Safety Data Sheet

according to UK REACH Regulation

Alkadur-HR-Hardener
Revision date: 02.04.2024 Product code: 5035198085 Page 1 of 18

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Alkadur-HR-Hardener
Further trade names
Safety Data Sheet valid for all package sizes
UFI: CCXE-43WQ-D89C-7M1E
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Epoxy resin-Plating agent/Primers/Two-pack performance coatings
(Hardener-component)
Uses advised against
No specific uses advised against are identified.
The product is intended for professional use.
1.3. Details of the supplier of the safety data sheet
Company name: STEULER-KCH GmbH
Siershahn
Street: Berggarten 1
Place: D-56427 Siershahn
Telephone: +49 2623 600 0 Telefax: +49 2623 600 513
E-mail: [email protected]
Contact person: Labor COS/RUL
E-mail: [email protected]
Internet: www.steuler-kch.de
Responsible Department: +49 2624 13 507
+49 2623 600 535
1.4. Emergency telephone number: (001) 352 3233500 Emtel-Customer-No. 99496
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GB CLP Regulation
Acute Tox. 4; H302
Acute Tox. 4; H332
Skin Corr. 1; H314
Eye Dam. 1; H318
Skin Sens. 1; H317
Repr. 1B; H360Fd
Aquatic Chronic 1; H410

Full text of hazard statements: see SECTION 16.

2.2. Label elements
GB CLP Regulation
Hazard components for labelling
benzyl alcohol
[3-(Aminomethyl)phenyl]methanamine reaction products with bis(4-glycidyloxyphenyl)methane
3-aminomethyl-3,5,5-trimethylcyclohexylamine
m-phenylenebis(methylamine)
bisphenol A; 4,4'-isopropylidenediphenol
4-nonylphenol, branched
Signal word: Danger
Pictograms:

Hazard statements
H302+H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H360Fd May damage fertility. Suspected of damaging the unborn child.
H410 Very toxic to aquatic life with long lasting effects.

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Precautionary statements
P260 Do not breathe mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or
shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
Special labelling of certain mixtures
Restricted to professional users.
Additional advice on labelling
Calculation method. On basis of test data.
2.3. Other hazards
Endocrine disrupting properties: bisphenol A; 4,4'-isopropylidenediphenol; 4-nonylphenol, branched.
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
Mixture related information:
Amines.

Relevant ingredients
CAS No Chemical name Quantity
EC No Index No REACH No
Classification (GB CLP Regulation)
100-51-6 benzyl alcohol 35 - < 40 %
202-859-9 603-057-00-5 01-2119492630-38
Acute Tox. 4, Acute Tox. 4, Eye Irrit. 2; H332 H302 H319
1083058-22-3 [3-(Aminomethyl)phenyl]methanamine reaction products with bis(4-glycidyloxyphenyl)methane 20 - < 25 %
Acute Tox. 4, Acute Tox. 4, Skin Corr. 1B, Eye Dam. 1, Skin Sens. 1, Aquatic Chronic 3; H332 H302 H314
H318 H317 H412
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine 15 - < 20 %
220-666-8 612-067-00-9 01-2119514687-32
Acute Tox. 4, Skin Corr. 1B, Eye Dam. 1, Skin Sens. 1A; H302 H314 H318 H317
1477-55-0 m-phenylenebis(methylamine) 10 - < 15 %
216-032-5 01-2119480150-50
Acute Tox. 4, Acute Tox. 4, Skin Corr. 1B, Eye Dam. 1, Skin Sens. 1, Aquatic Chronic 3; H332 H302 H314
H318 H317 H412 EUH071
80-05-7 bisphenol A; 4,4'-isopropylidenediphenol 1-<5%
201-245-8 604-030-00-0 01-2119457856-23
Repr. 1B, Eye Dam. 1, Skin Sens. 1, STOT SE 3, Aquatic Acute 1, Aquatic Chronic 1; H360F H318 H317
H335 H400 H410
84852-15-3 4-nonylphenol, branched 1-<5%
284-325-5 601-053-00-8 01-2119510715-45
Repr. 2, Acute Tox. 4, Skin Corr. 1B, Aquatic Acute 1, Aquatic Chronic 1; H361fd H302 H314 H400 H410
Full text of H and EUH statements: see section 16.

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Specific Conc. Limits, M-factors and ATE

CAS No EC No Chemical name Quantity
Specific Conc. Limits, M-factors and ATE
100-51-6 202-859-9 benzyl alcohol 35 - < 40 %
inhalation: ATE = 11 mg/l (vapours); inhalation: ATE = 1,5 mg/l (dusts or mists); dermal: LD50 = > 2000
mg/kg; oral: LD50 = 1580 mg/kg
1083058-22-3 [3-(Aminomethyl)phenyl]methanamine reaction products with 20 - < 25 %
bis(4-glycidyloxyphenyl)methane
inhalation: ATE = 11 mg/l (vapours); inhalation: ATE = 1,5 mg/l (dusts or mists); oral: ATE = 500 mg/kg
2855-13-2 220-666-8 3-aminomethyl-3,5,5-trimethylcyclohexylamine 15 - < 20 %
dermal: LD50 = > 2000 mg/kg; oral: ATE 1030 mg/kg Skin Sens. 1A; H317: >= 0,001 - 100
1477-55-0 216-032-5 m-phenylenebis(methylamine) 10 - < 15 %
inhalation: ATE = 11 mg/l (vapours); inhalation: LC50 = 1,34 mg/l (dusts or mists); dermal: LD50 = > 3100
mg/kg; oral: LD50 = 930 mg/kg
80-05-7 201-245-8 bisphenol A; 4,4'-isopropylidenediphenol 1-<5%
dermal: LD50 = ca. 3000 mg/kg; oral: LD50 = 4100 mg/kg Aquatic Acute 1; H400: M=1
Aquatic Chronic 1; H410: M=10
84852-15-3 284-325-5 4-nonylphenol, branched 1-<5%
oral: LD50 = 1412 mg/kg
Further Information
"[3-(Aminomethyl)phenyl]methanamine reaction products with bis(4-glycidyloxyphenyl)methane" - Exempted from
registration under REACH Annex V (4)
This mixture contains the following substances of very high concern (SVHC) which are included in the Candidate List
according to Article 59 of REACH:
CAS No.: 80-05-7 - bisphenol A; 4,4'-isopropylidenediphenol
CAS No.: 84852-15-3 - 4-nonylphenol, branched
SECTION 4: First aid measures
4.1. Description of first aid measures
General information
First aider: Pay attention to self-protection! Move victim out of danger zone. In case of accident or unwellness, seek
medical advice immediately (show directions for use or safety data sheet if possible). Remove contaminated, saturated
clothing immediately.
After inhalation
Provide fresh air. When in doubt or if symptoms are observed, get medical advice.
After contact with skin
After contact with skin, wash immediately with plenty of water and soap. Take off immediately all contaminated clothing
and wash it before reuse. In case of skin reactions, consult a physician.
After contact with eyes
Rinse immediately carefully and thoroughly with eye-bath or water. Remove contact lenses, if present and easy to do.
Continue rinsing. In case of troubles or persistent symptoms, consult an ophthalmologist.
After ingestion
Rinse mouth immediately and drink plenty of water. Do NOT induce vomiting. Adverse human health effects and
symptoms: Gastric perforation. Call a physician immediately. Do not allow a neutralisation agent to be drunk.
4.2. Most important symptoms and effects, both acute and delayed
May cause sensitisation especially in sensitive humans.
In all cases of doubt, or when symptoms persist, seek medical advice.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Water spray jet; Carbon dioxide (CO2); Dry extinguishing powder; alcohol resistant foam.
Use caution when applying carbon dioxide in confined spaces. Carbon dioxide can displace oxygen.
Unsuitable extinguishing media
High power water jet.
5.2. Special hazards arising from the substance or mixture
This material is combustible, but will not ignite readily.
In case of fire may be liberated:
Ammonia (NH3); Carbon dioxide (CO2); Carbon monoxide; Nitrogen oxides (NOx).
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Alkadur-HR-Hardener
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Burning produces heavy smoke.

5.3. Advice for firefighters
In case of fire: Wear self-contained breathing apparatus. Use personal protection equipment.
Co-ordinate fire-fighting measures to the fire surroundings. Use water spray jet to protect personnel and to cool
endangered containers. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface
water.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General advice
Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes and clothes. Use
personal protection equipment.
For non-emergency personnel
Move victim out of danger zone.
For emergency responders
Use personal protective equipment as required.
6.2. Environmental precautions
Do not allow to enter into surface water or drains.
Do not allow to enter into soil/subsoil.
6.3. Methods and material for containment and cleaning up
For containment
Stop leak if safe to do so. Cover drains.
For cleaning up
Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).
Treat the recovered material as prescribed in the section on waste disposal.
Other information
Clean contaminated articles and floor according to the environmental legislation.
6.4. Reference to other sections
Safe handling: see section 7
Personal protection equipment: see section 8
Disposal: see section 13
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling
Keep container tightly closed in a cool, well-ventilated place. Provide adequate ventilation. Wear personal protection
equipment.
Advice on protection against fire and explosion
No special fire protection measures are necessary.
Usual measures for fire prevention.
Advice on general occupational hygiene
Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme. Wash hands
and face before breaks and after work and take a shower if necessary. Do not eat, drink or smoke when using this
product.
Further information on handling
Epoxy resins in the construction industry - instructions
Persons with a history of skin sensitisation problems should not be employed in any process in which this product is used.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep only in the original container in a cool, well-ventilated place. Store in a place accessible by authorized persons only.
Ensure adequate ventilation of the storage area.
Hints on joint storage
Do not store together with: Oxidizing agents. acid.
Do not store together with: Food and fodder
Further information on storage conditions
Floors should be impervious, resistant to liquids and easy to clean. Observe in addition any national regulations!
7.3. Specific end use(s)
for professional use only Observe technical data sheet.
Epoxy resin products, CMR properties, sensitising, low in solvents or total solid
SECTION 8: Exposure controls/personal protection

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8.1. Control parameters

Exposure limits (EH40)
CAS No Substance ppm mg/m³ fibres/ml Category Origin

80-05-7 Bisphenol A, inhalable dust - 2 TWA (8 h) WEL

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DNEL/DMEL values
CAS No Substance
DNEL type Exposure route Effect Value
100-51-6 benzyl alcohol
Worker DNEL, long-term inhalation systemic 22 mg/m³
Worker DNEL, acute inhalation systemic 110 mg/m³
Worker DNEL, long-term dermal systemic 8 mg/kg bw/day
Worker DNEL, acute dermal systemic 40 mg/kg bw/day
Consumer DNEL, long-term inhalation systemic 5,4 mg/m³
Consumer DNEL, acute inhalation systemic 27 mg/m³
Consumer DNEL, long-term dermal systemic 4 mg/kg bw/day
Consumer DNEL, acute dermal systemic 20 mg/kg bw/day
Consumer DNEL, long-term oral systemic 4 mg/kg bw/day
Consumer DNEL, acute oral systemic 20 mg/kg bw/day
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Worker DNEL, long-term inhalation local 0,073 mg/m³
Consumer DNEL, acute oral systemic 0,3 mg/kg bw/day
Worker DNEL, acute inhalation systemic 20,1 mg/m³
Worker DNEL, acute inhalation local 0,073 mg/m³
Consumer DNEL, long-term oral systemic 0,3 mg/kg bw/day
1477-55-0 m-phenylenebis(methylamine)
Worker DNEL, long-term inhalation systemic 1,2 mg/m³
Worker DNEL, long-term inhalation local 0,2 mg/m³
Worker DNEL, long-term dermal systemic 0,33 mg/kg bw/day
80-05-7 bisphenol A; 4,4'-isopropylidenediphenol
Worker DNEL, long-term inhalation local 2 mg/m³
Worker DNEL, acute inhalation local 2 mg/m³
Worker DNEL, acute dermal systemic 0,066 mg/kg bw/day
Worker DNEL, acute inhalation systemic 2 mg/m³
Worker DNEL, long-term dermal systemic 0,066 mg/kg bw/day
Worker DNEL, long-term inhalation systemic 2 mg/m³
Consumer DNEL, acute dermal systemic 0,024 mg/kg bw/day
Consumer DNEL, acute inhalation systemic 1 mg/m³
Consumer DNEL, acute oral systemic 0,053 mg/kg bw/day
Consumer DNEL, long-term dermal systemic 0,024 mg/kg bw/day
Consumer DNEL, long-term inhalation systemic 1 mg/m³
Consumer DNEL, long-term oral systemic 0,053 mg/kg bw/day
Consumer DNEL, long-term inhalation local 1 mg/m³
Consumer DNEL, acute inhalation local 1 mg/m³
84852-15-3 4-nonylphenol, branched
Consumer DNEL, acute oral systemic 0,4 mg/kg bw/day
Worker DNEL, acute dermal systemic 15 mg/kg bw/day
Worker DNEL, acute inhalation systemic 1 mg/m³
Worker DNEL, long-term dermal systemic 7,5 mg/kg bw/day
Worker DNEL, long-term inhalation systemic 0,5 mg/m³
Consumer DNEL, acute dermal systemic 7,6 mg/kg bw/day
Consumer DNEL, acute inhalation systemic 0,8 mg/m³
Consumer DNEL, long-term dermal systemic 3,8 mg/kg bw/day

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Consumer DNEL, long-term inhalation systemic 0,4 mg/m³

Consumer DNEL, long-term oral systemic 0,08 mg/kg bw/day
,

PNEC values
CAS No Substance
Environmental compartment Value
100-51-6 benzyl alcohol
Freshwater 1 mg/l
Freshwater (intermittent releases) 2,3 mg/l
Marine water 0,1 mg/l
Freshwater sediment 5,27 mg/kg
Marine sediment 0,527 mg/kg
Micro-organisms in sewage treatment plants (STP) 39 mg/l
Soil 0,456 mg/kg
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Freshwater 0,06 mg/l
Freshwater (intermittent releases) 0,23 mg/l
Marine water 0,006 mg/l
Freshwater sediment 5,784 mg/kg
Marine sediment 0,578 mg/kg
Micro-organisms in sewage treatment plants (STP) 3,18 mg/l
Soil 1,121 mg/kg
1477-55-0 m-phenylenebis(methylamine)
Freshwater 0,094 mg/l
Freshwater (intermittent releases) 0,152 mg/l
Marine water 0,009 mg/l
Freshwater sediment 12,4 mg/kg
Marine sediment 1,24 mg/kg
Micro-organisms in sewage treatment plants (STP) 10 mg/l
Soil 2,44 mg/kg
80-05-7 bisphenol A; 4,4'-isopropylidenediphenol
Freshwater 0,023 mg/l
Freshwater (intermittent releases) 0,011 mg/l
Marine water 0,019 mg/l
Freshwater sediment 1,2 mg/kg
Marine sediment 0,24 mg/kg
Micro-organisms in sewage treatment plants (STP) 320 mg/l
Soil 3,7 mg/kg
84852-15-3 4-nonylphenol, branched
Freshwater 0,00061 mg/l
Freshwater (intermittent releases) 0 mg/l
Marine water 0,00057 mg/l
Freshwater sediment 4,62 mg/kg
Marine sediment 1,23 mg/kg
Secondary poisoning 2,36 mg/kg
Micro-organisms in sewage treatment plants (STP) 9,5 mg/l
Soil 2,3 mg/kg

Additional advice on limit values

CAS No. 80-05-7, bisphenol A; 4,4'-isopropylidenediphenol.
Limit value is only valid for the substance in solid form. Not relevant since the solid is in solution.
8.2. Exposure controls

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Appropriate engineering controls

Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. In the immediate working surroundings there must
be: Provide eye shower and label its location conspicuously
Individual protection measures, such as personal protective equipment
Eye/face protection
Suitable eye protection: (EN 166)
Eye glasses with side protection, goggles.
Hand protection
When handling with chemical substances, protective gloves must be worn with the CE-label including the four control
digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working
place concentration and quantity of hazardous substances.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above
together with the supplier of these gloves.
Suitable material: (EN ISO 374)
Butyl rubber. NBR (Nitrile rubber).
Breakthrough times and swelling properties of the material must be taken into consideration.
Skin protection
Wear long-sleeved work clothes.
Suitable protective clothing: Single-use suit.
(EN 1073; EN 13034; EN 14605)
Respiratory protection
With correct and proper use, and under normal conditions, breathing protection is not required.
Respiratory protection necessary at:
exceeding exposure limit values; insufficient ventilation; insufficient absorbtion.
Suitable respiratory protective equipment: (EN 14387)
Filtering device with filter or ventilator filtering device of type: ABEK(P)
Use only respiratory protection equipment with CE-symbol including four digit test number.
Thermal hazards
No risks worthy to mention.
Environmental exposure controls
See chapter 7. No additional measures necessary.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state: liquid
Colour: light yellow
Odour: like: amines
Odour threshold: No data available
Test method
Melting point/freezing point: No data available
Boiling point or initial boiling point and boiling 205 - 360 °C
range:
Flammability: This material is combustible, but will not ignite
readily.
Lower explosion limits: 1,2 vol. % benzyl alcohol
Upper explosion limits: 13 vol. % benzyl alcohol
Flash point: > 100 °C DIN EN ISO 2719
Auto-ignition temperature: 380 °C DIN 51794
Decomposition temperature: No data available
pH-Value (at 20 °C): 11,5 - 12 (30 g/L)
Viscosity / kinematic: 360 - 550 mm²/s calculated
(at 25 °C)
Water solubility: slightly soluble
(at 20 °C)
Solubility in other solvents
The product is miscible with most organic solvents
Dissolution rate: No data available
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Partition coefficient n-octanol/water: There are no data available on the mixture itself.
Dispersion stability: No data available
Vapour pressure: 0,07 hPa benzyl alcohol
(at 20 °C)
Vapour pressure: 0,67 hPa benzyl alcohol
(at 50 °C)
Density (at 20 °C): 1,07 g/cm³ DIN EN ISO 2811
Bulk density: not applicable
Relative vapour density: No data available
Particle characteristics: Liquid - not applicable
9.2. Other information
Information with regard to physical hazard classes
Explosive properties
The product is not explosive.
Sustaining combustion: Sustaining combustion
Oxidizing properties
Not oxidising.
Other safety characteristics
Viscosity / dynamic: 385 - 585 mPa·s Brookfield
(at 25 °C)
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non-reactive under normal use conditions.
10.2. Chemical stability
The mixture is chemically stable under recommended conditions of storage, use and temperature.
10.3. Possibility of hazardous reactions
No hazardous reaction when handled and stored according to provisions.
Exothermic reaction with: Acid, Peroxides.
10.4. Conditions to avoid
Keep away from heat.
Thermal decomposition can lead to the escape of irritating gases and vapours.
10.5. Incompatible materials
Alkali (lye), concentrated; Oxidising agent, strong; Acid, concentrated.
10.6. Hazardous decomposition products
Ammonia (NH3); Gases/vapours, corrosive.
Decomposition products in case of fire: see section 5.
SECTION 11: Toxicological information
11.1. Information on hazard classes as defined in GB CLP Regulation
Acute toxicity
Harmful if swallowed.
Harmful if inhaled.
ATEmix calculated
ATE (oral) 971,6 mg/kg; ATE (dermal) > 2000 mg/kg; ATE (inhalation vapour) 14,49 mg/l; ATE (inhalation
dust/mist) 1,932 mg/l

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CAS No Chemical name

Exposure route Dose Species Source Method
100-51-6 benzyl alcohol
oral LD50 1580 Mouse Cosmet. Toxicol. 11, OECD Guideline 401
mg/kg 1011-1013 (1973) (1
dermal LD50 > 2000 Rabbit Raw Material Data EPA OTS 798.1100
mg/kg Handbook, Vol.1:( Orga
inhalation vapour ATE 11 mg/l
inhalation dust/mist ATE 1,5 mg/l
1083058-22-3 [3-(Aminomethyl)phenyl]methanamine reaction products with bis(4-glycidyloxyphenyl)methane
oral ATE 500 mg/kg
inhalation vapour ATE 11 mg/l
inhalation dust/mist ATE 1,5 mg/l
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
oral ATE 1030 mg/kg
dermal LD50 > 2000 Rat Study report (2010) OECD Guideline 402
mg/kg
1477-55-0 m-phenylenebis(methylamine)
oral LD50 930 mg/kg Rat Study report (1973) OECD Guideline 401
dermal LD50 > 3100 Rat Study report (1975) TK 11813 was applied to
mg/kg a shaved area of
inhalation vapour ATE 11 mg/l
inhalation (4 h) dust/mist LC50 1,34 mg/l Rat Safety Data Sheet
80-05-7 bisphenol A; 4,4'-isopropylidenediphenol
oral LD50 4100 Mouse Study report (1982) This was an acute oral
mg/kg toxicity test wit
dermal LD50 ca. 3000 Rabbit Study report (1948) Acute toxicity by skin
mg/kg penetration
84852-15-3 4-nonylphenol, branched
oral LD50 1412 Rat Study report (1981) other: HLD protocol
mg/kg number P 1/152 and r
Irritation and corrosivity
Causes severe skin burns and eye damage. (On basis of test data)
Causes serious eye damage. (On basis of test data)
Sensitising effects
May cause an allergic skin reaction. ([3-(Aminomethyl)phenyl]methanamine reaction products with
bis(4-glycidyloxyphenyl)methane; 3-aminomethyl-3,5,5-trimethylcyclohexylamine; m-phenylenebis(methylamine);
bisphenol A; 4,4'-isopropylidenediphenol)
Carcinogenic/mutagenic/toxic effects for reproduction
May damage fertility. Suspected of damaging the unborn child.
Germ cell mutagenicity: Based on available data, the classification criteria are not met.
Carcinogenicity: Based on available data, the classification criteria are not met.
STOT-single exposure
Based on available data, the classification criteria are not met.
STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
Specific effects in experiment on an animal
The product has not been tested. Toxicological data are not available.
11.2. Information on other hazards
Endocrine disrupting properties
Endocrine disrupting properties: bisphenol A; 4,4'-isopropylidenediphenol.
Further information
The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP]. Special hazards arising from the
substance or mixture!
SECTION 12: Ecological information

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12.1. Toxicity
Very toxic to aquatic life with long lasting effects.

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CAS No Chemical name

Aquatic toxicity Dose [h] | [d] Species Source Method
100-51-6 benzyl alcohol
Acute fish toxicity LC50 > 100 96 h Oryzias latipes Review article or OECD Guideline
mg/l handbook (2009) 203
Acute algae toxicity ErC50 770 mg/l 72 h Raphidocelis subcapitata Review article or OECD Guideline
handbook (2009) 201
Acute crustacea toxicity EC50 230 mg/l 48 h Daphnia magna Review article or OECD Guideline
handbook (2009) 202
Fish toxicity NOEC 48,897 30 d Fish species http://epa.gov/oppt/e other: QSAR
mg/l xposure/pubs/episui
Crustacea toxicity NOEC 51 mg/l 21 d Daphnia magna Review article or OECD Guideline
handbook (2009) 211
Acute bacteria toxicity EC50 1385 mg/l 3 h activated sludge, Study report (1989) OECD Guideline
() domestic 209
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Acute fish toxicity LC50 110 mg/l 96 h Leuciscus idus REACh Registration EU Method C.1
Dossier
Acute algae toxicity ErC50 37 mg/l 72 h Desmodesmus REACh Registration EU Method C.3
subspicatus Dossier
Acute crustacea toxicity EC50 23 mg/l 48 h Daphnia magna REACh Registration OECD Guideline
Dossier 202
Crustacea toxicity NOEC 3 mg/l 21 d Daphnia magna REACh Registration other: OECD 202,
Dossier part 2
1477-55-0 m-phenylenebis(methylamine)
Acute fish toxicity LC50 75 mg/l 96 h Leuciscus idus Study report (1998) OECD Guideline
203
Acute algae toxicity ErC50 32,1 mg/l 72 h Desmodesmus REACh Registration OECD Guideline
subspicatus Dossier 201
Acute crustacea toxicity EC50 15,2 mg/l 48 h Daphnia magna (Big Safety Data Sheet OECD 202
water flea)
Crustacea toxicity NOEC 4,7 mg/l 21 d Daphnia magna REACh Registration OECD Guideline
Dossier 211
Acute bacteria toxicity EC50 > 1000 0,5 h Activated sludge from Study report (2004) OECD Guideline
mg/l ( ) laboratory wastewater 209
plant
80-05-7 bisphenol A; 4,4'-isopropylidenediphenol
Acute fish toxicity LC50 4,6 mg/l 96 h Pimephales promelas REACh Registration other: ASTM
Dossier E729-80
Acute algae toxicity ErC50 1,1 mg/l 96 h Raphidocelis subcapitata REACh Registration other:
Dossier EPA-600/9-78-018
Acute crustacea toxicity EC50 0,885 48 h Acartia clausi was the Environ Pollut 232, other: ISO 14669
mg/l most sensitive test 173-182 (2018)
species
Fish toxicity NOEC 0,016 28 d Oncorhynchus mykiss REACh Registration OECD Guideline
mg/l Dossier 215
Crustacea toxicity NOEC 0,025 21 d Daphnia magna REACh Registration OECD Guideline
mg/l Dossier 211
84852-15-3 4-nonylphenol, branched
Acute fish toxicity LC50 0,05 mg/l 96 h Acipenser oxyrhynchus Publication (2005) other: ASTM
E729-96 and
Committee on Met
Acute algae toxicity ErC50 1,3 mg/l 72 h Desmodesmus Study report (1989) other: Algal growth
subspicatus inhibition test acco
Acute crustacea toxicity EC50 0,0844 48 h Daphnia magna Study report (1993) other: ASTM 1991
mg/l E729-88a Standard
guide
Fish toxicity NOEC 0,006 91 d Oncorhynchus mykiss Study report (1993) other: ASTM
mg/l

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Safety Data Sheet
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Alkadur-HR-Hardener
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Algae toxicity NOEC 0,2 mg/l 14 d Microcystis aeruginosa ISSN 19950829, - Principle of test:
Inland Water The objective of t
Biology, 201
Crustacea toxicity NOEC 0,0247 28 d Potamopyrgus Study report (2020) OECD Guideline
mg/l antipodarium 242
Acute bacteria toxicity EC50 950 mg/l ( 3 h activated sludge of a Study report (1999) OECD Guideline
) predominantly domestic 209
sewag

12.2. Persistence and degradability

There are no data available on the mixture itself.
CAS No Chemical name
Method Value d Source
Evaluation
100-51-6 benzyl alcohol
OECD 301A (DOC reduction) 95 % 21
Readily biodegradable (according to OECD criteria).
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
OECD 301A/ ISO 7827/ EEC 92/69/V, C.4-A 8% 28
Not readily biodegradable (according to OECD criteria)
1477-55-0 m-phenylenebis(methylamine)
OECD 301B 49 % 28
Not easily bio-degradable (according to OECD-criteria).

12.3. Bioaccumulative potential

There are no data available on the mixture itself.
Partition coefficient n-octanol/water
CAS No Chemical name Log Pow
100-51-6 benzyl alcohol 1
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine 0,99
1477-55-0 m-phenylenebis(methylamine) ca. 0,18
80-05-7 bisphenol A; 4,4'-isopropylidenediphenol 3,4
84852-15-3 4-nonylphenol, branched 5,4

BCF
CAS No Chemical name BCF Species Source
100-51-6 benzyl alcohol 1,371 QSAR model http://epa.gov/oppt/
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylami 2,63 fish REACh Registration D
ne
1477-55-0 m-phenylenebis(methylamine) 3,16 no data Validated suite of c
80-05-7 bisphenol A; 4,4'-isopropylidenediphenol 20 - 67 Cyprinus carpio REACh Registration D
84852-15-3 4-nonylphenol, branched 1200 Gasterosteus aculeatus REACh Registration D

12.4. Mobility in soil

No information available.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to UK REACH.
12.6. Endocrine disrupting properties
Endocrine disrupting properties: bisphenol A; 4,4'-isopropylidenediphenol; 4-nonylphenol, branched.
12.7. Other adverse effects
No further relevant information available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Disposal recommendations
Dispose of waste according to applicable legislation. Evidence for disposal must be provided.
List of Wastes Code - residues/unused products
070208 WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic rubber
and man-made fibres; other still bottoms and reaction residues; hazardous waste

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Alkadur-HR-Hardener
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List of Wastes Code - contaminated packaging

150110 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging
waste); packaging containing residues of or contaminated by hazardous substances; hazardous waste
Contaminated packaging
This material and its container must be disposed of as hazardous waste. Handle contaminated packages in the same way
as the substance itself. Completely emptied packages can be recycled.
SECTION 14: Transport information
Land transport (ADR/RID)
14.1. UN number or ID number: UN 2735
14.2. UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S.
(m-phenylenebis(methylamine) / 4-nonylphenol, branched)
14.3. Transport hazard class(es): 8
14.4. Packing group: II
Hazard label: 8

Classification code: C7
Special Provisions: 274
Limited quantity: 1L
Excepted quantity: E2
Transport category: 2
Hazard No: 80
Tunnel restriction code: E
Inland waterways transport (ADN)
14.1. UN number or ID number: UN 2735
14.2. UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S.
(m-phenylenebis(methylamine) / 4-nonylphenol, branched)
14.3. Transport hazard class(es): 8
14.4. Packing group: II
Hazard label: 8

Classification code: C7
Special Provisions: 274
Limited quantity: 1L
Excepted quantity: E2

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Alkadur-HR-Hardener
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Marine transport (IMDG)

14.1. UN number or ID number: UN 2735
14.2. UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S.
(m-phenylenebis(methylamine) / 4-nonylphenol, branched)
14.3. Transport hazard class(es): 8
14.4. Packing group: II
Hazard label: 8

Marine pollutant: yes

Special Provisions: 274
Limited quantity: 1L
Excepted quantity: E2
EmS: F-A, S-B
Segregation group: IMDG-Code segregation group 18 - Alkalis
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number or ID number: UN 2735
14.2. UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S.
(m-phenylenebis(methylamine) / 4-nonylphenol, branched)
14.3. Transport hazard class(es): 8
14.4. Packing group: II
Hazard label: 8

Special Provisions: A3 A803

Limited quantity Passenger: 0.5 L
Passenger LQ: Y840
Excepted quantity: E2
IATA-packing instructions - Passenger: 851
IATA-max. quantity - Passenger: 1L
IATA-packing instructions - Cargo: 855
IATA-max. quantity - Cargo: 30 L
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: Yes

Danger releasing substance: 4-nonylphenol, branched

14.6. Special precautions for user
Warning: strongly corrosive.
Keep away from food, drink and animal feedingstuffs.
14.7. Maritime transport in bulk according to IMO instruments
Maritime transport in bulk according to IMO instruments not applicable.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
Authorisations (REACH, annex XIV):
Substances of very high concern, SVHC (REACH, article 59):
bisphenol A; 4,4'-isopropylidenediphenol; 4-nonylphenol, branched
Restrictions on use (REACH, annex XVII):
Entry 3, Entry 66, Entry 75
Directive 2004/42/EC on VOC in paints 55,251 % (591,188 g/l)
and varnishes:

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Alkadur-HR-Hardener
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Information according to Directive E1 Hazardous to the Aquatic Environment

2012/18/EU (SEVESO III):
Additional information
Directive 2004/42/EC on the limitation of emissions of volatile organic compounds:
Solvent not relevant, goes into the curing process.
National regulatory information
Employment restrictions: Observe restrictions to employment for juveniles according to the 'juvenile work
protection guideline' (94/33/EC). Observe employment restrictions under the
Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Water hazard class (D): 3 - highly hazardous to water
Skin resorption/Sensitization: Causes allergic hypersensitivity reactions.
Additional information
All ingredients of the mixture are public/active listed or exempted.
The regulations of the national employment safety and employment protection commission about the handling for
polyurethane/epoxy have to be observed.
15.2. Chemical safety assessment
For the following substances of this mixture a chemical safety assessment has been carried out:
benzyl alcohol
4-nonylphenol, branched
SECTION 16: Other information
Changes
This data sheet contains changes from the previous version in section(s): 1,2,8.
Abbreviations and acronyms

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Safety Data Sheet
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Alkadur-HR-Hardener
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Acute Tox: Acute toxicity

Skin Corr: Skin corrosion
Eye Dam: Eye damage
Eye Irrit: Eye irritation
Skin Sens: Skin sensitisation
Repr: Reproductive toxicity
STOT SE: Specific target organ toxicity - single exposure
Aquatic Acute: Acute aquatic hazard
Aquatic Chronic: Chronic aquatic hazard
CLP: Classification, labelling and Packaging
REACH: Registration, Evaluation and Authorization of Chemicals
GHS: Globally Harmonised System of Classification, Labelling and Packaging of Chemicals
UN: United Nations
CAS: Chemical Abstracts Service
DNEL: Derived No Effect Level
DMEL: Derived Minimal Effect Level
PNEC: Predicted No Effect Concentration
ATE: Acute toxicity estimate
LC50: Lethal concentration, 50%
LD50: Lethal dose, 50%
LL50: Lethal loading, 50%
EL50: Effect loading, 50%
EC50: Effective Concentration 50%
ErC50: Effective Concentration 50%, growth rate
NOEC: No Observed Effect Concentration
BCF: Bio-concentration factor
PBT: persistent, bioaccumulative, toxic
vPvB: very persistent, very bioaccumulative
ADR: Accord européen sur le transport des marchandises dangereuses par Route
(European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: Regulations concerning the international carriage of dangerous goods by rail
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways (Accord
européen relatif au transport international des marchandises dangereuses par voies de navigation intérieures)
IMDG: International Maritime Code for Dangerous Goods
EmS: Emergency Schedules
MFAG: Medical First Aid Guide
IATA: International Air Transport Association
ICAO: International Civil Aviation Organization
MARPOL: International Convention for the Prevention of Marine Pollution from Ships
IBC: Intermediate Bulk Container
SVHC: Substance of Very High Concern
VOC: Volatile Organic Compounds
For abbreviations and acronyms, see table at http://abbrev.esdscom.eu
Key literature references and sources for data
Information from our suppliers and data from the "Database of Registered Substances" of the European Chemicals
Agency (ECHA) were used to create this safety data sheet.
National workplace limit value lists of the respective countries in the currently valid version.
Transport regulations according to ADR, RID, IMDG, IATA in the currently valid version.
Classification for mixtures and used evaluation method according to GB CLP Regulation
Classification Classification procedure
Acute Tox. 4; H302 Calculation method
Acute Tox. 4; H332 Calculation method
Skin Corr. 1; H314 On basis of test data
Eye Dam. 1; H318 On basis of test data
Skin Sens. 1; H317 Calculation method
Repr. 1B; H360Fd Calculation method
Aquatic Chronic 1; H410 Calculation method
Relevant H and EUH statements (number and full text)
H302 Harmful if swallowed.
H302+H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.

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Alkadur-HR-Hardener
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H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H360F May damage fertility.
H360Fd May damage fertility. Suspected of damaging the unborn child.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH071 Corrosive to the respiratory tract.
Further Information
The above information describes exclusively the safety requirements of the product and is based on our present-day
knowledge. The information is intended to give you advice about the safe handling of the product named in this safety
data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the
case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not
necessarily valid for the new made-up material. The information is based on the present level of our knowledge. It does
not, however, give assurance of product properties and establishes no contract legal rights. The receiver of our product is
singularly responsible for adhering to existing laws and regulations.

(The data for the relevant ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)

Revision No: 4 - Replaces version: 3,00 GB - en Print date: 03.04.2024