SUBJECT : CHEMISTRY

SECTION-I 7. The pH of a 10 – 10 M NaOH solution is nearest

Attempt All 35 questions to:-

1. Which is the set of amphoteric species ? (1) 10 (2) 7

(1) H3O+, HPO2− 4 , HCO3
(3) 4 (4) – 10
(2) H2O, HPO2− −
3 , H 2 P O2
8. The correct relation between hydrolysis constant
(3) H2PO−4 , H2PO−3 , H2O (Kh) and degree of hydrolysis (h) for the
following equilibrium is :
(4) All of these A− + H2 O ⇌ AH + OH −
2. Ksp of AgCl is 1 × 10 – 10. Its solubility in 0.1 M
Kw . C Kw
KNO3 will be : (1) h=√ (2) h=√
Ka Ka . C
(1) 10 – 5 moles/liter (2) > 10 – 5 moles/litre Ka . C
(3) h=√ (4) Ka
–5 h=√
(3) < 10 moles/litre (4) None of these Kw Kw . C

3. Which of the following will not act as buffer:- 9. The solubility of A2B3 is x mol L – 1. Its Ksp is :-
(1) 6 x4 (2) 64 x4
⊕

(1) NH4OH + N H4
(2) HCN + KCN (3) 36 x5 (4) 108 x5
(3) CH3COOH + CH3COONa 10. Three reactions involving H2PO4 – are given
below :-
(4) HCl + NaCl
I. H3PO4 + H2O → H3O+ + H2PO4 –
4. Ka for CH3COOH is 1.8 × 10 – 5. Find out the II. H2PO4 – + H2O → HPO42 – + H3O+
percentage dissociation, in 2M CH3COOH :- III. H2PO4 – + OH – → H3PO4 + O2+
(1) 0.3 (2) 0.9 (3) 18 (4) 36 In which of the above does H2PO4 – act as an
5. The number of milli equivalents of acid in 100 acid ?
mL of 0.5N HCl solution is:- (1) II only (2) I and II
(1) 50 (2) 100 (3) .05 (4) 200 (3) III only (4) I only
6. 40% of HCOOH is neutralised by KOH, then 11. 0.01 M HA(aq.) is 2% ionized, [OH – ] of
determine pH of solution if Ka = 10 – 5 solution is
(1) pH = 7 (2) pH = 5 (1) 2×10 – 4 (2) 10 – 8
(3) pH = 4.78 (4) pH = 4.82 (3) 5×10 – 11 (4) 5×10 – 12
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12. If pkb of CN – is 4.7 then ionisation constant of 16. pH of pure water is 7 at 298K. If the solution is
HCN will be :- heated to 320K, which of the following statement
(1) 2 × 10 – 7 (2) 2 × 10 – 5 is true?
(3) 5 × 10 – 7 (4) 5 × 10 – 10 (1) pH will decrease
13. Percentage of hydrolysis of CH3COONa in its (2) pOH will increase
0.01 M aqueous solution at 25ᵒC is – (3) pH will increase
(Ka for CH3COOH = 1.6 × 10 – 5)
(4) pH will decrease and pOH will increase
(1) 25% (2) 0.25%
17. Conjugate acid of Zn(OH)2 will be :-
(3) 2.5% (4) 0.025%
(1) Zn+2
14. Given below are two statements.
Statement-I: During hydrolysis of CH3COONH4, (2) Zn(OH)+
the products formed undergo hydrolysis as (3) Zn(OH)+2
follow. (4) Zn+
−
CH3 COO + NH4+ + H2 O ⇌ CH3 COOH + NH4 OH
Statement-II:The degree of hydrolysis 18. Which of the following is not an acidic salt :-
of CH3COONH4 is independent of concentration (1) NaHSO4
of solution. (2) HCOONa
(1) Both statement-I & statement-II are correct
(3) NaH2PO3
(2) Only statement-I is correct
(4) None of them
(3) Only statement-II is correct
19. If it is known that H2S is a weak acid and it is
(4) Both statement – I & statement – II are incorrect
ionised into 2H+ and S – 2. Then in this solution
15. Ka for a weak acid HA is 1.44 × 10-5. What is HCl is added so, pH becomes less, then what
the concentration of A. when 0.01 mole of HA is
dissolved in 1L of 0.01M HCl solution? will happen :-

(1) 0.01 M (1) Decrease in S – 2 ion concentration

(2) 1.2 × 10-3 M (2) Concentration of S – 2 is not affected

(3) 1.44 × 10-5 M (3) Increase in S – 2 ion concentration
(4) 0.012 M (4) It is not possible, to add HCl in solution
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20. For a polybasic acid, the dissociation constants 24. If the solubility of calcium fluoride(CaF2) in
have a different value for each step e.g., pure water is x mol/L, Its solubility product is :
H3A ⇌ H+ + H2A – ; K = Ka1 (1) √ 2x (2) 2x2
H2A ⇌ H+ + HA2 – ; K = Ka2
(3) 4x3 (4) x2
HA2 – ⇌ H+ + A3 – ; K = Ka3
What is the observed trend of dissociation 25. Which of these mixtures constitute buffer solutions ?
constants in successive stages? Mixture 1 : 25 mL of 0.10 M HNO3 and 25 mL of
0.10 M NaNO3
(1) Ka1 > Ka2 > Ka3
Mixture 2 : 25 mL of 0.10 M HCl and 25 mL of
(2) Ka1 = Ka2 = Ka3 0.10 M NaOH
(3) Ka1 < Ka2 < Ka3 (1) 1 only (2) 2 only
(4) Ka1 = Ka2 + Ka3 (3) both 1 and 2 (4) neither 1 nor 2
21. Which of the following is not hydrolysed : Na+, 26. In Dumas' method of estimation of nitrogen
K+, ClO−4 , Cl – ? 0.35g of an organic compound gave 55 mL of
nitrogen collected at 300 K temperature and 715
(1) Only Na+ mm pressure. The percentage compostion of
(2) Only ClO−4 nitrogen in the compound would be :
(Aqueous tension at 300 K = 15 mm)
(3) Na+ and Cl – both
(1) 15.45 (2) 16.45
(4) All of the above
22. The solubility of sparingly soluble salt AxBy in
(3) 17.45 (4) 14.45
water is 'S' moles per litre, the solubility product 27. The Lassaigne's extract is boiled with conc
has the value :- HNO3 while testing for the halogens. By doing
so it :-
(1) S2 (2) xyyx.Sx+y
(1) decomposes Na2S and NaCN, if formed
(3) xxyy Sx+y (4) Sx+y
(2) helps in the precipitation of AgCl
23. Select the correct statement :-
(3) increases the solubility product of AgCl
(1) If [H+] = y × 10 – x then pH = x – log y
(4) increases the concentration of NO3 – ions
1
(2) If [H+] =
y
× 10 – x then pH = x + log y 28. Reagent for NH4+ identification test :
(3) pH of a solution = 14 + log [OH] (1) K2HgI2 (2) K2HgI4
(4) All of the above (3) KHgI4 (4) Na2HgI4
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29. Assertion (A): Paper chromatography is a type 32. Paper chromatography is an example of
of partition chromatography.
Reason (R): Moving phase is liquid and (1) Partition chromatography
stationary phase is solid. (2) Thin layer chromatography
(1) Both Assertion & Reason are True & the (3) Column chromatography
Reason is a correct explanation of the Assertion.
(2) Both Assertion & Reason are True but (4) Adsorption chromatography
Reason is not a correct explanation of the 33. During hearing of a court case, the judge
Assertion. suspected that some changes in the documents
(3) Assertion is True but the Reason is False. had been carried out. He asked the forensic
department to check the ink used at two different
(4) Both Assertion & Reason are False. places. According to you which technique can
30. Match the column. give the best results?
Column-I Column-II
(Method) (Separation) (1) Column chromatography
Steam
(A) distillation Aniline-water
(P) mixture (2) Solvent extraction
Simple
(B) distillation (Q) Aniline-chloroform (3) Distillation

Fractional (4) Thin layer chromatography

(C) distillation (R) Glycerol from spent
lye 34. Given below are two statements one is labelled
(D) Distillation at (S) Separate different as assertion (A) other is labelled as reason (R)
low pressure fraction of crude oil.
Assertion (A) : Prolonged heating is
(1) A→P, B→Q, C→S, D→R avoided during preparation of Mohr’s salt.
(2) A→P, B→Q, C→R, D→S Reason (R) : Fe2+ can get oxidised to Fe3+
on prolonged heating In the light of the above
(3) A→Q, B→P, C→S, D→R
statements,
(4) A→R, B→S, C→P, D→Q Choose the correct answer from the option given
31. In detection of 'P' by fusing with Na2O2 and below.
then extracting it with water, we add HNO3 (1) Both (A) and (R) are true but (R) is not
(conc) and ammonium molybdate to get the correct explanation of (A).
(1) Yellow ppt of (NH3)3PO4 (2) (A) is true but (R) is false
(2) Yellow ppt of (NH4)3PO4 . 12MoO3 (3) (A) is false but (R) is true
(3) White ppt of (NH4)3PO4 (4) Both (A) and (R) are true and (R) is
(4) White ppt of (NH4)2PO3 the correct explanation of (A).
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35. Given below are two statements: one is labelled as 38. In Carius method of estimation of halogen. 0.45 g
Assertion (A) and the other is labelled as Reason (R). of an organic compound gave 0.36 g of AgBr. Find
Assertion (A): Yellow coloured precipitate of lead out the percentage of bromine in the compound.
chromate is soluble in hot sodium hydroxide solution. (Molar masses : AgBr = 188 g mol-1: Br = 80 g
Reason (R): PbCrO4 ions react with hot mol-1)
sodium hydroxide solution to form Pb(OH)2. (1) 34.04% (2) 40.04%
In the light of the above statements, choose the most
appropriate answer from the options given below. (3) 36.03% (4) 38.04%
(1) Both (A) and (R) are correct and (R) is 39. Statement-1
–
: Brown ring– test can be done for
the correct explanation of (A) NO3 in presence of NO2 .
(2) Both (A) and (R) are correct but (R) is not
Statement-2 : Oxidation state of iron is changing
from +2 to +1 in the brown ring complex.
the correct explanation of (A)
(1) Statement-1 is true, statement-2 is true and
(3) (A) is correct but (R) is incorrect statement-2 is correct explanation for statement-1.
(4) (A) is incorrect but (R) is correct (2) Statement-1 is true, statement-2 is true and
36. Consider the following statements: statement-2 is NOT the correct explanation
Statement-I: Aqueous solution of ZnCl2 reacts with for statement-1.
NaOH solution to form white precipitate of Zn(OH)2.
Statement-II: Zn(OH)2 is soluble in excess of NaOH (3) Statement-1 is true, statement-2 is false.
solution on heating. (4) Statement-1 is false, statement-2 is true.
In the light of above statements choose the correct 40. Choose the correct matching :
option. Column-I Column-II
(1) Both statement I and statement II are true NaBr + Concn.
(P) (A) Colourless gas
(2) Statement I is true but statement II is false H2SO4 →
(3) Statement I is false but statement II is true (Q) Na2S + dil. HCl → (B) Brown Colour
Rotten Egg
(4) Both statement I and statement II are false (R) NaNO2 + dil HCl → (C)
smell
37. An organic compound contains carbon, (S) NaNO3 + Conc. H2SO4 (D) Paramagnetic
hydrogen and oxygen. Its elemental analysis
gave C, 38.71% and H, 9.67%. The empirical (1) P – B,D; Q – A,C; R – B; S – B,D
formula of the compound would be :- (2) P – B; Q – A,C; R – B,D; S – B,D
(1) CHO (2) CH4O (3) P – B,D; Q – A,C; R – B,D; S – B
(3) CH3O (4) CH2O (4) P – B; Q – A,C; R – A,C; S – B,D
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41. Given below are two statements: 43. Statement-I : The chlorides of Be2+ and Mg2+ do
Statement-I : A solution of [Ni(H2O)6]2+ is not impart any colour to the flame test.
green in colour.
Statement-II : A solution of [Ni(CN)4]2 – is Statement-II : The hydration energy of Be2+ is
colourless. higher than that of Mg2+.
In the light of the above statements, choose the (1) Both Statement I and Statement II are
most appropriate answer from the options given incorrect.
below:
(1) Both Statement-I and Statement-II are
(2) Statement I is correct but Statement II is
incorrect.
incorrect.
(2) Both Statement-I and Statement-II are (3) Statement I is incorrect but Statement II is
correct. correct
(3) Statement-I is incorrect but Statement-II is (4) Both Statement I and Statement II are
correct. correct.
(4) Statement-I is correct but Statement-II is 44. The metal present in the brown ring complex is :
incorrect. (1) Fe (2) Ca2+
42. List-I List-II (3) Al3+ (4) All
(Basic radical) (Group) 45. Why the concentration of sulphide is kept low
(P) Al+3 (1) II group
while performing group II radical test ?
(Q) Zn+2 (2) V group
(1) Radicals of group I can also give the test
(R) Ba+2 (3) IV group
(S) Pb+2 (4) III group (2) Radicals of group II is highly reactive.
(3) Radicals of group IV can also give the test
PQRS at high concentration of sulphide, so for
(1) 4 2 1 3 group II HCl is used to decrease the
(2) 2 4 1 3 concentration of S²¯ ion.
(3) 3 1 2 4 (4) Because it is easier to study the low
(4) 4 3 2 1 ionization process.
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46. Match Column I with Column II and choose the 47. What is the hydronium ion concentration of a
0.25 M HA solution?(Ka = 4 × 10 – 8)
correct combination from the options given.
(1) 10 – 10
Column-I Column II (Gas evolved on (2) 10 – 5
(Anion) reaction with dil. H2SO4)
(3) 10 – 7
Colourless gas which turns (4) 10 – 4
(A) (i)
lead acetate paper black 48. The pH of a 0.1 molar solution of the acid HQ is
Colourless gas which turns 3. The value of the ionization constant Ka of this
acid is :-
(B) (ii) acidified potassium
(1) 1 × 10 – 7
dichromate solution green.
(2) 3 × 10 – 7
Brown fumes which turns (3) 1 × 10 – 3
(C) (iii) acidified KI solution (4) 1 × 10 – 5
containing starch blue. 49. The aqueous solution of AlCl3 is acidic due to :-
Colourless gas evolved with (1) cation hydrolysis
(D) (iv) brisk effervescence, which (2) anion hydrolysis
turns lime water milky (3) hydrolysis of both the ions

(1) (A) → (iii); (B) → (i); (C) → (ii); (D) (4) dissociation
→ (iv) 50. At 25°C a weak acid HX has the dissociation
constant 1 × 10 – 5. It forms a salt NaX on
(2) (A) → (ii); (B) → (i); (C) → (iv); (D) reaction with alkali. The % of degree of
→ (iii) hydrolysis of 0.1M solution of NaX is :-
(1) 0.0001%
(3) (A) → (iv); (B) → (i); (C) → (iii); (D)
(2) 0.01%
→ (ii)
(3) 0.1%
(4) (A) → (iv); (B) → (i); (C) → (ii); (D)
(4) 0.15%
→ (iii)

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