQ3RTS 1 pc V8 (injector)

27 Face stator AQ3SF7 1 pc V8 (injector)

28 Stator AQ3SF6 1 pc V8 (injector)

29 Peristaltic tube cassette AQ3TCA 1 pc P4 (drain pump)

9-2. Optional Parts

Table 9-2. Optional Parts Consumables List
No. Parts names Parts Quantity Remarks
numbers
1 Sample loop 5μl GA1L05 1 pc For sample injector
2 Sample loop 20μl GA1L20 1 pc For sample injector
3 Sample loop 50μl GA1L50 1 pc For sample injector
4 Sample loop 100μl GA1L11 1 pc For sample injector
5 Sample loop 200μl GA1L21 1 pc For sample injector
6 Attachment set for high concentration AQF3PK 1 set

9-3. Parts Pictures

Table 9-3. GA-210 Parts Pictures
No. Parts names Pictures
1 GA1SB5
Syringe buret 5ml (Cavro®)

2 GA1ILF
Inline filter (with filter)

3 GA1IFP
Replacement filter
(For inline filter)
4 GA1NHF
Hexagonal nut
(HEX FITT, #9003)

9-2
 Section 9: Consumables

No. Parts names Pictures

5 GA3N31
Hexagonal nut φ3
(#9731, with ferrule #9704)
6 GA3N3
Hexagonal nut φ1/16
(#9734, with ferrule #9706)

7 VA5CNT
φ6/3 Reducer inlet connector
(30-6RU3-T-S)

8 GA163E
φ6/3 Reducer elbow connector
(30-6RUE3-S)

9 TN5FTS
φ3/2 PTFE tube 1m

10 TNFT42
φ4/2 PTFE tube 2m

11 GA1ABT
Absorption tube 10ml

12 GA1AB2
Absorption tube 20ml

13 AQ3OFT
Overflow tank (with O-ring)

14 TNP18
O-ring
(For overflow tank P18)

9-3
Section 9: Consumables

No. Parts names Pictures

15 GT8NZ1
PP tube L-16L

16 GA3NFB
φ3 Nut blue
(P306 with ferrule P343)
17 GA1PTB
PEEK tube inner diameter
0.25mm blue 3m φ1/16”/0.25

18 FN2QPG
Outer pyrolysis tube φ30 L375
with branch tube ball joint

19 AQ3QPN
Inner pyrolysis tube
(Flange joint)

20 SX1QSP
Spring for pyrolysis tube

21 AQ3BJU
Ball joint with U-shaped tube
(Quartz)

22 FN2BFE
Female ball joint, elbow, φ12.5

23 QF2JGT
φ6/4 Connector
(30-6RU4-S)
24 AQ3JFL
Flange joint φ15
(with O-ring and connector)

9-4
 Section 9: Consumables

No. Parts names Pictures

25 AQ3RIS
Thermal ring for pyrolysis
tube outlet

26 AQ3RTS
Seal rotor

27 AQ3SF7
Face stator

28 AQ3SF6
Stator

29 AQ3TCA
Peristaltic tube cassette

30 GA1L05
Sample loop 5μl
31 GA1L20
Sample loop 20μl
32 GA1L50
Sample loop 50μl
33 GA1L11 This sample loop is 20μl.
Sample loop 100μl
34 GA1L21
Sample loop 200μl

9-5
Section 9: Consumables

No. Parts names Pictures

35 AQF3PK
Attachment set for high
concentration
(Absorption tube 20ml and
Sample loop 20μl)

9-6