SECTION–I : (i) Only One option correct Type

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct. 3(–1)

2
1. The radial wave function for 1s electron in H-atom is R = 3/2
e  r / a 0 where a0 = radius of 1st orbit
a 0

of H-atom. The ratio of probability of 1s electron in hydrogen atom at distance a 0 from nucleus to
a0
that at distance from nucleus.
2
1 4 e
(A) equal (B) times (C) times (D) times
e e 4
Ans. (C)
2. Choose the correct statement among the following :-
I Radial distribution function (2.4r2dr) give probability at a particular distance along one
chosen direction
II 2 (r) give probability density at a particular distance for a definite direction
III For s orbital  (r) ()  () = (x, y, z) is independent of  and 
IV 2p orbital with quantum numbers. n = 2, l = 1, m = 0, also shows angular dependence
(A) II, III, IV (B) I, II, III, IV (C) I, III, IV (D) III, IV
Ans. (D)
3. For an electron, with n = 3 has only one radial node. The orbital angular momentum of the electron will
be

h h  h
(A) 0 (B) 6 (C) 2 (D) 3  2 
2 2  

,dbySDVªkWudsfy,n=3dslkFkdsoy,df=T;h;uksMgSAbySDVªkWudkd{kddks.kh;vk?kw.kZgksxk
h h  h 
(A) 0 (B) 6 (C) 2 (D) 3  
2 2  2 

Ans. (C)

(ii) One or more options correct Type

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct. 4(–1)
4. Choose the correct statements from among the following -
(A) A node is a point in space where the wave function () has zero amplitude.
(B) Total number of nodes in an orbital is equal to (n – 1)
(C) 2 represents the probability density of finding the electron
(D) Total no. of angular node in 2px orbital is one.

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 fuEu esa ls lgh dFku dk p;u dhft, -
(A),duksMvUrfj{kesa,dfcUnqgksrkgStgk¡rjaxQyu()dkvk;ke'kwU;gS
(B),dd{kkesauksMksdhdqyla[;k=(n–1)gksrhgS
(C)2,bysDVªkWudsik;stkusdhizkf;drk?kuRodksiznf'kZrdjrkgS
(D)2px d{kkesadks.kh;uksMdhdqyla[;k,dgS
Ans. (A,B,C,D)
5. The wave function of 3s and 3pz orbitals are given by -
1 3
1  1 2  z 2
   (6 – 6 +  ) e
2 –/2
3s  
9 3  4   a0 

1 3
1  3 2  z 2 2zr
3pz     . (4 – )e cos  ; =
–/2

9 6  4   a0  na 0
where a0 = 1st Bohr radius, z = Charge number of nucleus, r = distance from nucleus
From this we can conclude :
(A) Total number of nodal surface is same for 3s and 3pX orbitals

(B) The angular nodal surface of 3pz orbital occur at  =
2

(C) The radial nodal surface of 3s and 3pz orbitals are at equal distance from nucleus
(D) 3s electron have greater penetrating power into the nucleus compared to 3p z electron.
3srFkk3pz d{kdksadsrjaxQyufuEuizdkjfn;sx;sgSa
1 3
1  1 2  z 2
   (6 – 6 +  ) e
2 –/2
3s  
9 3  4   a0 
1 3
1  3 2  z 2 2zr
3pz     . (4 – )e cos  ; =
–/2

9 6  4   a0  na 0
tgk¡a0=1st cksgjf=T;k,z=ukfHkddhvkos'kla[;k;r=ukfHkdlsnwjh
bllsfu"d"kZfudyrkgS%
(A)3srFkk3pXd{kdksadsfy,uksMylrgksadhdqyla[;klekugSA


(B) 3pz d{kd dh dks.kh; uksMy lrg] q = ij gksrh gSA
2

(C)3srFkk3pzd{kdksadhf=T;h;uksMylrgukfHkdlslekunwjhijgSaA
(D)3pzbysDVªkWudhrqyukesa3sbysDVªkWu]ukfHkddhvksjvf/kdHksnu{kerkj[krsgSaA
Ans. (A,B,D)

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6. Which statement is not true, regarding2s orbital.
(A)Number of radial nodes is greater than zero
(B) Angular nodes is equal to zero
(C) () = constant
(D)Probability density is zero at nucleus
2sd{kddslanHkZeasdkSulkdFkulR;ughagS
(A) f=T;h;uksMksdhla[;k'kwU;lsvf/kdgksrhgS
(B)dks.kh;uksM'kwU;dscjkcjgksrkgS
(C) () = fu;rkad
(D) ukfHkdijizkf;drk?kuRo'kwU;gksrkgS
Ans. (D)
7. Which of the following graphs of radial part of wave function () v/s distance from nucleus is/are correctly
labelled ?

1s 3s 3p 2s
 
 
(A) (B) (C) (D)
r r r
r
Ans. (A,B,C,D)
8. Among the following, select the correct information(s)
(A) The opposite lobes in any d-orbital have the same sign of wave function.
(B) 2pz orbital is the only orbital for which the sign of wave function does not have radial as well as
angular dependency.
(C) The number of radial nodes is always greater than that of angular nodes.
(D) All the orbitals belonging from an orbit have the same number of total nodes.
Ans. (A, D)
9. Select the correct statement(s) among the following:
(A) Outside any orbital, the probability of finding electron is zero.
(B) For single electronic atom or ion, the most probable distance of electron in an orbital having no
n 2a o
radial node is from the nucleus, where a0 is the first Bohr radius.
Z
(C) The average distance of electron (belonging from the same orbit) from the nucleus decreases with
the increase in the value of angular momentum quantum number for the orbital.
(D) The angular wave function of any s-orbital is independent from  and .
Ans. (B,C,D)

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 (iii) Paragraph Type
This section contains 1 paragraph each describing theory, experiment, data etc. 2 questions. Each
question of a paragraph has only one correct answer among the four choices (A), (B), (C) and (D).
3(0)
(Paragraph for Q.10 for Q.11
In three dimension (wave function) may be expressed in spherical co-ordinate system (r, , )
r = Represents distance of electron from the nucleus
 = Angle from 'z' axis, varying from 0 to 
 = Angle from 'x' axis ...............0 to 2
 may be represented as
 (r, , ) = R(r). A (, )
The R(r) is determined by 'n' & 'l' . The A (, ) determine how probability change from point to point
at a given distance from the centre of the atom.
10. Which of the following is R(r) part of '3p' atomic orbital of hydrogen atom [Given a 0 = 0.529Å]
3/ 2
2 2  1   r r 2   r / 3a 0
(A) e r / a0 (B)  27  18  2 2  e
(a 0 )3 / 2 27  3a 0   a0 a0 
3/ 2
1  r  1  2  r  r  r / 3a 0
(C) 3/ 2 
2   e  r / 2a 0 (D)   6 a  a e
(2a 0 )  a0  81 3  a 0   0  0
Ans. (D)
(A) ; 1s
(B) ; 3s
(C) ; 2s
(D) ; 3p
1
11. Angular part of 'H' atom wave equation A(, ) = . Hence , atomic orbital is-
4
(A) 'd'xz orbital (B) 'p'x orbital (C) 'p'y orbital (D) s-orbital
Ans. (D)
A() = independent of  & .

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 SECTION-II (ii): (Integer Second Decimal) : 4(0)
 This section contains 2 questions.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value (If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places; e.g. 6.25,
7.00, –0.33, –.30, 30.27, –127.30, if answer is 11.36777..... then both 11.36 and 11.37 will
be correct) by darken the corresponding bubbles in the ORS.
For Example : If answer is –77.25, 5.2 then fill the bubbles as follows.
+ – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9

 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.
1. The minimum number of waves made by a Bohr electron in an orbit of maximum magnetic quantum
number 3 will be -
Ans. (4.00)
2. Suppose the electron is in 1s orbital of a hydrogen atom. What is the probability of finding the electron
3
in a small region of volume 1.0 pm at a distance a0 from the nucleus relative to the probability of finding
it in the same small region located right at the nucleus? The radial function for 1s electron is
3/2
1  1 
R(r) =  a  e r/a 0 .
 o

Ans. (0.13 or 0.14)

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