JEE Mains (11th)

Sample Paper - IV

DURATION ::180
DURATION Minutes
90 Minutes M. MARKS : 300

ANSWER KEY

PHYSICS CHEMISTRY MATHEMATICS

1. (4) 31. (3) 61. (1)

2. (1) 32. (3) 62. (1)
3. (3) 33. (4) 63. (2)
4. (2) 34. (1) 64. (1)
5. (1) 35. (2) 65. (3)
6. (4) 36. (4) 66. (2)
7. (3) 37. (4) 67. (3)
8. (2) 38. (4) 68. (1)
9. (4) 39. (3) 69. (1)
10. (4) 40. (4) 70. (3)
11. (2) 41. (2) 71. (3)
12. (2) 42. (2) 72. (2)
13. (3) 43. (4) 73. (3)
14. (3) 44. (3) 74. (4)
15. (1) 45. (4) 75. (3)
16. (3) 46. (4) 76. (2)
17. (3) 47. (1) 77. (1)
18. (1) 48. (2) 78. (1)
19. (3) 49. (2) 79. (3)
20. (2) 50. (3) 80. (2)
21. (14) 51. (8) 81. (16)
22. (7) 52. (4) 82. (40)
23. (0.075) 53. (8) 83. (5)
24. (11.67) 54. (2) 84. (27)
25. (600) 55. (0) 85. (3)
26. (100) 56. (4) 86. (9)
27. (445) 57. (4) 87. (3)
28. (1.0) 58. (7) 88. (4)
29. (10) 59. (5) 89. (6)
30. (112) 60. (6) 90. (17)

[1]
 PHYSICS
1. (4) According to problem, mass A moves in a
Velocity of a particle at maximum height h is perpendicular direction and let the mass B moves at
v = v cos  angle  with the horizontal with velocity v.
where v = initial velocity of the particle at which it is Initial horizontal momentum of system
projected, (before collision) = mv ...(i)
 = angle of projection
Final horizontal momentum of system
Angular momentum, L = mvh = mv cos  h
𝑚𝑣ℎ
(after collision) = mV cos  ...(ii)
= mvh cos 45° = . From the conservation of horizontal linear
√2
2. (1) momentum, mv = mV cos 
F + F cos  = mg sin   v = V cos  ...(iii)
mg sin 
F= Initial vertical momentum of system (before
1 + cos  collision) is zero.
 
mg 2sin cos mv
F= 2 2 Final vertical momentum of system = − mv sin 
2
3
2cos
2 From the conservation of vertical linear momentum
mv
− mv sin  = 0
3
v
 = V sin  ...(iv)
3
By solving (iii) and (iv), we get

   2 
 sin  = 2sin 2  cos 2 and 1 + cos  = 2cos 2 
v2 +
v2
3
(
= V 2 sin2  + cos2  )
 4v 2 2
= mg tan  = V 2 V = v.
2 3 3
3. (3) 5. (1)
dv
P = Fv = m v 3m − m g
dt a= g=
3m + m 2
dv P dv dx P
or v = or v   = Acceleration of centre of mass
dt m dx dt m
dv P P g mg
or v 2 = or v2 dv = dx 3m  −
dx m m = 2 2 =g
On integration, we get; 3m + m 4
1/3 6. (4)
v3 Px  3xP 
= or v = 
3 m  m 
4. (2)
Let mass A moves with velocity v and collides
inelastically with mass B, which is at rest. 2R
l=
4
2l
or R =

 I = mR2
2
 2l 
= m 
 

0.4 ml2 (as 2 10)

[2]
7. (3) 1
 h11g + h22 g = 1v2
The particles will always remain diametrically 2
opposite so that the force on each particle will be
  
directed along the radius. Considering the circular  v = 2  h1 + h2 2  g .
motion of one particle.  1 

mv2 Gm2 Gm
= 2
or v = 12. (2)
r (2r ) 4r
dQ dQ1 dQ2
= +
dt dt dt
8. (2) 4R2 (1 − 2 )
Let V be the volume of the load and  be its relative K
L
density. Then
R2 (1 − 2 ) 3R2 (1 − 2 )
FL V gL = K1 + K2
Y= = ...(i) L L
Ala Ala
K1 + 3K2
or 4K = K1 + 3K2 or K = .
When load is immersed in liquid, the net weight = 4
weight-upthrust
F L (V g − V  1  g ) L 13. (3)
 Y= = ...(ii)
Alw Alw Internal energy of n moles of an ideal gas at
temperature T is given by:
Equating eqns. (i) and (ii),
f
 ( − 1) l U= nRT [f = degree of freedom]
= or  = a 2
la l la − lw
U1 = U2
Here, f2 = degree of freedom of He = 3
9. (4)
and f1 = degree of freedom of H2 = 5
W = T  A = T  2  4R2
n1 f 2T2 3  2 6
4  = = = .
and V = R3 n2 f1T1 5  1 5
3
When volume is doubled new radius becomes
14. (3)
R = (2)1/3 R
PV = RT = constant. ...(i)
 W  = T  2  4R 2
Also, VP2 = constant ...(ii)
= T  2  4(2)2/3 R2 RT
From eqn. (i), P =
= T  2  4(4)1/3 R2 = (4)1/3W V
2
 RT 
From eqn. (ii), V 
 V 
= constant
10. (4)
Let h be the height of liquid surface in the vessel. The R2T 2 T2
velocity of efflux is given by: = constant or = constant
V V
veff. = (2gh)
T 2 T 2
If H be the height of table, then  = or T  2 = 2T 2
V 2V
1
H = gt 2 or t = (2H / g)  T  = 2T .
2
 R = veff.  t = 2gh 2H / gR2
15. (1)
R2
R2 = 4hH or h =  y2 
( )
. 1 1
4H K = m 2 A2 − y 2 = m2 A2 1 − 2 
2 2  A 
11. (2)
Net pressure = h11g + h22 g . A 1  1
when y = , K = m2 A2 1 − 
According to Bernoulli's theorem, this pressure 2 2  4
energy will be converted into KE while flowing 3E 1
through the hole A. = . (Where E = m2 A2 )
4 2
[3]
16. (3) 21. (14)
I = I1 + I2 + 2 ( )
I1I2 cos  Position time relation of the particle, s = t3 + 3

= I 0 + 4I 0 + 2 ( I0 )( 4I0 ) cos 
ds d 3
Speed of the particle, v = =
dt dt
( )
t + 3 = 3t 2

= 5I0 + 4I0 cos  Tangential acceleration,

As  = 0, , so cos  = 1 at =
dv d 2
=
dt dt
( )
3t = 6t
 I = 5I0 + 4I0 = 9I0 At time t = 2s
Speed of the particle, v = 3(2)2 = 12 m/s
17. (3) Tangential acceleration, at = 6(2) = 12 m/s2
L = 1 m = 100 cm, m = (0.5/100) Centripetal acceleration,
= 5 × 10–3 g/cm and p = 4 v2 (12)2 144
ac = = = = 7.2 m/s2
In the transverse arrangement the frequency of the R 20 20
vibrating string is equal to the frequency of the tuning
fork, i.e., 200 Hz. Net acceleration, a = ( ac )2 + ( at )2
p T
Now, n = = (7.2)2 + (12)2  14 m/s2
2L m
4 T
or 200 = 22. (7)
2  100 5  10−3 Net external torque is zero. Therefore, angular
 T = 5 × 105 dyne. momentum of system will remain conserved, i.e.,
Li = Lf
18. (1) Initial angular momentum Li = 0.
P  T2  Final angular momentum should also be zero, or
PT–2 = constant angular momentum of man = angular momentum of
platform in opposite direction,
  
 1−  or mv0r = I 
compare with PT = constant
mv0 r 70  10  2
Cp  = =
= =2 I 200
Cv
  = 7 rad/sec.

19. (3)
23. (0.075)
For capillary tube
1
Energy stored = × work done
2T 2
h=
rg 1
=  F  x
We can say 2
1 1 1 YA  YAx 
h
r
or h 
d
=  x  x
2 L  F = b 
h1 d2 Substituting values
So, =
h2 d1 1 2  1011  3  10−6  1  10−3  10−3
E= 
4 d 2 4
 =
x 2d E = 0.075 J
 x = 8 cm
24. (11.67)
20. (2) m
PV = RT
M
 = 2t3 = 6t 2
m (m / 2)
d 20  V = R  300, P  V = R  350
= = 6t 2 − 12t M M
dt
140
 = 0  12t − 12 = 0  t = 1s .  P = = 11.67 atm.
12
[4]
25. (600) 28. (1.0)
Maximum heat supplied by water The frequencies are in the ratio of 5 : 7 : 9. Hence, it
Q1 = 500 × 1 × (20 – 0) is a COP.
= 10,000 cal  v
Now, 425 = 5  
Heat required to raise the temperature of ice upto 0°C  4l 
Q2 = 200 × 0.5 × 20 5v 5  340
 l= = = 1.0 m.
= 2000 cal 4  425 4  425
Q1 – Q2 = 8000 cal
Melts the ice 29. (10)
8000 = m × 80 When the man is approaching the factory:
m = 100 g  v + vo   320 + 2   322 
n =  n=  800 = 
  320 
800
So, mass of water is 500 +100 = 600 g.  v   320 
When the man is going away from the factory,
26. (100)
 v − vo   320 − 2   318 
2 n =  n=  800 = 
  320 
800
 =  x  v   320 

 2 1.25  322 − 318
 n − n =  800 = 10 .
=   320 
4  100
1
 = m/s
10 30. (112)
1 Radiation  T4
v = n = 1000  = 100 m/s.
10 4
R T 
So 1 =  1 
R2  T2 
27. (445)
4
v – 5 = 440 Hz 7  500 
=
x  1000 
and v – 8 = 437 Hz
 v = 445 Hz (by both the methods) x = 112 cal/cm2s

It could have been 435 Hz. It would have satisfied

440 – v = 5 but this would not have satisfied 437 Hz.

CHEMISTRY
32. (3) h2
=
Number of molecules =
mass
 NA 322ma 02
M.M.
.
32. (3) 33. (4)
rn  n 2 Screening effect is not observed in single electron
system.
r2 = (2)2 a0 = 4a0
nh 2h
mvr = = 34. (1)
2 2 Bond angle  E.N. of central atom
h
v= (r = 4a 0 )
mr 35. (2)
h SF6 is sp3d2 hydridised
v=
m(4a 0 ) Bond angle = 90°
So, K.E. = 1/2 mv2 no. of d orbitals
2 % d character = 100
1  h  Total no.of orbitals
= m 
2  m(4a 0 ) 
[5]
36. (4) 45. (4)
K.E.  T –M and –I effect stablise the carbanion
8RT
avg =
M 46. (4)
Ketone has higher priority and hence is main
37. (4) functional group.
m
PV = RT
M.M. 47. (1)
+ −
38. (4) ON− Cl + CH3 − CH = CH2 →
rGo  0 describe spontaneous process +

 stable oxidation state of Pb is + 2 and Sn is +4. C H3 − C H − CH 2 − NO


39. (3) C H3CH(Cl)CH 2 NO
KC = [OH–]3 [Fe3+]
3
1 3
KC =   OH   Fe 
− 3+
48. (2)
4  Br2/FeBr3 – Electrophilic aromatic substitution
64. KC = [OH–]3 [Fe3+]
49. (2)
40. (4)
Informative
 H +  =  H +  +  H + 
Total HCl H 2O

= 10–8 + 10–7 50. (3)

= 1.1 × 10–7
Ksp = [Ag+] [Cl–]
pH = – log(1.1 × 10–7)
pH = 6.95

41. (2) 4 10−10 = Ag+  (0.08)CaCl2

+6
K2 Cr 2 O7 →Cr 3+
M.M. M 51. (8)
Eq. wt. = =
n − factor 6 Weak electrolytes → do not dissociate completely
(Change in O.S. of Cr in K2Cr2O7 is (2 × 3) = 6)
52. (4)
42. (2)
Estimation of hardness of water. The hardness of Divide the given equation by (3), we get
water due to Ca2+ and Mg2+ ions is usually K´ = (K)1/3
estimated volumetrically. A known volume of hard
water contining buffer solution of pH 10 is titrated 53. (8)
against a standard solution of EDTA (ethylenediamine 0.4 MH2SO4 = 0.8 M H+
tetraacetic acid disodium salt) using Eriochrome
0.1 M HCl = 0.1 M H+
Black T as indicator. Under these conditions, Ca2+
and Mg2+ ions form complexes with EDTA. When [H + ]H2SO4 8
all the Ca2+ and Mg2+ ions are consumed, the next =
[H + ]HCl 1
drop of EDTA changes the colour of the indicator
from wine red to blue.
54. (2)
43. (4) PM = dRT
Al4C3 +12.H 2O → 4Al(OH)3 + 3CH4 PM
d=
Be2C + 4H 2O → 2Be(OH)2 + CH 4 RT
(4P)M
Now, d ' =
44. (3) R(2T)
Emerald has cyclic structure 2PM
Asbestos – Chain silicate d' =
Talc – Sheet silicate
RT
Mica – Chain silicate
[6]
55. (0) If r is the radius of Ag atom, volume of 1 Ag atom
BrF5 is sp3d2 hybridized with 1 lone pair 4 3
= r
It has square pyramidal shape 3
But due to repulsion by lone pair on the bond pairs, 4 108
Thus, r 3 =
all the four planar bond angles decreases from 90° 3 10.5 6.02 1023
to 84.8°. The axial bond also no longer remains 90° This gives r = 1.6 × 10–8 cm = 1.6 × 10–10 m
with the planer bonds.
Area occupied by 1 Ag atom =  r 2
Equilibrium constant for the reaction
= 3.14 × (1.6 × 10–10)2 m2
A3 (g) + 3B2 (g) 3AB2 (g) is 64.0. Then the Hence, no. of Ag atoms on a surface area of
equilibrium constant for the reaction 10−12
10−12 m2 = −10 2
= 1.25  107
1
A3 (g) + B2 (g) AB2 (g) will be 3.14  (1.6  10 )
3  x=7
56. (4)
59. (5)
E.N.F on pauling scale = 4
57. (4)
Total no. of nodes = n – 1
58. (7)
108 3
Volume of 1 mole of Ag atoms = cm 60. (6)
10.5
108 1 Hydrides of group 15, 16 and 17 have more
 Volume of 1 Ag atom =  electrons than required to form normal covalent
10.5 6.02 1023 bonds and hence are electron rich hydrides.

MATHEMATICS
61. (1)
h cot  − h cot  = 2 63. (2)
2 Let r + 1 = 7  r = 6
 h=
cot  − cot 
9
 3 
Given expansion is  3 + 3 n x , x > 0
2sin  sin   84 
=
sin( − ) We have Tr+1 = Cr (x) a for (x + a)n.
n n–r r

A  According to the equation.

3
 3 
( )
6
729 = C6  3  .
9
3l n x
 84 
h
33 3
 36 = 84   3  ( n x)6
84
 
P 2 Q B  ( n x) 6 = 1  x = e

62. (1)
The given equation is 64. (1)
(a – 2b + c)x2 + (b – 2c + a)x + (c – 2a + b) = 0  tan  − i[sin( / 2) + cos( / 2)] 
Re  =0
(a − 2b + c) = 0  1 + 2i sin( / 2) 
 One root of this equation is 1.        
  tan  − i  sin + cos   1 − 2i sin  
Now,   2 2   2 
sec  + tan  = 1
Re 
 =0
.......(i)  
1 + 4sin 2
We know that  2 
sec2  − tan2  = 1
sec  − tan  = 1 .......(ii)
 On solving eqs. (i) and (ii),
we get sec  = 1
 One root of given equation is sec
[7]
      2
 tan  − 2sin 2  cos 2 + sin 2    1
    m2 + 1
     
 −i  tan .2sin + sin + cos    4  m2 + 1
 2 
 
2 2
 =0
 1 + 4sin 2   m2 − 3  0
 2 
   (m − 3)(m + 3)  0
 
   m  (−, − 3]  [ 3, )

 tan  = 2sin 2 + sin 
2 69. (1)
sin  (7C0 + 7C1) + (7C1 + 7C2) + .... + (7C6 + 7C7)
 = sin  + 1 − cos 
cos  = 8C1 + 8C2 + ..... + 8C7
 sin  = sin .cos  + cos  − cos2  = 8C0 + 8C1 + 8C2 + ..... + 8C7 + 8C8 – (8C0 + 8C8)
 sin (1 − cos ) = cos (1 − cos ) = 28 – (1 + 1) = 28 – 2
 sin  = cos , cos  = 1
 70. (3)
  = n + ,  = 2n where n  Z
4 a2, b2, c2 are in A.P.
Adding ab + bc + ca to each of these terms.
65. (3)
a2 + ab + bc + ca, b2 + ab + bc + ca, c2 + ab + bc +
30 marks to be alloted to 8 questions. Each question
ca are in A.P.
has to be given  2 marks
Let marks of questions be a, b, c, d, e, f, g, h (a + b) (a + c), (b + c) (b + a), (c + a) (c + b) are in
and a + b + c + d + e + f + g + h = 30 A.P.
Let a = a1 + 2 so, a1  0 Dividing each term by (b + c) (c + a) (a + b),
b = a2 + 2 so, a2  0,……, a8  0 1 1 1
, , are in A.P.
a + a + .... + a8  b+c c +a a +b
So, 1 2  = 30
+2 + 2 + .... + 2  b + c, c + a, a + b are in H.P.
 a1 + a2 + ..... + a8 = 30 −16 = 14
So, this is a problem of distributing 14 articles in 8 71. (3)
groups. Given (a, a2) falls inside the angle made by
Number of ways =14+8–1C8–1= 21C7 x
y = , x  0 and y = 3x, x > 0
2
66. (2)
a
The centre of given circle is (–g, –f).  a 2 − 3a  0 and a 2 − 0
2
If the given line ax + bx + c = 0 is normal to the
1 1 
circle, then it passes through the centre of circle   a  3  a   ,3 
 a(–g) + b(–f) + c = 0 2 2 
 ag + bf – c = 0 72. (2)
Let us make the truth table for the given statements,
as follows:
67. (3)
The coordinates of the vertices of the rectangle are pq q→ p p→ p→
p q
A(1, 4), B(6, 4), C(6, 10) and D(1, 10).
( q → p) ( p  q)
The equation of diagonal AC is
T T T T T T
10 − 4
y–4= ( x − 1)  6 x − 5 y + 14 = 0 T F T T T T
6 −1
F T T F T T
F F F T T T
68. (1)
If the line y = mx + 2 cuts the circle x2 + y2 = 1 at From table ne observe
distinct or coincident points, then p → (q → p) is equivalent to p → ( p  q)
Length of perpendicular from centre  Radius
[8]
73. (3) Solving the above three lines in pairs, we get the
Sum of quantities n / 2(a + l ) point A, B, C as
x= =
n n  a a 
 sec  − tan  , sec  − tan   ,
1
= (1 + 1 + 100d ) = 1 + 50d  
2  a −a 
1
M.D. =  xi − x  sec  + tan  , sec  + tan   and (0, 0)
 
n
Since the one vertex is the origin therefore the area
of the triangle ABC is
1
 255 = (50d + 49d + ... + d + 0 + d + ... + 50d ) 1
101 ( x1 y2 − x2 y1 )
2
2d  50  51  255 101
=  d= = 10.1
101  2  50  51 =
a2 

−1
− 2
1 
2 
2  sec  − tan  sec  − tan  
2 2

74. (4) a2
a1 + a2 (2cos2 x − 1) + a3 (1 − cos2 x) = 1 = (−2) = −a2 = a2 sq. unit
2
or (2a2 − a3 )cos2 x + (a1 − a2 + a3 − 1) = 0
This can hold for all x if 79. (3)
2a2 – a3 = 0 and a1 – a2 + a3 – 1 = 0 We have  +  = −b and  = 1
As there are two equations in three unknowns, the  1   1 
number of solutions is infinite. Let S = −   +  +  −   +  
     
75. (3)  1 1
Let d be the common difference = −( + ) −  + 
 
a7 = 9
  +  b
 a1 + 6d = 9 =b −  = b −  −  = 2b
Let D = a1a2a7 = (9 − 6d )(9 − 5d )9     1
   1    1 
9 
2
33  And P =  −   +   −   +  
= 270  d −  −       
 20  400   
 1  1
For least value of D, =   +   + 
33    
d− =0
20 1 1
=  + + 2 =1+ + 2 = 4
 d=
33  1
20  The required equation is x2 – Sx + P = 0
76. (2)  x2 − 2bx + 4 = 0
Given that sin x + cosec x + tan y + cot y = 4
  80. (2)
 x = and y =
2 4 Number of elements in A × B = 2 × 4 = 8
 tan y = 1 Required number of subsets
2tan y / 2 y y = 8C3 + 8C4 + ..... + 8C8
 = 1  tan 2 + 2tan − 1 = 0 = (8C0+ 8C1 + ..... 8C8) – (8C0 + 8C1 + 8C2)
1 − tan y / 2
2
2 2
= 28 – (1 + 8 + 28) = 219
77. (1) 81. (16)
(2 x − 3)( x − 1)  ( x + 1) A = {–2, –1, 0, 1, 2}
lim
x→1 ( x − 1)(2 x + 3)( x + 1) R = {(–2, –2), (0, 0), (1, 1), (2, 2)}
−1 −1 As R has four elements, the power set of R contains
= = 16 elements
5.2 10
82. (40)
78. (1) 1 1 
Any tangent to the hyperbola at ar = 6  − 
 r r +1
P(a sec , a tan ) is 20
 1  120 40 k
x sec  − y tan  = a ......(i)   ar = 6 1 −  = = =
r =1  21  21 7 7
Also x – y = 0 ......(ii)
 k = 40
x+y=0 ....... (iii)
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83. (5) Y
We have x + 2y + 3z + 4w = 50 x=c
Using the fact A.M  G.M., we get
 x   y   z   4w 
2   + 4   + 3  + 1 
2  2 1  1  A(1,1) D(c,1)
B(9,1)
2 + 4 + 3 +1 c
1/10 E(c, 9 )
 x  2  y  4 3 
     ( z ) (4w)  O(0,0)
X
 2   2  
1/10
 x2  y 4   The equation of OB is y = x
1
 5   2  4  ( z)3 (22 w)  9
 2  2   Hence, the point E is (c, c/9)
 x2 y 4 z3 w 
1/10 Now, the area of BDE is 2 sq units.
 5  1 c
 16  Therefore, 1 −  (9 − c) = 2
2 9
84. (27)  (9 − c) = 36
2

 3   3   9 − c = 6  c = 3
cos  x −  + sin  + x  + sin(32 + x) 88. (4)
 2  2  Radius of given circle
−18cos(19 − x) + cos(56 + x) − 9sin( x + 17)
= − sin x − cos x + sin x + 18cos x + cos x
x2 + y2 + 4x – 2 2 y + c = 0
+ 9sin x = 18cos x + 9sin x is 4 + 2 − c = 6 − c = a (let)
a + b = 27 a
Now radius of circle S1 = ,
2
85. (3)
a
Here a = 1. Any tangent having slope m is Radius of circle S2 = and so on.
1 2
y = mx + a a
m Now, a + + + ..... = 2 (given)
If passes through (–2, –1). Therefore, 2 2
2m2 – m – 1 = 0  a = 2− 2 = 6−c
1
or m = 1, −  4+2−4 2 =6−c
2
1 + (1/ 2)  c=4 2
or tan  = =3 89. (6)
1 − (1/ 2) n(n − 1)
(1 + ax)n = 1 + n(ax) + (ax)2 + ...
86. (9) 1.2
Equating coefficients of x and x2
We have, na = 8 ....... (1) and
x2 + bx – 1 = 0 ......(i)
n(n − 1) 2
x2 + x + b = 0 .....(ii) a = 24 .....(2)
On subtracting (ii) from (i), we get 2
b +1  a=
8
x(1 − b) + 1 + b = 0  x =
b −1 n
On putting value of x in (ii), We get Substitute the value of a in (2)
n(n − 1) 64
= 24
2
 b +1  b +1
 b −1  +  b −1  + b = 0 2 n2
     4n − 4 = 3n
 (b + 1) + (b + 1)(b − 1) + b(b − 1)2 = 0
2
 n=4
 b3 + 3b = 0  b(b2 + 3) = 0 8
 a= =2
But b  0 4
 b2 = −3  b4 = 9 90. (17)
(100− r )

87. (3)
tr+1 = 100Cr x 2
(y )
1/3 r

1 100 − r r
Area of OAB = (1)(8) = 4 sq units so should be integer as well as should
2 2 3
be integer. r = 0, 6, 12, 18, ......, 96
Thus r can assume total 17 terms.

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