Protective-Coating-Guide-for-Fans-FE-400
Protective-Coating-Guide-for-Fans-FE-400
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FAN ENGINEERING – FE-400
Thermoplastic Chemical Composition of Generic
Thermoplastic is a coating which will dissolve in its own Coatings (Thermosetting)
solvent system. It is usually a single package material Epoxy — Epoxies require a catalyst to bring about the
which dries only by solvent evaporation. crosslinking that gives the coating its many desirable
Thermoplastic coatings are typified by vinyls and properties. The most commonly used catalysts are the
phenoxies. They cure by solvent evaporation and there reactive amines and polyamide resins.
is no crosslinking of the resin. The coating will redissolve
readily in the original solvent system. The term Polyesters — Coatings based not on epoxy resins but
thermoplastic means that if the coating is exposed to on modified alkyd chemistry, formed by the
heat (thermo) then it will become more plastic, i.e., soft polycondensation of dicarboxilic acids and dihyroxy
and pliable. alcohols.
Phenolics — Phenolic resins are made by the reaction
Thermosetting of phenol and formaldehyde. The reaction is driven by
Thermosetting is a coating which will not dissolve in its heat.
own solvent system. It is normally a two component Inorganic Zincs — Zinc dust is added to inorganic
coating which cures by solvent evaporation followed by binders. The Zinc metal acts as the cathode and
a chemical reaction. This chemical reaction of crosslinking corrodes in preference to the steel substrate.
enables a low molecular weight material to become a
large molecule or network of large molecules. Epoxy Phenolics — Coatings are modified phenolic
The following table is the generic classification of coatings created by blending phenolic resins with epoxy
coatings differentiated by their chemical composition: resins.
Polyurethane — Coatings are derived from prepolymers
Table 2. Various Generic Coating Types containing isocyanate groups and hydroxyl-containing
materials such as polyols and drying oils.
Thermoplastic Thermosetting
Alkyds Bake Phenolic Epoxy Polyamides — These coatings have a slower
crosslinking which leads to a more flexible finish.
Vinyls Epoxy-Phenolic
Acrylics Water Base Epoxy Practical Properties & Application
Typical water base Inorganic Zincs Requirements of Various Coatings
house paints Polyurethanes The following description of generic coatings provides a
Polyesters guide to specifying and selecting corrosion resistant
coatings for fan equipment. For chemical resistance to
specific chemicals, refer to Table 3.
ACRYLICS
Advantages: Excellent gloss retention, weathering
resistance, moderate flexibility, high
Here is a quick breakdown of some generic types by temperature resistance.
the thermoplastic or thermosetting definition. Some Disadvantages: Poor chemical resistance, poor solvent
alkyds and acrylics are baked and become thermosetting resistance.
coatings. VINYLS
Advantages: Fast dry in warm weather, excellent
Chemical Composition of Generic water and acid resistance, good adhesion,
Coatings (Thermoplastic) flexible.
Disadvantages: Usually low film builds, can lift other
Acrylics — Acrylic acid, made from acrylonitrile, is coatings, poor solvent resistance.
converted to various acrylates. These and methyl
methacrylate are the raw materials that are polymerized ALKYDS
into acrylic resins. Advantages: Inexpensive, good adhesion, flexible,
good gloss, may be applied over most
Vinyls — Resins are typically made by linking together other alkyds.
(polymerization) of vinyl chloride, a very toxic gas, vinyl Disadvantages: Poor chemical resistance, slow drying,
acetate and vinyl alcohol. These resins are formed by a low film build.
reaction between acetylene and an acid. EPOXY POLYAMIDES
Advantages: Moisture tolerant during cure, long pot
Alkyds — Commonly referred to as oil based paints. life, excellent adhesion.
Chemically, alkyds are modified polyesters. The Disadvantages: Less solvent resistant, more expensive,
modification is the natural oil, used along with the less chemically resistant.
alcohol, to react with a dibasic acid to form the polymer.
The curing mechanism is a reaction between oxygen in POLYESTER
the air and the oil of the polymer. This is a complex Advantages: High solids, excellent mineral acid
reaction and not completely understood. resistance; strong and hard films.
Disadvantages: Poor solvent resistance, marginal
adhesion.
(continued on page 4)
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INORGANIC ZINCS specification should read that the paint should be “salt
Advantages: Protect steel with single coat, not spray tested to ASTM B117 for 200 hours and have no
subject to ultraviolet degradation. scribe blisters. Maximum creep from the scribe should
Disadvantages: Dry spray in hot windy weather, porous be 1.0 mm creep.”
film to topcoat, limited pH range.
Color matching is both important and difficult; important
EPOXY PHENOLICS because of the customer reaction to mismatched colors
Advantages: Heavy build, excellent acid and solvent and difficult because of human variability in color
resistance. perception. Two panels which appear to be the same
Disadvantages: Requires shotblasting. color to one person may seem dissimilar to someone
else. A color may also change when viewed from
POLYURETHANE
different lighting, fluorescent versus outdoor light, for
Advantages: Excellent weathering, enamel-like finish,
instance. Color chips are used as a general practice in
flexible, damage resistant.
the fan industry to offer matched colors.
Disadvantages: Low film build, expensive, moisture
intolerant, chemical cure, temperature Corrosion Resistant Guide — The use of the information
sensitive. in Table 4 is straightforward. For example, if the
airstream has formic acid at between 15 to 85%
Testing Paints concentration, then air dried phenolic would be
acceptable. The other coatings that require steelblasting
The major reasons for testing paints are to: would also be acceptable but at a higher cost. The
• Evaluate products higher cost would be due to the cost of steelblasting
• Control quality and going to a better grade of epoxy paint. Sometimes
• Ensure process control there is no acceptable coating for the environment or
Paint viscosity is a very important property to control substance being handled and the fan itself must be
since it affects the quality of the applied paint. Viscosity constructed of a corrosion resistant material. For
is the resistance of a liquid to flow. Paint viscosity must instance, if the airstream contains over a 15%
be such that the proper atomization and flow-out can concentration of chromic acid, no coating would be
be achieved. acceptable. In this case, the fan would have to be
There are many instruments to measure viscosity. A constructed of 316 stainless steel.
common method is to use a Zahn cup. Paint viscosity
is determined by measuring the time required for a given
quantity of paint to flow through a hole in the bottom Field Problems
of a metal cup.
Field problems are defects which occur after the fan has
Film thickness of dry paint is important. Thin films will been painted and cured. Typically, they appear after the
not provide corrosion resistance. Thick films are likely to fan has been placed in service by the customer. Some
crack. There is a direct correlation between wet film and service defects occur or are made worse as a result of
dry film. Dry film is usually controlled by measuring the processes used in painting. Some defects listed as
wet film with a gauge with various “V” notches. There service defects are normal wear-out processes for the
are many commercial gauges to measure dry film paint.
thickness.
Fading is the gradual loss of color intensity. It is
Tape adhesion is a test to measure the adhesion of a observed with most paints as they age. It usually results
paint film to its substrate. It is often measured by pulling from a reaction of the paint with moisture or sunlight.
the paint away from a scribed “X” or grid with a strip These reactions are impossible to avoid if outdoor
of tape. The tape is pulled back upon itself as nearly in exposure is involved. Sometimes ultraviolet (UV)
the plane of the painted surface as possible. A numerical stabilizers can be added to the paint to retard
rating system is used to evaluate the tape adhesion test degradation but generally UV-resistant pigments must be
results. If a scribed grid has been used, the failure of used to slow down the process. Some pigments have
adhesion may be expressed as the percentage of such a low UV-resistance that they cannot be used in
squares which have experienced some loss of paint. outdoor paints.
Salt spray testing is the use of a salt spray system in Face and Scratch Rusting. Face rusting is the
an attempt to accelerate the corrosion process and appearance of rust on an undamaged paint surface.
cause early paint failure. Panels are usually exposed up Scratch rust occurs in locations where the paint has
to 14 days to a mist of 5 percent (weight-to-volume) been damaged by impact or scratching. To prevent
sodium chloride solution at 92° to 97°F. The mist is rusting, constant attention to process parameters is
produced by blowing hot, saturated air through a 5 essential. Rinsing is particularly critical to ensuring rust
percent salt solution. The panels are evaluated for two resistance. During shipping and the installation process
types of rusting: it is important to consider the nature of the coating and
handle the fan accordingly to prevent scratching and
1. Face Rusting — The percentage of the surface which
impact damage.
has rust visible through the paint.
Corrosion (Rusting). Corrosion is a defect in which the
2. Scratch-Creepback Rusting — the distance in 32nds
paint has failed to protect the underlying surface from
of an inch which has rusted away from a line
the corrosive action of the environment. Moisture from
scratched through the film to the metal.
the air reacts with the base material, generally with the
Sometimes acetic acid is added to the salt spray formation of the oxides, which then swells up beneath
solution to accelerate the corrosion. A common problem the paint and lifts it from the coated surface. Corrosion
has been that customers have asked if the paint is salt usually occurs if the exposure conditions are more
spray tested to an ASTM standard. The problem with severe than the paint can withstand. Assuming the paint
this is that the ASTM standard does not have has been properly applied, the only solution is to use a
acceptance/rejectance limits. As an example, the more corrosion resistant coating. Corrosion is more likely
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FAN ENGINEERING – FE-400
to occur if the paint is applied too thinly or if it is
overbaked or underbaked. Poorly cleaned or rinsed
Cost
surfaces will result in low adhesion and make it easier After selecting the proper coating for a fan the final
for moisture to displace the paint film from the surface consideration is its cost. The cost of coatings varies
being protected. greatly from thermoplastic to thermosetting coatings and
with the surface preparation that is required. The
Peeling (Lifting, Flaking, Poor Adhesion). Peeling results following chart is a guideline of the relative cost
when a paint film loses contact with the surface. (compared to enamel) of the coatings that have been
Sometimes the paint curls off the surface or can be mentioned in this document.
peeled by hand. Other times it falls off in small pieces
with or without rubbing. The major cause of this problem
is simply poor adhesion between the paint film and the
surface. This may be a result of a surface contaminated Table 3. Relative Coating Costs
by oil or grease-like material. The solution is to look at
the cleaning process or for contaminants which have Surface Relative
Coating
coated the surface before painting. Common difficulties Preparation Cost
with the cleaning systems include temperatures, Enamel 1.0
pressures, and times that are too low, inadequate Asphaltum 2.5
rinsing, and concentrations which are too high or low.
No Vinyl 2.5
Clean surfaces may become contaminated in a variety
of ways. Touching the surface with oily hands or gloves Blasting Zinc (some require
can contaminate it. Allowing the fan to wait a long time blasting) 3.5
between cleaning and painting can allow contamination Epoxy 3.5
from the air to accumulate and cause problems. Synthetic Resin 3.5
Blisters (Swelling). Blisters are tiny areas beneath the Air Dried Phenolic 6.5
paint film where moisture has collected as a result of Baked Phenolic 18.5
passage through the paint film from the top. Usually Epoxy 19.0
such areas represent locations on the surface where salt
crystals occur as a result of poor rinsing after Blasting Phenolic Epoxy 19.0
phosphating or other cleaning operations. Salt crystals Heavy Vinyl 21.0
dissolve in the water and then pass through the paint Hi-Bake Epoxy 26.0
film and form droplets of salt solution. This solution can
produce enough pressure beneath the paint film to
cause it to lift away from the surface. Blisters are usually
a result of poor cleaning and rinsing processes. The
solution is to be sure that the cleaner concentrations
and temperatures are correct, pump pressures are up to
standard, filters are clean, and spray nozzles are
unobstructed. This way the parts receive adequate
cleaning solution and rinse water during all stages of the
preparation process.
Chalking. Chalking is a breakdown of the paint film.
Chemically, it results from the degradation of the paint
binder, usually as a result of exposure to moisture and
ultraviolet radiation. Chalked paint can be rubbed off the
surface with finger pressure. Chalking is an inherent
property of a paint film. It is not particularly influenced
by application variables.
Normal Paint Wear Out. The normal deterioration of a
paint film is a step-wise process which involves binder
degradation, pigment failure and finally, large scale
cracking and peeling. The binder degrades by reaction
with water, sulfur dioxide, and other chemicals. The
binder breakdown products work loose from the surface
by thermal expansion and contraction. Pigment failure
follows binder degradation. Once exposed as a result of
binder loss, the pigment begins to fail by reaction with
moisture and gases in the air. Large scale cracking and
peeling follow pigment failure because moisture is now
easily able to penetrate the paint film through cracks
and openings under the paint.
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Table 4. Corrosion-Resistant Guide to Generic Coatings
NO STEEL BLASTING STEEL BLASTING
AIR
CORROSIVE ASPHALT- SYNTHETIC HEAVY BAKED PHENOLIC HI-BAKED
VINYL ZINC EPOXY DRIED EPOXY
UM RESIN VINYL PHENOLIC EPOXY EPOXY
PHENOLIC
NUMBER OF COATS 2 2 2 1 4 3 5 2 2 2 2
ACIDS
ASCETIC F F U G G E G G E E E
BORIC E G E G G E E E E E E
CARBOLIC F U U G G U U G E E E
CARBONIC F G E E G E E E E E E
CHROMIC F G U F U G G U F U G
CITRIC G G U G G G E G E E E
FLUOROBIC X G U X G X E X X X X
FORMIC F G X G E G E E E E E
HYDROBROMIC X X U X U G E X U X U
HYDROCHLORIC G G U G G E E G E G E
HYDROFLOURIC F F X G U U F G U E E
HYDROCHLOROUS F X X F X E F F F G G
LACTIC F G U G E E G E E E E
NITRIC F G U G G E G F F X X
PERCHLORIC U F U F F U E U G U G
PHOSPHORIC F G U G G E E G E E E
PICRIC F X X U X E F X X X X
SULFURIC ACID F F U G G G U U E G G
SULFUROUS ACID X G U G G G U G E E E
HYDROCARBONS
BENZENE U F E G G U E E E E E
BUTANE X X X X G E G X E X X
GASOLINE U G E G G E G E E E E
XYLOL / TOLUOL G U G G U U U E E E G
AMMONIA (WET) X X X F U X X X U X X
CHLORINE (DRY) G G X G G E E G E E E
HYDROGEN SULFIDE G G U G G G E E E E E
SULFUR DIOXIDE X X U X G G U U E U U
KEY: E — Satisfactory from 15%-85% (depending upon coating) of concentration of fumes and for continuous operation.
Also suitable for splash or condensation.
G — Good for up to 5%-15% concentration of fumes. Not recommended for applications involving splash or condensation.
F — Fair. Recommended for low (maximum 5%) concentration application.
Should not be specified unless detail application is available.
U — Unsatisfactory and is not recommended.
X — Sufficient data not available. User comments would be appreciated.
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FAN ENGINEERING – FE-400
Table 4 (continued). Corrosion-Resistant Guide to Generic Coatings
NO STEEL BLASTING STEEL BLASTING
AIR
CORROSIVE ASPHALT- SYNTHETIC HEAVY BAKED PHENOLIC HI-BAKED
VINYL ZINC EPOXY DRIED EPOXY
UM RESIN VINYL PHENOLIC EPOXY EPOXY
PHENOLIC
NUMBER OF COATS 2 2 2 1 4 3 5 2 2 2 2
ALUMINUM CHLORIDE G G X G G E E E E E E
ALUMINUM NITRATE F F X X F E X X G F X
ALUMINUM SULPHATE G G E G G E E E E E E
AMMONIUM CHLORIDE F G G G G G E G F U E
AMMONIUM HYDROXIDE E G G G U E E F E U E
AMMONIUM NITRATE E E E E G X E E G G E
AMMONIUM SULFATE G G G G F E E G E G E
BRINE X X X G G E X G E E E
BROMINE U U U X U X X U U U U
CALCIUM CHLORIDE E E G F G E E E E G E
CALCIUM CARBONATE E E X E G E E E E E E
CALCIUM HYDROXIDE E E G E E E E E E E E
CALCIUM DISULPHIDE F G E G G U U E E E E
COPPER SUPHATE G G E G E E E E E E E
FERRIC CHLORIDE G G E G E E E E E E E
HYDROGEN PEROXIDE F F X G U G U U U U G
POTASSIUM CYANIDE X X X X G X E X E X X
POTASSIUM HYDROXIDE E E U G F E E U U U G
POTASSIUM DICHROMATE G F E F G X E G E E E
SODIUM BICARBONATE E E X G E E E E E G E
SODIUM CHLORIDE E E E E E E E E E E E
SODIUM DICHROMATE E X E X U X X X F X X
SODIUM HYDROXIDE F G G G U G E G U U G
SODIUM HYPOCHLORITE F F U F U G U U U U G
ZINC CHLORIDE X X X X G E G X G X X
ZINC SULFATE G X U G G E U E E E E
MISCELLANEOUS
ABRASION U U G U G G G G G G G
FORMALDEHYDE F G E G G X G E E E E
MOISTURE E E E E E E E E E E E
SALT SPRAY E E E E G E E E E E E
ACETONE U U E G G U U G E E E
ALCOHOL F F E G G E E E E E E
MINERAL OILS E E X E F U G G E G X
POLYVINYL ACETATE X X X E U X X X G X X
TRI CHLORETHYLENE X U U G G U U U E U U
KEY: E — Satisfactory from 15%-85% (depending upon coating) of concentration of fumes and for continuous operation.
Also suitable for splash or condensation.
G — Good for up to 5%-15% concentration of fumes. Not recommended for applications involving splash or condensation.
F — Fair. Recommended for low (maximum 5%) concentration application.
Should not be specified unless detail application is available.
U — Unsatisfactory and is not recommended.
X — Sufficient data not available. User comments would be appreciated.
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