Lakshya JEE Main (2025)

MANTHAN
Chemistry Amines
Exercise -1 (b) Hoffmann bromamide reaction
(c) Reimer Tiemann reaction
(d) Friedal Crafts reaction
NITROGEN CONTAINING COMPOUNDS 10. N, N–dimethyl acetamide is obtained in the reaction:
(a) Acetyl chloride and methanamine
Preparation of Amines (b) Acetyl chloride and ethanamine
1. Which reaction does not give primary amine? (c) Acetyl chloride and dimethylamine
2
(a) CH3CONH2 →
Br /KOH (d) Acetyl chloride and diethylamine
4→ LiAlH 11. Aniline on direct nitration produces:
(b) CH3—C ≡ N 
LiAlH
(a) o–Nitroaniline (b) m–­Nitroaniline
4→
(c) CH3—N C  (c) p–Nitroaniline (d) All of these
(d) None of these 12. Which of the following amine will not react with nitrous
2. Gabriel phthalimide reaction is used in the preparation of: acid to give nitrogen?
(a) Secondary amine (b) Primary aliphatic amine (a) CH3NH2 (b) CH3–CH2–NH2
(c) Primary aromatic amine(d) Tertiary amine
(c) CH3 – CH – NH 2 (d) (CH3)3N
3. C2H5NH2 cannot be prepared by the reduction of: |
(a) C2H5NO2 (b) CH3CH=NOH CH3
(c) C2H5NC (d) CH3CN 13. Aniline on treatment with bromine in CCl4 gives:
4. On heating acetamide in presence of P4O10, which of the (a) Aniline bromide (b) o-bromoaniline
following is formed? (c) o- and p-bromoaniline (d) 2, 4, 6-tribromoaniline
(a) Ammonium acetate (b) Acetonitrile
14. Identify the product Z in the following reaction:
(c) NH3 (d) Methylamine
Ac O Br /CCl HO
5. Aniline can be obtained by: C6 H5 NH 2 

2
→ X 
2 4
→ Y 
2
→Z
(a) Benzoyl chloride and ammonia
(a) p-Bromoaniline (b) p -Bromoacetophenone
(b) Reduction of benzamide
(c) Phenol and ammonia in presence of ZnCl2 (c) o-Bromoacetophenone (d) o-Bromoacetonilide
(d) Benzoic anhydride and ammonia 15. CH3NH2 + CHCl3 + 3KOH → X + Y + 3H2O; Compounds
6. How many molecules of methyl bromide should react with X and Y are:
ethylamine successively to convert the later into a quaternary (a) CH3CN + 3KCl (b) CH3NC + 3KCl
ammonium salt? (c) CH3CONH2 + 3KCl (d) CH3NC + K2CO3
(a) One (b) Two
16. The compound obtained by the reaction between primary
(c) Three (d) Four
amine and aldehyde is:
Reaction of Amines (a) An amide (b) Imine
7. Hinsberg’s reagent is used to distinguish between: (c) Nitrite (d) Nitro
(a) 1° amine and 2° amine (b) 2° amine and 3°amine 17. Nitration of aniline comes under:
 
(c) 1° amine and 3° amine (d) All of these (a) N u-addition (b) N u-substitution
⊕ ⊕
8. Tertiary amine is obtained in the reaction: (c) E -addition (d) E -substitution
CH I CH I
3 → 
(a) Aniline  3 → 18. Lowest boiling point will be of the compound:
CH I
3 → (a) Ethylamine (b) Ethylmethylamine
(b) Aniline 
Sn /HCl
(c) 1-Propanamine (d) N,N-Dimethylmethanamine
(c) Nitrobenzene  →
19. Aqueous bromination of aniline gives:
(d) None of these
(a) 2–Bromoaniline (b) 4–Bromoaniline
9. Which of the following involves nitrene as an intermediate? (c) 2,4,6–Tribromoaniline (d) 2,6–Dibromo aniline
(a) Carbylamine reaction

1
 20. Aniline reacts with alkyl halide to give: 27. Benzenediazonium chloride can be converted into benzene
(a) Amino compound on treatement with:
(b) Tertiary compound (a) H3PO3 (b) H3PO4
(c) Quaternary ammonium compound
(c) H3PO2 (d) HPO3
(d) Azomethane
21. Aniline when treated with conc. HNO3 gives: Cl
NH2 NH2
NO2 28. Diazonium salt + Cu + HCl → ; the reaction is known
(a) (b) as:

(a) Chlorination (b) Sandmeyer’s reaction

NH2
(c) Perkin reaction (d) Gattermann reaction
O NO2 29. Which of the following compound will not undergo azo
coupling reaction with benzene diazonium chloride?
(a) Aniline (b) Phenol
(c) (d)
(c) Anisole (d) Nitrobenzene
30. Para toluidine is treated with HNO2 at ice cold conditions
O and then boiled with water. The final product:
22. Nitro group in nitrobenzene is a: (a) Anthranilic acid (b) p-cresol
(a) Ortho director (b) Meta director (c) Toluic acid (d) Phenol
(c) Para director (d) Ortho and para director 31. In the reaction sequence A, B and C are:
23. Which of the following compound doesn’t gives Hoffmann’s Sn NaNO /HCl H O/ ∆
A  2
→ B  2
→ C → C6H5OH
carbylamine test? HCl 0°C

(a) Benzene, nitrobenzene, aniline

(a) (b) (b) Nitrobenzene, aniline and diazonium salt
NH2 (c) Nitrobenzene, benzene, aniline
(d) Benzene, amino compound, aniline
NH2
(c) (d) Preparation and Chemical Reaction of Alkyl
Cyanides and Nitrocompounds
24. In carbylamine reaction: 32. Nitrobenzene and CH3Cl in presence of anhydrous AlCl3 gives:
(a) The nucleophile is a RNH2 and electrophile is :CCl2. (a) o–Nitrotoluene (b) p–Nitrotoluene
(b) The nucleophile is primary amine and electrophile is (c) Both the above (d) Reaction will not occur
–
CCl3.
– 33. Nitration of which of the following compound is difficult?
(c) The nucleophile is CCl3 and the electrophile is primary
amine. (a) Benzene (b) Nitrobenzene
(d) All of these (c) Toluene (d) Phenol
Reactions of Benzene Diazonium Chloride 34. Choose the false statement amongst the following:
NH2 (a) —NH2 is a strongly activating while —NHCOCH3 is
moderately activating group.
(b) —NO2 is a strongly deactivating while —CHO is
NaNO
2 →(A) 
2 → H O moderately deactivating group.
25.  (B);
HCl, 0 −5°C Boil (c) — NHCR and —CH O are both m–directing groups.
||
Product (B) will be: O
OH N2Cl Cl (d) —CF3 and — CR are both m–directing groups.
||
O
(a) (b) (c) (d) 35. In the reaction:
2 H O/H +
26. In the reaction, the product (C) is: CH3CN + CH3 MgI 
→(A) →(B)
2 NaNO –HCl 2 CuCN H + /H O The compound (B) is
C6 H5 NH 2 
→(A) 
→(B) →(C)
0–5°C KCN (a) Acetic acid (b) Acetone
(a) C6H5CH2NH2 (b) C6H5COOH (c) Acetaldehyde (d) Ethyl alcohol
(c) C6H5OH (d) None of these

2
 4. The final product C, obtained in this reaction would be:
HNO3 /H 2SO 4 (i)Sn/HCl
36. → X 
→ Y . Identify Y. NH2
(ii) OH −

NH2 NH2 Ac O
2 → A 
2 Br
2 →C H O
 → B 
+
CH3COOH
H

(a) (b)
CH3
NH2 NH2 COCH3
NH2 NO2
COCH3 Br
(a) (b)
(c) (d)
NH2
CH3 CH3
NH2 NH2 NHCOCH3
37. Presence of a nitro group in a benzene ring:
Br Br
(a) Activates the ring towards electrophilic substitution.
(b) Deactivates the ring towards nucleophilic substitution. (c) (d)
(c) Deactivates the ring towards electrophilic substitution.
(d) None of these.
CH3 CH3
38. Reduction of alkane nitrile gives:
(a) Primary amine (b) Secondary amine HNO2
A
(c) Carboxylic acid (d) Nitro alkane C6H5CHO
39. Isocyanide reaction involves the intermediate formation of: B
5. C2H5NH2 NOCl
(a) :CCl2 (b) CH3+ C
(c) CH3¯ (d) CCl3• C6H5SO2Cl
D
Which product is a Schiff’s base?
Exercise -2 (a) A (b) B (c) C (d) D
O
1. In a set of reactions, propionic acid yielded a compound (D);
SOCl NH KOH C ⊕
CH3CH2COOH (A) →
2
(B) 
3
→(C) 
→ (D). 6.
(i) KOH
3 
NH → A →B+ C
H O
Br2
(ii)C2 H5Br
What is the structure of (D)? C
(a) CH3CH2CH2NH2 O
(b) CH3CH2CONH2 B and C in the above sequence are:
(c) CH3CH2NHCH3 (a) Benzoic acid + aniline (b) Phthalic acid + ethylamine
(d) CH3CH2NH2 (c) Phthalic acid + aniline (d) Benzoic acid + ethylamine
PCl Na /EtOH
5 → A → B
2. CH3CONH2  7. Which one of the following tests can be used to identify
I II
primary amino group in a given organic compound?
Reaction II is called:
(a) Iodoform test (b) Victor Meyer’s test
(a) Clemmensen reduction
(c) Carbylamine reaction (d) Libermann’s reaction
(b) Stephen reduction
8. At 0°C temperature, reaction of aniline with HNO2 and
(c) Mendius reduction
subsequent treatment with alkaline β–naphthol solution
(d) Bouveault–Blanc reduction produces a precipitate whose colour would be
3. In which of the given reaction, alkylamine is not formed? (a) Black (b) Purple (c) White (d) Orange
(a) R—X + NH3 →
9. In the reaction:
Na
(b) R—CH NOH + [H] →
alc.
O
||
H3O + [H]
H
+ R – C– OH ←  X  → RCH 2 NH 2 ; (X) is:
(c) R—CN + H2O 
→
LiAlH
(a) Isonitrile (b) Nitrile
4→
(d) RCONH2 + 4[H]  (c) Nitrite (d) Oxime

3
 10. Which of the following compound has the maximum value
of dipole moment?
Cl CH3
NO2
H SO
14. C
2 4 → (X). Product (X) is:

NO2
(a) (b) N
OH

Cl
Cl NO2 O

Cl (a) C—NH—CH3
(c) (d)

NO2
O
11. Which of the following statement(s) is/are correct?
(i) In Sandmeyer reaction, nucleophiles like Cl–, Br– and (b) NH—C—CH3
CN– are indroduced in benzene ring in the presence of
Cu+ ion.
 (ii) In Gattermann reaction, nucleophiles are introduced in
benzene ring in the presence of copper powder and HCl.
(iii) The yield in Gattermann reaction is found to be better O
than in Sandmayer reaction. (c) NH2—C—H
(a) (i) and (ii) (b) (i), (ii) and (iii)
(c) (ii) and (iii) (d) (i) and (iii)
12. The major product of the reaction between m-dinitrobenzene
with NH4HS is:
NHSH NH2 O
(d) C—NH2
(a) (b)
NO2 NO2 O
KOBr
NH2 NH2 15. C—NH2 → (A); The compound (A) is:

(c) (d) (a) Ph – CH2 – NH2

NH2 NH2 (b) Ph – NH2
H2N
(c) Ph – CO2H
NH2
aq. NaNO
(d) Ph – NH – CH3
13. 2 → (A). The compound (A) is:

HCl (0°C) O
NH2
OH + –
Br
N2 Cl 16. 2 → (B); Product (B) will be:
N—H 
KOH
(a) (b)
– O
OH N2Cl
N N CO2 CO2
(c) N (d) N (a) (b)
O N
NH2 CO2
H
(c) NH2 NH2 (d) NH2

4
 HNO HF ∆ NHCOCH3 NH2
17. Ph – NH2 
2 → A 
→ B → C , C is:
0°C BF3
Br Br
(a) (b)
(a) Ph – N+ ≡ N BF4

(b) F CH3 CH3

 OH
N2Cl
(c) F F Br
Br
(c) (d)
(d) Ph – F
18. N-Ethyl pthalimide on hydrolysis gives:
CH3
(a) Methyl alcohol (b) Ethyl amine CH3
(c) Dimethyl amine (d) Diethyl amine 23. Which of the following sequence is best suited to convert
19. Which is the best method of preparing 2° amine? benzene to 3-chloro aniline?
(a) CH3Cl + NH3 → (a) Nitration, reduction, chlorination
(b) Chlorination, nitration, reduction
KCN
(b) CH3Cl → 
→
Sn/HCl (c) Nitration, chlorination, reduction
(d) Nitration, reduction, acetylation, chlorination, hydrolysis
O
24. An aromatic amine (X) was treated with alcoholic potash
LiAlH
(c) CH3 C 4→
NH2  and another compound (Y) then foul smelling gas C6H5NC
is formed. The compound (Y) was formed by reacting
CHCl3 /KOH
(d) CH3 NH 2  Sn/HCl
→  → compound (Z) with Cl2 in the presence of slaked lime. The
∆ compound (Z) is:
20. Which of the following amine form N-nitroso derivative (a) CHCl3 (b) CH3COCH3
when treated with NaNO2 and HCl? (c) CH3OH (d) C6H5NH2
25. p-Chloro aniline and anilinium hydrogen chloride can be
(a) CH3NH2 (b) NH2 distinguished by:
(a) Sandmayer reaction (b) Carbyl amine reaction
R R (c) Hinsberg’s reaction (d) AgNO3
26. In order to prepare a 1° amine from an alkyl halide with
(c) N—H (d) N R simultaneous addition of one (—CH2—) group in the
carbon chain, the reagent used as source of nitrogen is
___________.
21. What sequence of reaction would best accomplish the
(a) Sodium amide, NaNH2
following reaction?
(b) Sodium azide, NaN3
? (c) Potassium cyanide, KCN
CN CH2 –
(d) Potassium phthalimide, C6H4(CO)2N K+
(a) LiAlH4,3CH3I/AgOH, ∆
27. (i) CH3COCl
 → product. The major product
(b) LiAlH4,P2O5/∆ (ii) LiAlH 4
N
(c) 20% H2SO4/∆, P2O5/∆
(d) H2, Pd-BaSO4 H
O
obtained is:

NH—C—CH3 (a) (b)

N N
Br
2 → A →
2 H + /H O
22.  B CH2CHO CH2CH3
H 2O
2 NaNO + HCl
2 →D H O
→ C 
 (c) (d)
∆
CH3 N N
In the above sequence of reactions which one is not correct?
CH2CH2OH COCH3

5
 28. The reagents that can be used to convert benzene diazonium CH3
chloride to benzene are_______.
(i) SnCl2,HCl (ii) CH3CH2OH
N N
(iii) H3PO2 (iv) LiAlH4 (b) and CH3CH2NH2
(a) (i) and (ii) (b) (ii) and (iii)
N
(c) (iii) and (iv) (d) (i) and (iii) H3C CH3
29. Which gas will be evolved when [CH 3 CH 2 NH 2 + (c) CH3–CH=NH and CH3CH2NH2
(CH3)2CHNH2] is treated with sodium nitrite and HCl? OH
(a) Chlorine (b) Ammonia |
(c) Dinitrogen (d) NO2 (d) CH3CHNH 2 and (CH3CH2)2NH
30. Which set of the following compounds on reaction with an 35. Primary amines on being heated with CS2 in the presence
alkyl amine gives schiff’s base? of HgCl2 form alkyl/aryl isothiocyanates. The reaction is
(a) HCHO, C6H5CHO, CH3CHO known as:
(b) HCHO, NH2OH, NH2 - NH2 (a) Hoffmann hypobromite reaction
(c) CH3CHO, NH2OH, NH2-NH2 (b) Hoffmann elimination reaction
(d) CH3COCH3, C2H5OH (c) Hoffmann-Martius reaction
(d) Hoffmann mustard oil reaction
31. Consider the following sequence of reactions
CH3 36. When nitrobenzene is heated with fuming HNO3 and conc.
| H2SO4, the product would be:
Br2 1. CH3I(excess)
CH3CH 2 CH CONH 2  → A → B (a) T.N.T. (b) T.N.B. (c) D.D.T. (d) T.E.L.
KOH,heat 2. AgOH,heat
The major product (B) is: 37. Which is the best preparation of butanamine?
CH3 (a) + NH3
| Cl
(a) CH3CH2CH=CH2 (b) CH3CH 2 CHCON(CH3 )2 O
NH3 LiAlH4
CH3 (b)
| OC2H5 D
(c) CH3CH=CHCH3 (d) CH3CH 2 CHN(CH3 )2 O
32. Which of the following statement is not correct regarding
KOH Br N2H4
ethylamine and aniline? (c) N—H D
(a) Each has a –NH2 group.
(b) Both dissolve in HCl.
O
(c) Each reacts with a mixture of CHCl3 and KOH to form
a bad smelling compound temp. CN LiAlH4
(d)
(d) Each reacts with HNO2 at ice-cold temp to give a
hydroxy compound. 38. Arrange the following in increasing basic strength order :
33. Consider the following sequence of reactions: I. F2CHCH2NH2 II. F3C CH2NH2
HNO K Cr O NH2
X(C3 H9 N) 
2 2 7→C H O
2 → C H O 
3 8 3 6 2
H 2SO 4
The
compound (X) is: III.
(a) CH3CH2NHCH3 (b) CH3CH2CH2NH2
(c) (CH3)2CHNH2 (d) (CH3)3N
(a) I < II < III (b) II < I < III
34. The products (A) and (B) are formed in two separate (c) I < III < II (d) II < III < I
reactions of acetaldehyde:
NH
39. Which is weaker base than aniline?
3→
CH3CHO  (A) NH2 O
(i) NH
CH3CHO 
3
→ (B) CN
(ii)H 2 / Ni (a) (b) NH—C—CH3
Here (A) and (B) are
CH3
O
(a) HN NH and CH3CH2NH2 (c) CH3—C NH2

(d) All.
H3C N CH3
H

6
 NO2 NO2
40. Which has least pKb value? + – + – + –
N2Cl N2Cl N2Cl
NH2
O2N NO2
IV. V. VI.
(a) (b)
CH3
N NO2 CH3 CH3
H 47. How many toluidines on reaction with NaNO2/HCl followed
by H3PO2 treatment gives Toluene?
(c) (d) 48. How many N atoms are present in final product?
NH
N NH2

H Sn/HCl
2 3 2→ NaNO /HCl H PO
41. Aniline in a set of reactions yielded a product 
→ 
→ 
NH2 Sn/HCl NaNO 2 /HCl H3PO 2
 →
NO
2
→  → Final product.
NaNO2 CuCN H2 HNO2
A B C D 49. What is the total number of amines that can be prepared by
HCl Ni
Gabriel’s phthalimide synthesis?
The structure of the product D would be
CH2—NH2
(a) C6H5NHOH (b) C6H5NHC2H5 NH2
(c) C6H5CH2OH (d) C6H5CH2NH2
42. In the following reaction, (a) (b)
CH3
NaNO2
NH2 CH3
HCl/D
The expected product(s) is/are NH2
H
CH3 CH 3 N
(a) OH (b) (c) (d)
OH
CH3
Me
OH CH 3
(c) CH 3 (d) N
(e) (f)
43. The incorrect statement(s) between Curtius and Hoffmann NH2
degradation is/are:
(a) Both involve nitrene intermediate (g) NH2 (h) N
(b) Both involve intramolecular alkyl shift
(c) Curtius reaction uses NaN3 while Hoffmann degradation H
uses NaOBr (i) NH2
(d) Curtius reaction gives 1° amine while Hoffmann
degradation gives 2° amine. 50. How many of the following gives visible change when
treated with nitrous acid? (NaNO2 + HCl)?
INTEGER TYPE QUESTIONS
i. CH3CH2CH2NH2 ii. CH2CH2NHCH3
44. How many amide isomers exist for C 5H 11ON that on H
treatment with NaOH/Br2 give amines?
45. How many isomeric diaminobenzoic acid can be converted N
into m-phenylene diamine on decarboxylation? N
iii. iv.
46. How many of the following diazonium salts are less reactive
than (I) towards Diazo coupling reaction?
+ – + – + – v. CH3CH2CONH2 vi. CH3CH2CH(CH3)NO2
N2Cl N2Cl N2Cl
NHCH3
NO2 vii. CH3CH2N(CH3)2 viii.
I. II. III.

ix. CH3COOC2H5
NO2 NO2

+ – + – + –
N2Cl N2Cl N2Cl 7
O2N NO2
IV. V. VI.
CH
 Exercise -3

SINGLE CORRECT TYPE: (1-45)

1. Primary, secondary and tertiary amines can be separated by
the following except:
(a) Fractional distillation
(b) Fractional method using diethyl oxalate

(c) Hinsberg’s method using C6 H5SO2Cl2
(a) I < IV < II < III (b) IV < II < I < III
(d) Selective crystallisation
(c) I < II < IV < III (d) III < IV < II < I
2. Predict about the relative boiling point of the following two
amines.

(I) (II)

(a) Boiling point of I > II 7.

(b) Boiling point of II > I
(c) Both should have equal boiling points
(d) It can’t be predicted. Identify the product (B) in the above reaction sequence.
3. Predict the nature of A in the following reaction:

( CH3 )3 CCH 2 NH 2 →
HONO
A ( main product ) (a) (b)
(a) (CH3)3CCH2OH
(b) (CH3)3CCH = CH2
(c) (CH3)3C(OH)C2H5
(d) (CH3)3CCH2NH(NO)
(c) (d)

4.
8. Structure of ‘A’ is
(a) (b)

(a) (b)

(c) (d)
(c) (d)
5. In which one of the following reactions does the amine
behaves as an acid? 9. The major product formed in the following reaction is
 
(a) ( C 2 H 5 )3 N + BF3
(b) CH3NH2 + H2O

(a) H3C – CH = CD2

(c) + C4H9Li
(d) (C2H5)2NH + H2PtCl6
6. For the following diazonium ions, the correct order of (b)
reactivity towards diazo coupling with phenol in the presence
of dil. NaOH is
(c) H2C = CH – CD3
(d) H2C = N – CH3

8
 (c)
10.

(d) All of these

14. Which one of the following will not undergo Hoffmann
(a) bromamide reaction?

(b) (a)

(c)
(b)

(d)
(c)
11. → Intermediate + N2 What is the nature
of intermediate in above reaction?
(a) Carbonium ion (b) Carbanion
(c) Carbene (d) Free radical
(d)
12. A compound (X) has the molecular formula C3 H7NO. With
Br2 and KOH, (X) gives (Y). (Y) responds to mustard oil
reaction. (Y) upon treatment with HNO2 evolves N2 and
gives an alcohol (Z) which gives iodoform test. (X) is likely ONE OR MORE THAN ONE CORRECT TYPE:
to be
(a) C2 H5 CONH2 (b) CH3 CONH2 STATEMENT TYPE:
(c) CH3 COONH4 (d) C2 H5 CNO 15. Statement-I: Aryl amines cannot be prepared by Gabriel’s
13. Which one of the following products will be obtained in phthalimide synthesis.
the given (consider minor product also) Beckmann-type Statement-II: Aromatic halides do not give SN2 reactions.
rearrangement?
(a) Both statement-I and statement-II are correct.
(b) Statement-I is correct but statement-II is incorrect.
(c) Statement-I is incorrect but statement-II is correct.
(d) Both statement-I and statement-II are incorrect.
16. Statement-I: Methyl cyanide has higher boiling point than
methyl isocyanide.
Statement-II : Methyl cyanide has co-ordinate bond
(a) between N and C.
(a) Both statement-I and statement-II are correct.
(b) Statement-I is correct but statement-II is incorrect.
(c) Statement-I is incorrect but statement-II is correct.
(b)
(d) Both statement-I and statement-II are incorrect.

9
MATCH-MATRIX TYPE: 20. Of the following amines how many can give carbyl amine
reaction?
17. Match the following:
Column-I Column-II
(I) Curtius reaction (p) R–CO–NH–O–
OH −
CO–R’ 
→
(II) Gabriel (q)
phthalimide RCON3 ∆
→ 21. Of the following amines, how many can be separated by
− N2
reaction R – N = C = O Hoffmann’s mustard oil reaction?
H2O
 →
RNH2+CO2
(III) Lossen (r) Conversion of an
rearrangement alkyl phthalimide
into RNH2
(IV) Schmidt reaction (s) Involves S N2 Exercise -4 (PYQ’s)
displacement
(t) RCOOH + N3H PREPARATION AND CHEMICALREACTIONS
H 2SO 4
→
OF ALIPHATIC AMINES
RNH2+CO2+N2 Single Correct
(a) (I)- q; (II)- r, s; (III)- p; (IV)- t
1. CH3NH2 + CHCl3 + KOH → Nitrogen containing compound +
(b) (I)- p; (II)- q, r; (III)- s; (IV)- t
KCl + H2O. Nitrogen containing compound is (IIT JEE 2006)
(c) (I)- r; (II)- q, p; (III)- s; (IV)- t (a) CH3CN (b) CH3NHCH3
(d) (I)- s; (II)- p, q; (III)- r; (IV)- t – + + –
(c) CH3 N C (d) CH3 N C
18. Match the following:
2. Carbylamine test is performed in alc. KOH by heating a mixture
Column-I (Reactant) Column-II of
(I) RX+KCN (p) (a) chloroform and silver powder (IIT JEE 1984)
ethanol
→ (b) trihalogenated methane and a primary amine
(c) an alkyl halide and a primary amine
(II) RX+CH3COOAg (q) RCN
(d) an alkyl cyanide and a primary amine
(III) LiAlH
(r) CH3COOR
CH3C≡N →
4
3. Acetamide is treated separately with the following reagents. Which
of these would give methylamine? (IIT JEE 1983)
(IV) (s) CH3CH2NH2
(a) PCl5 (b) Sodalime
(c) NaOH + Br2 (d) Hot, conc.H2SO4
Hofmann 's 4. The compound which on reaction with aqueous nitrous acid at low
 →
deg radation temperature produces an oily nitrosamine, is  (IIT JEE 1981)
(t) RNC (a) methylamine (b) ethylamine
(a) (I)- q; (II)- r; (III)- s; (IV)- p (c) diethylamine (d) triethylamine
(b) (I)- p; (II)- r; (III)- s; (IV)- t Multiple Correct
(c) (I)- r; (II)- q; (III)- s; (IV)- t 5. The major product of the reaction is (JEE Adv. 2015)
(d) (I)- s; (II)- p; (III)- r; (IV)- t
H 3C CO2H
19. Examine the structural formula of following compounds and NaNO2, aq.HCI
identify how many compounds are more basic than aniline? CH3 NH2
0°C

H 3C NH2 H 3C CO2H
(a) (b)
CH3 OH CH3 OH
H 3C CO2H H 3C NH2
(c) (d)
CH3 OH CH3 OH

10
 6. Reaction of RCONH2 with a mixture of Br2 and KOH gives R – NH2 Fill in the Blanks
as the main product. The intermediates involved in this reaction
10. (CH3OH2+) is _________ acidic than (CH3NH3+). (IIT JEE
are (IIT JEE 1992) 1997)
(a) RCONHBr (b) RNHBr
(c) R – N = C = O (d) RCONBr2 Subjective
NaNO2,HCI
11. C5H13N (tertiary alcohol + other
Comprehension/Passage Based – N2
optically active products)
Treatment of compound O with KMnO4 /H+gave X
Find X and Y. Is Y optically active? Write the intermediate steps.
P, which on heating with ammonia gave Q.
 (IIT JEE 2005)
The compound Q on treatment with Br2/NaOH
12. Give reasons for the following in one or two sentences. Dimethylamine
produced R. On strong heating, Q gave S, which is a stronger base than trimethylamine in H2O. (IIT JEE 1998)
on further treatment with ethyl 2-bromopropanoate
13. A basic volatile nitrogen compound gave a foul smelling gas when
in the presence of KOH followed by acidification, treated with chloroform and alcoholic KOH. A 0.295g sample
gave a compound T. (O) of the substance dissolved in aq. HCl and treated with NaNO2
solution at 0°C, liberated a colourless, odourless gas whose volume
corresponds to 112mL at STP.
7. The compound T isC-28.12 W-70.01 UA-1.87 (JEE Adv. After evolution of the gas was complete, the aqueous solution was
2016) distilled to give an organic liquid which did not contain nitrogen and
which on warming with alkali and iodine gave a yellow precipitate.
(a) glycine (b) alanine Identify the original substance assuming that it contains one N-atom
(c) valine (d) serine per molecule (IIT JEE 1993)
8. The compound R isC-31.64 W-66.15 UA-2.21 (JEE ADV. 2016) 14. Give a chemical test and the reagent used to distinguish between
O the following: “Ethylamine and diethylamine”. (IIT JEE 1988)
NH2 15. Arrange the following in increasing order of basic strength:
Br methylamine, dimethylamine, aniline, N-methylaniline.
(a) (b)  (IIT JEE 1988)
Br
NH2 16. Following reaction gives two products. Write the structures of the
products.
O (CH3CO)2O, heat
O O CH3CH2NH2  (IIT JEE 1988)
17. For nitromethane molecule, write structures
NHBr (i) showing significant resonance stabilisation
(c) (d) NBr (ii) indicating tautomerism (IIT JEE 1986)
NHBr
18. State the equation for the preparation of following compounds:
n-propyl amine from ethyl chloride (IIT JEE 1982)
O O
Match the Column PHYSICAL PROPERTIES OF ALIPHATIC
9. Match each of the compounds in Column-I with its characteristic AMINES
reaction(s) in Column-II (IIT JEE 2009)
Single Correct
Column-I Column-II
19. The order of basicity among the following compounds is
(A) CH3CH2CH2CN (p) Reduction with Pd-
C-50.87 W-31.28 UA-17.85 (JEE Adv. 2017)
C//H2
NH

(B) CH3CH2OCOCH3 (q) Reduction with N NH
SnCl2//HCl H3C NH2

(C) CH2CH = CHCH2OH (r) Development of foul (I) (II)
smell on treatment
with chloroform and NH2
alcoholic KOH H N N
H2N NH
(D) CH3CH2CH2CH2NH2 (s)  Reduction with
diisobutylalu (III) (IV)
minium hydride
(a) II > I > IV > III (b) I > IV > III > I
(DIBAL-H)
(c) IV > II > III > I (d) IV > I > II > III
(t)  Alkaline hydrolysis

11
20. The correct order of basicities of the following compounds 23. Benzamide on treatment with POCl3 gives  (IIT JEE 2004)
is (IIT JEE 2001) (a) aniline (b) benzonitrile
NH (c) chlorobenzene (d) benzyl amine
H3C C , CH3 CH2 NH2, 24. In the following reaction,
NH O

1 O 2
N Conc.HNO3
H X
Conc.H2SO4
(CH3)2NH, H3C C NH2
3 4 The structure of the major product X is (IIT JEE 2003)
O
(a) 2 > 1 > 3 > 4 (b) 1 > 3 > 2 > 4 (a)
NO2
(c) 3 > 1 > 2 > 4 (d) 1 > 2 > 3 > 4 N
H
Numerical/Integer Types O 2N
O
21. The reaction of 4-methyloct-ene (P, 2.52 g) with HBr in the (b)
presence of (C6H5CO)2O2 gives two isomeric bromides in a 9 : 1 N
ratio, with combined yield of 50%. Of these, the entire amount of H
the primary alkyl bromide was reacted with an appropriate amount O
of diethylamine followed by treatment with eq. K2CO3 to given a (c)
non-ionic product S in 100% yield.  N
 C-0.87 W-60.36 UA-38.77 (JEE Adv. 2023) H
NO2
The mass (in mg) of S obtained is __.
O
[Use molar mass (in g mol–1) : H = 1, C = 12, N = 14, Br = 80]
(d)
O 2N N
PREPARATION AND CHEMICAL H
REACTIONS OF AROMATIC AMINES 25. Examine the following two structures of anilinium ion and
Single Correct choose the correct statement from the ones given below:
 (IIT JEE 1993)
22. The major product of the following reaction is
O +
NH3 NH3
C (i) KOH
NH +
C
(ii) Br CH2Cl
O I II
 (IIT JEE 2011)
O (a) II is not an acceptable canonical structure because
carbonium ions are less stable than ammonium ions
C
(b) II is not an acceptable canonical structure because it is non-
(a) N CH2 Br aromatic
C (c) II is not an acceptable canonical structure because the nitrogen
O has 10 valence electrons
O (d) II is an acceptable canonical structure
C Multiple Correct
(b) N CH2Cl
26. Correct option(s) for the following sequence of reaction is are
C
 C-20.86 W-33.54 UA-36.03 PC-9.58 (JEE Adv. 2021)
O
V
O
Br2 1.Q CHCl3
C PhCH3 (P) (R)
KOH
(S)
light 2.H2,Pd/C
(c) N (i) KMnO4 (ii) H3O+
foul smelling
C KOH, heat
O CH2 Br (T)
(i)NH3
(U)
(W)
O (ii)heat

C (a) Q = KNO2,W = LiAlH4

(d) N (b) R = benzamine, V = KCN
C (c) Q = AgNO2,R = phenylmethanamine
O CH2Cl (d) W = LiAlH4,V = AgCN

12
 27. In the reaction shown below, the major product(s) formed (b) Statement-I is correct; Statement-II is correct; Statement-
is/are II is not the correct explanation of Statement-I.
NH2 (c) Statement-I is correct; Statement-II is incorrect.
(d) Statement-I is incorrect, Statement-II is correct.

Acetic Comprehension/Passage Based

NH2 anhydride
Product (S) RCONH 2 is converted into RNH 2 by means of Hoffmann’s
CH2Cl2
bromamide degradation.
O O O
 C-12.5 W-79.18 UA-8.32 (JEE Adv. 2014) Cl Cl
N NH2 NHBr
H CH3
(i) (ii)
O
O
(a) C
O
NH2 + CH3COOH N Cl Cl
N�Br
O (iv) (iii)

NH2
– +
OM
O
H N Cl NH2 Cl
(b)
N CH3 +CH3COOH H
(v) (vi)

O O
In this reaction, RCONHBr is formed from which this
reaction has derived its name. Electron donating group
H
at phenyl activates the reaction. Hoffmann’s degradation
N CH3
reaction is an intramolecular reaction.
31. How can the conversion of (i) to (ii) be brought about?
O
(c) H  (IIT JEE 2006)
N CH3+H2O (a) KBr (b) KBr + CH3ONa
(c) KBr+KOH (d) Br2 + KOH
O O
32. Which is the rate determining step in Hoffmann’s bromamide
⊕ degradation? (IIT JEE 2006)
NH3CH2COO
(a) Formation of (i) (b) Formation of (ii)
(c) Formation of (iii) (d) Formation of (iv)
H 33. What are the constituent amines formed when the mixture of
(d) N CH3 (1) and (2) undergoes Hoffmann’s bromamide degradation?
 (IIT JEE 2006)
O O 15
CONH2 CONH2
28. A positive carbylamine test is given by (IIT JEE 1999)
D (1) (2)
(a) N, N-dimethyl aniline (b) 2, 4-dimethyl aniline
(c) N-methyl-o-methyl aniline (d) p-methyl benzyl amine
29. p-chloroaniline and anilinium hydrochloride can be distinguished (a) NH2,
15
NH2, NH2,
by (IIT JEE 1998)
(a) Sandmeyer reaction (b) NaHCO3 D D 15
NH2,
(c) AgNO3 (d) Carbylamine test
(b) 15
Assertion Reason/Statement Based NH2, NH2

30. Statement-I: In strongly acidic solution, aniline becomes more

D
reactive towards electrophilic reagents.
Statement-II: The amino group being completely protonated in
15
(c) NH2, NH2
strongly acidic solution, the lone pair of electrons on nitrogen is
no longer available for resonance. (IIT JEE 2001)
(a) Statement-I is correct; Statement-II is correct; (d) 15
NHD, NH2
Statement-II is the correct explanation of Statement-I.

13
 Fill in the Blanks PREPARATION AND CHEMICAL REACTIONS
34. The high melting point and insolubility in organic solvents OF DIAZONIUM SALTS
of sulphanilic acid are due to its...... structure. (IIT JEE
Single Correct
1994)
35. In an acidic medium, ......... behaves as the strongest base. 45. The major product of the following reaction is
(nitrobenzene, aniline, phenol) (IIT JEE 1981)  C-34.83 W-43.21 UA-21.96 (JEE Adv. 2017)
OH
Subjective
(i) NaNO2/HCl/0°C
CH2Cl (ii) (aq.NaOH)

C2H5ONa/EtOH H3O+/D NH2

36. KCN – +
(A) (B) (C) ONa
DMF C6H5CHO Heat OH
SOCl2
(D)
CH3NH2
(a) (b)

Identify A to D. (IIT JEE 2004)
N N NH2
37. Which of the following is more acidic and why? (IIT JEE 2004)
+ +
NH3 NH3 N N OH OH

(c) (d)   

I
F Cl
II
46. Amongst the compounds given, the one that would form a brilliant
38. There is a solution of p-hydroxybenzoic acid and p-amino coloured dye on treatment with NaNO2 in dil. HCl followed by
benzoic acid. Discuss one method by which we can separate addition to an alkaline solution of β -naphthol is (IIT JEE 2011)
them and also write down the confirmatory test of the
N(CH3)2 NHCH3
functional group present. (IIT JEE 2003)
(a) (b)
39. What would be the major product in the following reaction?
O

Br2/Fe NH2 CH2NH2

N
(c) (d)

 (IIT JEE 2000) H3C

40. Following reaction gives two products. Write the structures

(CH3)2NH
of the products. 47. F NO2 (A)
DMF, D
Br2/Fe

CH3CONHC6H5  (IIT JEE 1998) (i) Fe/HCl
41. Write the structure of foul smelling compound obtained when (ii) NaNO2/HCl/0°C
(B)
aniline is treated with chloroform in the presence of KOH. (ii) H2/Ni
 (IIT JEE 1996)  (IIT JEE 2003)
CH3
42. Write the structure of the major organic product expected (a) H2N N
from the following reaction. (IIT JEE 1992) CH3
CH3
N + HNO2
CH3 (b) H2N NH2
43. Complete the following with appropriate structures:
 (IIT JEE 1986) CH3
(c) O2N N
NH2 + COCl
Base
? CH3

44. State the conditions under which the following preparation (d) O 2N NH2
is carried out. “Aniline from benzene” (IIT JEE 1983)

14
 48. Benzene diazonium chloride on reaction with phenol in
U = 1. CH3CH2OH; 2. KMnO4 - KOH, heat
weakly basic medium gives (IIT JEE 1998) NO2
(a) diphenyl ether (b) p-hydroxy azobenzene (d) Q = R = H2/Pd, ethanol
(c) chlorobenzene (d) benzene HOOC
49. Chlorobenzene can be prepared by reacting aniline with OH
(IIT JEE 1984) T =
(a) hydrochloric acid H3C
(b) cuprous chloride
(c) chlorine in the presence of anhyd AlCl3 52. The reaction sequence(s) that would lead to o-xylene as the
major product is (are)
(d) nitrous acid followed by heating with cuprous chloride
 C-18.66 W-18.08 UA-51.84 PC-11.42 (JEE Adv. 2021)
Multiple Correct Me
50. Considering the reaction sequence given below, the correct NH2 1. NaNO2/HCl, 273 K
2. CuCN
statement(s) is/are: C2.05 W20.77 UA47.80 (JEE Adv.
2022) (a) 3. DIBAL-H, then H3O+
4. N2H4,KOH, heat
1. Br2, red phosphorous Me
H3C
COOH 1. Mg, CO2, H3O+
2. H2O 2. SOCl2
(b)
O 3. H2,Pd-BaSO4
1.
 
Br 4. Zn-Hg, HCl
N K
COOH 1.(i) BH3
Me (ii) H2O2,NaOH
O
(P)
2. NaOH
(Q) + (c) 2. PBr3
3. H3O + COOH 3. Zn, dil.HCl
(a) (P) can be reduced to a primary alcohol using NaBH4.
1. O3,Zn/H2O
(b) Treating (P) with conc. NH4OH solution followed by (d) 2. N2 H4, KOH, heat
acidification gives (Q).
(c) Treating (Q) with a solution of NaNO2 in aq. HCl liberates 53. Aniline reacts with mixed acid (conc.HNO3 and conc.
N2. H2SO4 at 288 K to give P (51%),Q (47%) and R (2%). The
(d) (P) is more acidic than CH3CH2COOH. major product(s) of the following sequence is (are)
51. Consider the following reaction sequence,  C-15.46 W-39.21 UA-45.33 PC-0 (JEE Adv. 2018)
NO2 (1) AC2O, pyridine (1) Sn/HCl
(2) Br2,CH3CO2H (2) Br2/H2O (excess)
(P)
(Q)
(R)
(S)
H 2O
(T) R S
(3) H3O+ (3) NaNO2, HCl/273-278 K
H3C (4) NaNO2, HCl/273-278 K (5) H3PO2
(U)
(5) EtOH, ∆
COOH
Br Br

Br Br
the correct option(s) is/are:
 C7.65 W11.47 UA37.48 (JEE Adv. 2022) (a) (b)
(a) P = H2/Pd, ethanol R = NaNO2/HCl Br Br
U =1. H3PO2; 2. KMnO4 - KOH, heat
Br Br
(b) P = Sn/HCl R = HNO2
 
Br Br
N2Cl
S =
H 3C
(c) (d)
  Br Br Br Br
N2Cl OH
(c) S = T = Br
H 3C H 3C

15
 54. The product(s) of the following reaction sequence is (are) Assertion Reason/Statement Based
NH2 Read the following question and answer as per the direction given below:
(i) Acetic anhydride. Pyridine (a) Statement-I is correct; Statement-II is correct Statement-II is the
(ii) KBrO3/Br correct explanation of Statement-I
(iii) H3O+, Heat (b) Statement-I is correct; Statement-II is correct Statement-II is not
(iv) NaNO2 /HCL, 273-278 K the correct explanation of Statement-I
(v) Cu/H Br
(c) Statement-I is correct; Statement-II is incorrect
 C-18.12 W-45.71 UA-36.17 PC-0 (JEE Adv. 2016) (d) Statement-I is incorrect; Statement-II is correct
Br Br
56. Statement-I: Aniline on reaction with NaNO2/HCl at 0°C
followed by coupling with b-naphthol gives a dark blue
(a) (b)
coloured precipitate.
Br
Br Statement-II: The colour of the compound formed in the
Br reaction of aniline with NaNO2/HCl at 0°C followed by
Br
(c) Br Br (d) Br Br
coupling with b-naphthol is due to the extended conjugation.
 (IIT JEE 2008)
Comprehension/Passage Based
Br
A trinitro compound, 1, 3,5 tris-(4-nitrophenyl) benzene, on complete
55. In the following reactions, the major product W is reaction with an excess of Sn/HCl gives major product, which on
NH2 treatment with an excess of NaNO2/HCl at 0°C provides P as the
product. P, upon treatment with excess of H2O at room temperature,
NH2
NaNO2, HCl , NaOH gives the product Q. Bromination of Q in aqueous medium furnishes
V W the product R. The compound P upon treatment with an excess of
0°C
phenol under basic conditions gives the product S.
 (JEE Adv. 2015)
The molar mass difference between compounds Q and R is 474 mol–1
and between compounds P and S is 172.5 g mol–1.

(a) 57. The number of heteroatoms present in one molecule of R is _____.

 C-11.06 W-63.06 UA-25.87 (JEE Adv. 2023)
N N OH
[Use: Molar mass (in g mol–1): H = 1, C = 12, N = 14, O = 16, Br
= 80, Cl = 35.5
Atoms other than C and H are considered as heteroatoms]
58. The total number of carbon atoms and heteroatoms present
in one molecule of S is _____.
OH  C-5.54 W-66.75 UA-27.71 (JEE Adv. 2023)
(b)
[Use: Molar mass in g mol–1]: H = 1, C = 12, N = 14, O = 16,
N N Br = 80, Cl = 35.5
Atoms other than C and H are considered as heteroatoms.

Numerical/Integer Types
59. Consider the reaction sequence from (P) to (Q) shown below. The
OH overall yield of the major product (Q) from (P) is 75%. What is the
(c) amount in grams of (Q) obtained from 9.3 mL of (P)? (Use density
N N of P = 1.00 g mL–1, Molar mass of C = 12.0, H = 1.0, O = 16.0 and
N = 14.0 g mol–1)
 C-1.94 W-68.07 UA-29.99 (JEE Adv 2020)
HO
(i) NaNO2+HCl/0-5°C
NH2 (Q)
OH +NaOH

(d) (P) (ii)

N N
(iii) CH3CO2H/H2O

16
 60. Scheme 1 and 2 describe the conversion of (P) to (Q) and O I
(R) to (S), respectively. Scheme 3 describes the synthesis
NH C CH3 NO2
of (T) from (Q) and (S). The total number of Br atoms in a
molecule of (T) is ________. I
 (IIT JEE 1994)
 C-28 W-57 UA-15 (JEE Adv. 2019)
67. How will you bring about the following conversion?
Scheme 1:

“4-nitro aniline to 1,2,3-tribromobenzene.”(IIT JEE 1990)
NH2 (i) Br (excess), H2O
68. How would you convert aniline into chlorobenzene ?
2
(ii) NaNO2 HCl, 273 K
(iii) CuCN/KCN  (IIT JEE 1985)
+ (Q)
(iv) H3O ,  (major) 69. State the equation for the preparation of following compound.
(v) SOCl2, pyridine Chlorobenzene from aniline (in 2 steps). (IIT JEE 1982)
(P)
Scheme 2: NITRO COMPOUNDS
(i) Oleum
(ii) NaOH,  Single Correct
(Q)
70. The most unlikely representation of resonance structures of
+
(iii) H (major)
(iv) Br2,CS2 273 K p-nitrophenoxide ion is (IIT JEE 1999)
(R)
O– + O O– O–
Scheme 3: N +
N
(i) NaOH
(S) (T)
(ii) Q (major)
(a) (b)
Subjective
61. Convert
O– O
NO2 NO2
O ⊕ O O– + O
N N
to
OH
(c) (d)
in not more than four steps. Also mention the reaction conditions –
and temperature. (IIT JEE 2004)
62. Convert (in not more than 3 steps): (IIT JEE 2003) O O
COOH COOH
Multiple Correct
71. When nitrobenzene is treated with Br2 in the presence of
F FeBr3, the major product formed is m-bromonitrobenzene.
63. How would you bring about the following conversion (in 3 Statements which are related to obtain the m-isomer, are
steps)?  (IIT JEE 1992)
Aniline → Benzylamine (IIT JEE 2000) (a) the electron density on meta carbon is more than that
64. Complete the following with appropriate structure: on ortho and para positions
NH2 (b) the intermediate carbonium ion formed after initial
attack of Br+ at the meta position is less destabilised
NO2
(i) NaNO2 and HCI at 5°C
A (IIT JEE 1995) (c) loss of aromaticity when Br+ attack at the ortho and
(ii) Anisole para positions and not at meta position
NO2
(d) easier loss of H+ to regain aromaticity from meta position
65. How will you bring about the following conversions? than from ortho and para positions
“Benzamide from nitrobenzene” (IIT JEE 1994)
Subjective
66. Complete the following reactions with appropriate reagents
72. How will you bring about the following conversions?
“4-nitrobenzaldehyde from benzene” (IIT JEE 1994)

17
73. Outline a synthesis of p-bromonitrobenzene from benzene O
in two steps. (IIT JEE 1993) Cl2/FeCl3 Na·Hg/HCI
CH2CH2CH3 A B
MISCELLANEOUS CI
CH2 CHCH2–ONa+ HNO3/H2SO4
Subjective D H 2O C

74. Write structures of the products A, B, C, D and E in the

following scheme H2/Pd/C
 E
(IIT JEE 2002)

18
 Answer Key (Abhedya)

Exercise - 1
1. (c) 2. (b) 3. (c) 4. (b) 5. (c) 6. (c) 7. (d) 8. (a) 9. (b) 10. (c)
11. (d) 12. (d) 13. (c) 14. (a) 15. (b) 16. (b) 17. (d) 18. (d) 19. (c) 20. (c)
21. (c) 22. (b) 23. (a) 24. (a) 25. (a) 26. (b) 27. (c) 28. (d) 29. (d) 30. (b)
31. (b) 32. (d) 33. (b) 34. (c) 35. (b) 36. (b) 37. (c) 38. (a) 39. (a)

Exercise - 2
1. (d) 2. (c) 3. (c) 4. (c) 5. (b) 6. (b) 7. (c) 8. (d) 9. (b) 10. (b)
11. (a) 12. (b) 13. (d) 14. (b) 15. (b) 16. (a) 17. (d) 18. (b) 19. (d) 20. (c)
21. (a) 22. (d) 23. (c) 24. (b) 25. (d) 26. (c) 27. (b) 28. (b) 29. (c) 30. (a)
31. (a) 32. (d) 33. (b) 34. (a) 35. (d) 36. (b) 37. (c) 38. (b) 39. (d) 40. (c)
41. (c) 42. (b) 43. (d) 44. [5] 45. [3] 46. [3] 47. [3] 48. [0] 49. [4] 50. [4]

Exercise - 3
1. (d) 2. (b) 3. (c) 4. (c) 5. (c) 6. (b) 7. (a) 8. (c) 9. (c) 10. (b)
11. (c) 12. (a) 13. (d) 14. (c) 15. (a) 16. (b) 17. (a) 18. (a) 19. (5) 20. (3)
21. (4)

Exercise - 4 (PYQ’s)
1. (d) 2. (b) 3. (c) 4. (c) 5. (c) 6. (a, c) 7. (b) 8. (a)
9. A → p, q, s, t; B →s, t; C → p; D → r 10. More 19. (d) 20. (b) 21. [1791]
22. (a) 23. (b) 24. (b) 25. (c) 26. (c, d) 27. (a) 28. (b, d) 29. (c) 30. (d) 31. (d)

32. (d) 33. (b) 34. Zwitter ionic or Dipolar ion 35. Aniline 45. (a) 46. (c) 47. (a) 48. (b)

49. (d) 50. (b, c, d) 51. (a, b, c) 52. (a, b) 53. (d) 54. (b) 55. (a) 56. (d) 57. [9] 58. [51]

59. [18.6] 60. [4] 70. (c) 71. (a,b,d)

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