CHEMICAL KINETICS LEVEL-1

CHEMICAL
KINETICS
CHEMICAL KINETICS LEVEL-1
CHEMICAL KINETICS LEVEL-1
1. Chemical kinetics a branch of physical chemistry, deals with
1) Structure of molecules
2) Heat changes in a reaction
3) Physical changes in a reaction

4) Rate of reactions

Solution :
Rate of reactions
CHEMICAL KINETICS LEVEL-1
2. Slowest reaction among the following under identical conditions is
1) NaOH + HCl → NaCl + H2O
2) H+ + OH− → H𝟐 O
3) 2NO + O𝟐 → 2NO𝟐
4) CH𝟒 + 2O𝟐 →CO𝟐 + 2H𝟐 O

Solution :
In ionic compounds, reaction is very fast. But in covalent compounds, if
more bond rearrangements, then much time and reaction is slow.
CHEMICAL KINETICS LEVEL-1
3. Which of the following reaction is a fast reaction at laboratory
temperature
1) Reaction between KMnO4 and oxalic acid
2) Reaction between KMnO4 and mohr's salt
3) Hydrolysis of ethyl acetate
4) Thermal decomposition of N2O5

Solution :
If the reactants are more ionic in nature, then reaction is very fast.
CHEMICAL KINETICS LEVEL-1
4. Under a given set of experimental conditions with increase in the
concentration of the reactants, the rate of chemical reaction
1) Decreases
2) Increases
3) Remains
4) First decreases and increases

Solution :

Rate ∝ (Concentration of reactants)𝐧

CHEMICAL KINETICS LEVEL-1
5. In a chemical reaction, rate of a chemical reaction increases with
temperature. The reason is due to

1) Number of collisions between molecules increases

2) Decreases in activation energy
3) Increase in the number of effective collisions of molecules and
decrease activation energy

4) Kinetic energy of reactants increases

CHEMICAL KINETICS LEVEL-1
Solution :
In a chemical reaction, effective collisions result in more products, effective
collisions are caused by activated molecules. Activated molecules are
formed due to lower activation energy.

∴KEY= (3)
CHEMICAL KINETICS LEVEL-1
6. K represents the rate constant of a reaction when log K is plotted
against 1/T (T=temperature) the graph obtained is a
1) Curve
2) A straight line with a constant positive slope
3) A straight line with constant negative slope
4) A straight line with no slope
Solution :

Rate ∝ Temperature
𝐑𝐚𝐭𝐞
Rate constant (K) =
𝐑𝐞𝐚𝐜𝐭𝐚𝐧𝐭𝐬 𝐧

∴ K ∝ Rate
CHEMICAL KINETICS LEVEL-1
7. With increase in temperature the value of the rate constant of a
reaction generally
1) Increases
2) Decreases
3) May increase or decrease
4) May not change
Solution :
Rate constant ∝ Temperature
CHEMICAL KINETICS LEVEL-1
8. In reactions involving gaseous reactants and gaseous products the units
of rate are
1) Atm 2) Atm-sec 3) Atm.sec-1 4) Atm2 sec2

Solution :
For gaseous reactants instead of concentrations, partial pressures are
considered. So,
Units : (Atm) sec-1

Hence, n = order of reaction.

CHEMICAL KINETICS LEVEL-1
𝐤𝟏 𝐤𝟐 𝐤𝟑
9. In the sequence of reaction A B C D K3>K2>K1; then the
rate determining step of the reaction is

1) C→D 2) A→B 3) B→C 4) A→D

Solution :

The slowest step in the reaction is ‘Rate determining step’. In the given
reaction

K𝟑 > K𝟐 > K𝟏 . So, K𝟏 is slowest.

CHEMICAL KINETICS LEVEL-1
10. A graph is drawn between the concentration of the reactants (taken
on y-axis) and the time of reaction (taken on x-axis). The slope of the
tangent drawn to the graph at a point corresponding to reaction time
t sec. gives
1) Rate of the reaction 2) Rate constant of the reaction
3) Rate of reaction at time t 4) Half life period of the reaction

Solution : 𝐝𝐜
Slope of tangent = Rate = .
𝐝𝐭

Rate of reaction is not constant. It changes with time. So rate of reaction

should be mentioned at a given point of time.
CHEMICAL KINETICS LEVEL-1
11. In which of the following cases, does the reaction go fastest
to completion
1) K=102
2) K=10-2
3) K=10
4) K=1

Solution :
Higher is the rate constant (K), more is the completion of the reaction.
CHEMICAL KINETICS LEVEL-1
𝐤𝟏 𝐤𝟐
12. Chemical reactions of the type X Y Z are called

1) Consecutive reactions
2) Parallel reactions
3) Reversible reactions
4) Chain reactions

Solution :
Sequencial reactions are called ‘Consecutive reaction’.
CHEMICAL KINETICS LEVEL-1
13. The rate of chemical reaction would
1) Increase as the reaction proceeds
2) Decrease as the reaction proceeds
3) May increase or decrease during the reaction
4) Remains constant as the reaction proceeds

Solution :

Rate of reaction decreases as long time as reaction proceeds.

CHEMICAL KINETICS LEVEL-1
14. The factor which does not influence the rate of reaction is
1) Nature of reactants 2) Concentration of the reactants
3) Temperature 4) Molecular mass

Solution :
Factors influencing the rate of reaction are:

1) Nature of reactants
2) Concentration of the reactants
3) Temperature
4) Catalyst
CHEMICAL KINETICS LEVEL-1
15. The rate of chemical reaction depends on the nature of reactants
because
1) The number of bonds broken in the reactant molecules and the
number of bonds formed in product molecules changes

2) Some of the reactants are solids at the room temperature

3) Some of the reactants are coloured

4) Some of reactants are liquid at room temperature

CHEMICAL KINETICS LEVEL-1
Solution :
For ionic compounds rate of reaction is very fast. But in covalent
compounds, it depends on the no.of bonds breaking in reactants and no.of
bonds making in the products.

∴KEY= (1)
CHEMICAL KINETICS LEVEL-1
16. The rate of a reaction decreases with increase in
1) The concentration of the reactants
2) Temperature of the reaction
3) Time of the reaction
4) With all the three

Solution :
Rate of reaction ∝ (Reactants)
As time increases concentration of reactants decreases. So, rate of reaction
decreases.
𝟏
∴ Rate of reaction ∝
𝐓𝐢𝐦𝐞
CHEMICAL KINETICS LEVEL-1
17. Dimensions of rate of reaction involves
1) Concentration only
2) Time only
3) Both concentration and time
4) Neither time nor concentration
Solution :

Rate of reaction ∝ Concentration of reactants

𝟏
Rate of reaction ∝
𝐓𝐢𝐦𝐞
CHEMICAL KINETICS LEVEL-1
18. Which of the following about the rate constant k of a reaction wrong?
1) It remains unchanged throughout the course of reaction
2) It provides a convenient measure of reaction rate
3) It is expressed in the same unit(sec)-1 for all reactions
4) The more rapid the reaction, the larger is the value of k,
the slower the reaction the smaller is its value

Solution :
Units of nth order reaction rate const :
Lit𝐧−𝟏 . mole𝟏−𝐧 . 𝐬𝐞𝐜 −𝟏 (or) Atm 𝟏−𝐧 . sec−𝟏
CHEMICAL KINETICS LEVEL-1
19. For an irreversible chemical reaction, the concentration of the
products with time
1) Increases
2) Decreases
3) Does not change
4) Some more data required

Solution :

As time increases concentration of reactants decreases, concentration of

products increases.
CHEMICAL KINETICS LEVEL-1
20. A catalyst
1) Increases the heat of the reaction
2) Decreases the heat of the reaction
3) Does not alter the heat of the reaction
4) Increases the number of collisions

Solution :

Catalyst increases the rate of reaction by altering the path of the reaction,
but not heat of reaction.
CHEMICAL KINETICS LEVEL-1
21. For the reaction 2NO2→2NO+O2 which of the following is false
1) The decrease in [NO2] and the increase in [NO] proceed at the
same rate
2) The rate of formation of NO is twice the rate of formation of O2

3) The average rates of increase in the concentration of NO and

d d
O2 are expressed as NO and O
dt dt 𝟐

d NO 2d O𝟐
4) =
dt dt
CHEMICAL KINETICS LEVEL-1
Solution :

For the given reaction,

1 d NO𝟐 1 d NO d O𝟐
Rate = − =+ =
2 dt 2 dt dt
1 d NO d O𝟐
∴+ =+
2 dt dt

∴KEY= (3)
CHEMICAL KINETICS LEVEL-1
22. The term dc/dt in a rate equation refers to
1) Concentration of reactants
2) Change in concentration of reactants or products with time
3) Velocity constant of the reaction
4) Concentration of products
Solution :
Change in concentration of reactans and products can be represented as

dc dR dp
=− =+
dt dt dt
CHEMICAL KINETICS LEVEL-1
23. The rate constant is given by the equation K = A.e−𝑬𝒂/𝑹𝑻 which
factor should register a decrease for the reaction to proceed more
rapidly
1) T 2) K 3) A 4) Ea
Solution :
1
Rate of reaction ∝
E𝒂
If activation energy E𝒂 is less, then rate of reaction is more. So, rate
constant (K) also more.
CHEMICAL KINETICS LEVEL-1
24. In Arrhenius plot, intercept is equal to
E 2) ln A 4) log𝟏𝟎 a
1) – 𝒂 3) ln K
R
Solution :
Arrhenious equation :
Ea
log K = − + log A
2.303R
In the form of Y = mx + c
Ea
− is slope and intercept is ‘log A’
2.303R
CHEMICAL KINETICS LEVEL-1
25. In the reaction A→B if the concentration of A is increased by four
times, the rate of the reaction becomes doubled, the order of the
reaction is
1) Zero 2) 1 3) 1/2 4) 2
Solution :
For the given reaction
Rate (r) = K[A]
∵ 2r = K[4A]𝐱
∴ x = 1/2
CHEMICAL KINETICS LEVEL-1
26. In the reaction A+B → Products, if B is taken in excess, then it is an
example of
1) Second order reaction 2) Zero order reaction
3) Fractional order reaction 4) First order reaction

Solution :

Order of the reaction can be known from the no.of reactants participated in
rate determining step (slow step). In the reaction if ‘B’ is taken in excess,
also no.effect on the reaction. Hence the rate of the reaction depends only
on the conc of ‘A’. So it is ‘First order’.
CHEMICAL KINETICS LEVEL-1
27. The units of rate constant for a second order reaction
1) litre sec.
2) lit.mole sec.
3) moles-1.lit.sec- 1
4) moles.sec

Solution :

Units for ‘nth’ order reaction

Lit𝐧−𝟏 . mole𝟏−𝐧 . 𝐬𝐞𝐜 −𝟏 .
CHEMICAL KINETICS LEVEL-1
28. A chemical reaction A+2B→AB2 follows in two steps
A+B → AB(slow)
AB+B → AB2(fast)
Then the order of the reaction is

1) 3 2) 2 3) 1 4) 0

Solution :

Order of the reaction is the no.of reactants involved in slow step.

CHEMICAL KINETICS LEVEL-1
29. The rate equation for the hydrolysis of an ester in presence of NaOH
is, rate = k[ester] [NaOH]. If the concentration of NaOH is increased
by 100 times than that of ester, the order of the reaction will be

1) 1 2) 2 3) 0 4) 3

Solution :

Even the concentration of one of the reactants is increased, if it is not

influenced/it is not included in the r.d.s (slow step).
CHEMICAL KINETICS LEVEL-1
30. When molecules of type A react with molecules of type B in one-step
process to give AB2,the rate law is

1) rate =K[A]1 [B]2 2) rate=K[A]2 [B]1

3) rate=K[2A] [B] 4) rate=K[A] [B]

Solution :

For the given data, rate equation

A + 2B → AB𝟐
𝟐
∴ Rate = K A B
CHEMICAL KINETICS LEVEL-1
31. The rate expression for a chemical reaction
2NO2F→ 2NO2+F2 is given by rate =K[NO2F]
The rate determining step may be
1) 2NOF2 → 2NO2+F2 2) NO2F +F → NO2+F2

3) NO2F → NO2+F 4) NO2+F → NO2F

Solution :

In any chemical reaction, reactants are directly converted into products, in

a single step. The 1st step i.e., slow step is known ‘rate determining step’,
which gives intermediate products and which on further reaction gives final
products.
CHEMICAL KINETICS LEVEL-1
32. The units of rate of reaction and rate constant are identical for
1) Fraction-order reaction 2) Zero-order reaction
3) First-order reaction 4) Second-order reaction
Solution :
Units for nth order reaction
Lit𝐧−𝟏 . mole𝟏−𝐧 . 𝐬𝐞𝐜 −𝟏 .
∴ Units for zero order reaction
mole. lit−𝟏 . 𝐬𝐞𝐜 −𝟏 .
Rate constant for zero order reaction
CHEMICAL KINETICS LEVEL-1
x
(K) = ; x = Concentration = mol.lit−𝟏
t
t = time = sec.
∴ Units for K = mol.lit−𝟏 sec-1

∴KEY= (2)
CHEMICAL KINETICS LEVEL-1
33. The dimensions of rate constant of a second order reaction involves.

1) Neither time nor concentration 2) Only time

3) Time and concentration 4) Time square and concentration

Solution :
Units for second order reaction rate constant:
Lit𝐧−𝟏 . mole𝟏−𝐧 . 𝐬𝐞𝐜 −𝟏 .
It depends on concentration and time.
CHEMICAL KINETICS LEVEL-1
−d NH𝟑
34. represents
dt
1) Rate of formation of Ammonia
2) Rate of decomposition of Ammonia
3) Rate of consumption of N2
4) Rate of consumption of H2
Solution :
Rate is decrease (-ve) in concentration of reactants, or ‘increase (+ve) in
d NH𝟑
concentration of products. So, − is decrease in concentration of
dt
NH𝟑 .
CHEMICAL KINETICS LEVEL-1
35. Which of the following is not a first order reaction
1) Hydrolysis of an ester in acidic medium
2) Decomposition of N2O5
3) Decomposition of H2O2
4) Oxidation of nitric oxide

Solution :

The sum of the powers of the concentration terms of reacting substances is

‘order’ of that reaction.
CHEMICAL KINETICS LEVEL-1
36. The order of a reaction
1) can never be zero
2) can never be fraction
3) must be a whole number
4) can be an integer or a fraction or zero

Solution :

order of reaction can be an integer (or) fraction (or ) zero

CHEMICAL KINETICS LEVEL-1
37. For the reaction A→B the rate law is, rate=k[A]. which of the
following statement is incorrect ?
1) The reaction follows first order kinetics
2) The t𝟏 of reaction depends upon initial concentration of reactants
𝟐
3) k is constant for the reaction at a constant temperature
4) The rate law provides a simple way of predicting the concentration
of reactants and products at any time after the start of the reaction
Solution :

For a first order reaction t𝟏 does not depends on initial concentration of

𝟐
reactants
CHEMICAL KINETICS LEVEL-1
38. The decomposition of Cl𝟐 O is
1) Explosive reactions
2) Second order reactions
3) First order reactions
4) Thermal reactions

Solution :

2Cl𝟐 O → 2Cl𝟐 + O𝟐
Rate = K Cl𝟐 O 𝟐

∴ Order = 2
CHEMICAL KINETICS LEVEL-1
39. For a first order reaction, if ‘a’ is the initial concentration of reactant,
then the half life time is
1) independent of a 2) ∝ a 3) ∝ a2 4) ∝ a3

Solution :

For first order reaction,

0.693
Halt-life t 𝟏/𝟐 =
K
It is independent of initial concentration.
CHEMICAL KINETICS LEVEL-1
dx 𝟏 𝟑
40. The rate expression for a reaction is =K A 𝟐 B 𝟐 the overall order
dt
of the reaction is.
1 3 4) 1
1) 2 2) 3)
2 2

Solution :
1 3
Order = + = 𝟐
2 2
CHEMICAL KINETICS LEVEL-1
41. Which of the following statements is false?
1) A fast reaction has a large rate constant and short half-life
2) Half life depends on concentration of reactants for first order
reaction.
3) For a first order reaction, the half-life is independent of
concentration
4) The half-life of a reaction is half the time required for the reaction
to go to completion

Solution :
For first order reaction, helf-life is independent of concentration of
reactants.
CHEMICAL KINETICS LEVEL-1
42. The hydrolysis of ethyl acetate
𝑯+
CH𝟑 COOC𝟐 H𝟓 + H𝟐 O CH𝟑 COOH + C𝟐 H𝟓 OH is a reaction of
1) Pseudo first order 2) Second order
3) Third order 4) Zero order

Solution :

Rate of reaction is independent of concentration of H𝟐 O.

∴ Rate = K CH𝟑 COOC𝟐 H𝟓 𝟏

∴ Order = 1; but molecularity = 2

CHEMICAL KINETICS LEVEL-1
43. The rates of a reaction at different times are given below
Time (in min) Rate
0 2.8 × 10-2
10 2.8 × 10-2
20 2.8 × 10-2
30 2.79 × 10-2
The order of the reaction is
1) 2nd order 2) zero order
3) 3rd order 4) 1st order
Solution :
For ‘Zero order’ reaction, rate of reaction does not depend on the time.
CHEMICAL KINETICS LEVEL-1
44. Diazonium salt decomposes as
𝟐 Cl → C𝟔 H𝟓 Cl+N𝟐
C 𝟔 H𝟓 N + −

At 0 𝟎 C, the evolution of nitrogen becomes two times faster when the

initial concentration of the salt is doubled therefore it is.

1) A first order reaction.

2) A second order reaction.

3) Independent of the initial concentration of the salt.

4) A zero order reaction
CHEMICAL KINETICS LEVEL-1

Solution :
𝐧
Rate (r) = K A …….(1)
𝐧
2r = K 2A …….(2)
From 1 and 2 equation
∴ n = 1, first order reaction

∴KEY= (1)
CHEMICAL KINETICS LEVEL-1
45. C0=initial concentration of the reactant Ct=concentration of the
reactant at time t, k=rate constant of the reaction. Then the equation
applicable for a first order reaction is
C
1) Ct=C0e-kt 2) Ct=C0ekt 3) C0=Cte-kt 4) 𝟎 = 𝟏
C𝒕
Solution :
For first order reaction
2.303 a
K= log (or)
t a−x
a
=e−𝐤𝐭 According to
a−x
c𝐭 = c𝟎 . e−𝐤𝐭
CHEMICAL KINETICS LEVEL-1
46. A zero order reaction is one whose rate is independent of
1) Temperature of the reaction
2) The concentration of the reactants
3) The concentration of the products

4) The volume of the vessel in which the reaction is carried out

Solution :

For a zero order reaction rate is independent of the concentration of

reactants
CHEMICAL KINETICS LEVEL-1
47. Molecularity of a reaction can be known from
1) The stoichiometric equation
2) The mechanism of the reaction
3) The order of the reaction
4) The energy of activation of the reaction

Solution :

Molecularity of a reaction can be known from the mechanism of the

reaction
CHEMICAL KINETICS LEVEL-1
48. The molecularity of a reaction will be

1) Fractional 2) Zero

3) Positive whole number 4) Negative

Solution :

Molecularity of reaction is always whole number (or) integer. But never

becomes zero (or) negative (or) fractional.
CHEMICAL KINETICS LEVEL-1
49. Which statement is correct ?
1) Molecularity of a reaction is same as the order of reaction
2) In some cases order of reaction may be same as the molecularity of
the reaction
3) Molecularity may be zero
4) Molecularity may be fractional

Solution :

In some cases order of reaction may be same as the molecularity of the

reaction
CHEMICAL KINETICS LEVEL-1
50. Collision theory is applicable to
1) Unimolecular reactions
2) Bimolecular reactions
3) Trimolecular reactions
4) Tetra molecular reactions

Solution :
A + A → A∗ + A
A∗ + A∗ → Products
A∗ = Activated molecule
CHEMICAL KINETICS LEVEL-1
51. To increase the rate of a chemical reaction, catalyst
1) increase the activation energy
2) decrease activation energy
3) reacts with products
4) do not changes the activation energy

Solution :
Catalyst increases the rate of reaction by changing the path of reaction to
decrease the activation energy.
CHEMICAL KINETICS LEVEL-1
52. The energy of activation of a reaction is dependent on
1) Temperature
2) Pressure
3) Concentration
4) Nature of reactants

Solution :

Activation energy depends on nature of reactants, but not on concentration

(or) temperature (or) pressure.
CHEMICAL KINETICS LEVEL-1
53. If the activation energy of both the forward and the backward
reactions are equal then H of the reaction is
1) Zero 2) +Ve 3) -Ve 4) Cannot be predicted

Solution :
For a reversible reaction
If E𝒂𝒇 > E𝒂𝒃 ; ∆H = +Ve
If E𝒂𝒇 < E𝒂𝒃 ; ∆H = -Ve
If E𝒂𝒇 = E𝒂𝒃 ; ∆H = 0
E𝒂𝒇 = E𝒂 of forward reaction
E𝒂𝒃 = E𝒂 of backward reaction
CHEMICAL KINETICS LEVEL-1
54.The rate constant (K1) of one reaction is found to be double that of
the rate constant of (K2) another reaction. Then the relationship
between the corresponding activation energies of two reactions (E1
and E2) can be represented.
1) E1 > E2 2) E1 < E2
3) E1 = E2 4) E1 = 4E2
Solution :
−E𝒂
K = A.e
RT
Lower the E𝒂 , higher is the rate constant.
∴ K𝟏 = 2K𝟐 K𝟏 > 2K𝟐 ∴ E𝟏 < E𝟐
CHEMICAL KINETICS LEVEL-1
55.The rate of a reaction can be increased in general by all the factors
except
1) using a catalyst
2) increasing the temperature
3) increasing the activation energy
4) increasing the concentration of reactants
Solution :
Lower is the activation energy, higher is the rate of reaction.
CHEMICAL KINETICS LEVEL-1
56. The excess of energy required for the reactant molecules to undergo
a reaction is
1) Potential energy
2) Kinetic energy
3) Thermal energy
4) Activation energy

Solution :

The excess of energy required for the reactant molecules to undergo a

reaction is called activation energy
CHEMICAL KINETICS LEVEL-1
57. Threshold energy (TE), internal energy of reactants (IE) and energy
of activation (AE) are related as
1) AE = TE + IE
2) TE = AE + IE
3) IE = AE – TE
4) TE = AE = IE

Solution :

Threshold energy (TE)= Energy of activion (AE) + Internal energy (IE)

CHEMICAL KINETICS LEVEL-1
58. For the exothermic reaction A+B→C+D. H is the heat of reaction
and Ea is the activation energy. The activation energy for the
formation of A+B will be
1) Ea 2) H 3) Ea+ H 4) H – Ea

Solution :
For exothermic reaction
∆H = − ve
A + B→ C + D + heat ∆H
∴ A + B← C + D +∆H + E𝐚
∴ ∆H + E𝒂 is required to form A + B.
CHEMICAL KINETICS LEVEL-1
59.The energy to be possessed by the molecule participating in the
reaction to give the products
1) < Activation energy
2) Threshold energy
3) < Average energy
4) Threshold energy + average energy

Solution :

The energy to be possessed by the molecule participating in the reaction

to give the products is called threshold energy
CHEMICAL KINETICS LEVEL-1
60. For a given reaction which one is higher than the rest among the
following
1) Average energy
2) Threshold energy
3) Activation energy
4) Normal energy

Solution :

Threshold energy
CHEMICAL KINETICS LEVEL-1
61. The value of energy of activation for radio active decay is

1) High 2) Low 3) Almost zero 4) Moderate

Solution :

Radio active substance decays it self. So, external energy is not required.
CHEMICAL KINETICS LEVEL-1
62. In Arrhenius equation, the fraction of effective collisions is given by
1) K=Ae-Ea/RT 2) A 3) e-Ea/RT 4) RT

Solution :

K = A.e−𝐄𝐚/𝐑𝐓
K = Sp. rate
A = Collision frequency (or)
No. of collisions per unit volume
e−𝐄𝐚/𝐑𝐓 = No. of activated molecules
CHEMICAL KINETICS LEVEL-1
63. On increasing the temperature by 100C,
1) Number of collisions get doubled
2) Value of rate constant does not change
3) Energy of activation increases
4) Number of fruitful collisions gets doubled

Solution :
As temperature increases KE of molecules increases and no.of fruitful
collisions increased.
CHEMICAL KINETICS LEVEL-1
64. The threshold energy of a chemical reaction depends upon
1) Nature of reacting species
2) Temperature
3) Concentration of species
4) Number of collisions

Solution :
Threshold energy depends on only nature of reactants. But not on
temperature, concentration pressure or collisions.
CHEMICAL KINETICS LEVEL-1
65. Activation energy is ________ to rate of reaction
1) directly proportional
2) inversely proportional
3) equal
4) not related
Solution :

Lower the activation energy higher is the rate of reaction.

1
∴ E𝒂 ∝
Rate of reaction
CHEMICAL KINETICS LEVEL-1
66.The energy of activation of positive catalyzed reaction as compared
to that of an uncatalyzed reaction is
1) more 2) less
3) same 4) may be more or less

Solution :
Catalyst decreases the activation energy by changing the reaction path.
CHEMICAL KINETICS LEVEL-1
67. For producing the effective collisions, the colliding molecules must
posses
1) A certain minimum amount of energy
2) Threshold energy and proper orientation
3) Proper geometry
4) Energy equal or greater than threshold energy

Solution :
Effective collisions lead to form products. To form products, the molecules
must possess the greater than or equal to threshold energy.
CHEMICAL KINETICS LEVEL-1

Thank you…