CHEMISTRY

Quiz #5

COLLIGATIVE PROPERTIES

1. The depression of freezing points of 0.1 M aqueous solution of HCl , CuSO4 and K 2SO4 are
(A) all are equal (B) in the ratio of 1:2:3
(C) in the ratio of 1:1:1.5 (D) in the ratio of 2:4:3

0
2. The freezing point of water is depressed by 0.37 C in a 0.01 molal NaCl solution. The
0
freezing point of a 0.02 molal solution of sucrose in C is
(A) −0.370 (B) −0.185 (C) −0.740 (D) −0.1850

3. 30 mL of 0.1 M KIaq and 10 mL of 0.2 M AgNO3 are mixed. The solution is then filtered out.
Assuming no change in total volume, the resulting solution will freeze at
(Given, K f for H2O =1.86 K kg mol assume molarity = molality)
−1

(A) 0.28 (B) 0.22 (C) 0.0744 (D) 0.149

4. 38.2 g of Na 2B4O7 .nH2O dissolved in 250 g water shows an elevation in b.pt by 0.5820C. If
K b of water is 0.52 kg molality-1, then n is
(A) 6 (B) 5 (C) 8 (D) 10

−1
5. 0.2 molal acid HX is 20% ionized in solution. K f = 1.86K molality . The freezing point of the
solution is
(A) −0.45 C (B) −0.90 C (C) −0.31 C (D) −0.53 C
0 0 0 0

6. The solution having highest vapour pressure is: (Assume 100% ionization of electrolytes)
1 N Ba ( NO3 )2 1 N Al2 ( SO4 )3 1 N Th ( NO3 )4
(A) 1 N KNO3 (B) (C) (D)

7. Which of the aqueous equimolal solution will have its vapour pressure near to solvent?
Ba ( NO3 )2 Al ( NO3 )3
(A) Urea (B) (C) NaNO3 (D)

8. The elevation in boiling point of a solution of 13.44g. of CuCl2 assuming 100% ionization in
1 kg of water using the following information will be (Molecular weight of CuCl2 =134.4and
K b = 0.52K molal−1 )
(A) 0.16 (B) 0.05 (C) 0.1 (D) 0.2

9. Which one of the following statements is false

(A) the correct order of osmatic pressure for 0.01 M aqueous solution of each compound is
BaCl2  KCl  CH3COOH  sucrose.

1
 (B) the osmatic pressure (  ) of a solution is given by the equation  = MRT, M is the
molarity of the solution
(C) Raoult’s law states that the vapour pressure of a component over a solution is
proportional to its mole fraction.
(D) two sucrose solutions of same molality prepared in different solvents will have the
same freezing point depression.

10. When 20g of naphthoic acid ( C11H8O2 ) is dissolved in 50g of benzene

(K f = 1.75 K kg mol −1 ) ,
a freezing point depression of 2 K is observed. The van’t Hoff factor
(i) is
(A) 0.5 (B) 1 (C) 2 (D) 3

Co ( NH3 )5 ( NO2 ) Cl
11. A 0.0020 m aqueous solution of an ionic compound freezes at
−0.007320 C Number of moles of ions which 1 mol of ionic compound produces on being

dissolved in water will be (K f = 1.860 C /m )

(A) 3 (B) 4 (C) 1 (D) 2

The Heny’s law constant for the solubility of N2 gas in water at 298 K is 1.0 10 atm. The
5
12.
mole fraction of N2 in air is 0.8. The number of moles of N2 from air dissolved in 10 moles
of water at 298 K and 5 atm pressure is
−4 −5 −4 −6
(A) 4.0 10 (B) 4.0 10 (C) 5.0  10 (D) 4.0 10

13. Which of the following solutions has the lowest freezing point
(A) 1% glucose (B) 1% sucrose (C) 1%KCl (D) 1% BaCl2

14. The molecular weight of benzoic acid in benzene as determined by depression in freezing
point method corresponds to
(A) ionization of benzoic acid (B) dimerization of benzoic acid
(C) trimerization of benzoic acid (D) solvation of benzoic acid

15. A substance is completely trimerised on dissolution in a solvent.The van’t Hoff’s factor (i)
for such change is
(A) 1 (B) 2 (C) 3 (D) 1/3

16. Aqueous solution of 0.004 M Na 2SO4 and 0.01 M glucose are isotonic. The degree of
dissociation of Na 2SO4 is
(A) 28% (B) 60% (C) 75% (D) 85%

17. pk a for monobasic acid is 6. What will be its vant Hoff factor at 0.01 M concentration.
(A) 1.01 (B) 1.02 (C) 1.03 (D) 1.10

18. What is the osmotic pressure of 5.85% (w/v) NaCl aqueous solution at 300 K when it is 50%
ionized?
(A) 42.3 atm (B) 36.9 atm (C) 39.3 atm (D) 32 atm

The degree of dissociation (  ) of weak electrolyte x y is related to van’t Hoff factor (i) by
A B
19.
2
 the expression
i −1 i −1 x + y −1 x + y +1
= = = =
(A) ( y − 1)
x + (B) ( y + 1)
x + (C) i −1 (D) i −1

0
20. 122 g of benzoic acid is dissolved in 1000 g of benzene at 10 C at which vapor pressure of
benzene is 66.6 cm of Hg. If benzoic acid is completely dimerised in benzene, the vapour
pressure of the solution of the benzoic acid in benzene is
(A) 66.20 cm of Hg (B) 66.00 cm of Hg (C) 64.10 cm of Hg (D) 65.92 cm of Hg

21. A solution contains 0.1 mole of acetamide in 1 L of glacial acetic acid. When the solution is
cooled, the first crystal that appeared at the freezing point contains the molecule(s) of
(A) acetamide (B) acetic acid (C) Both (a) and (b)
(D)either acetamide or acetic acid depending on condition of the experiment

An aqueous solution of a solute AB has boiling point of 101.08 C and freezes at −1.80 C.
0 0
22.
AB is found to be 100%ionised at boiling point. if K b / K f = 0.3, then AB
(A) is 100% ionised at the freezing point of solution
(B) behaves as non-electrolyte at the freezing point of solution
(C)forms dimer at the freezing point of solution
(D) forms trimer at the freezing point of solution

23. Osmolarity of 0.02 M potassium ferrocyanide solution at 300 K is (assume solute is 100%
ionised)
(A) 0.10 osmol (B) 0.20 osmol (C) 0.02 osmol (D) 0.004 osmol

24. Which has the highest boiling point?

(A) 0.1 m Na 2SO4 (B) 0.1 m C6H12O6 (glucose)
Al ( NO3 )3
(C) 0.1 m MgCl2 (D) 0.1 m

Multiple Type

25. To 10 mL of 0.5 M BaCl2 solution, 5mL of 0.5 M K 2SO4 is added. BaSO4 is precipitated
What will happen with respect to original solution of BaCl2 ?
(A) f.pt will decrease (B) f.pt will increase
(C) b.pt will increase (D) b.pt will decrease

26. Which statements are correct about antifreeze mixtures to use melt ice or snow on roads?

(A) Antifreeze mixture of CaCl2 + water (

f.pt. − 500 C )
is preferred over KCl + water
( f.pt. − 10 C)
0

(B) The low f.pt. of CaCl2 + water is due to the formation of CaCl2 . 6H2O at low
temperature
(C) The use of antifreeze for salt solutions causes major problems of corrosion of steel car
bodies and reinforcement bars in concrete road structures.
(D) More is the mass of salt spreaded on road, easier is melting of ice

27. Following solutions have been provided at temperature Tk.

(i) 1M aqueous glucose solution.
(ii) 1M aqueous sodium chloride solution
(iii) 1M aqueous ammonium phosphate solution
(iv) 1M benzoic acid in benzene
3
 Select correct statements for the above solution
(A) All are isotonic solutions (B) III is hypertonic of I, II and IV
(C) IV is hypotonic of I, II, and III (D) II is hypotonic of III but hypertonic of I and IV

−1
28. One molal aqueous glucose solution has density 1.180g mL . Also, K f /K b = 3. thus
(A) Tb / Tf = 3
(B) osmotic pressure at 300 K is 24.63 atm
(C) osmotic pressure at 300 K is 29.06 atm
(D) Tb / Tf = 0.33

0 0
29. For a mixture of binary components A and B with vapour pressures PA and PB in pure
P = PA0 + ( PB0 − PA0 ) x B
state, total vapour pressure is total where X B is mole fraction of
component B in the mixture. From this equation, it is concluded that
(A) total vapour pressure over the solution can be related to the mole fraction of any
component
(B) total vapour pressure over the solution varies linearly with the mole fraction of the
component B
(C) total vapour pressures over the solution may decrease or increase with increase of mole
fraction of component A depending on vapour pressures of individual components
Ptotal = PB0 + ( PA0 − PB0 ) x A
(D)

30. In a 0.2 molal aqueous solution of a weak acid (HX), depression in freezing point is
0.3830 C. Kf is 1.860 mol−1kg. Assume molarity equal to molality.
Match the parameters in Column I with their values in Column II and select the answer
from the codes given below.

Column – I Column – II

i. Van’t Hoff factor (i) p. 0.03

ii. Degree of ionization q. 2.22

iii. pK a of HX r. 1.03

iv. pH of HX s. 3.73

Codes
i ii iii iv i ii iii iv
(A) p q r s (B) s q p r
(C) p s r q (D) r p s q

Passage – I
Hgl2 is insoluble in water. This solute is added into KI solution.

31. In the above case

(A) freezing point is lowered
(B) boiling point is elevated
(C) freezing point is elevated
(D) boiling point and freezing point remain unchanged

32. Van’t Hoff factor in this example

4
 (A) increases by 1 unit (B) decreases by 2 unit
(C) decreases by 1 unit (D) increases by 2 unit

Passage – II
A solution containing 10 g of a dibasic acid in 1000 g of water freezes at −0.15 C . 10 mL of
0

K ( H O) = 1.860 mol−1kg 
the acid is neutralized by 12 mL of 0.1 N NaOH solution.  f 2

33. vant’t Hoff factor (i) of the dibasic acid is

(A) 1.34 (B) 2.00 (C) 2.72 (D) 3.00

34. pH of the solution of the acid is

(A) 2.00 (B) 1.70 (C) 3.40 (D) 4.20

Passage – III

A solution containing 0.684 g of cane sugar ( C12H22O11 ) in 100 g water freezes at −0.037 C .
0

A solution containing 0.585 g of NaCl in 100 g water freezes at −0.342 C.

0

35. Apparent molecular weight of NaCl is

−1 −1 −1 −1
(A) 58.5 g mol (B) 31.6 g mol (C) 29.25 g mol (D) 117.0 g mol

36. van’t Hoff factor (i) is

(A) 2.0 (B) 1.5 (C) 1.85 (D) 0.85

Integer Type

37. Relative decrease in vapour pressure of an aqueous NaCl solution is 0.167 Thus number of
moles of NaCl present in 180 g of H2O is

38. Aqueous solution of barium phosphate which is 100% ionised has Tf / K f as 0.40. Hence,
−2
give solution is x 10 molal. what is the value of x?

PA0 5
0
=
39. For an ideal mixture of two liquids A and B, PB 3 and mole fraction of A=0.5. How
many repeated distillation are to be done in order to get a small quantity of distillate
containing at least 0.8 mole fraction of A?

K Fe ( CN)6 
The freezing point depression of a 1.00  10 molal aqueous solution of x 
−3
40. is

7.44 10−3 K. if K f ( H2O) = 1.86 K kg mol . what is the value of x? ( K x Fe ( CN)6  is 100%
−1  
ionised)

Key

1. C 2. A 3. A 4. D 5. A 6. C 7. A
5
8. A 9. D 10. A 11. D 12. A 13. D 14. B

15. D 16. C 17. A 18. B 19. A 20. C 21. B

22. B 23. A 24. D 25. BD 26. ABCD 27. BCD 28. BD

29. ABCD 30. D 31. C 32. C 33. A 34. B 35. B

36. B 37. 1 38. 8 39. 3 40. 3