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Science Olympiad

This document is an examination paper for the Third Semester B.Sc. Degree in Chemistry and Industrial Chemistry, focusing on Physical Chemistry I. It includes various sections with questions ranging from definitions and calculations to explanations of concepts such as thermodynamics and crystal structures. The examination covers theoretical and practical aspects of physical chemistry, with a total of 80 marks available.

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vaishnavs211180
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9 views

Science Olympiad

This document is an examination paper for the Third Semester B.Sc. Degree in Chemistry and Industrial Chemistry, focusing on Physical Chemistry I. It includes various sections with questions ranging from definitions and calculations to explanations of concepts such as thermodynamics and crystal structures. The examination covers theoretical and practical aspects of physical chemistry, with a total of 80 marks available.

Uploaded by

vaishnavs211180
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 4

(Pages : 4) P – 4087

Reg. No. : .............................

Name : ..................................

Third Semester B.Sc. Degree Examination, January 2023

Career Related First Degree Programme Under CBCSS

CHEMISTRY AND INDUSTRIAL CHEMISTRY

Core Course VI

IC 1342 : PHYSICAL CHEMISTRY I

(2019 admission onwards)

Time : 3 Hours Max. Marks : 80

SECTION – A

Answer all questions.

1. Explain Bravis lattices.

2. Write Poisuille’s equation.

3. Write the expression for RMS velocity.

4. Define van’t Hoff factor.

5. What is Kirchoff's equation?

6. Define miller indices -

7. Define axis of Symmetry.

8. What is a liquid crystal?

P.T.O.
9. Explain Boyle temperature?

10. What is meant by point group?

(10  1 = 10 Marks)
SECTION – B

Answer any eight questions. Each question carries 2 marks.

11. Calculate RMS velocity of hydrogen gas at room temperature.

12. Explain plane of symmetry, centre of symmetry.

13. Define fugacity.

14. Explain 3 rd law of thermodynamics.

15. Distinguish between molality and molarity.

16. What is meant by abnormal molecular mass?

17. Define collision frequency?

18. Write Vander Waal equation and explain the terms.

19. Differentiate between anisotropy and isotropy.

20. What are isotonic solutions?

21. Explain zero’ th law of thermodynamic.

22. Calculate the maximum efficiency of a Carnot’s engine operating between 110°C
and 25°C.
23. What is collision number?

24. What are the deviation observed from ideal behaviour for real gases?

25. Explain Schottky defect.

26. Briefly explain Rast’s Method.

(8  2 = 16 Marks)

2 P – 4087
SECTION – C

Answer any six questions. Each question carries 4 marks.

27. What are seven crystals systems, explain with example?

28. Explain BCC and FCC lattice type crystal with example.

29. Describe one method for the determination of viscosity.

30. Explain Carnot cycle and its efficiency.

31. Explain Gibbs and Helmholtz free energies and their significances

32. Calculate the entropy change in the evaporation of one mole of water at 100o C
Het of evaporation of water at 100o C = 2259 j/g.

33. Derive Gibb’s-Helmholtz equation.

34. What is meant by fugacity and explain the graphical method for its determination

35. Explain the structure of NaCl with diagram.

36. Describe Beckmann method for determination of molecular mass.

37. Derive the relation between Cp and Cv.

38. Explain state function and path function.

(6  4 = 24 Marks)
SECTION – D

Answer any two questions. Each question carries 15 marks.

39. (a) What are critical constants and explain one method for its determination.

(b) Show the relation between critical constants and wander Wall’s constant.

40. Give an illustration on various types of defects in crystal systems.

3 P – 4087
41. Explain different types of liquid crystals and its applications.

42. (a) Draw the group multiplication table for C2V point group.

(b) Show that in an isothermal expansion of an ideal gas (a)  U = 0 (b)  H= 0

43. Explain Joule-Thomson effect and derive the expression for Joule-Thomson
coefficient.

44. (a) Calculate the change in enthalpy accompanying the heating of one mole
He gas, assumed ideal from a temperature of 298K to a temperature of
1000K at constant pressure. Assume Cv = 3/2R.

(b) Explain the physical significance of entropy determination.


(2  15 = 30 Marks)

————————

4 P – 4087

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