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Atomic Structure _ DPP 04 (Extra) __ NSEC 2024

The document is a question paper for NSEC 2024 in Physical Chemistry, focusing on atomic structure and quantum numbers. It contains multiple-choice questions regarding quantum numbers, electron configurations, and angular momentum. An answer key is provided at the end for reference.

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7 views

Atomic Structure _ DPP 04 (Extra) __ NSEC 2024

The document is a question paper for NSEC 2024 in Physical Chemistry, focusing on atomic structure and quantum numbers. It contains multiple-choice questions regarding quantum numbers, electron configurations, and angular momentum. An answer key is provided at the end for reference.

Uploaded by

MILLU XD
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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1

NSEC 2024
Physical Chemistry

Atomic Structure DPP-04


1. Which of the following statements concerning the 7. Spin angular momentum for electron:
four quantum numbers is false: h h
(1) s(s + 1) (2) 2 s(s + 1)
(1) n gives idea of the size of an orbital 2 2
h
(2)  gives the shape of an orbital (3) s(s + 2) (4) None
2
(3) m gives the energy of the electron in the
orbital 8. An electron is in one of 4d-orbital. Which of the
(4) s gives the direction of spin of the following orbital quantum number value is not
possible:
electron in an orbital (1) n = 4 (2) l = 1
(3) m = 1 (4) m = 2
2. The magnetic quantum number for valence
electron of sodium atom is: 9. Any nf -orbital can accomodate upto:
(1) 14 electrons
(1) 3 (2) 2
(2) Six electrons
(3) 1 (4) Zero (3) Two electrons with parallel spin
(4) Two electrons with opposite spin
3. The set of quantum number for the 19th electron in
chromium is: 10. If n &  are principal and azimuthal quantum no.
(1) n=4, =0, m=0, s =+1/2 or -1/2 respectively then the expression for calculating the
total no. of electron in any energy level is:
(2) n=3,  =2, m=1, s=+1/2 or -1/2 =n =n −1
(1)  2(2 + 1) (2)  2(2 + 1)
(3) n=3,  =2, m= -1, s=+1/2 or -1/2 =0 =1
=n +1 =n −1

(4) n=4,  =1, m=0, s=+1/2 or -1/2 (3) =0


2(2 + 1) (4)  2(2
=0
+ 1)

4. The following quantum no. are possible for how 11. Which of the following sets of quantum numbers
is correct for an electron in 4 f-orbital?
many orbitals n = 3,  = 2, m = +2 ? 1
(1) n = 4, l = 3, m = +4, s = +
(1) 1 (2) 2 2
(3) 3 (4) 4 1
(2) n = 4, l = 4, m = –4, s = –
2
1
5. Number of possible orbitals (all types) in n = 3 (3) n = 4, l = 3, m = +1, s = +
2
energy level is:
1
(1) 1 (2) 3 (4) n = 3, l = 2, m = –2, s = +
2
(3) 4 (4) 9
12. If elements with principal quantum number
6. Which sub-shell is not permissible: n > 4 is not allowed in nature, the number of
(1) 2d (2) 4f possible elements would be:
(1) 60 (2) 32
(3) 6p (4) 3s
(3) 64 (4) 50
2
13. Correct set of four quantum numbers for the 15. The electrons identified by quantum numbers n
valence (outer most) electron of rubidium and 
(Z = 37) is:
1 1 (a) n = 4,  = 1 (b) n = 4,  = 0
(1) 5,0,0, + (2) 5,1,0, +
2 2
(c) n = 3,  = 2 (d) n = 3,  = 1
1 3
(3) 5,1,1, + (4) 5,0,0, –
2 2 can be placed in order of increasing energy as:
(1) (d) < (b) < (c) < (a)
14. What are the values of the orbital angular (2) (b) < (d) < (a) < (c)
momentum of an electron in the orbitals 1s, 3s, 3d (3) (a) < (c) < (b) < (d)
and 2p:
(4) (c) < (d) < (b) < (a)
(1) 0, 0, 6 , 2 (2) 1, 1, 4 , 2
(3) 0, 1, 6 , 3 (4) 0, 0, 20 , 6
3
ANSWER KEY
1. (3) 9. (4)
2. (4) 10. (4)
3. (1) 11. (3)
4. (1) 12. (1)
5. (4) 13. (1)
6. (1) 14. (1)
7. (1) 15. (1)
8. (2)

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