Sample Paper-03 Class 11th NEET (2024)

CHEMISTRY
ANSWER KEY
1. (4) 26. (3)
2. (3) 27. (1)
3. (3) 28. (2)
4. (1) 29. (2)
5. (1) 30. (1)
6. (2) 31. (2)
7. (2) 32. (1)
8. (2) 33. (3)
9. (3) 34. (2)
10. (2) 35. (2)
11. (1) 36. (4)
12. (4) 37. (1)
13. (2) 38. (2)
14. (4) 39. (4)
15. (3) 40. (3)
16. (4) 41. (4)
17. (1) 42. (1)
18. (2) 43. (2)
19. (2) 44. (1)
20. (4) 45. (3)
21. (2) 46. (1)
22. (2) 47. (2)
23. (2) 48. (4)
24. (2) 49. (1)
25. (4) 50. (1)
 HINTS AND SOLUTION
1. (4) 9. (3)
Addition of reactant will disturb the equilibrium If Δng = + ve, at constant volume, the addition of
and increase the product formation. inert gases does not affect the equilibrium.
2. (3)
Molecules Hybridization Shape 10. (2)
Due to two lone pairs of oxygen atom and 2
PCl5 sp3d Trigonal hydrogen atoms.
bipyramidal
SF4 sp3d Seesaw 11. (1)
XeF4 sp3d2 Square planar CO2 have regular geometry.
BF3 sp2 Trigonal planar
12. (4)
3. (3) CO2 is a symmetrical molecule. So its dipole
Molecules Hybridization moment become zero.
PCl5 sp3d
SF6 sp3d2 13. (2)
NO2+ sp F has 7 electrons in valence shell. Thus, to attain
NH4+ sp3 stability it should have lost one electron.
4. (1)
XeF2, XeF4, XeF6 have linear, square planar and 14. (4)
distorted octahedral shape respectively. XeF2 has Number of radial nodes = n − l − 1
3 lone pairs of electrons. XeF4 has 2 lone pairs of For 3s orbital, number of radial nodes = 3 − 0 − 1 = 2
electrons. XeF6 has 1 lone pair of electrons. For 4p orbital, number of radial nodes = 4 − 1 − 1 = 2

5. (1) 15. (3)

Common ion Cl– will suppress the ionization of
AgCl. In Cl2 & Br2 bond formed by overlapping of p-p
orbital
6. (2)
Statement I is correct, but Statement II is 16. (4)
incorrect. Carbon dioxide reacts with lime water n = 3, l = 0 means last shell is 3s
(calcium hydroxide) to form milky precipitate of Electronic configuration will be
calcium carbonate.
1s22s22p63s1 or 2
7. (2) So, Atomic no. is 11 or 12
SO2 is a bent molecule that has net dipole
moment. 17. (1)
ΔH value is positive and ΔS value is negative
8. (2)
Let total number of NiO molecules is 100. 18. (2)
So, total negative charge on 100 NiO molecules as
4B + 3O2 2B2O3
oxygen exist in O2– = – 200
To maintain electrical neutrality, 98 Ni ions
should have total charge of + 200. B+
Let number of Ni3+ = x
 Number of Ni2+ = (98 – x)
Now, 3x + 2(98 – x) = 200
x = 94
94
% of Ni2+ = × 100 = 96%
98
% of Ni3+ = 100 – 96 = 4%
19. (2) 30. (1)
Use ΔU = q + w = 500 kJ -250 kJ =250 kJ Hydrogen peroxide has a bleaching action due to
its oxidising nature.
20. (4)
31. (2)
It can take up as well as release one proton Covalent character α charge on cation
behaving as conjugate acid or conjugate base. 1

melting point
21. (2)
+ −
order of covalent character Sn2+ < Sn4+ and Pb2+ < Pb4+
I − Cl ⎯⎯⎯ ⎯→ I+ + [AlCl4 ]−
AlCl
3
Anhyd.
32. (1)
I N2 + O2 2NO
2
PNO
+I Kp = …(i)
PN2 .PO2
2NO N2 + O2
22. (2) PN2 .PO2
The degree of ionisation of a solute depends upon K 'p = 2
…(ii)
its nature, concentration, and temperature. PNO
From equation (i) and (ii), we have
23. (2) 1 1
When the concentration of any reactant is added K 'p = = = 0.01
K p 100
to the reactant side, it favours the reaction to
proceed in a forward direction i.e. the equilibrium
is shifted to the right. 33. (3)
B2H6 + 6H2O → 2H3BO3 + 6H2
24. (2)
3 34. (2)
CH3OH(g) + O2 → CO2 + 2H2O CH3 CH3
2 NaOH/CaO
CH3 C COOH CH3 CH CO2
Heat evolved when 1.5 mole of oxygen used
= 900 kJ/mol CH3 CH3
Therefore, heat evolved when 0.5 mole of oxygen
used = 300 kJ/mol. 2,2-dimethyl Isobutane
propanoic acid
25. (4)
If bond is weaker, less energy is required to break
it. So it can release H(+). 35 (2)
G = H − TS
26. (3) = (–54.07) – (298 × 10 × 10–3)
B2H6 + 6H2O → 2H3BO3 + 6H2 G = −57.05kJ mol−1
2NaH + B2H6 → NaBH4
At eq, G = −2.303 RT log K
From B2H6, all can be prepared except B2(CH3)6.
 G
log K = −
27. (1) 2.303 RT
Inert pair effect increases from Si to Pb and thus −(−57.05)
stability of M4+ ions decreases from Si to Pb. =
2.303  8.314  10−3  298
log  10
28. (2)
CO2 is acidic oxide, which on dissolution in water
36. (4)
develops acidic nature.
Kp only depends on temperature. As pressure is
increased, the equilibrium will shift in backward
29. (2)
direction (with decrease in the number of moles of
110 name as Ununnilium
gaseous species) to nullify the effect of increased
for 1 = un
pressure. This decreases the degree of dissociation .
0 = nil
37. (1) 43. (2)
It is the glassy bead that is formed on heating Borazine (B3N3H6) is also known as inorganic
borax. On heating borax first gives sodium tetra benzene.
borate and finally gives a mixture of sodium
metaborate and B2O3 called borax glass. 44. (1)
The stability of resonance structures is given by:
38. (2) 1. Neutral species are more stable than charged
Phenyl group in (IV) increases the stability of ones.
carbanion by resonance and + I effect of methyl 2. Structures in which the octet of all the
group decrease the stability of carbonanion in (I), elements are complete are more stable rather
(II) & (III). As number of methyl group in than incomplete ones.
carbanion increases the stability of carbanion 3. In case of charged species, negative charge
decreases. on more E.N. element is stable than positive
charge.
In the given structures, I is neutral; in II, all
the elements have their octet complete; & III
is least stable.
 The stability order is: I > II > III
39. (4)
As -I effect of fluorine is more than -I effect of 45. (3)
chlorine and with increase in number of fluorine The electron is in the second orbit (n = 2)
atom in molecule -I effect also increases which nh 2h h
increase the stability of carbanion by decreasing Hence L = = =
the negative charge on the carbanion. 2 2 
+I O –I O
CH3 C O < Cl CH2 C O 46. (1)
Due to inert effect the stability of lower oxidation
–I O –I O state gradually increases while stability of higher
< F CH2 C O < F2 CH2 C O oxidation state gradually decreases down the group
in elements of group 13th to 15th.
40. (3) 47. (2)
Peroxide
CH3 – CH = CH2 + HBr ⎯⎯⎯⎯⎯⎯⎯⎯⎯
→ Mendeleev’s Periodic Law is based on atomic
antimarkovnikovaddition
weight.
CH3 CH2 CH2
Br [n-propylbromide] 48. (4)
Inert pair effect increases from Si to Pb and thus
41. (4) stability of M4+ ions decreases from Si to Pb.
NO2
Conc. H2SO4
49. (1)
Neon has 10 electrons while oxygen has 8
HNO3
electrons, so it gains two electrons forming a
[Benzene] [Nitro benzene] anion O2− with 10 electrons and having the same
HNO3 + 2H2SO4 2HSO4– + H3O+ + NO 2 number as neon.
HNO3 acts as base it reacts with H2SO4 to form
50. (1)
the electrophile NO
2 ion. In C-60, all carbons are identical and have sp2
hybridization.
42. (1)
For Cr2O3
2x + 3(–2) = 0
2x – 6 = 0
x=+3

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