MAHESH JANMANCHI

IIT 2010 PAPER 1

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MAHESH JANMANCHI

IIT 2010 PAPER 1

PAPER-1
Maximum Marks: 84

Question paper format and Marking scheme: 1. For each question is Section.I, you will be awarded 3 marks if you have darkened only the bubble corresponding to the correct answer and zero mark if no bubbles are darkened. In all other cases, minus one (.1) will be awarded. For each question is Section.II, you will be awarded 3 marks if you have darken only the bubble corresponding to the correct answer and zero mark if no bubbles are darkened. Partial marks will be answered for partially correct answers. No negative marks will be awarded in this Section. For each question is Section.III, you will be awarded 3 marks if you have darken only the bubble corresponding to the correct answer and zero mark if no bubbles are darkened. In all other cases, minus one (.1) will be awarded. For each question is Section.IV, you will be awarded 3 marks if you darken the bubble corresponding to the correct answer and zero mark if no bubbles is darkened. No negative marks will be awarded for in this Section.

2.

3.

4.

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MAHESH JANMANCHI
SECTION I (Single Correct Choice Type)

IIT 2010 PAPER 1

This Section contains 8 multiple choice questions. Each question has four choices A), B), C) and D) out of which ONLY ONE is correct. 1. The synthesis of 3 octyne is achieved by adding a bromoalkane into a mixture of sodium amide and an alkyne. The bromoalkane and alkyne respectively are BrCH2CH2CH2CH2CH3 and CH3CH2C CH (B) BrCH2CH2CH3 and CH3CH2CH2C CH (C) BrCH2CH2CH2CH2CH3 and CH3C CH (D) BrCH2CH2CH2CH3 and CH3CH2C CH
(A)

Sol.

(D)
NaNH 2 CH3 CH2 C CH CH3 CH2 C C - Na+

CH3 CH2 CH2 CH2 Br + Na+ C C CH2 CH3 CH3 CH2 CH2 CH2 C C CH2 CH3 Oct 3 - yne 2. The correct statement about the following disaccharide is

A) Ring (a) is pyranose with - glycosidic link B) Ring (a) is furanonse with - glycosidic link C) Ring (b) is furanose with - glycosidic link D) Ring (b) is pyranose with - glycosidic link Sol. (A) Ring (a) is in pyranose form with -glycosidic linkage and ring (b) is in furanose form with -glycosidic linkage.

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MAHESH JANMANCHI
3. In the reaction,

IIT 2010 PAPER 1

the products are (A)

(B) (C)

(D) Sol. (D) Alkyl aryl ethers or phenolic ethers are cleaved at the alkyl-oxygen bond due to the more stable aryloxygen bond. This reaction yields phenol and alkyl halide. Moreover phenoxide ion is resonance stabilised

4.

Plots showing the variation of the rate constant (k) with temperature (T) are given below. The plot that follows Arrhenius equation is

(A)

(B)

(C)

(D)

Sol.

(A) Page 4

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MAHESH JANMANCHI

IIT 2010 PAPER 1

According to Arrhenius equation,

k = Ae- Ea / RT As temperature increases, rate constant ,k increases exponentially

5.

The species which by definition has ZERO standard molar enthalpy of formation at 298 K is (A) Br ( g ) (B) Cl ( g ) (C) H O ( g ) (D) CH ( g ) 2 2 2 4 (B) Hf of elements in their standard state is taken to be zero. Cl2 is gas at 298 K .Therefore,Hf of (Cl2,g) = 0

Sol.

6.

The bond energy (in kcal mol-1) of a C C single bond is apporxmately (A) 1 (B) 10 (C) 100 (C) Bond energy of a C C single bond is approximately 100 KCal/mole. The correct structure of ethylenediaminetetraacetic acid (EDTA) is

(D) 1000

Sol.

7.

(A)

(B)

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MAHESH JANMANCHI

IIT 2010 PAPER 1

C)

(D)

Sol.

(C) Structure of EDTA is

8.

The ionization isomer of Cr H O Cl NO Cl is 2 4 2 (A) Cr H O O N Cl (B) [Cr H O Cl ] NO 2 4 2 2 2 4 2 2 (C) Cr H O Cl ( ONO ) Cl (D) Cr H O Cl NO H O 2 4 2 4 2 2 2

) (

( (

)( )

( ) ( )

( (

) )

Sol.

(B) Ionization isomerism arises when the counter ion in a complex salt is itself a potential ligand and can displace a ligand which can then become the counter ion. The ionisation isomer for the given compound is obtained by the exchange of ligand with counter ion. i.e., Cl is replaced by NO in ionization sphere. 2

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MAHESH JANMANCHI

IIT 2010 PAPER 1

SECTION II (Multiple Correct Choice Type) This section contains 5 multiple choice questions. Each question has four choices A), B), C) and D) out of which ONE OR MORE may be correct. 9. In the Newman projection for 2,2-dimethylbutane

X and Y can respectively be (A) H and H (B) H and C2H5 Sol. (B, D)

(C) C2H5 and H

(D) CH3 and CH3

On C2 C3 bond axis X = CH3 Y = CH3 On C1 C2 bond axis X=H Y = C2H5 10. Aqueous solutions of HNO3, KOH, CH3COOH, and CH3COONa of identical concentrations are provided. The pair (s) of solutions which form a buffer upon mixing is(are) (A) HNO3 and CH3COOH (C) HNO3 and CH3COONa Sol. (B) KOH and CH3COONa (D) CH3COOH and CH3COONa

(C, D) (A) Both the compounds are acidic and hence they can never form buffer. (B) Both the compounds are basic and hence they can never form buffer. In option (C), if HNO3 is present in limiting amount then this mixture will be a buffer. CH3COONa + HNO3CH3COOH + NaNO3 The mixture given in option (D) has a weak acid (CH3COOH) and its salt with strong base NaOH. Page 7

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MAHESH JANMANCHI

IIT 2010 PAPER 1

11.

In the reaction

the intermediate(s) is (are)

(A)

(B)

(C)

(D)

Sol.

(A,C)

Phenoxide ion is ortho and para directing.

12.

The reagent(s) used for softening the temporary hardness of water is(are) (A) Ca
3

( PO4 )2

(B) Ca ( OH ) 2

(C) Na 2 CO

(D) NaOCl

Sol

(B)

Ca HCO +Ca ( OH )2 2CaCO 2H O 3 2 3 2 [Clarkes method]

( By IITs)

13.

Among the following, the intensive property is (properties are) (A) molar conductivity (B) electromotive force (C) resistance (D) heat capacity (A,B) Resistance and heat capacity are extensive as these are mass dependent properties. Molar conductivity and electromotive force (emf) are intensive properties as these are size independent.

Sol.

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MAHESH JANMANCHI
SECTION-III (Paragraph Type)

IIT 2010 PAPER 1

This section contains 2 paragraphs. Based upon the first paragraph 2 multiple choice questions and based upon the second paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices A),B), C) and D) out of WHICH ONLY ONE CORRECT. Paragraph for Question Nos. 14 to 15 The concentration of potassium ions inside a biological cell is at least twenty times higher than the outside. The resulting potential difference across the cell is important in several processes such as transmission of nerve impulses and maintaining the ion balance. A simple model for such a concentration cell involving a metal M is: M(s)|M+(aq; 0.05 molar)| |M+(aq), 1 molar)| M(s) | For the above electrolytic cell the magnitude of the cell potential |Ecell|= 70 mV. 14. For the above cell (A) Ecell < 0; G > 0 (C) Ecell < 0; G 0 > 0 (B) M(s)|M+(aq; 0.05 molar)| |M+(aq), 1 molar)| M(s) Anode : M (s) M+ (aq) (0.05 molar) + eCathode : M+ (aq) (1 molar) + e- M (s) _____________________________________ Overall reaction M+ (aq) (1 molar) M+ (aq) (0.05 molar) According to Nernst equation,
2.303 RT [Products] log nF [Re ac tan ts ] M+ 2.303 RT E =0log 0.05 M Cell 1.F M+ 1M E Cell =0-

(B) Ecell > 0; G < 0 (D) Ecell > 0; G 0 > 0

Sol.

=0-

2.303 RT log 5 102 F

=0= +ve
G =

0.059 log 5 102 1

Ecell is + 70 mV - nFEcell . As Ecell is + ve. G < 0

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MAHESH JANMANCHI
15.

IIT 2010 PAPER 1

If the 0.05 molar solution of M+ is replaced by 0.0025 molar M+ solution, then the magnitude of the cell potential would be (A) 35 mV (B) 70 mV (C) 140 mV (D) 700 mV (C) For the given cell,
E cell = 0 0.059 log ( 0.05 ) 1 E'cell = 0 0.059 log 0.0025 1

Sol.

After changing the concentration, From these

E'cell = 2 xEcell E'cell = 2 x70mv

= 140 mV

Paragraph for Question Nos. 16 to 18 Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copper include chalcanthite (CuSO4. 5H2O), atacamite (Cu2Cl(OH)3) , cuprite (Cu2O) , copper glance (Cu2S) and malachite (Cu2(OH)2CO3) . However, 80% of the world copper production comes from the ore of chalcopyrite (CuFeS2). The extraction of copper from chalcopyrite involves partial roasting, removal of iron and self-reduction. 16. Partial roasting of chalcopyrite produces (A) Cu2S and FeO (C) CuS and Fe2O3 (A) 2 CuFeS2 + 4O2 Cu2S + 2FeO + 3SO2 Iron is removed from chalcopyrite as (A) FeO (B) FeS (D) Iron is removed in the form of slag, FeSiO3 FeO + SiO FeSiO 2 3 ( slag ) In self-reduction, the reducing species is (A) S (B) O2 (C)
(C) Fe2O3 (D) FeSiO3

(B) Cu2O and FeO (D) Cu2O and Fe2O3

Sol.

17.

Sol.

18.

(C) S 2

(D) SO2

Sol.

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MAHESH JANMANCHI
S2- acts as reducing agent in self reduction..

IIT 2010 PAPER 1

Cu S + 2Cu O 6Cu + SO 2 2 2 ( Blister copper )

S 2 S 4 + is oxidation, So, S 2 is reducing agent
SECTION-IV (Integer Type) This section contains TEN questions. The answer to each question is a single digit integer ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled. 19. A student performs a titration with different burettes and finds titre values of 25.2 mL, 25.25 mL and 25.0 mL. The number of significant figures in the average titre value is 3
25.2 + 25.25 + 25.0 = 25.15 3 25.15 can be rounded off to 25.2

Sol.

Average titre value = =

Therefore,number of significant figures will be 3.

20.

The concentration of R in the reaction R P was measured as a function of time and the following data is obtained: [R] (molar) 1.0 T (min.) 0.0 The order of the reaction is 0.75 0.05 0.40 0.12 0.10 0.18

Sol.

0 Using Hit and Trial method,

From the given data, for zero order kinetics K o =

X t ( Where X = Amount reacted in time t , t = time taken)

From 1 and 2 K I = From 2 and 3 K II =

X 1 0.75 0.25 = = =5 t 0.05 0 0.05 X 0.75 0.40 0.35 = = =5 t 0.12 0.05 0.07

As the value of K is constant, the reaction follows zero order kinetics.

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MAHESH JANMANCHI
21. The number of neutrons emitted when
90 38

IIT 2010 PAPER 1

235 92

U undergoes controlled nuclear fission to

142 54

Xe and

Sr is

Sol.

4 (By IITs)
92 U 235 + n1 Xe142 + Sr 90 + 4 n1 0 54 38 0

22.

The total number of basic groups in the following form of lysine is

Sol.

2
O C O and NH2 are basic groups in lysine.

23. Sol.

The total number of cyclic isomers possible for a hydrocarbon with the molecular formula C4H6 is 5 Degree of unsaturation = 2. Degree of unsaturation or Index no =

n(V -2)+ 1
2

Where n = no of atoms, V = valency of atom

4(4 2) + 6(1 2) +1 = 2 2

Therefore one ring and one double bond or two rings are possible in case of cyclic compounds Possible cyclic isomers are

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MAHESH JANMANCHI
24.

IIT 2010 PAPER 1

In the scheme given below, the total number of intra molecular aldol condensation products formed from Y is

Sol.

25.

Amongst the following, the total number of compound soluble in aqueous NaOH is

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MAHESH JANMANCHI

IIT 2010 PAPER 1

Sol.

These four are soluble in aqueous NaOH. 26. Amongst the following, the total number of compounds whose aqueous solution turns red litmus paper blue is KCN K2SO4 (NH4)2C2O4 NaCl Zn(NO3)2 FeCl3 K2CO3 NH4NO3 LiCN 3 KCN (Salt of strong base, KOH and weak acid, HCN), K2CO3 (Salt of strong base, KOH and weak acid, H2CO3) LiCN (Salt of strong base, LiOH and weak acid, HCN). KCN, K2CO3, LiCN are basic in nature due to anionic hydrolysis and their aqueous solutions turns red litmus paper blue. 27. Sol. Based on VSEPR theory, the number of 90 degree FBrF angles in BrF5 is 0 or 8 (By IITs) Experimental bond angle is 84.8

Sol.

All four planar bonds (FBrF) get reduced from 90o to 84.8o due to lp bp repulsion.

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MAHESH JANMANCHI
28. Sol. The value of n in the molecular formula Be Al Si O is n 2 6 18 3 Be Al Si O n 2 6 18 Be 2+ , Al3+, (SiO32-)6 or Si6O182(as per charge balance in a molecule) 2n + 6 + 24 36 = 0 n=3 Therefore the molecular formula is Be Al Si O ( Beryl ) 3 2 6 18 This is a blue coloured gem stone.It is an alumino silicate with Be as impurity.

IIT 2010 PAPER 1

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