WB JEE

Engineering Entrance Exam

Solved Paper 2018

Physics
Category-I (Q. Nos. 1 to 30) X -axis and perpendicular to the xy-plane.
The reflected ray passes through the point
Only one answer is correct. Correct answer will
fetch full marks 1. Incorrect answer or any (3, 3). What is the path length of the ray
combination of more than one answer will fetch from (0, 1) to (3, 3)?
1 (a) 5 (b) 13
− marks. No answer will fetch 0 marks. (c) 2 3 (d) 1 + 2 3
4
4. Two identical
1. Four resistors, 100 Ω, 200 Ω, 300 Ω and 400 Ω
equiconvex lenses,
are connected to form four sides of a square.
each of focal length f
The resistors can be connected in any order.
are placed side by side
What is the maximum possible equivalent
in contact with each
resistance across the diagonal of the square?
other with a layer of
(a) 210Ω (b) 240Ω
water in between
(c) 300Ω (d) 250Ω
them as shown in the figure. If refractive
2. What will be current through the 200 Ω index of the material of the lenses is greater
resistor in the given circuit, a long time after than that of water, how the combined focal
the switch K is made on? length F is related to f ?
f
(a) F > f (b) <F<f
100Ω 1µF 400Ω 2
f
(c) F < (d) F = f
2
200Ω 300Ω 2µF
5. There is a small air bubble at the centre of a
solid glass sphere of radius r and refractive
6V K index µ. What will be the apparent distance
of the bubble from the centre of the sphere,
(a) Zero (b) 100 mA when viewed from outside?
(c) 10 mA (d) 1 mA r
(a) r (b)
µ
3. A point source is placed at coordinates (0, 1)  1
(c) r  1 −  (d) Zero
in x y-plane. A ray of light from the source is  µ
reflected on a plane mirror placed along the

Page 1 of 44
 6. If Young’s double slit experiment is done 12. In case of a simple harmonic motion, if the
with white light, which of the following velocity is plotted along the X -axis and the
statements will be true? displacement (from the equilibrium position)
(a) All the bright fringes will be coloured. is plotted along the Y -axis, the resultant
(b) All the bright fringes will be white. curve happens to be an ellipse with the ratio:
(c) The central fringe will be white. major axis (along X )
(d) No stable interference pattern will be visible. = 20 π
minor axis (along Y)
7. How the linear velocity v of an electron in the What is the frequency of the simple harmonic
Bohr orbit is related to its quantum number n? motion?
1 1 1
(a) v ∝ (b) v ∝ (a) 100 Hz (b) 20 Hz (c) 10 Hz (d) Hz
n n 2 10
1
(c) v ∝ (d) v ∝ n 13. A block of mass m2 is placed on a horizontal
n
table and another block of mass m1 is placed
8. If the half-life of a radioactive nucleus is on top of it. An increasing horizontal force
3 days, nearly what fraction of the initial F = αt is exerted on the upper block but the
number of nuclei will decay on the third day? lower block never moves as a result. If the
(Given, 3 0.25 ≈ 0 .63) coefficient of friction between the blocks is µ 1
and that between the lower block and the
(a) 0.63 (b) 0.5 (c) 0.37 (d) 0.13 table is µ 2 , then what is the maximum
9. An electron accelerated through a potential possible value of µ 1 / µ 2 ?
m2 m2 m1 m1
of 10000 V from rest has a de-Broglie wave (a) (b) 1 + (c) (d) 1 +
length λ. What should be the accelerating m1 m1 m2 m2
potential, so that the wavelength is doubled?
14. In a triangle ABC, the sides AB and AC are
(a) 20000 V (b) 40000 V (c) 5000 V (d) 2500 V
represented by the vectors 3 $i + $j + k$ and
10. In the circuit shown, inputs A and B are in $i + 2 $j + k$ , respectively. Calculate the angle
states 1 and 0 respectively. What is the only
∠ ABC.
possible stable state of the outputs X and Y ?
5 6
(a) cos −1 (b) cos −1
A 11 11
(1) X
 5  5
(c)  90° − cos −1  (d)  180° − cos −1 
 11   11 
(0)
Y
B 15. The velocity (v) of a particle (under a force F)
(a) X = 1, Y = 1 (b) X = 1, Y = 0 depends on its distance (x) from the origin
(c) X = 0, Y = 1 (d) X = 0, Y = 0 1
(with x > 0) v ∝ . Find how the magnitude
11. What will be the current flowing through the x
6 kΩ resistor in the circuit shown, where the of the force (F) on the particle depends on x?
breakdown voltage of the Zener is 6 V? 1 1 1
(a) F ∝ (b) F ∝ (c) F ∝ 2
(d) F ∝ x
x3 / 2 x x
6 kΩ
16. The ratio of accelerations due to gravity g1 : g2
10V on the surfaces of two planets is 5 : 2 and the
4 kΩ
ratio of their respective average densities
ρ1 : ρ2 is 2 : 1. What is the ratio of respective
escape velocities v1 : v2 from the surface of the
2 3
(a) mA (b) 1mA (c) 10 mA (d) mA planets?
3 2
(a) 5 : 2 (b) 5 : 2 (c) 5 : 2 2 (d) 25 : 4

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17. A spherical liquid drop is placed on a 22. For an ideal gas with initial pressure and
horizontal plane. A small disturbance causes volume p i and Vi respectively, a reversible
the volume of the drop to oscillate. The time isothermal expansion happens, when its
period of oscillation (T) of the liquid drop volume becomes V0 . Then, it is compressed to
depends on radius (r) of the drop, density (ρ) its original volume Vi by a reversible
and surface tension (S) of the liquid. Which adiabatic process. If the final pressure is p f ,
among the following will be a possible then which of the following statement(s)
expression for T (where, k is a dimensionless is/are true?
constant)? (a) pf = pi (b) pf > pi
ρr ρ2 r ρr 3 ρr 3 p p
(a) k (b) k (c) k (d) k (c) pf < pi (d) f = i
S S S S2 V0 Vi

18. The stress along the length of a rod (with 23. A point charge − q is carried from a point A to
rectangular cross-section) is 1% of the another point B on the axis of a charged ring
Young’s modulus of its material. What is the of radius r carrying a charge + q. If the point
approximate percentage of change of its 4
volume? (Poisson’s ratio of the material of A is at a distance r from the centre of the
3
the rod is 0.3.) 3
(a) 3% (b) 1% (c) 0.7% (d) 0.4% ring and the point B is r from the centre but
4
19. What will be the approximate terminal velocity on the opposite side, what is the net work
of a rain drop of diameter 1.8 × 10 −3 m, when that need to be done for this?
density of rain water ≈ 10 3 kgm −3 and the 7 q2 1 q2
(a) − ⋅ (b) − ⋅
5 4 πε0 r 5 4 πε0 r
coefficient of viscosity of air ≈ 1.8 × 10 −5 N-sm
−2 7 q2 1 q2
? (Neglect buoyancy of air) (c) ⋅ (d) ⋅
5 4 πε0 r 5 4 πε0 r
(a) 49 ms −1 (b) 98 ms −1 (c) 392 ms −1 (d) 980 ms −1

20. The water equivalent of a calorimeter is 10 g 24. Consider a region in free space bounded by
and it contains 50 g of water at 15°C. Some the surfaces of an imaginary cube having
amount of ice, initially at − 10 °C is dropped sides of length a as shown in the figure. A
in it and half of the ice melts till equilibrium charge + Q is placed at the centre O of the
is reached. What was the initial amount of cube. P is such a point outside the cube that
ice that was dropped (when specific heat of the line OP perpendicularly intersects the
surface ABCD at R and also OR = RP = a /2.
ice = 0 .5 cal gm −1 ° C−1 , specific heat of water
A charge + Q is placed at point P also. What is
. cal gm −1 ° C−1 and latent heat of melting
= 10 the total electric flux through the five faces
of ice = 80 cal gm −1 )? of the cube other than ABCD?
(a) 10 g (b) 18 g (c) 20 g (d) 30 g A
a
B
21. One mole of a monoatomic ideal gas
a/2 a/2
undergoes a quasistatic process, which is O P
depicted by a straight line joining points a +Q R +Q
D
(V0 , T0) and (2 V0 , 3T0) in a V-T diagram. What
is the value of the heat capacity of the gas at
a C
the point (V0 , T0)?
3 Q 5Q
(a) R (b) R (a) (b)
2 ε0 6ε0
(c) 2R (d) 0 10Q
(c) (d) zero
6 ε0

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25. Four equal charges of value + Q are placed at B at its centre. If instead, a circular loop of
any four vertices of a regular hexagon of side radius 2r , made of same material, having the
‘a’. By suitably choosing the vertices, what same cross-section is connected to the same
can be the maximum possible magnitude of voltage source, what will be the magnetic
electric field at the centre of the hexagon? field at its centre?
Q 2Q B B
(a) (b) (a) (b) (c) 2B (d) B
2 4
4 πε0 a2 4 πε0 a2
3Q 2Q 29. An alternating current is flowing through a
(c) (d)
4 πε0 a2 4 πε0 a2 series L-C-R circuit. It is found that the
current reaches a value of 1 mA at both
26. A proton of mass m moving with a speed v 200 Hz and 800 Hz frequency. What is the
(<< c, velocity of light in vacuum) completes resonance frequency of the circuit?
a circular orbit in time T in a uniform (a) 600 Hz (b) 300 Hz
magnetic field. If the speed of the proton is (c) 500 Hz (d) 400 Hz
increased to 2 v, what will be time needed to
30. An electric bulb, a capacitor, a battery and a
complete the circular orbit?
switch are all in series in a circuit. How does
(a) 2 T (b) T the intensity of light vary when the switch is
T T
(c) (d) turn on?
2 2
(a) Continues to increase gradually
27. A uniform current is flowing along the length (b) Gradually increases for sometime and then
of an infinite, straight, thin, hollow cylinder becomes steady
of radius R. The magnetic field B produced at (c) Sharply rises initially and then gradually
a perpendicular distance d from the axis of decreases
the cylinder is plotted in a graph. Which of (d) Gradually increases for sometime and then
gradually decreases
the following figures looks like the plot?
B Category-II (Q. Nos. 31 to 35)
(a) Only one answer is correct. Correct answer will
d
fetch full marks 2. Incorrect answer or any
B
R combination of more than one answer will fetch
1
− marks. No answer will fetch 0 marks.
(b) 2
d 31. A light charged particle is revolving in a
R
B circle of radius r in electrostatic attraction of
a static heavy particle with opposite charge.
(c) How does the magnetic field B at the centre
of the circle due to the moving charge
d depend on r ?
R
1 1
B (a) B ∝ (b) B ∝
r r2
1 1
(d) (c) B ∝ (d) B ∝
r3/ 2 r5/ 2
d 32. As shown in the figure, a rectangular loop of
R
a conducting wire is moving away with a
28. A circular loop of radius r of conducting wire constant velocity v in a perpendicular
connected with a voltage source of zero direction from a very long straight conductor
internal resistance produces a magnetic field carrying a steady current I. When the

Page 4 of 44
 breadth of the rectangular loop is very small conductor with uniform surface charge
compared to its distance from the straight density σ is placed below it. What will be the
conductor, how does the emf. E induced in time period of the pendulum for small
the loop vary with time t ? amplitude oscillations?
v
L

I
m
1 1 1
(a) E ∝ (b) E ∝ (c) E ∝−ln(t ) (d) E ∝ σ
t2 t t3
L L
33. A solid spherical ball and a hollow spherical (a) 2 π (b)
 mq   mqσ 
ball of two different materials of densities ρ1 g −  g − 
 ε0 σ   ε0 
and ρ2 respectively have same outer radii and
same mass. What will be the ratio, the 1 L L
(c) (d) 2 π
moment of inertia (about an axis passing 2π  qσ   qσ 
g −  g − 
through the centre) of the hollow sphere to  ε0 m   ε0 m 
that of the solid sphere?
5  5
Category-III (Q. Nos. 36 to 40)
ρ2  ρ 3 ρ2   ρ2  3 
(a) 1 − 2  (b) 1 − 1 − 
ρ1  ρ1  ρ1   ρ1   One or more answer(s) is (are) correct. Correct
 
answer(s) will fetch full marks 2. Any combination
5  5
containing one or more incorrect answer will fetch
ρ2  ρ 3 ρ  ρ1  3 
(c) 1 − 1  (d) 2 1 −  1 −  0 marks. Also, no answer will fetch 0 marks. If all
ρ1  ρ2  ρ1   ρ2  
  correct answers are not marked and also no
incorrect answer is marked then score
34. The insulated plates of a charged parallel = 2 × number of correct answers marked ÷ actual
plate capacitor (with small separation number of correct answers.
between the plates) are approaching each
other due to electrostatic attraction. 36. A non-zero current passes through the
Assuming no other force to be operative and galvanometer G shown in the circuit when
no radiation taking place, which of the the key K is closed and its value does not
following graphs approximately shows the change when the key is opened. Then, which
variation with time ()
t of the potential of the following statement(s) is/are true?
difference (V) between the plates?
Ω

30
0

V V
0
20

(a) (b) K
t t
O O G
10
0
Ω

V V
(c) (d) 10 V

t t (a) The galvanometer resistance is infinite.

O O
(b) The current through the galvanometer is 40 mA.
35. The bob of a pendulum of mass m, (c) After the key is closed, the current through the
suspended by an inextensible string of length 200 Ω resistor is same as the current through
the 300 Ω resistor.
L as shown in the figure carries a small
(d) The galvanometer resistance is 150 Ω.
charge q. An infinite horizontal plane

Page 5 of 44
37. A ray of light is incident R 39. Which of the following statements(s) is/are
on a right angled true?
isosceles prism parallel Q “Internal energy of an ideal gas ……… .”
to its base as shown in S (a) decreases in an isothermal process.
the figure. Refractive (b) remains constant in an isothermal process.
index of the material of (c) increases in an isobaric process.
P
the prism is 2. Then, (d) decreases in an isobaric expansion.
which of the following statement(s) is/are true?
40. Two positive charges Q and 4Q are placed at
(a) The reflection at P is total internal.
points A and B respectively, where B is at a
(b) The reflection at Q is total internal.
distance d units to the right of A. The total
(c) The ray emerging at R is parallel to the ray
incident at S. electric potential due to these charges is
(d) Total deviation of the ray is 150°. minimum at P on the line through A and B.
What is (are) the distance (s) of P from A?
38. The intensity of a sound appears to an (a)
d
units to the right of A
observer to be periodic. Which of the 3
following can be the cause of it? d
(b) units to the left of A
(a) The intensity of the source is periodic 3
d
(b) The source is moving towards the observer (c) units to the right of A
(c) The observer is moving away from the source 5
(d) The source is producing a sound composed of (d) d units to the left of A
two nearby frequencies

Chemistry
Category-I (Q. Nos. 41 to 70) 44. The ease of hydrolysis in the compounds
Only one answer is correct. Correct will fetch full CH 3COCl(I),CH 3  CO  O  COCH 3 (II),
marks 1. Incorrect answer or any combination of CH 3COOC2H 5 (III) and CH 3CONH 2 (IV) is of
more than one answer will detch − 1/4 marks. No the order
answer will fetch 0 marks. (a) I > II > III > IV
(b) IV > III > II > I
41. Cl 2O 7 is the anhydride of (c) I > II > IV > III
(a) HOCl (b) HClO 2 (d) II > I > IV > III
(c) HClO 3 (d) HClO 4
45. CH 3  C ≡≡ C MgBr can be prepared by the
42. The main reason that SiCl 4 is easily reaction of
hydrolysed as compared to CCl 4 is that (a) CH3  C ≡≡ C Br with MgBr2
(a) Si  Cl bond is weaker than C  Cl bond (b) CH3  C ≡≡ CH with MgBr2
(b) SiCl 4 can form hydrogen bonds (c) CH3  C ≡≡ CH with KBr and Mg metal
(c) SiCl 4 is covalent
(d) CH3  C ≡≡ CH with CH3MgBr
(d) Si can extend its coordination number beyond
four 46. The number of alkene (s) which can produce
43. Silver chloride dissolves in excess of 2-butanol by the successive treatment of
ammonium hydroxide solution. The cation (i) B 2H 6 in tetrahydrofuran solvent and
present in the resulting solution is (ii) alkaline H 2O 2 solution is
(a) 1 (b) 2
(a) [Ag(NH3 )6 ]+ (b) [Ag(NH3 )4 ]+
(c) 3 (d) 4
(c) Ag + (d) [Ag(NH3 )2 ]+

Page 6 of 44
47. Identify ‘M’ in the following sequence of 51. If aniline is treated with conc. H 2SO 4 and
reactions heated at 200°C, the product is
CH3
(a) anilinium sulphate
Cl (b) benzenesulphonic acid
NH3 Br2
C8H6Cl2O C8H8ClNO (c) m-aminobenzenesulphonic acid
NaOH
M H2N (d) sulphanilic acid
O O 52. Which of the following electronic
configuration is not possible?
Cl C C
Cl Cl (a) n = 3, l = 0, m = 0
(a) (b)
(b) n = 3, l = 1, m = − 1
CH3 Cl (c) n = 2, l = 0, m = − 1
CH3 (d) n = 2, l = 1, m = 0
CHO Cl
53. The number of unpaired electrons in Ni
(c) (d) Cl
(atomic number = 28) are
Cl C
(a) 0 (b) 2 (c) 4 (d) 8
CH2Cl CH3
O
54. Which of the following has the strongest
48. Methoxybenzene on treatment with HI H-bond?
produces (a) O  H ... S (b) S  H ... O
(a) iodobenzene and methanol (c) F  H ... F (d) F  H ... O
(b) phenol and methyl iodide
55. The half-life of C14 is 5760 years. For a
(c) iodobenzene and methyl iodide
(d) phenol and methanol
200 mg sample of C14 , the time taken to
change to 25 mg is
K 2 Cr2 O7 I /NaOH
49. C 4 H10O → C 4 H 8O →
2
CHI3 (a) 11520 years (b) 23040 years
H 2 SO 4 Warm
N (c) 5760 years (d) 17280 years
Here, N is
56. Ferric ion forms a prussian blue precipitate
OH
(a) OH (b) due to the formation of
(a) K 4 [Fe(CN)6 ] (b) K 3 [Fe(CN)6 ]
(c) Fe(CNS)3 (d) Fe 4 [Fe(CN)6 ]3
(c) O (d)
OH
64
57. The nucleus 29 Cu accepts an orbital electron
50. The correct order of reactivity for the addition to yield,
reaction of the following carbonyl (a) 65
28 Ni (b) 64
30 Zn (c) 64
28 Ni (d) 65
30 Zn
compounds with ethylmagnesium iodide is
58. How many moles of electrons will weigh one
H H3C
kilogram?
C=
=O C=
=O 1
H H3C (a) 6.023 × 1023 (b) × 1031
(I) (II) 9108
.
6.023 1
(c) × 1054 (d) × 108
H (CH3)3C .
9108 9108
. × 6.023
C=
=O C=
=O
H3C (CH3)3C 59. Equal weights of ethane and hydrogen are
(III) (IV) mixed in an empty container at 25°C. The
(a) I > III > II > IV fraction of total pressure exerted by hydrogen
(b) IV > III > II > I is
(c) I > II > IV > III (a) 1 : 2 (b) 1 : 1
(d) III > II > I > IV (c) 1 : 16 (d) 15 : 16

Page 7 of 44
60. The heat of neutralisation of a strong base 66. Which of the following is present in
and a strong acid is 13.7 kcal. The heat maximum amount in ‘acid rain’?
released when 0.6 mole HCl solution is added (a) HNO 3 (b) H2SO 4
to 0.25 mole of NaOH is (c) HCl (d) H2CO 3
(a) 3.425 kcal (b) 8.22 kcal
67. Which of the set of oxides are arranged in the
(c) 11.645 kcal (d) 13.7 kcal
proper order of basic, amphoteric, acidic?
61. A compound formed by elements X and Y (a) SO 2 ,P2O 5 ,CO (b) BaO,Al 2O 3 ,SO 2
crystallises in the cubic structure, where X (c) CaO,SiO 2 ,Al 2O 3 (d) CO 2 ,Al 2O 3 ,CO
atoms are at the corners of a cube and Y
atoms are at the centre of the body. The
68. Out of the following outer electronic
configurations of atoms, the highest
formula of the compounds is
oxidation state is achieved by which one?
(a) XY (b) XY2
(c) X 2 Y3 (d) XY3 (a) (n − 1)d 8 ns 2 (b) (n − 1)d 5 ns 2
(c) (n − 1)d ns3 2
(d) (n − 1)d 5 ns1
62. What amount of electricity can deposit
1 mole of Al metal at cathode when passed 69. At room temperature, the reaction between
through molten AlCl 3 ? water and fluorine produces
(a) 0.3 F (b) 1 F (a) HF and H2O 2 (b) HF, O 2 and F2O 2
(c) 3 F (d) 1/3 F (c) F − , O 2 and H+ (d) HOF and HF

63. Given the standard half-cell potentials (E°) of 70. Which of the following is least thermally
the following as stable?
Zn → Zn 2+ + 2 e − ; E° = + 0 .76 V (a) MgCO 3 (b) CaCO 3
(c) SrCO 3 (d) BeCO 3
Fe → Fe2+ + 2 e − ; E° = 0 .41 V
Then the standard e.m.f. of the cell with the Category-II (Q. Nos. 71 to 75)
reaction Fe2+ + Zn → Zn 2+ + Fe is Only one answer is correct. Correct answer will
(a) − 0.35 V (b) + 0.35 V fetch full marks 2. Incorrect answer or any
(c) + 117
. V (d) − 117
. V combination of more than one answer will fetch −
64. The following equilibrium constants are 1/2 marks. No answer will fetch 0 marks.
given Br 2 NaNH 2
N 2 + 3H 2 c
2NH 3 ; K 1 71. [ P] → C2H 4Br2 →
NH
[ Q]
3
N2 + O 2
1
c
2NO;K 2 20% H 2 SO 4
[ Q] → [ R] → [ S]
Zn -Hg/HCl

H2 + O 2
2
c
H 2O; K 3 Hg 2+ , ∆

The species P, Q, R and S respectively are

The equilibrium constant for the oxidation of
(a) ethene, ethyne, ethanal, ethane
2 mole of NH 3 to give NO is (b) ethane, ethyne, ethanal, ethene
K2 K 33
(a) K1 . (b) K 2 . (c) ethene, ethyne, ethanal, ethanol
K3 K1 (d) ethyne, ethane, ethene, ethanal
K 32 K3
(c) K 2 . (d) K 22 72. The number of possible organobromine
K1 K1
compounds which can be obtained in the
allylic bromination of 1-butene with
65. Which one of the following is a condensation
N-bromosuccinimide is
polymer?
(a) 1 (b) 2
(a) PVC (b) Teflon
(c) 3 (d) 4
(c) Dacron (d) Polystyrene

Page 8 of 44
 O
73. A metal M (specific heat 0.16) forms a metal
OH
chloride with 65% chlorine present in it. The
(a) (b)
formula of the metal chloride will be
(a) MCl (b) MCl 2 CH2OH
(c) (d) H2C CH2
(c) MCl 3 (d) MCl 4

74. During a reversible adiabatic process, the

77. The major products obtained in the following
pressure of a gas is found to be proportional
reaction is/are
to the cube of its absolute temperature. The
Cp H3C H
ratio for the gas is C=
=C + Br2
CV
H C2H5
3 7
(a) (b) CH3 CH3
2 2
H Br H Br
5 9 (a) (b)
(c) (d)
3 7 H Br Br H
C2H5 C2H5
75. [ X ] + dil. H 2SO 4 → [ Y ] :
Colourless, suffocating gas CH3 CH3
[ Y ] + K 2Cr2O 7 + H 2SO 4 → Br H Br H
(c) (d)
Green colouration of solution H Br Br H
Then,[ X ] and[ Y ] are
C2H5 C2H5
(a) SO23 − , SO2
(b) Cl − , HCl 78. Which statements are correct for the
(c) S2 − , H 2 S peroxide ion?
(d) CO23 − , CO2 (a) It has five completely filled anti-bonding
molecular orbitals
Category-III (Q. Nos. 76 to 80) (b) It is diamagnetic
(c) It has bond order one
One or more answer(s) is (are) correct. Correct (d) It is isoelectronic with neon
answer(s) will fetch full marks 2. Any combination
containing one or more incorrect answer will fetch 79. Among the following, the extensive variables
are
0 marks. Also no answer will fetch 0 marks. If all
(a) H (Enthalpy) (b) p (Pressure)
correct answers are not marked and also no
(c) E (Internal energy) (d) V (Volume)
incorrect answer is marked then score
= 2 × number of correct answers marked ÷ actual 80. White phosphorous P4 has the following
number of correct answers. characteristics
(a) 6P  P single bonds
76. The possible product(s) to be obtained from (b) 4P  P single bonds
the reaction of cyclobutyl amine with HNO 2 (c) 4 lone pair of electrons
is/are (d) P  P  P angle of 60°

Page 9 of 44
 Mathematics
Category-I (Q. Nos. 1 to 50) 6. Let f :[ a , b] → R be such that f is
Only one answer is correct. Correct answer will differentiable in (a , b), f is continuous at x = a
fetch full marks 1. Incorrect answer or any and x = b and moreover f (a) = 0 = f (b). Then
combination of more than one answer will (a) there exists at least one point c in (a, b ) such that
fetch-1/4 marks. No answer will fetch 0 marks. f ′(c ) = f(c )
(b) f ′( x) = f( x) does not hold at any point in (a, b )
1. The approximate value of sin31° is (c) at every point of (a, b ), f ′( x) > f( x)
(a) > 0.5 (b) > 0.6 (d) at every point of (a, b ), f ′( x) < f( x)
(c) < 0.5 (d) < 0.4
7. Let f : R → R be a twice continuously
2. Let f1(x) = e x , f 2(x) = e f1 (x ), ……, differentiable function such that
f n + 1 (x) = e f n (x ) for all n ≥ 1. Then for any fixed f (0) = f ()
1 = f ′ (0) = 0 . Then
d (a) f ′ ′(0) = 0
n, f n(x) is (b) f ′ ′(c ) = 0 for some c ∈ R
dx
(c) if c ≠ 0, then f ′ ′(c ) ≠ 0
(a) fn ( x)
(d) f ′( x) > 0 for all x ≠ 0
(b) fn ( x)fn − 1( x)
 x cos 3 x − sin x 
(c) fn ( x)fn − 1( x)…f1( x) 8. If ∫ esin x ⋅  2  dx = e
sin x
f (x) + c,
(d) fn ( x)… f1( x)e x  cos x 
1 − | x| where c is constant of integration, then f (x) is
3. The domain of definition of f (x) = is equal to
2 − | x|
(a) sec x − x (b) x − sec x
(a) (−∞, − 1) ∪ (2, ∞ ) (c) tan x − x (d) x − tan x
(b) [−1, 1] ∪ (2, ∞ ) ∪ (−∞, − 2 )
1
(c) (−∞, 1) ∪ (2, ∞ ) 9. If ∫ f (x) sin x cos x dx = log f (x) + c,
2(b − a 2) 2
(d) [−1, 1] ∪ (2, ∞ )
where c is the constant of integration, then
Here (a , b) ≡ { x : a < x < b} and
f (x) is equal to
[ a , b] ≡ { x : a ≤ x ≤ b} 2 2
(a) (b)
4. Let f :[ a , b] → R be differentiable on [ a , b] (b 2 − a2 )sin2 x ab sin2 x
2 2
and k ∈ R. Let f (a) = 0 = f (b). (c) (d)
(b 2 − a2 )cos 2 x ab cos 2 x
Also let J (x) = f ′ (x) + kf (x). Then
(a) J( x) > 0 for all x ∈[a, b ] π /2 π /4
cos x sin x cos x
(b) J( x) < 0 for all x ∈[a, b ]
10. If M = ∫ x +2
dx , N = ∫ (x + 1)2
dx , then
0 0
(c) J( x) = 0 has at least one root in (a, b )
the value of M − N is
(d) J( x) = 0 through (a, b ) π 2 2
(a) π (b) (c) (d)
5. Let f (x) = 3 x 10
− 7 x + 5 x − 21 x + 3 x − 7 .
8 6 3 2 4 π−4 π+ 4
f (1 − h) − f ()
1
tan −1 x
2014
Then lim
h→ 0 h + 3h
3 11. The value of the integral I = ∫ x
dx is
1 / 2014
50
(a) does not exist (b) is π π
3 (a) log 2014 (b) log 2014
53 22 4 2
(c) is (d) is 1
3 3 (c) πlog 2014 (d) log 2014
2

Page 10 of 44
 π /3
sin x 19. Given that n numbers of arithmetic means
12. Let I = ∫ x
dx . Then
are inserted between two sets of numbers
π /4
a , 2 b and 2a , b where a , b ∈ R. Suppose further
1
(a) ≤ I≤1 (b) 4 ≤ I ≤ 2 30 that the mth means between these sets of
2
numbers are same, then the ratio a : b equals
3 2 2 3
(c) ≤ I≤ (d) 1 ≤ I ≤ (a) n − m + 1: m (b) n − m + 1: n
8 6 2
(c) n : n − m + 1 (d) m : n − m + 1
13. The value of 20. If x + log 10(1 + 2x ) = x log 10 5 + log 10 6 , then
5π / 2 tan −1 (sin x )
e
I= ∫ tan −1 (sin x ) tan −1 (cos x )
dx , is the value of x is
π /2 e +e (a)
1
(b)
1
π 2 3
(a) 1 (b) π (c) e (d) (c) 1 (d) 2
2
2 πr 2 πr 10
14. The value of 21. If Z r = sin − i cos , then ∑ Z r is equal
1 2 π 2π nπ  11 11 r=0
lim sec + sec 2 + ... + sec 2  is
n→ ∞ n 4n 4n 4 n to
π 4 (a) −1 (b) 0 (c) i (d) −i
(a) loge 2 (b) (c) (d) e
2 π
22. If z1 and z 2 be two non-zero complex
15. The differential equation representing the z1 z 2
numbers such that + = 1, then the
family of curves y 2 = 2 d(x + d), where d is a z 2 z1
parameter, is of origin and the points represented by z1 and z 2
(a) order 2 (b) degree 2 (a) lie on a straight line
(c) degree 3 (d) degree 4 (b) form a right angled triangle
(c) form an equilateral triangle
16. Let y(x) be a solution of (d) form an isosceles triangle
dy
(1 + x 2) + 2 xy − 4 x 2 = 0 and y(0) = − 1. Then 23. If b1b2 = 2(c1 + c2) and b1 , b2 , c1 , c2 are all real
dx
1 is equal to
y() numbers, then at least one of the equations
1 1 x 2 + b1 x + c1 = 0 and x 2 + b2 x + c2 = 0 has
(a) (b)
2 3 (a) real roots
1
(c) (d) −1 (b) purely imaginary roots
6 (c) roots of the form a + ib (a, b ∈ R, ab ≠ 0)
(d) rational roots
17. The law of motion of a body moving along a
1 24. The number of selection of n objects from 2n
straight line is x = vt. x being its distance
2 objects of which n are identical and the rest
from a fixed point on the line at time t and v are different, is
is its velocity there. Then (a) 2 n (b) 2 n − 1
(a) acceleration f varies directly with x (c) 2 n − 1 (d) 2 n − 1 + 1
(b) acceleration f varies inversely with x
(c) acceleration f is constant 25. If (2 ≤ r ≤ n), then nC r + 2 ⋅ nC r + 1 + nC r + 2 is
(d) acceleration f varies directly with t equal to
n+1
(a) 2 ⋅n C r + 2 (b) Cr +1
18. Number of common tangents of y = x 2 and n+ 2 n+1
(c) Cr + 2 (d) Cr
y = − x 2 + 4 x − 4 is
(a) 1 (b) 2 26. The number (101)100 − 1 is divisible by
(c) 3 (d) 4 (a) 104 (b) 106
(c) 108 (d) 1012

Page 11 of 44
27. If n is even positive integer, then the 33. On the set R of real numbers, the relation ρ is
condition that the greatest term in the defined by xρy , (x , y) ∈ R.
expansion of (1 + x)n may also have the
(a) If| x − y| < 2, then ρ is reflexive but neither
greatest coefficient, is symmetric nor transitive.
n n+2 n n+1 (b) If x − y < 2, then ρ is reflexive and symmetric but
(a) < x< (b) < x<
n+2 n n+1 n not transitive.
n+1 n+2 n+2 n+ 3 (c) If| x| ≥ y, then ρ is reflexive and transitive but not
(c) < x< (d) < x<
n+2 n+1 n+ 3 n+2 symmetric.
(d) If x >| y|, then ρ is transitive but neither reflexive
−1 7 0  13 −11 5  nor symmetric.
28. If 2 1 −3 = A, Then −7 −1 25  is

    34. If f : R → R be defined by f (x) = e x and
3 4 1 −21 −3 −15
g : R → R be defined by g(x) = x 2 . The
(a) A 2 (b) A 2 − A + I3
mapping gof : R → R be defined by (gof ) (x)
(c) A 2 − 3 A + I3 (d) 3 A 2 + 5 A − 4I3
= g[ f (x)] ∀ x ∈ R. Then,
(I 3 denotes the det of the identity matrix of (a) gof is bijective but f is not injective
order 3) (b) gof is injective and g is injective
(c) gof is injective but g is not bijective
29. If a r = (cos 2rπ + i sin 2rπ)1/ 9, then the value of
(d) gof is surjective and g is surjective
a1 a2 a 3
a 4 a5 a 6 is equal to 35. In order to get a head at least once with
 
probability ≥ 0 .9 , the minimum number of
a 7 a8 a 9
times a unbiased coin needs to be tossed is
(a) 1 (b) −1 (a) 3 (b) 4 (c) 5 (d) 6
(c) 0 (d) 2
 2r x n(n + 1)  36. A student appears for tests I, II and III. The
student is successful if he passes in tests I, II
30. If Sr = 6 r 2 − 1 y n (2 n + 3), then the
2
 3  or I, III. The probabilities of the student
4 r − 2 nr z n3 (n + 1)  passing in tests I, II and III are respectively
n
p , q and 1/2. If the probability of the student
value of ∑ Sr is independent of to be successful is 1/2. Then
r =1
(a) p(1 + q ) = 1 (b) q (1 + p) = 1
(a) only x (b) only y 1 1
(c) only n (d) x, y, z and n (c) pq = 1 (d) + =1
p q
31. If the following three linear equations have a 37. If sin 6θ + sin 4θ + sin 2θ = 0, then general
non-trivial solution, then
value of θ is
x + 4 ay + az = 0 nπ π nπ π
x + 3 by + bz = 0 (a) , nπ ± (b) , nπ ±
4 3 4 6
x + 2 cy + cz = 0 nπ π nπ π
(c) , 2 nπ ± (d) , 2 nπ ±
(a) a, b, c are in AP (b) a, b, c are in GP 4 3 4 6
(c) a, b, c are in HP (d) a + b + c = 0 (n is an integer)

32. On R, a relation ρ is defined by xρy if and only π

38. If 0 ≤ A ≤ , then
if x − y is zero or irrational. Then, 4
1 
(a) ρ is equivalence relation tan −1  tan 2 A + tan −1 (cot A) + tan −1 (cot 3 A)
2 
(b) ρ is reflexive but neither symmetric nor transitive
(c) ρ is reflexive and symmetric but not transitive is equal to
π π
(d) ρ is symmetric and transitive but not reflexive (a) (b) π (c) 0 (d)
4 2

Page 12 of 44
39. Without changing the direction of the axes, 45. Let the eccentricity of the hyperbola
the origin is transferred to the point (2, 3). x2 y2
− = 1 be reciprocal to that of the ellipse
Then the equation x 2 + y 2 − 4 x − 6 y + 9 = 0 a2
b2
changes to x 2 + 9 y 2 = 9 , then the ratio a 2 : b2 equals
(a) x2 + y2 + 4 = 0
(a) 8 : 1 (b) 1 : 8
(b) x2 + y2 = 4 (c) 9 : 1 (d) 1 : 9
(c) x2 + y2 − 8 x − 12 y + 48 = 0
46. Let A , B be two distinct points on the
(d) x2 + y2 = 9
parabola y 2 = 4 x . If the axis of the parabola
40. The angle between a pair of tangents drawn touches a circle of radius r having AB as
from a point P to the circle diameter, the slope of the line AB is
x 2 + y 2 + 4 x − 6 y + 9 sin 2 α + (a) −
1
(b)
1
(c)
2
(d) −
2
r r r r
13 cos 2 α = 0 is 2α. The equation of the locus of
the point P is 47. Let P (at2 , 2at), Q, R(ar 2 , 2ar) be three points on
(a) x2 + y2 + 4 x + 6 y + 9 = 0 a parabola y 2 = 4 ax . If PQ is the focal chord
(b) x2 + y2 − 4 x + 6 y + 9 = 0 and PK, QR are parallel where the co-ordinates
(c) x2 + y2 − 4 x − 6 y + 9 = 0 of K is (2 a , 0), then the value of r is
(d) x2 + y2 + 4 x − 6 y + 9 = 0 t 1− t2 t2 + 1 t2 − 1
(a) (b) (c) (d)
1− t 2
t t t
41. The point Q is the image of the point P(1, 5)
about the line y = x and R is the image of the x 2 y2
48. Let P be a point on the ellipse + = 1 and
point Q about the line y = − x . The 9 4
circumcentre of the ∆PQR is the line through P parallel to the Y-axis
(a) (5, 1) (b) (−5, 1) meets the circle x 2 + y 2 = 9 at Q, where P , Q
(c) (1, − 5) (d) (0, 0)
are on the same side of the X -axis. If R is a
42. The angular points of a triangle are A(−1, − 7), PR 1
point on PQ such that = , then the locus
B(5 , 1) and C(1, 4). The equation of the bisector RQ 2
of the angle ∠ABC is of R is
(a) x = 7 y + 2 (b) 7 y = x + 2 x2 9 y2 x2 y2
(a) + =1 (b) + =1
(c) y = 7 x + 2 (d) 7 x = y + 2 9 49 49 9
43. If one of the diameter of the circle, given by x2 y2 9 x2 y2
(c) + =1 (d) + =1
the equation x 2 + y 2 + 4 x + 6 y − 12 = 0 , is a 9 49 49 9
chord of a circle S, whose centre is (2 , − 3), the 49. A point P lies on a line through Q(1, − 2, 3) and
radius of S is x y z
(a) 41 unit (b) 3 5 unit is parallel to the line = = . If P lies on
1 4 5
(c) 5 2 unit (d) 2 5 unit the plane 2 x + 3 y − 4 z + 22 = 0 , then segment
44. A chord AB is drawn from the point A(0 , 3) on PQ equals
(a) 42 units (b) 32 units
the circle x 2 + 4 x + (y − 3)2 = 0 , and is
(c) 4 units (d) 5 units
extended to M such that AM = 2 AB. The locus
of M is 50. The foot of the perpendicular drawn from the
(a) x +
2
y − 8x − 6y + 9 = 0
2 point (1, 8, 4) on the line joining the point
(b) x2 + y2 + 8 x + 6 y + 9 = 0 (0, −11, 4) and (2, −3, 1) is
(c) x2 + y2 + 8 x − 6 y + 9 = 0 (a) (4, 5, 2) (b) (−4, 5, 2)
(d) x2 + y2 − 8 x + 6 y + 9 = 0 (c) (4, −5, 2) (d) (4, 5, −2)

Page 13 of 44
 Category-II (Q. No. 51 to 65) 56. From a collection of 20 consecutive natural
Carry 2 marks each if only one option is correct. numbers, four are selected such that they are
In case of incorrect answer or any combination of not consecutive. The number of such
more than one answer, 1/2 mark will be selections is
deducted. (a) 284 × 17 (b) 285 × 17
(c) 284 × 16 (d) 285 × 16
51. A ladder 20 ft long leans against a vertical
57. The least positive integer n such that
wall. The top end slides downwards at the n
rate of 2 ft per second. The rate at which the  π π
 cos sin 
lower end moves on a horizontal floor when  4 4  is an identity matrix of
it is 12 ft from the wall is π π
 − sin cos 
−8 6  4 4
(a) (b)
3 5 order 2 is
3 17 (a) 4 (b) 8
(c) (d)
2 4 (c) 12 (d) 16

52. For 0 ≤ p ≤ 1 and for any positive a , b; let 58. Let ρ be a relation defined on N, the set of
I (p) = (a + b)p , J (p) = a P + bP , then natural numbers, as
(a) I( p) > J( p) ρ = {(x , y) ∈ N × N : 2 x + y = 41}. Then
(b) I( p) ≤ J( p) (a) ρ is an equivalence relation
(b) ρ is only reflexive relation
(c) I( p) < J( p) in  0,  and I( p) > J( p) in  , ∞ 
p p
 2   2  (c) ρ is only symmetric relation
 p   p (d) ρ is not transitive
(d) I( p) < J( p) in , ∞  and J( p) < I( p) in 0,
 2   2 
59. If the polynomial
→
$ →
53. Let α = i$ + j$ + k, β = i$ − j$ − k$ and (1 + x)a (2 + x)b 1 
→ → f (x) =  1 (1 + x) (2 + x)b, then the
a
γ = − i$ + j$ − k$ be three vectors. A vector δ , in  
(2 + x) (1 + x)a
b
→ → → 1
the plane of α and β , whose projection on γ
1 constant term of f (x) is
is , is given by (a) 2 − 3 ⋅ 2 b + 2 3 b (b) 2 + 3 ⋅ 2 b + 2 3 b
3
(c) 2 + 3 ⋅ 2 − 2
b 3b
(d) 2 − 3 ⋅ 2 b − 2 3 b
(a) − $i − 3 $j − 3k$ (b) $i − 3 $j − 3k$
[a and b are positive integers]
(c) − $i + 3 $j + 3k$ (d) $i + 3 $j − 3k$
60. A line cuts the X-axis at A(5, 0) and the Y-axis
→ → →
54. Let α , β , γ be the three unit vectors such that at B(0 , − 3). A variable line PQ is drawn
→ → → → →
perpendicular to AB cutting the X-axis at P
α ⋅ β = α ⋅ γ = 0 and the angle between β and and the Y-axis at Q. If AQ and BP meet at R,
→ → then the locus of R is
γ is 30°. Then α is (a) x2 + y2 − 5 x + 3 y = 0 (b) x2 + y2 + 5 x + 3 y = 0
→ → → →
(a) 2(β × γ ) (b) −2(β × γ ) (c) x2 + y2 + 5 x − 3 y = 0 (d) x2 + y2 − 5 x − 3 y = 0
→ → → →
(c) ±2(β × γ ) (d) (β × γ ) 61. Let A be the centre of the circle
x 2 + y 2 − 2 x − 4 y − 20 = 0 . Let B(1, 7) and
55. Let z1 and z 2 be complex numbers such that
D(4 , − 2) be two points on the circle such that
z1 ≠ z 2 and|z1| = |z 2|. If Re(z1) > 0 and tangents at B and D meet at C. The area of the
z + z2
Im(z 2) < 0 , then 1 is quadrilateral ABCD is
z1 − z 2 (a) 150 sq units (b) 50 sq units
(a) one (b) real and positive (c) 75 sq units (d) 70 sq units
(c) real and negative (d) purely imaginary

Page 14 of 44
  π 67. A particle is in motion along a curve 12 y = x 3.
−2 sin x , if x ≤ −
 2 The rate of change of its ordinate exceeds
 π π that of abscissa in
62. Let f (x) =  Asin x + B, if − < x < . Then,
 2 2 (a) −2 < x < 2 (b) x = ± 2
 cos x , π (c) x < − 2 (d) x > 2
if x ≥
 2 68. The area of the region lying above X-axis, and
(a) f is discontinuous for all A and B included between the circle x 2 + y 2 = 2 ax and
(b) f is continuous for all A = − 1and B = 1 the parabola y 2 = ax ,a > 0 is
(c) f is continuous for all A = 1and B = − 1 π 2
(d) f is continuous for all real values of A, B (a) 8 πa2 (b) a2  − 
 4 3
63. The normal to the curve y = x 2 − x + 1, drawn (c)
16 πa2
(d) π 
27
+ 3a2 
at the points with the abscissa x1 = 0 , x 2 = − 1 9  8 
and x 3 = 5 / 2 69. If the equation x 2 − cx + d = 0 has roots equal
(a) are parallel to each other to the fourth powers of the roots of
(b) are pairwise perpendicular x 2 + ax + b = 0 , where a 2 > 4 b , then the roots
(c) are concurrent
(d) are not concurrent of x 2 − 4 bx + 2 b2 − c = 0 will be
(a) both real
64. The equation x log x = 3 − x (b) both negative
(a) has no root in (1, 3) (c) both positive
(b) has exactly one root in (1, 3) (d) one positive and one negative
(c) xlog x − (3 − x) > 0 in [1, 3]
70. On the occasion of Dipawali festival each
(d) xlog x − (3 − x) < 0 in [1, 3]
student of a class sends greeting cards to
65. Consider the parabola y = 4 x . Let P and Q be
2 others. If there are 20 students in the class,
the number of cards sends by students is
points on the parabola where P(4 , − 4) and
(a) 20
C2 (b) 20
P2 (c) 2 × C 2 (d) 2 ×
20 20
P2
Q(9 , 6). Let R be a point on the arc of the
parabola between P and Q. Then, the area of 71. In a third order matrix A, a ij denotes the
∆PQR is largest when element in the ith row and jth column.
(a) ∠PQR = 90° (b) R(4, 4) If a ij = 0 for i = j
(c) R  , 1 (d) R  1,  = 1 for i > j
1 1
4   4 = −1 for i < j
Then the matrix is
Category-III (Q. Nos. 66 to 75)
(a) skew symmetric (b) symmetric
Carry 2 marks each and one or more option(s) is/are (c) not invertible (d) non-singular
correct. If all correct answers are not marked and
also no incorrect answer is marked then score = 2 × 72. The area of the triangle formed by the
number of correct answers marked, ÷ actual number intersection of a line parallel to X-axis and
of correct answer. If any wrong option is marked or passing through P(h, k), with the lines y = x
if, any combination including a wrong option is and x + y = 2 is h2 . The locus of the point P is
marked, the answer will considered wrong, but (a) x = y − 1 (b) x = − ( y − 1)
there is no negative marking for the same and zero (c) x = 1 + y (d) x = − (1 + y)
marks will be awarded.
73. A hyperbola, having the transverse axis of
1
x 3 cos 3 x length 2sinθ is confocal with the ellipse
66. Let I = ∫ 2+ x 2
dx . Then 3 x 2 + 4 y 2 = 12. Its equation is
0
1 1 1 1 (a) x2 sin2 θ − y2 cos 2 θ = 1
(a) − < I < (b) − < I < (b) x2cosec 2θ − y2 sec 2 θ = 1
2 2 3 3
(c) −1 < I < 1
3
(d) − < I <
3 (c) ( x2 + y2 )sin2 θ = 1 + y2
2 2 (d) x2cosec 2θ = x2 + y2 + sin2 θ

Page 15 of 44
  π
74. Let f (x) = cos   , x ≠ 0 , then assuming k as 75. Consider the function y = log a (x + x 2 + 1),
 x
an integer, a > 0, a ≠ 1. The inverse of the function
 1 1 (a) does not exist
(a) f( x) increases in the interval  , 
 2k + 1 2k  (b) is x = log1/ a ( y + y2 + 1)
 1 1
(b) f( x) decreases in the interval  ,  (c) is x = sinh ( y log a)
 2k + 1 2k 
(d) is x = cos h  − y log 
1
 1 1  
(c) f( x) decreases in the interval  ,  a
 2 k + 2 2 k + 1
 1 1 
(d) f( x) increases in the interval  , 
 2 k + 2 2 k + 1

Answers
Physics
1. (d) 2. (c) 3. (a) 4. (b) 5. (d) 6. (c) 7. (a) 8. (d) 9. (d) 10. (c)
11. (a) 12. (c) 13. (b) 14. (a) 15. (c) 16. (c) 17. (c) 18. (d) 19. (b) 20. (c)
21. (c) 22. (b) 23. (b) 24. (a) 25. (c) 26. (b) 27. (c) 28. (b) 29. (d) 30. (c)
31. (d) 32. (a) 33. (d) 34. (a) 35. (d) 36. (b,c,d) 37. (a,c) 38. (a,d) 39. (b) 40. (a)

Chemistry
41. (d) 42. (d) 43. (d) 44. (a) 45. (d) 46. (b) 47. (b) 48. (b) 49. (b) 50. (a)
51. (d) 52. (c) 53. (b) 54. (c) 55. (d) 56. (d) 57. (c) 58. (d) 59. (d) 60. (a)
61. (a) 62. (c) 63. (b) 64. (b) 65. (c) 66. (b) 67. (b) 68. (b) 69. (c) 70. (d)
71. (a) 72. (a) 73. (b) 74. (a) 75. (a) 76. (a,c) 77. (a, d) 78. (b,c) 79. (a,c,d) 80. (a,c,d)

Mathematics
1. (a) 2. (c) 3. (b) 4. (c) 5. (c) 6. (a) 7. (b) 8. (b) 9. (c) 10. (d)
11. (b) 12. (c) 13. (b) 14. (c) 15. (c) 16. (c) 17. (c) 18. (b) 19. (d) 20. (c)
21. (b) 22. (c) 23. (a) 24. (a) 25. (c) 26. (a) 27. (a) 28. (a) 29. (c) 30. (d)
31. (c) 32. (c) 33. (d) 34. (c) 35. (b) 36. (a) 37. (a) 38. (c) 39. (b) 40. (d)
41. (d) 42. (b) 43. (a) 44. (c) 45. (a) 46. (c,d) 47. (d) 48. (a) 49. (a) 50. (d)
51. (a) 52. (b) 53. (c) 54. (c) 55. (d) 56. (a) 57. (b) 58. (d) 59. (a) 60. (a)
61. (c) 62. (b) 63. (c) 64. (b) 65. (c) 66. (b) 67. (c,d) 68. (b) 69. (a,d) 70. (b,c)
71. (a,c) 72. (a,b) 73. (b) 74. (a,c) 75. (c)

Page 16 of 44
 Answer with Explanations
Physics
1. (d) For maximum equivalent resistance across the 3. (a) Ray diagram for the question,
diagonal of the square, the given resistors
Y
connected as
P(3,3)
Q
Ω

20

S(0,1)
0

0
30

P X′ X
O M Plane mirror
R
Ω
40

I(0,–1)
0
0

10
Ω

Y′
S
I is image of source S by the plane mirror placed
Resistance of PQR arm, R1 = 300 + 200 = 500 Ω perpendicularly along X-axis.
Resistance of PSR arm, R2 = 400 + 100 Ω = 500 Ω
Q SM = IM
The equivalent resistance between P and R.
1 1 1 ∴PM + MS = PM + MI = PI
= +
Req R1 R2
∴ PI = (3 − 0)2 + (3 + 1)2
1 1 1+1
= + = = 9 + 16 = 25 = 5
500 500 500
500 4. (b) The given combination of lenses
∴ Req = = 250 Ω
2 L2
2. (c) 100 Ω 1µF 400 Ω
f1

200 Ω 300 Ω 2 µF f1

L1 L3
6V K
f2

In steady state, arm having capacitors does not flow Here, f1 = focal length of equiconvex lenses of glass.
current. So, we can neglect them. f2 = focal length of lens formed by water (concave).
∴The given circuit reduces to The focal length of the combination.
1 1 1 1 1 1 1 2 1
200 Ω 400 Ω ∴ = + + = − + = −
F f1 f2 f3 f1 f2 f1 f1 f2
1 2 f2 − f1 f1 f2
= ⇒F= [Q f3 = f1 ]
6V F f1 f2 2 f2 − f1
f1
F= ...(i)
f
∴ Rnet = 200 + 400 = 600 Ω 2− 1
f2
∴Current in circuit,
1 2
I= =
V 6
= 0.01 A Here, = (µ g − 1) , for L1 and L3
R 600 f1 R

= (µ w − 1)  −  , for L2
= 10mA 1 2
and
f2  R

Page 17 of 44
 Given, µ w < µ g Number of nuclei that will decay on the 3rd day,
f
Thus, 1 <1 N 3 = N 2 − N1 = 0.63 N 0 − 0.5N 0 = 013
. N0
f2 In the term, fraction is 0.13.
f1
So, F> ...(ii) 9. (d) QKinetic energy of a electron due to
2 accelerated by a potential V, KE = eV
From Eqs. (i) and (ii), we get 1
f1 f me v2 = eV
< F < f1 or < F< f (Q f1 = f) 2
2 2 1 × p2
⇒ = eV [Qp = mv]
5. (d) 2me
∴ p = 2eVme
Small air Solid glass
r

bubble O Q de-Broglie wavelength of a particle having

momentum p,
h
λ=
As the object is at centre of the sphere. p
∴All rays will fall normally on surface, hence they According to question,
do not deflect. Thus, a virtual image is formed at the λ1 p2 2 eV2me V2
= = =
centre O. λ 2 p1 2 eV1 me V1
∴ Apparent depth = Real depth Q λ 2 = 2λ1 (given)
6. (c) Young’s double slit experiment with white λ1 V2
⇒ =
light which consist wavelength from range 4000 Å 2λ1 10000
to 7000 Å.
104
QAt the centre of the screen, the path difference is ∴ Potential V2 = = 2500 V
zero for all wavelengths. The bright fringes of these 4
wavelengths overlap at the centre. Thus, the white 10. (c) A
(1) X
fringe at the centre is formed.
7. (a) QLinear velocity of an electron in a orbit of
H like atom, (0)
Y
Z c Z B
v = 218
. × 10 × m/s = 0 ⋅
6
n 137 n ∴ X = AY = Y = 0
where, Z = number of protons in nucleus, Y = BX = 1
n = principal quantum number
and c 0 = speed of light in free space, 11. (a) 6 kΩ
Thus, we have
1 +
v∝ 10V 6V 4 kΩ
n –
8. (d) Given, t1 / 2 = 3 days
Number of active nuclei remaining after time t, In the given circuit, the zener diode is used as a
t voltage regulating device. The voltage across 6 kΩ
N = N 0   1 / 2
1 t resistance is (10 − 6) V = 4 V
 2 Current through 6 kΩ resistor,
After t = 2days, 4V 4 2 2
I= = = × 10− 3 = mA
2/ 3
6k Ω 6 × 103 3
N1 = N 0  
1 N0 N 3
= = 0 = 0.63 N 0
 2 22/ 3 41 / 3
12. (c) In representation of simple harmonic motion
∴ N1 = 0.63N 0 in ellipse as velocity along X-axis and
After t = 3days, displacement along Y-axis.
N0 Major axis (along X - axis)
N2 = = 0.5N 0 Q = 20π
2 Minor axis (along X - axis)

Page 18 of 44
 ωA = ( 32 + 12 + 12) ⋅( 22 + 12) cos θ
⇒ = 20 π ⇒ ω = 20 π
A
⇒ 6 − 1 = 11 × 5 ⋅ cos θ
⇒ 2π n= 20 π
The frequency of the simple harmonic motion 5 5 5
∴ cos θ = = = θ = cos–1 =
∴ n = 10 Hz 55 11 11

13. (b) According to the question, 15. (c) According to the question,
µ1 1
v∝
m1 F=α t
x
k
m2 or v= ...(i)
µ2 x
1
FBD of lower block of mass m2, dv d K − 1 − 2 − 1 dx
= ⋅ =k ⋅ ⋅x ⋅
N1 =m1g dt dt x 2 dt
3
k − 2 k  dx
from Eq.(i)
k
fr1 a =− ⋅x ⋅ Q = v and v =
2 x  dt x 

fr 2 − k2 1
= ⋅ 2
2 x
N2
∴Force, F = Mass × |Acceleration |
m2 g
k2 1
∴ N 2 = m2 g + N1 = (m1 + m2) g =m ⋅ 2 (magnitude)
2 x
QLower block never moves.
k2 m
∴ fr2 ≥ fr1 F= ⋅
2 x2
µ 2 N 2 ≥ µ 1 N1 ⇒ µ 2(m1 + m2) g ≥ µ 1 m1 g 1
m1 + m2 µ 1 ∴ F∝ 2
⇒ ≥ x
m1 µ2
µ1 m 16. (c) QEscape velocity from a planet,
∴ ≤1 + 2
µ2 2GM 2GM
m1 ve = = R
R R2
µ1 m2
∴ =1 + = 2gR ...(i)
µ2 max
m1
According due to gravity
14. (a) C 4
G πR 3 ⋅ρ
GM 3 4
g= = = GπRρ
R2 R2 3
θ 3g
A B ∴ Radius R = ...(ii)
4πGρ
$ and AC = $i + 2$j + k
AB = 3$i + $j + k $
From Eqs. (i) and (ii), we get
∴ $)
BA = − (3$i + $j + k 3g 3 g2
ve = 2g ⋅ =
∠ABC is angle between BA and BC 4πGρ 2 π Gρ
g
Thus, ve ∝
ρ
θ
A B ve1 g1 ρ 5 1
∴ = × 2 = ×
BC = AC + BA ve 2 ρ1 g2 2 2
= AC − AB (Q BA = − AB) g1 5 ρ
$ $ ) = − 2$i + $j (given, = and 1 = 2 : 1)
= i + 2 j + k − (3i + j + k
$ $ $ $
g2 2 ρ2
∴ BA ⋅ BC =| BA|| BC|cosθ 5
$ ) ⋅ (− 2$i + $j) =
− (3$i + $j + k 2 2

Page 19 of 44
17. (c) According to the question, 19. (b) Terminal velocity, v = 2 r 2 (ρ − σ) g
9 η
time period, T ∝ r ρ S
a b c

Neglecting buoyancy effect of the fluid,

T = kr aρbS c ...(i) 2 ρ
v = ⋅ r2g
Thus, putting dimension, we get 9 η
[T] = [L]a [ML− 3]b [MT− 2]c Putting the given values, we get
[T] = [M]b + c ⋅[L]a − 3b ⋅[T]− 2c 2 103 × (0.9 ×10− 3)2
v= × × 9.8 = 98 ms −1
Equating the dimensions of both sides, we get 9 1.8 × 10− 5
b + c = 0, a − 3b = 0
20. (c) Let the mass of ice = m
and − 2c = 1
1 Applying calorimetry principle,
∴ c =−
2 heat given = heat taken
mL
∴ b=
1 (m1 + m2) s1 (t1 − t) = + ms 2(t − t2)
2 2
3 Putting values, we get
and a = 3b =
m
2 (10 + 50) × 1 × (15 − 0) = × 80 + m × 0.5[0 − (−10)]
Putting these value of a, b and c into Eq. (i), we get 2
m
3 1
−
1
⇒ 60 ×15= 40 m + ×10 = 45m
T = k⋅ r 2ρ 2 ⋅ S 2 2
ρ 3 60 × 15
=k r ∴ m= = 20 g
S 45

18. (d) QStress, F = 1% of Y = Y 21. (c) Heat capacity of an ideal gas in a

∆A 100 thermodynamic process,
F QIdeal gas is monoatomic,
stress ∆A f R 3R
But Young’s modulus, Y = = CV = =
strain ∆l 2 2
l p dV
Cprocess = CV + ⋅
Y n dT
∴ Y = 100  putting F = Y  3 p V
∆l   = R+ ⋅ 0
 ∆A 100  2 n 2T
l 3 nRT
∆l 1 ∴ Cprocess = R + [Q pV = nRT]
∴ = 2 n2T
l 100 3 R
∆r = R + = 2R
− 2 2
Poisson’s ratio, σ = r
∆l 22. (b) In p-V diagram, the slope of an adiabatic curve
l at any point in steeper than that of isothermal
∆r ∆l − 0.3 curve at that point.
∴ =−σ⋅ =
r l 100
∆r − 0.3 C ( pf,Vi )
= pf
r 100
Adiabatic
∆ V 2∆ r ∆ l compression
∴Change in volume, = + pi A
V r l (pi,Vi)
2 × (− 0.3) 1 p
= +
100 100 p2 B
1 − 0.6 0.4 Isothermal
= = expansion
100 100
O Vi V0
∴ ∆V % = 0.4% V
Thus, p f > pi

Page 20 of 44
23. (b) A charged circular ring of radius R is shown 25. (c) E D
in figure.
EB EA
C
d 60°
r +Q +Q
P F EC O EF C
O x
30°

From the figure, d = x 2 + r 2 …(i) A+Q M B+Q

Q/2
∴ Potential due to a uniform ring of positive charge
q at point P, (Regular hexagon)
1 q AM
V= ⋅ In ∆AOM , sin 30° =
4 πε0 d AO
1 q a
= ⋅ [from Eq. (i)]
4 πε0 x + r2
2 ∴ AO = 2 = a
1/ 2
Now, For maximum electric field at centre O charges
C should be placed at F, A , B and C.
r QElectric field due to charges at F and C is equal and
A B opposite at O.
O ∴Net electric field at centre O due to charges at A
and B.
4 Angle between E A and E B is 60°.
—r 3
3 —r
4 ∴E net at O,
2 E net = E 2A + E B2 + 2E AE B cos 60° (QE A = E B = E)
OC 2 + OB2 = r 2 +   r 2 = r
3 5
∴ CB =
 4 4 1 Qcos 60° = 1 
= E 2 + E 2 + 2E 2 ⋅  
5 2  2
Similarly, AC = r
3 1 Q
=E 3= ⋅ 3
∴ Work done in bringing a point charge − q from A 4 πε0 a 2
to B,
W = − q(VB − V A) 26. (b) QWhen a charged particle moves at a circular
path in uniform magnetic field, it time period is
 1 q 1 q 
= − q ⋅ − ⋅  independent from its speed.
 4 πε 0 CB 4 πε 0 CA  ∴Time period of proton will not change with change
  in its speed.
−1 1 1 
= ⋅ q2 −  27. (c) QMagnetic field due to a hollow cylinder of
4 πε0 5
 r
5
r radius r.
4 3 
− 1 q2 1 1 q2
= ⋅ [4 − 3] = − ⋅ ⋅
4 πε0 5r 5 4 πε0 r

24. (a) For surface ABCD electric flux is zero. Because

at surface ABCD net electric field is zero.
Using Gauss’s law,
Q
∫ E⋅ dS = εin0 O r A

Electric flux through the five faces of the cube, Binside = 0 (for d < r)
φE =
Q µ i
Boutside = 0 ⋅ (for d ≥ r)
ε0 2π d

Page 21 of 44
 So, graph between B and d. 1 q q
Fcentripetal = mrω2 = ⋅ 1 2
4 πε0 r 2
1 q q q1 q 2
1
B∝— ∴ ω2 = ⋅ 1 2 ⇒ ω=
B r 4 πε0 m r 3 4 πε0 mr 3
1
O R ω∝ ...(i)
r d r 3/ 2
Current produced due to moving q1 ,
28. (b) ω
i= q1 ...(ii)
2π
O r
Thus, magnetic field due to motion of q1 in circular
path at point O
µ i µ ωq
B= 0 ⋅ = 0 ⋅ 1 [using Eq. (ii)]
I 2 r 2 2πr
µ I ω
B= 0 ⋅ Hence, B ∝
2 r r
V
Q I1 = 1
Magnetic field B ∝ 5/ 2 [using Eq. (i)]
R1 r
Case (I) l1 = 2πr (length of the loop),
32. (a) E2=vB2l
l µ I B2
R1 = ρ 1 and B1 = 0 ⋅ 1 ...(i)
A 2 r b l v=constant
Case (II) l 2 = 2π ⋅ 2r = 2l1 B1
l 2l E1=vB1l
R2 = ρ ⋅ 2 = ρ ⋅ 1 = 2R1 y
A A
V V I
I2 = = = 1
R2 2R1 2 I
µ I µ I ∴Motional emf in the loop,
B2 = 0 ⋅ 2 = 0 ⋅ 1 ...(ii)
2 2r 2 2 ⋅ 2r E = E1 − E 2 = vl(B1 − B2)
From Eqs. (i) and (ii), µ I µ 0I 
= vl  0 ⋅ −
µ0
⋅
I1
 2π y 2 π( y + b) 
B2 2 2⋅ 2r 1
= = µ  y+ b − y µ 0 vlI
µ0 = 0 ⋅ I ⋅ vl   = 2π ⋅ y(y + b) b
B1 I 4
⋅ 1
2 r 2π  y( y + b) 
Magnetic field B2 =
B1 Q b << y
4 µ vlI
∴ E= 0 ⋅ 2 b
29. (d) QResonance frequency, f0 = f1 f2 2π y
Qv = constant (∴ y = vt)
= 200 × 800 = 400 Hz
µ vlI
Thus, E= 0 ⋅ 2 2 b
30. (c) Initially, there will be no voltage drop across 2π v t
capacitor, so intensity of bulb will rise sharply and 1
gradually voltage drop across capacitor will Hence, E∝ 2
t
increase as a result voltage drop across bulb
decreases, so intensity of bulb will decreases. 33. (d) Solid sphere Hollow sphere
ρ1 ρ2
31. (d)
q1 OA=R O′B=R
r A O B O′ O′C=r
O
q2 C

Page 22 of 44
 4 3 4
∴ M1 = ρ1 πR and M 2 = ρ 2 π( R3 − r 3) 35. (d)
3 3
4 4 σ qE
∴ ρ1 πR3 = ρ2 π(R3 − r 3) E= —
ε0 m
3 3
mg
⇒ ρ1 R3 = ρ2(R3 − r 3) + + + + + + + +
ρ1 r3 σ
⇒ =1 − 3
ρ2 R ∴Apparent weight of the bob, w′ = mg − qE
1 mg′ = mg − qE
r  ρ 3
∴ = 1 − 1  ...(i) ∴ g′ = g −
qE
R  ρ2  m
Moment of inertia, QTime period of a pendulum,
2  R5 − r 5  L
M2  3 3
T = 2π
IH
=
5 R − r  geff
IS 2
M1 R2 = 2π
L
= 2π
L
5 qE  qσ 
g− g− 
4  R5 − r 5  m ε
ρ2 π (R3 − r 3)  3 3   0 m

=
3  (R − r ) 
4 3 2 36. (b, c, d)
ρ1 πR R

30
Ω

30
3

0
0

20
20

Ω
ρ2  R5 − r 5  ρ2   r  

Ω
5
=  I3
 = 1 −   
ρ1  R  ρ1 
5
R  K IG

 5
I H ρ2   ρ 3

10
G
1 − 1 − 1  
10

∴ = G

0
0

ρ1   ρ2  

Ω
Ω

IS
 

34. (a) A
10 V 10 V
Moving each other 10
∴ IG =
100 + G
B
10
Plates of a charged capacitor 300 I 3 = G
moving toward each other 100 + G
due to electrostatic attraction.
 1 
G
1 σ I3 = 100 + G 
Force = ⋅ q 30
2 ε0  
 (300 + G)
10 +  =
1 G
∴Relative acceleration of plates, ∴ I3 + IG =
2F (100 + G)  30  (100 + G) × 30
a rel =
M According to the problem,
Potential difference, V = Ed  200 300 G   (300 + G) 
...(i) 10 =  + 
1  3 300 + G   (100 + G) 30 
where, d = d0 − a rel t 2 (Qplates are moving)
2 [Q V = RI]
60000 + 1100 G 1 1

V = E d0 − a rel t 2 
1 10 = × ×
∴
 2  3 100 + G 30
This is a equation of a parabola with downward ⇒ 900(100 + G) = 60000 + 1100 G
concavity. ⇒ 30000 = 200 G
∴ G = 150 Ω

Page 23 of 44
 IG =
10
=
10
= 40 mA ∴Partial reflection and refraction at Q.
100 + 150 250 As SP || QR , emergent ray at R is parallel to incident
200 300 ray at S.
As = ∴Net deviation =180°.
100 150
So, I 200 = I 300 38. (a, d) The intensity of a sound source appears to
be periodic due to
37. (a, c) µ=√2
(i) source intensity is periodic.
(ii) source is producing a sound composed of two
nearby frequencies.

R 45° 39. (b) QInternal energy of an ideal gas depends only

on the temperature of gas.
30°
Q 15° 15° E in ∝ T
15° 45° Q 4Q
40. (a) P B
75° 75° 30° S A r
15°
P d
QVP is minimum.
Critical angle θC = sin−1   = 45° ∴ EP = 0 ⇒ E A = EB
1
 2 1 Q 1 4Q
⇒ ⋅ = ⋅
Snell’s law at points, (Qn1 sin θ1 = n2 sin θ2) 4 πε0 r 2 4 πε0 (d − r)2
1 sin 45° = 2 sinθ 1 2
⇒ = ⇒ d − r = 2r
∴ θ= 30° r d− r
At PQincidence angle at P = 75°> θC . d
∴ Distance of P from the A r = units to the right of A.
∴ TIR at point P. 3
At Q Q incidence angle at Q=15° < θC .

Chemistry
41. (d) Cl 2O 7 is the anhydride of HClO 4 . It reacts with The hydrolysis of SiCl 4 occurs due to coordination
of OH with empty 3d-orbitals of Si-atom of SiCl 4
water slowly to give perchloric acid.
molecule.
Cl 2O 7 + H 2O → 2HClO 4 OH
Perchloric acid
Cl Cl Cl Cl Cl OH
Its structure is as follows: 2H2O
Si Si Si
O O O –2H+ –2Cl–
Cl Cl Cl Cl Cl OH
Cl 117.6° Cl OH 2H2O
O O O O –2H+

It is less reactive than other oxides of chlorine and OH

does not react with P, S, coal or paper at room HO OH Cl OH
temperature. Si Si
–2Cl–
HO OH Cl OH
42. (d) The main reason that SiCl 4 is easily OH
hydrolysed as compared to CCl 4 is that Si can
extend its coordination number beyond four 43. (d) Silver chloride dissolves in excess of
because it has vacant d-orbital. On the other hand, ammonium hydroxide solution. The cation
carbon has no d-orbital thus, it cannot extend its present in the resulting solution is [Ag (NH 3)2]+
coordination number beyond four, so its halides In aqueous solution, silver chloride exist as Ag+
are not attacked (hydrolysed) by water. The
vacant d-orbitals of Si can coordinate with water and Cl − . Ag + present in solution reacts with NH 3
molecules and hence their halides are hydrolysed to form [Ag (NH 3)2]+ .
by water. Ag+ Cl − + 2NH 3 → [Ag(NH 3 )2 ]+ Cl –

Page 24 of 44
44. (a) The ease of hydrolysis of carbonyl compounds Step-I It involves the formation of an amide on
depend on the group attached to the carbonyl carbon. reaction of ammonia and acetyl chloride so, M must be
Among the given options, chlorine (— Cl) group is O
electron withdrawing group which makes the
carbonyl group electrophilic. Hence, hydrolysis can C
Cl
occur most easily. The order for electron withdrawing
tendency among given options is as follows: Cl
 Cl >  OCOCH 3 >  OC2 H 5 >  NH 2
CH3
So, the correct order for the ease of hydrolysis in
the given compounds is as follows: Step-II It involves the Hofmann-bromamide
reaction.
CH 3 COCl > CH 3 COOCOCH 3
I II
CH3

> CH 3 COOC2 H 5 > CH 3 CONH 2 Cl

Br2
III IV C8H8ClNO NaOH
45. (d) CH 3  C ≡≡ CMg Br can be prepared by the H2N
reaction of CH 3  C ≡≡ CH with CH 3 MgBr. This
In this reaction, migration of an alkyl or aryl group
method is used in preparation of higher alkynes
from lower alkynes. The chemical equation for the takes place from carbonyl carbon of the amide to
formation of CH 3  C ≡≡ CMgBr is given below the N-atom. So, C8 H 8 Cl NO must be an amide with
− 2+ − structural formula.
CH 3  C ≡≡ CH +CH 3 MgBr → CH3
− 2+
− Cl
CH 3  C ≡≡ CMg X
46. (b) The number of alkene(s) that can produce H2N
2-butanol by the successive treatment of B2 H 6 in C
tetrahydrofuran solvent and alkaline H 2O 2 solution
O
is 2. The alkenes are cis-but -2- ene and
trans-but-2-ene. The hydration product is obtained 48. (b) Methoxybenzene on treatment with HI
in accordance with opposite Markownikoff’s rule. produces phenol and methyl iodide. This is due
In this reaction, addition takes place through the the more stable aryl oxygen bond. Here,
initial formation of π-complex which changes into methyl phenyl oxonium ion is formed by the
a cyclic four centre transition state with the protonation of ether. The bond between O  CH 3
addition of boron atom to the less hindered carbon is weaker than the bond between O  C6 H 5
atom. because the carbon of phenyl group is
(i) B2H6 sp 2 -hybridised and there is a partial double bond
H3C HC CH CH3 – CH3 CH CH2CH3
(ii) H2O2/OH character. Thus, the reaction yields phenol and
But-2-ene
OH alkyl halide.
Butan-2-ol OCH3 OH

47. (b) Given sequence of chemical equation is 373K

CH3 + HI + CH3I
Methyl
Cl Anisole Phenol Iodide
NH3 Br2
C8H6Cl2O (Step I) C8H8ClNO NaOH (Methoxy benzene)
(M) (Step II) H N
2
49. (b) Given sequence of chemical equation is
The structural formula of C8 H 6 Cl 2 O( M ) will be
K2Cr2O7 I2/NaOH
O C4H10O C4H8O CHI3
H2SO4 Warm
(N) (step I) (step II)
C
Cl OH
Cl Here, N will be (IUPAC name = Butan-2-ol)
CH3 Step I It involves the oxidation of secondary
alcohol to corresponding alcohol in the presence of
The various step involves in the above road map can
K 2 Cr2 O7 and H 2 SO4 .
be explain as follows

Page 25 of 44
 OH K2Cr2O7 O 52. (c) n = 2, l=0, m= – 1 is not a possible electronic
configuration. With n = 2 and l=0, the orbital is 2s
H2SO4
having only one ml value i.e. 0. As the value of
[C4H10O] [C4H8O] ml = − l to + l
(N )
Other options are correct.
Step II It involves the iodoform reaction. Ketone
formed in step I have one methyl group linked to Orbital
the carbonyl carbon atom are oxidised by sodium n = 3, l = 0, m = 0 3s
hypohalite to sodium salts of corresponding
carboxylic acids having one carbon atom less than n = 3, l = 1, m = – 1 3p
that of carbonyl compound. n = 2, l = 1, m = 0 2p
O I2/NaOH O

O–Na+ + CHI3
53. (b) The number of unpaired electrons in Ni
[C4H8O] (Yellow ppt.)
(atomic number=28) are 2. It can be easily
concluded from the electronic configuration of Ni.
50. (a) The correct order of reactivity for the addition Electronic configuration of
reaction of the given carbonyl compounds with Ni=1s 2 2 s 2 2p 6 3s 2 3p 6 4s 2 3d 8
ethylmagnesium iodide is I > III > II >IV.
3d8
H H H3C
=O >
C= C= =O > C==O Orbitals of Ni in 3d =
H H3C H3C Unpaired electrons
(I) (III) (II)
(CH3)3C 54. (c) The strongest H-bond is FH------ F because
> C==O in this case, a hydrogen is bonded to a most
(CH3)3C electronegative atom i.e. fluorine. In all other
(IV) options, hydrogen is bonded to oxygen and
sulphur that are less electronegative atom than
This order can be explained on the basis of
fluorine.
following two factors:
(i) Inductive effect Greater the number of alkyl The correct electronegativity order of elements are
(electron releasing) groups attached to carbonyl as follows: F > O > S
group, greater will be the electron density on
55. (d) Given,
carbonyl carbon. Thus, it lowers the attack of
nucleophile and hence, reactivity decreases. Half-life of C14 , t1 / 2 = 5760 years
(ii) Steric effect As the number of alkyl group Initial concentration of sample of C14 , N 0 = 200 mg
attached to carbonyl carbon increases, the attack
of nucleophile on carbonyl group becomes more Final concentration of sample of C14 , N t = 25mg
and more difficult due to steric hinderance. The given decay is radioactive and all radioactive
51. (d) When aniline is treated with conc. H 2SO 4 decay follows first order kinetics.
0.693
followed by heating at 200° C, the product obtained is t1 / 2 =
sulphanilic acid i.e. p-aminobenzene sulphonic acid λ
+ 0.693 0.693 −1
NH2 NH3HSO4
– ∴ λ= = yr
t1 / 2 5760
We know that, for first order reaction
+ Conc. H2SO4 2.303 N .
2303 [200]
t= log 0 = log
Aniline Anilinium hydrogen λ N t 0.693 [25]
sulphate 5760
+
NH3 NH2 .
2303 × 5760
= log 8
0.693
200°C
a =17, 286. 78 yrs ≈17, 280 yrs
Therefore, the time taken to change 200 mg to
– 25 mg is 17, 286.78 yr, which is very close to option
SO3 SO3H
Zwitter ion Sulphanilic acid
(d) i.e. 17280 yrs.

Page 26 of 44
 C2H 6 H2
Alternative method Initial gram weight = w g wg
200 mg sample
w w
t1/2 = 5760 years Number of moles =
30 2
100 mg According to Henry’s law,
w
t1/2 = 5760 years pH 2 nH 2 2
17280 years = χH 2 = =
ptotal nH 2 + nC2 H 6 w
+
w
50 mg 2 30
w
t1/2 = 5760 years pH 2 2 w 30 15
= = × =
25 mg ptotal 15w + w 2 16 w 16
30
56. (d) Ferric ion forms a prussian blue precipitate So, the fraction of total pressure exerted by
due to the formation of Fe4 [Fe(CN)6]3. This hydrogen is 15 : 16.
complex is formed during the determine action of
presence of nitrogen in the given sample. In this 60. (a) Given, the heat of neutralisation of a strong
method, to portion of sodium fusion extract, base and a strong acid is 13.7 kcal.
freshly prepared ferrous sulphate, FeSO 4 solution The reaction of neutralisation is as follows
is added and warmed. Then about 2 to 3 drops of HCl + NaOH → NaCl + H 2O; ∆H = − 137 . kcal
FeCl 3 solution are added and acidified with 1 mol 1 mol
conc. HCl. The appearance of a prussian blue According to question,
colour indicate the presence of nitrogen.
HCl + NaOH → NaCl + H 2O … (i)
FeSO 4 + 2NaOH → Fe(OH)2 + Na 2SO 4
0.6 mol 0.25 mol
6NaCN + Fe(OH)2 → Na 4 [Fe(CN)6] + 2NaOH
Sodium ferrocyanide
In equation (i), NaOH acts as a limiting reagent. For
1 mole of NaOH and 1 mole of HCl, heat of
3 Na 4 [Fe (CN)6] + 4FeCl 3 → neutralisation = 137
. kcal.
Fe4 [Fe (CN)6]3 +12NaCl ∴For 0.25 mole of NaOH and 0.6 mole of HCl, heat
Ferric ferrocyanide of neutralisation = 137
. × 0.25 ⇒ 3.425 kcal
(prussian blue)
61. (a) Number of X atoms at the corners = 8
57. (c) The nucleus 64
29 Cu accepts an orbital electron 1
Number of X atoms per unit cell = 8 × = 1 atom
to yield 64
28 Ni. The atomic number of Cu is 29, 8
which is equal to the number of electrons and also Number of Y atoms at the centre of the body = 1 atom
equal to the number of protons. Hence, the formula of the compound is XY.
When 64 29 Cu accepts an orbital electron then
electrons subtract from the atomic number, i.e.
62. (c) The number of electrons involved in the
reaction are three as shown below
29 −1 = 28
64 Cu + e 0 → 64 Ni Al 3+ + 3e − → Al
29 −1 28 It means the conversion of every aluminium ion to
58. (d) Mass of an electron = 9.108 ×10−31 kg aluminium atom requires three electrons.
Mass of one mole of electron Therefore, the amount of electricity required for
= (9.108 × 10−31 × 6.023 × 1023) kg one mole of Al 3+ ions = 3F.

Then, number of mole of electron in 1 kg 63. (b) Given,

1
= Zn → Zn2+ + 2e − ; E° = + 0.76 V … (i)
. × 6.023×10−8
9108 −
Fe → Fe 2+
+ 2e ; E° = + 0.41 V … (ii)
1
= ×108 mole of e − On reversing the above equation (i) and (ii), we get
. × 6.023
9108
Zn2+ + 2e − → Zn ; E° = − 0.76 V
59. (d) Given, equal weights of ethane and hydrogen
are mixed in an empty container at 25°C. Fe2+ + 2e − → Fe; E° = − 0.41 V
[where, E° = standard reduction potential]

Page 27 of 44
 To find, the standard emf of the cell with the 66. (b) H 2SO 4 (sulphuric acid) is present in maximum
reaction.
Oxidation (anode)
amount in ‘acid rain’. Oxides of nitrogen and
sulphur, released into the atmosphere from
2+ 2+
Fe + Zn Zn + Fe thermal power plants, industries and automobiles
Reduction (cathode)
are the main sources of acid rain. These oxides on
°
oxidation followed by hydrolysis give sulphuric
So, E cell = E° − E° acid and nitric acid that alongwith HCl are
Fe2+ / Fe Zn 2+ / Zn
responsible for the acidity of rain. The oxidation
= − 0.41 V + 0.76 V = + 0.35V
reaction is catalysed by particulate matter present
64. (b) Given, in the polluted atmosphere.
[NH 3]2 l → 2H 2SO 4 (aq)
2SO 2(g) + O 2(g) + 2H 2O()
N 2 + 3H 2 c 2NH 3; K 1 = … (i)
[N 2] [H 2]3 4NO 2(g) + O 2(g) + 2H 2O()l → 4HNO 3(aq)
[NO]2 67. (b) The correct set of oxides arranged in the
N2 + O 2 c 2NO; K 2 = … (ii)
[N 2] [O 2] proper order of basic, amphoteric, acidic are
BaO, Al 2O 3 , SO 2.
1 [H 2O]
H2 + O 2 c H 2O; K 3 = … (iii) Oxides of non-metallic elements are acidic such as
2 [H 2] [O 2]1 / 2
CO 2, NO 2 , SO 2 etc. Oxides of less electropositive
The chemical equation for the oxidation of 2 mol of elements (such as BeO, Al 2O 3 , Bi 2O 3, ZnO etc.) are
NH 3 to give NO is amphoteric i.e. these behaves as acids toward strong
5 bases and as bases towards strong acids. Oxides of
2NH 3 + O 2 2NO + 3H 2O
c … (iv)
2 electropositive elements (Na 2O, CaO, Tl 2O, BaO
To get the equation (iv) from equation (i), (ii) and etc.) are basic and contain discrete O 2− ions.
(iii) following steps are followed: 68. (b) Out of the given outer electronic configuration
Reversing equation (i), we get of atoms, the highest oxidation state is achieved
2NH 3 N 2 + 3H 2 so K ′ =
1
… (v) by (n − 1)d 5ns 2 i.e. 7.
c K1 A large number of oxidation state is due to the fact
Multiplying equation (iii) by 3, we get the (n − 1)d-electrons may get involved along with ns
3 electrons in bonding as electrons in (n − 1) d- orbitals
3H 2 + O 2c 3H 2O so K ′ = K 33 … (vi)
2 are in an energy state comparable to ns -electrons.
Adding equation (ii) and (vi) Oxidation state of other options are as follows:
5
N 2 + 3H 2 + O 2
c 2NO + 3H 2O Electronic configuration Oxidation state
2
(n − 1) d ns
8 2
+ 2, + 3, + 4
so, K ′ = K 2 . K 33 … (vii)
(n − 1) d ns
3 2
+ 2, + 3, + 4, + 5
On combining (v) and (vii), we get the required
K3 (n −1) d ns
5 1
+ 2, + 3, + 4, + 5, + 6
equation having equilibrium constant K ′ = K 2 . 3 .
K1
69. (c) At room temperature, the reaction between
65. (c) Dacron is a condensation polymer. It is also water and fluorine produces F − , O 2 and H + .
known as terylene. It is a polymer obtained by Fluorine, being non-polar molecule, readily
condensation reaction between ethylene glycol dissolves with water and forms mixture of oxygen
and terephthalic acid at 420-460 K in the presence and ozone as shown below
of zinc acetate-antimony trioxide catalyst.
2F2 + 2H 2O → 4HF + O 2
nHOH2C — H2COH + nHOOC— —COOH 3F2 + 3H 2O → 6HF + O 3
Ethylene glycol HF exist as H + and F − in a solution.
Terephthalic
acid
O O 70. (d) BeCO 3 is least thermally stable. The thermal
stability of carbonates increases down the group
420-460K
—O—CH2CH2—O—C— —C— i.e from Be to Ba.
–nH2O
Dacron or Terylene
n BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3
(523 K) (813 K) (1173 K) (1562 K) (1633 K)

Page 28 of 44
 BeCO 3 is unstable to the extent that it is stable only 73. (b) Given, specific heat = 0.16
in atmosphere of CO 2. These carbonates show
reversible decomposition in closed container. Let metal chloride be MCl x then,
6.4
MCO 3 c
MO + CO 2 = Atomic weight of metal
More stable the oxide is formed, lesser will be specific heat
stability of carbonates. 6.4
= Atomic weight of metal
016
.
71. (a) Given reactions are Atomic weight = 40
Br NaNH
[P] →
2
C2H 4Br2 →
2
[Q] 40 is the atomic weight of calcium. According to
NH 3
question, metal chloride (MCl x ) have ≈ 65% chlorine
20%/ H 2SO4 Zn -Hg / HCl present in it.
[Q] → [R] → [S]
Hg 2 + , ∆ x × Atomic weight of chlorine
× 100 = 65
[P] is an alkene with two carbon atoms i.e. ethene. 40 + x × Atomic weight of chlorine
When it reacts with Br2, addition reaction occurs x × 355
.
× 100 = 65
and C2H 4Br2 is formed. 40 + x × 355
.
H H
H H x = 209
. ≈ 2(approx.)
C=
=C + Br2 H—C—C—H So, the formula of metal chloride will be MCl 2.
H H 74. (a) For a reversible adiabatic process,
Ethene [P] Br Br
(C2H4) 1,2-dibromoethane γ
(C2H4Br2)
pT 1 − γ = constant … (i)
C2H 4Br2 (1, 2-dibromoethane) on reaction with
According to question, during a reversible adiabatic
NaNH 2 / NH 3 gives ethyne (C2H 2).
NaNH 2 / NH 3
process the pressure of a gas is found to be
H 2 C  CH 2 → HC ≡≡ CH proportional to the cube of its absolute
  Ethyne [Q]
(C2 H 2 )
temperature.
Br Br p ∝ T3
Ethyne [Q] in presence of 20% H 2SO 4 , Hg 2+ at 333 K
pT −3 = constant …(ii)
gives ethanal.
Equating equation (i) and (ii), we get
Hg2 + / H +
CH ≡≡ CH + H  OH → CH 2 == C  H γ
=−3
333 K
 1−γ
OH
Tautomerisation γ = − 3 (1 − γ)
→ CH 3CHO
Ethanal [ R] γ = − 3 + 3γ
Ethanal [R] undergoes reduction in presence of − 2γ = − 3
Zn-Hg / HCl to give ethane [S] 3
γ=
Zn- Hg/ HCl 2
CH 3CHO → CH 3  CH 3
Ethanal Clemmensen Ethane
As we know, the ratio of molar heat capacities at
[ R] reduction [ S] constant pressure and constant volume is
C 3
72. (a) The number of possible organobromine represented by γ. So, the ratio of p for the gas is .
CV 2
compounds which can be obtained in the allylic
bromination of but-l-ene with N-bromosuccinimide 75. (a) According to question,
is 1.
NBS
[X] + Dil. H 2SO 4 → [ Y ] :
CH2 CH CH2 CH3 CH2 CH CH CH3 Colourless, suffocating gas
But-1-ene Br
[Y ] + K 2Cr2O 7 + H 2SO 4 →
CH2 CH CH CH3 Green colouration of solution.
Br All sulphites when treated with dil. H 2SO 4 gives
3-bromobut-1-ene colourless and suffocating sulphur dioxide gas.

Page 29 of 44
 SO 23− (s) + Dil.H 2SO 4 (aq) → SO 42− (aq) + SO 2(g) In next step, Br − attacks a carbon atom of the
Sulphite ion Sulphur bromonium ion. This release the strain in the three
[ X] dioxide[ Y ]
membered ring and form a vicinal dibromide.
+ H 2O(l) + CH3 CH3
SO 2 gas [Y ] turns acidified potassium dichromate Br
paper green due to reduction of Cr (VI) to Cr (III). H3C H H—C—Br Br—C—H
s
K 2Cr2O 7(aq) + H 2SO 4 (aq) + 3SO 2(g) → C—C + Br +
[Y] H C2H5 H—C—Br Br—C—H
K 2SO 4 (aq) +Cr2(SO 4)3(aq) + H 2O()
l
Green
C2H5 C2H5
76. (a, c) The possible product(s) to be obtained from
the reaction of cyclobutyl amine with HNO 2 is/are 78. (b, c) The correct statements for peroxide ion
OH (O 2−
2 ) are that it is diamagnetic and it has bond
order one.
cyclobutanol = and cyclopropylmethanol
Electronic configuration of O 2−
2 (peroxide ion) is
CH2OH
= . The chemical reactions involved σ1s 2 , σ *1s 2 , σ 2s 2 , σ * 2s 2 , σ 2pz2 , [π 2px2 = π 2p 2y ],
are as follows: [π * 2px2 = π * 2p 2y ], σ * 2pz0
NH2
r QBond order =
HNO2
N2 No. of electrons present in bonding
–N2 − No. of electrons present in non - bonding
Cyclobutylamine r 2
10 − 8 2
r CH2
Ring
∴ BO = = =1
contraction 2 2
Number of unpaired electrons = 0
OH So, O 2−
2 is diamagnetic in nature.
CH2OH
79. (a, c, d) Among the given options, the extensive
Cyclobutanol Cyclobutyl variables are H (enthalpy), E (internal energy),
methanol
V (volume).These variables have values that
77. (a, d) The major product(s) obtained in the given depends upon the quantity or size of matter
reaction are present in the system. Other examples are heat
CH3 CH3 capacity, entropy, free energy, length and mass.
H3C H H Br Br H 80. (a, c, d) White phosphorus (P4) has 6P  P single
C=
=C + Br2 +
H Br Br H bonds, 4 lone pairs of electrons and P  P  P
H C2H5
C2H5 C2H5
angle of 60°. It is a translucent white waxy solid.
It has large atomic size and less electronegativity.
Enantiomers So, it forms single bond instead of pπ - pπ multiple
The mechanism for the above given reaction is as bond. It consists of discrete tetrahedral P4
follows. When the π-electrons of the alkene approach molecule as shown in the figure.
a molecule of Br2, one of the bromine atom accepts
them and releases the shared electrons to the other P
bromine atom. A cyclic bromonium ion is formed. 60°
Br+ P P
H3C H H3C H
C=
=C + Br—Br C———C
H C2H5 H C2H5 P
(Cyclic bromonium ion)

Page 30 of 44
Mathematics
1. (a) We know that, sin 30° = 1 = 0.5 4. (c) We have, f : [a , b] → R be differentiable
2
on [a , b] and k ∈ R, also f (a) = 0 = f (b)
In 1st quadrant sin x is increasing function.
and J(x) = f '(x) + kf (x)
∴ sin 31° > sin 30°
Let g(x) = kxf (x) which is continuous in [a , b] and
⇒ sin 31° > 0.5 differentiable in (a , b) such that
2. (c) We have, f1 (x) = e x g(a) = 0 = g(b)
f2(x) = e f1 ( x ) Then, for every c ∈ (a , b), g'(c) = 0
(by Rolle’s theorem)
…… …… …… …… Now, g′(x) = kf (x) + kxf '(x)
…… …… …… …… ⇒ g'(c) = kf (c) + kcf '(c)
fn + 1 (x) = e f n( x ) ⇒ kf (c) + kcf '(c) = 0
Now, fn (x) = e f n−1 ( x ) ⇒ f (x) = 0,for every x = c ∈(a , b)
On taking log both sides, we get ∴ J(x) = 0 has atleast one root in (a , b).

5. (c) We have,
log { fn (x)} = fn − 1 (x) log e f (x) = 3x10 − 7 x 8 + 5x 6 − 21 x 3 + 3x 2 − 7
d d
⇒ log ( fn (x)) = fn − 1 (x) (Qlog e = 1) ∴ f (1 − h) = 31
( − h)10 − 71
( − h)8
dx dx
1 d + 51
( − h)6 − 211
( − h)3 + 31
( − h)2 − 7
⇒ fn (x) = fn′ − 1 (x)
fn (x) dx = 31
( − 10h + 45h2 − 120h3 + ...... + h10)

⇒
d
fn (x) = fn (x) fn′ − 1 (x) ... (i) − 71
( − 8h + 28h2 − 56h3 + ..... + h8)
dx + 51
( − 6h + 15h2 − 20h3 + ..... + h6)
Now, f1′ (x) = e x
− 211
( − 3h + 3h2 − h3)
and f2(x) = e f1 ( x )
+ 31
( − 2h + h2) − 7
⇒ log f2(x) = f1 (x) log e = f1 (x) ⇒ f (1 − h) = − 24 + 53h + h2(−46) + h3(− 47) + ....
1 and 1 = − 24
f()
⇒ ⋅ f2′ (x) = f1′(x)
f2(x) f (1 − h) − f ()
1
∴ lim
h→ 0 h3 + 3h
⇒ f2′(x) = f2(x) ⋅ f1′(x)
−24 + 53h + h2(− 46) + h3(− 47) + ... − ( − 24)
= f2(x) ⋅ e x (Q f1′(x) = e x ) = lim
h→ 0 h(h2 + 3)
= f2(x) ⋅ f1 (x) [Q e x = f1 (x)] ...(ii) 53h + h2(− 46) + h3(− 47) + K
= lim
From Eq. (i), h→ 0 h(h2 + 3)
d 53 + h (− 46) + h2 (− 47) + ... 53
fn (x) = fn (x) ⋅ fn −1 (x) .... f1 (x) [using Eq. (ii)] = lim =
dx h→ 0 h2 + 3 3

6. (a) Let g(x) = e − x f (x)

3. (b) We have, f (x) = 1 − |x| such that g(a) = 0, g(b) = 0
2 − |x|
and g(x) is continuous and differentiable.
f (x) is defined for all x satisfying
Then, for atleast one value of c ∈(a , b) such that
1 − |x| |x| − 1
≥0 ⇒ ≥0 g'(c) = 0
2 − |x| |x| − 2
Now, g'(x) = e − x f '(x) + ( − e − x ) f (x)
⇒ |x|≤ 1or |x|> 2
⇒ g'(c) = e − c f '(c) + (− e − c) f (c) = 0
⇒ x ∈ [−1, 1]or x ∈ (−∞ , − 2) ∪ (2, ∞)
−c
⇒ x ∈ (−∞ , − 2) ∪ [−1, 1] ∪ (2, ∞) ⇒ e f '(c) = e − c f (c) ⇒ f '(c) = f (c)

Page 31 of 44
 dt
7. (b) We have, Put 2x = t ⇒ dx =
2
f : R → R be a twice continuously differentiable π 2
function such that f (0) = f () 1 = f ′(0) = 0 sin t
Now, for atleast one value of c1 ∈(0, 1),
∴ N= ∫0 4( t 2 + 1)
2
dt

f ′(c1) = 0 (by Rolle's theorem) π 2 sin t

Again, f ′(0) = 0 = f ′(c1)
= ∫0 (t + 2)2
dt
⇒ f ′′(c) = 0 for some c ∈(0, c1) π 2 1
(by Rolle’s theorem) ∴ M−N= ∫0 (cos x) ⋅
(x + 2)
dx

8. (b) We have, π 2 sin x

 x cos3 x − sin x 
− ∫0 (x + 2)2
dx
∫e   dx = esin x f (x) + c
sin x

 cos2 x  π 2
 sin x  π 2 sin x
⇒ ∫e
sin x
(x cos x − sec x tan x) dx = e sin x
f (x) + c = 
 x + 2 0
− ∫0 −
(x + 2)2
dx

∫e
⇒ sin x
(x cos x − 1 + 1 − sec x tan x) dx sin x π 2

(x + 2)2
dx − ∫0
= esin x f (x) + c
sin π 2 1 2
= = =
⇒ ∫ [esin x cos x(x − sec x) + esin x (1 − sec x tan x)] dx π 2+ 2 π + 4 π + 4
= esin x f (x) + c 2
d sin x 11. (b) We have,
⇒ ∫ dx {e (x − sec x)}dx = e f (x) + c
sin x

2014 tan−1 x
⇒ esin x (x − sec x) = esin x f (x) + c
I= ∫1 2014 x
dx ... (i)

⇒ f (x) = x − sec x 1
Let x=
t
9. (c) We have,
−1
1 ⇒ dx = dt
∫ f (x) sin x cos x dx = 2(b 2 − a 2) log( f (x)) + c t2
1 2014 tan−1 (1 t)  − 1 
⇒ f (x)sin x cos x =
1
⋅
1
⋅ f ′(x)
Now, I= ∫2014 1t
 2 dt 
 t 
2(b 2 − a 2) f (x)
f ′(x) cot −1 t
2014
⇒ f (x) sin 2x = 2
1
⋅ = ∫1 2014
t
dt
b − a 2 f (x)
2014 cot −1 x
1 f ′(x) =∫ dx ... (ii)
⇒ sin 2x = 1 2014 x
b 2 − a 2 ( f (x))2
On adding Eqs. (i) and (ii), we get
1 f ′(x)
⇒ ∫ sin 2x dx = b 2 − a 2 ∫ ( f (x))2 dx 2I = ∫
2014 π 2 π
dx = ( log x )
2014
1 2014
1 2014 x 2
− cos 2x 1  −1  π
⇒ = 2 ⋅  = ( log 2014 − log1 2014)
2 b − a 2  f (x)  2
cos 2x (b 2 − a 2) 1 π  1 
⇒ = ⇒ I =  log 2014 − log 
2 f (x) 4  2014 

⇒ f (x) = 2
2 π
= (log 2014 + log 2014)
(b − a 2) cos 2x 4
π 2 π π
10. (d) Given, M = ∫ cos x dx = (2 log 2014) = log 2014
0 (x + 2) 4 2
π 4 sin x cos x
and N=∫ dx 12. (c) We have,
0 (x + 1)2 π 3 sin x
π / 41 sin 2x
I= ∫π 4 dx
=∫ ⋅ dx x
0 2 (x + 1)2

Page 32 of 44
 sin x 16. (c) We have,
Since, is a decreasing function.
x dy
(1 + x 2) + 2xy − 4 x 2 = 0
π sin π 3 π sin π 4
∴ × ≤I≤ × dx
12 π3 12 π4 dy  2x  4x2
⇒ +  2
y=
3 2 dx  1+ x  1 + x2
⇒ ≤I≤
8 6 ∫
2x
1 + x2 2
Here, IF = e = elog(1 + x )
= 1 + x2
13. (b) Let
−1 2
4x
etan y (1 + x 2) = ∫ (1 + x 2) ×
(sin x )
5π 2 ∴ dx + C
I= ∫π 2 etan
−1
(sin x )
+ etan
−1
(cos x )
dx (1 + x 2)
⇒ y (1 + x 2) = ∫ 4 x 2dx + C
5π 2 tan −1 (sin x )
e
= ∫0 etan
−1
(sin x )
+ etan
−1
(cos x )
dx
⇒ y(1 + x 2) =
4x3
+ C
−1
3
π 2 etan (sin x )
4x3
−∫ −1 −1
dx ...(i) ⇒ y (1 + x 2) = −1 [y(0) = − 1]
0
etan (sin x )
+ etan (cos x )
3
−1
5π 2 etan (cos x ) 4x3 1
⇒ y= −
I= ∫0 e tan −1 (cos x )
+ etan
−1
(sin x )
dx
( + x 2) 1 + x 2
31
−1 4 1 1
π 2 etan (cos x ) ∴ 1 = − =
y()
−∫ −1 −1
dx ...(ii) 6 2 6
0
etan (cos x )
+ etan (sin x )

 using, b f (x) dx = b f (a + b − x) dx 
17. (c) We have, x = 1 vt
 ∫a ∫a 
2
⇒ x=
1 dx
t Q v = dx 
On adding Eqs. (i) and (ii), we get 2 dt  dt 
5π 2 π 2
2 dt dx
2I = ∫0 dx – ∫0 dx ⇒
t
=
x
⇒ 2I = (x)50π 2 − (x)π0 / 2 dt dx
⇒ 2⋅ ∫ = ∫
5π π t x
⇒ 2I = − = 2π ⇒ I= π
2 2 ⇒ 2log |t| + log |c| = log |x|
⇒ log (t 2 ⋅ c) = log x
14. (c) We have,
1  2 π 2π nπ  ⇒ x = t 2c
lim sec + sec2 + .... + sec2 
n→ ∞ n 4n 4n 4n  ⇒
dx
= 2tc
n
rπ πx  dt
sec2   = 2
1 1
= lim
n→ ∞
∑n  4n  ∫0 sec  4 
 d2x
r =1 ⇒ = 2c
1 dt 2
 πx 
tan  
4
= ⇒ acceleration f is constant.
π   4   0
4 4 18. (b) We have,
= ×1 =
π π equation of parabola y = x 2
Let P(α , α 2) is a point on the parabola,
15. (c) Given, y 2 = 2d (x + d) ... (i)
∴ y − α 2 = 2α (x − α)
⇒ 2y y1 = 2d ⇒ d = y y1
From Eq. (i),  
dy dy
Q Q = 2x ⇒ = 2α 
y 2 = 2y y1 (x + y y1 )  dx dx( α , α 2) 
 
⇒ y 2 − 2y y1 x = y y1 ⋅ 2y y1
⇒ y = 2αx − α 2
⇒ (y − 2y y1 x) = 4(y y1)3
2 2
Also, given y = − x 2 + 4 x − 4
So, degree of above equation is 3.

Page 33 of 44
 ∴ − x 2 + 4 x − 4 = 2αx − α 2 or t − 2= 0
⇒ x + 2x (α − 2) + (4 − α ) = 0
2 2 ⇒ t=2 [Q neglect t = − 3]
⇒ 2x = 2 ⇒ x = 1
Discriminant = 0
4(α − 2)2 − 4 (4 − α 2) = 0 21. (b) We have, Zr = sin 2πr − i cos 2πr
11 11
⇒ (α − 2) − (4 − α ) = 0
2 2
 2πr 2πr 
⇒ α 2 − 4α + 4 − 4 + α 2 = 0 = − i  cos + i sin 
 11 11 
⇒ α 2 − 2α = 0 i 2πr
= − ie 11
⇒ α = 0, α = 2
10 10 i 2πr
19. (d) 2b = (n + 2)th form ∴ ∑ Zr = − i∑ e 11

r =0 r =0
= a + (n + 2 − 1) d
⇒ 2b = a + (n + 1) d =−i×0 =0
2b − a 22. (c) We know that, if z1 , z2 and z3 are the vertices
⇒ d=
n+1 of an equilateral triangle. Then,
 2b − a  z12 + z22 + z32 − z1 z2 − z2z3 − z3z1 = 0 …(i)
∴ m th mean = a + m  
 n+1  Now, but we have
and also, b = (n + 2)th form z1 z
+ 2 =1
= 2a + (n + 2 − 1) d z2 z1
= 2a + (n + 1) d ⇒ z12 + z22 = z1 z2
b − 2a
⇒ d= ⇒ z12 + z22 − z1 z2 = 0
n+1
Here, z3 = 0
 b − 2a 
∴ m th mean = 2a + m   Hence, given points form an equilateral triangle.
 n+1 
23. (a) We have equations
According to the question,
x 2 + b1 x + c1 = 0
 2b − a   b − 2a 
a + m  = 2a + m   D1 = b12 − 4c1
 n+1   n+1 
a m and x + b2 x + c 2 = 0
2
⇒ =
b n+1− m D2 = b22 − 4c 2
Now, D1 + D2 = b12 + b22 − 4(c1 + c 2)
20. (c) We have,
= b12 + b22 − 2b1 b2 [Qb1 b2 = 2(c1 + c 2)]
x + log10 (1 + 2x ) = x log10 5 + log10 6
= (b1 − b2) ≥ 02
⇒ log10 (1 + 2x ) = x log10 5 + log10 6 − x
⇒ At least one of D1 and D2 are non-negative
= log10 5x + log10 6 − x log10 10
real roots.
= log10 (5x ⋅ 6) − log10 10x
 5x ⋅ 6 
24. (a) Number of ways of selection of n objects from
⇒ log10 (1 + 2x ) = log10  x  2n objects, where as n objects are identical in out
 10  of 2n objects.
5x ⋅ 6 6 n identical and no different object = 1 ways
⇒ 1 + 2x = = x
10x 2 = n C0
⇒ 2x (1 + 2x ) = 6 n −1 identical and 1 different object = 1 × n C1
⇒ t(1 + t) = 6 (let 2 = t)
x
n − 2 identical and 2 different object = 1 × n C2
⇒ t2 + t − 6 = 0 …………………………………………………
⇒ (t + 3) (t − 2) = 0 0 identical and n different objects = 1 × n Cn
⇒ t + 3= 0 = n C0 + n C1 + n C2 + ....... + n Cn = 2n

Page 34 of 44
25. (c) n Cr + 2 ⋅ n Cr + 1 + n
Cr + 13 −11 1
2
= 15 −7 −1 5 (R3 → R3 – R2)
= n Cr + n Cr + 1 + n Cr + 1 + n Cr + 2
0 0 −6
n+1 n+1
= Cr + 1 + Cr + 2 = 15 {0 − 0 − 6 (−13 − 77)}
n+1
(Qn Cr + n Cr + 1 = Cr + 1 ) = 15 {(− 6) (− 90)} = 90 × 90 ... (ii)
n+ 2 From Eqs. (i) and (ii),
= Cr + 2
B = A2
26. (a) (101)100 − 1 = (1 + 100)100 − 1
29. (c) We have,
= (1 + 100
C1 ⋅100 + 100
C21002 + ......) − 1 2rπi

= 100
C1100 + 100
C2(100)2 + a r = (cos 2rπ + i sin 2rπ)1 / 9 = e 9

2πi 4 πi 6πi
100
C3(100)3 + ........ + 100
C100 (100)100 e 9 e 9 e 9
a1 a2 a3 8 πi 10 πi 12πi
= 104 (1 + 100
C2 + 100
C3102 + ....
Now, a 4 a5 a6 = e 9 e 9 e 9
+ 100
C100 (100)98 14 πi 16 πi 18 πi
a7 a8 a9
e 9 e 9 e 9
= 10 (1 + an integer multiple of 10)
4

2πi 4 πi
27. (a) For greatest term of (1 + x)n , we have
1 e 9 e 9
n n+1 n 2πi 8 πi 2πi 4 πi
< < +1
2 1+ x 2 =e 9 ×e 9 1 e 9 e 9
14 πi 16πi 18 πi
n n+1 n+1 n
⇒ < and < +1 e 9 e 9 e 9
2 1+ x 1+ x 2
n+1 n+1 2πi 8 πi
⇒ 1+ x< and <1 + x
n2 n
+1 =e 9 ×e 9 ×0 (Q R1 and R2 are identical)
2 =0
n+1− n 2
⇒ x< 2r x n(n + 1)
n2
30. (d) We have, Sr = 6r − 1
2
y n2(2n + 3)
n + 1 − (n 2 − 1)
and < x 4r 3 − 2nr z n3(n + 1)
n+ 2
2 n
2∑ r x n(n + 1)
n+ 2 n
⇒ x< and < x r =1
n n+ 2 n n
⇒ ∑ Sr = ∑ (6r − 1) y n2(2n + 3)
2
n n+ 2
⇒ < x< r =1 r =1
n+ 2 n n
∑ (4r − 2nr) n3(n + 1)
3
z
28. (a) We have, r =1

−1 7 0 n(n + 1) x n(n + 1)
A= 2 1 −3 = n2(2n + 3) y n2(2n + 3)
3 4 1 n3(n + 1) z n3(n + 1)

= − 1 (1 + 12) − 7 (2 + 9) =0 (Q C1 and C3 are identical)

n
= − 13 − 77 = − 90
13 −11 5
... (i) Hence, ∑ Sr is independent of x, y, z and n.
r =1
And let B= −7 −1 25
−21 −3 −15
31. (c) For non-trivial solution,
1 4a a
13 −11 1 We have, 1 3b b = 0
= 3 × 5 −7 −1 5 1 2c c
−7 −1 −1
⇒ 1(3bc − 2bc) − (4ac − 2ac) + 1(4ab − 3ab) = 0

Page 35 of 44
 ⇒ bc − 2ac + ab = 0 35. (b) We have, P(H) = 1 , P(T) = 1
⇒ bc + ab = 2ac 2 2
⇒ b(a + c) = 2ac Now, P(X ≥ 1) = 1 − P(X = 0)
n
2ac
= 1 − n C0 (p)0 (q)n = 1 −  
⇒ b= 1
a+ c  2
⇒ a , b , c are in HP. Q
1
1 − n ≥ 0.9
2
32. (c) On the set R, 1
xρy ⇒ x − y is zero or irrational number. ⇒ 01. ≥
2n
Now, xρ x 1 1
⇒ x− x=0 ⇒ ≥
10 2n
⇒ρ is reflexive.
⇒ 2n ≥ 10
If xρy ⇒ x − y is zero or irrational.
⇒ n≥ 4
= − (y − x) is zero or irrational.
∴Minimum number of tossed = 4
⇒ yρx is zero or irrational.
⇒ρ is symmetric. 36. (a) Let X be the event that student will be
And if successful.
xρy ⇒ x − y is 0 or irrational. X1 be the event that student will be pass in test-I.
yρz ⇒ y − z is 0 or irrational. X 2 be the event that student will be pass in test-II.
Then, (x − y) + (y − z) = x − z may be 0 or rational. X 3 be the event that student will be pass in test-III.
⇒ρ is not transitive. ∴ P(X) = P(X1 ∩ X 2 ∩ X ′3) + P(X1 ∩ X ′2 ∩ X 3)
+ P(X1 ∩ X 2 ∩ X 3)
33. (d) On the set R of real numbers ⇒ P(X) = P(X1) ⋅ P(X 2) ⋅ P(X' 3) + P(X1) ⋅ P(X' 2) ⋅ P(X 3)
For reflexive, + P(X1) ⋅ P(X 2) ⋅ P(X 3)
xρx ⇒ (x , x) ∈ R 1 1 1 1
⇒ = p ⋅ q ⋅ + p(1 − q) + pq
⇒ x > |x|which is not true. 2 2 2 2
⇒ρ is not reflexive. 1 1 1 1 1
⇒ = p⋅ q⋅ + p⋅ − p⋅ q⋅ + p⋅ q⋅
For symmetric, 2 2 2 2 2
(x , y) ∈ R ⇒ x > |y| ⇒
1 1
= p⋅ + p⋅ q⋅
1
and (y, x) ∈ R ⇒ y > |x| 2 2 2
So, x > |y| ≠ y > |x| ⇒ (p + pq) = 1
⇒ ρ is not symmetric. ⇒ p(1 + q) = 1
For transitive, 37. (a) We have, sin 6θ + sin 4θ + sin 2θ = 0
(x , y) ∈ R ⇒ x > |y|, (y, z) ∈ R ⇒ y > |z|
⇒ sin 6θ + sin 2θ + sin 4θ = 0
⇒ x > |z| ⇒ (x , z) ∈ R
⇒ 2sin 4θ ⋅ cos 2θ + sin 4θ = 0
⇒ ρ is transitive.
⇒ sin 4θ(2cos 2θ + 1) = 0
34. (c) We have, f : R → R, defined by f (x) = e x ⇒ sin 4θ = 0 or 2cos 2θ + 1 = 0
and g : R → R defined by g(x) = x 2 −1 2π
⇒ 4θ = nπ or cos 2θ = = cos
2 3
Now, We have
nπ 2π
(gof) (x) = g( f (x)) ⇒ θ= or 2θ = 2nπ ±
4 3
= g(e x ) nπ π
⇒ θ= or θ = nπ ± , where n ∈ z
= (e x )2 4 3
= e 2x , ∀x ∈ R π
38. (c) We have, 0 ≤ A ≤
⇒ gof is injective and g is neither injective nor 4
−1  1 
surjective. tan  tan 2A + tan−1 (cot A) + tan−1 (cot 3 A)
⇒ gof is injective but g(x) is not bijective. 2 

Page 36 of 44
  cot A + cot 3 A 
= tan−1  tan 2A + tan−1 
1 41. (d) Given, point P(1, 5) image of the point P(1, 5)

2   1 − cot A 
4
about the line y = x is Q(5, 1) and image of the
 1 2tan A   tan A  point Q on line y = − x is R(− 1, − 5)
= tan−1  ⋅  + tan−1   P(1,5)
 2 1 − tan 2
A   tan A − 1 
2

 tan A   tan A 
= tan−1   − tan−1  
 1 − tan A   1 − tan A 
2 2

=0 Q(5,1)
R(–1,–5)

39. (b) Put x = x' + 2 ∴ Required circumcentre = Mid-point of P and R

1 − 1 5 − 5
and y = y' + 3 =  ,  = (0, 0)
∴ x 2 + y2 − 4 x − 6 y + 9 = 0  2 2 

⇒ (x' + 2)2 + (y ' + 3)2 − 4(x' + 2) 42. (b) Here, AB = (5 + 1)2 + (1 + 7)2 = 36 + 64 = 10
− 6(y' + 3) + 9 = 0 A(–1,–7)
⇒ x' 2 + 4 + 4 x' + y ' 2 + 9
10 P
+ 6 y ' − 4 x' − 8 − 6 y ' − 18 + 9 = 0
⇒ x ′2 + y′2 − 4 = 0 B(5,1) C(1,4)
5
⇒ x 2 + y2 = 4
BC = (1 − 5)2 + (4 − 1)2 = 16 + 9 = 5
40. (d) We have equation of circle By angle bisector theorem,
x 2 + y 2 + 4 x − 6 y + 9sin2 α + 13cos2 α = 0 AP : CP = 10 : 5 = 2 : 1
Here, C ≡ (− 2, 3)  2 × 1 + 1 × (− 1) 2 × 4 + 1 × (− 7)  1 1 
∴ P ,  = P , 
Radius = (− 2)2 + (3)2 − (9sin2 α + 13cos2 α)  2+ 1 2+ 1   3 3

= 4 + 9 − 9sin2 α − 13cos2 α Required equation of BP is

1
= 13 − 131
( − sin2 α) − 9sin2 α −1
y −1 = 3 (x − 5)
1
= 13sin2 α − 9sin2 α −5
3
= 4sin2 α = 2sin α −2
⇒ y −1 = (x − 5)
−14
A
⇒ 7y − 7 = x − 5
⇒ 7y = x + 2
α
P(h,k) α C(–2,3) 43. (a) Given, equation of circle is
x 2 + y 2 + 4 x + 6 y − 12 = 0
Centre C(−2, −3)
AC
Here, sinα = and radius = (−2)2 + (−3)2 + 12 = 5
PC
⇒ PC sin α = AC
S
⇒ PC 2 sin2 α = AC 2 = (2sin α)2
C2
⇒ [(h + 2)2 + (k − 3)2]sin2 α = 4 sin2 α (2,–3)
⇒ (h + 2)2 + (k − 3)2 = 4 C1
P
(–2,–3)
⇒ h + 4 + 4h + k + 9 − 6k = 4
2 2

⇒ h2 + k2 + 4h − 6k + 9 = 0
Hence, locus of a point is
x 2 + y 2 + 4 x + 6 y − 12 = 0
x 2 + y2 + 4 x − 6 y + 9 = 0

Page 37 of 44
  2 
46. (c, d) Centre of circle =  t1 + t2 , (t1 + t2)
2
∴ C1 C2 = (2 + 2)2 + (−3 + 3)2
 2 
= (4)2 + (0)2 = 4
2
A(t1,2t1)
∴ Radius of circle, S Y
2
B(t2,2t2)
= (4) + (5) = 16 + 25 =
2 2
41 unit
r
44. (c) Given, AM = 2AB X′ X

y2=4x

Y′
(x1,y1) Since, circle touch the x-axis, so equation of tangent
A(0,3)
B M is y = 0
⇒ B is mid-point of AM. Q Radius = Perpendicular distance from centre to
0 + x1 3 + y1  the tangent
∴Coordinate of B is  ,  ⇒ Radius = |t1 + t2| = r
 2 2 
2 2
x y + 3 Slope of AB = =
=  1 , 1  t1 + t2 ± r
 2 2 
Since, B lies on the circle x 2 + 4 x + (y − 3)2 = 0 Y
47. (d)
P(at ,2at)
2
2
y + 3
2 ar)
∴ 1  + 4  1  +  1 − 3 = 0 r2 ,2
x x
R(a
 2  2  2 
2
x12 y −
+ 2x1 +  1
3 F K(2a, 0)
⇒  =0 X′ X
4  2 
x12 y 2 + 9 − 6 y1
⇒ + 2x1 + 1 =0
4 4 Q y 2 = 4ax
⇒ x12 + y12 + 8 x1 − 6 y1 + 9 = 0
Y′
Hence, locus of a point is a −2a 
Here, coordinate of Q will be  2 , .
x 2 + y2 + 8 x − 6 y + 9 = 0 t t 
2
45. (a) Given equation of ellipses is x 2 + 9 y2 = 9 Slope of QR =
1
x2 y2 r−
⇒ + =1 t
9 1 2at 2t
Slope of PK = 2 =
Here, a = 3, b = 1 at − 2a t 2 − 2
c = (3)2 − (1)2 = 8 Since, Slope of QR = Slope of PK
c 2 2t
∴Eccentricity of ellipse, e = ∴ =
1 t2 − 2
a r−
8 t
⇒ e=
3 t2 − 1
⇒ r=
3 t
∴Eccentricity of hyperbola =
8 2 2
2 48. (a) Since, point P on the ellipse x + y = 1
b 9 9 4
⇒ 1+ =
a2 8 ∴ P(3cosθ, 2sinθ)
b2 1 Now, equation of line parallel of Y-axis is
⇒ =
a2 8 x = 3cosθ
⇒ a2 : b2 = 8 :1 and above line meets circle at Q
∴ Q(3cosθ, 3sinθ)

Page 38 of 44
 Given,
PR 1
= ⇒ 4λ + 2 + 64λ − 88 + 9λ + 9 = 0
RQ 2 ⇒ 77λ − 77 = 0
R(h, k) ⇒ λ =1
P Q ∴Required foot of perpendicular,
(3 cos q, 2 sin q) (3 cos q, 3 sin q)
P(4, 5, − 2)
3cosθ + 6 cosθ 3sinθ + 4sinθ
∴h= , k=
3 3 51. (a)
7 20 y
⇒ h = 3cosθ, k = sinθ
3
3k
⇒ cosθ = h 3, sinθ = x
7 x 2 + y 2 = (20)2 = 400
9k2
Now, cos θ + sin θ = h 9 +
2 2 2
=1 We have,
dy
= 2ft /sec
49 dt
x 2 9 y2 When x = 12
Hence, locus of a point is + =1
9 49 then (12)2 + y 2 = 400
49. (a) Equation of line through Q (1, − 2, 3) and ⇒ 144 + y 2 = 400

parallel to the line

x y z
= = ⇒ y 2 = 400 − 144 = 256
1 4 5 ⇒ y = 16
x −1 y + 2 z − 3
is = = =λ (say) Now, 2x
dx dy
+ 2y = 0
1 4 5 dt dt
Since, point P lies on above line. dx dy
⇒ x =− y
∴ P(λ + 1, 4λ − 2, 5λ + 3) dt dt
Since, P lies on the given plane.  dx 
⇒ 12  = − 16(2)
∴ 2(λ + 1) + 3(4λ − 2) − 4(5λ + 3) + 22 = 0  dt 
⇒ 2λ + 2 + 12λ − 6 −20λ − 12 + 22 = 0 dx −8
⇒ =
⇒ − 6λ + 6 = 0 dt 3
⇒ λ =1 1
52. (b) Here, let p=
∴ P(2, 2, 8) m
∴ PQ = (2 − 1)2 + (2 + 2)2 + (3 − 8)2 then (a p + b p)1 p = (a1 m + b1 m)m
⇒ PQ = 1 + 16 + 25 = 42 = a + b + k, k ≥ 0
∴ a p + b p ≥ (a + b)p ≥ (a + b)
50. (d) Equation of line joining points (0, − 11, 4) and
⇒ J(p) ≥ I (p)
(2, − 3, 1) is
x − 2 y + 3 z −1 53. (c) We have,
= = =λ (say)
2 8 −3 → → →
δ = α + λβ
Q(1, 8, 4)
= (i + j + k$) + λ (i$ − $j − k$)
$ $
→
⇒ δ = (1 + λ)i$ + (1 − λ) $j + (1 − λ)k$
→→
δ. γ 1
P(2λ+2, 8λ–3, – 3λ+1) Given, =
→ 3
| γ|
Let P is any point of the above line then coordinate
(1 + λ) (− 1) + (1 − λ) ()
1 + (1 − λ) (− 1) 1
of P is (2λ + 2, 8λ − 3, − 3λ + 1). ⇒ =
∴DR’s of PQ is (2λ + 1, 8λ − 11, − 3λ − 3) 3 3
Now, (2λ + 1) (2) + (8λ − 11) (8) + (− 3λ − 3) ⇒ λ=−2
→
(− 3) = 0 ∴ δ = − i$ + 3$j + 3k$

Page 39 of 44
54. (c) α = λ  β × γ  = λ(|β| |γ| |sin 30°|  k k  where, k = 1 
→ → → → →
⇒ A=   
   − k k  2
→  → 1
 k k  k k  0 2k2 
⇒ |α| = |λ| |β| |γ|⋅  ⇒ A2 =     =  
 2  − k k  − k k  −2k 2
0 
1
⇒ 1 = |λ|⋅ 1 ⋅ 1 ⋅  0 2k2   0 2k2 
2 A4 =    
⇒ |λ| = 2  −2k
2
0   −2k 2
0 
⇒ λ=±2  −4 × 1 0 
→ → →   −4k4 0   4
A4 =   = 
∴ α = ± 2 β × γ 
 0 −4k4   0 1
  −4 × 
 4
55. (d) Let z1 = x1 + iy1 and z2 = x 2 + iy2  −1 0 
⇒ A4 =  
Re (z1) > 0 ⇒ x1 > 0  0 −1
and Im (z2) < 0  −1 0   −1 0   1 0
⇒ y2 < 0 ⇒ A8 =    = 
 0 −1  0 −1  0 1 
Given, |z1| = |z2|
⇒ |z1|2 = |z22| 58. (d) We have, ρ = {(x , y) ∈ N × N : 2x + y = 41}
⇒ z1 z1 = z2z2 For reflexive,
 z1 + z2   z1 + z2  xρx ⇒ 2x + x = 41
Now,   +  
 z1 − z2   z1 − z2  ⇒ 3x = 41
 z + z2   z1 + z2  41
⇒ x= ∉N
= 1  +   3
 z1 − z2   z1 − z2 
So, ρ is not reflexive.
z z + z2z1 − z1 z2 − z2z2 + z1 z1 + z1 z2 − z2z1 + z2z2
= 1 1 For symmetric,
(z1 − z2) (z1 − z2)
xρy ⇒ 2x + y = 41
2(| z1|2 − |z2|2)
= =0 (Q|z1|2 = |z2|2) and yρx ⇒ 2y + x = 41
(z1 − z2) (z1 − z2)
⇒ xρy ≠ yρx
z + z2
= 1 is purely imaginary. So, ρ is not symmetric.
z1 − z2
For transitive,
56. (a) Given, numbers are 1, 2, 3 ........ 20 xρy ⇒ 2x + y = 41
Here, number of ways of selecting four consecutive and yρz ⇒ 2y + z = 41
numbers = 17 ⇒ xρ/ z
∴Required number of selecting 4 non-consecutive ⇒ρ is not transitive.
numbers = 20 C4 − 17 (1 + x)a (2 + x)b 1
20 × 19 × 18 × 17 59. (a) Given, f (x) = (1 + x) (2 + x)b
a
= − 17 1
4 × 3× 2×1
(2 + x)b 1 (1 + x)a
= 285 × 17 − 17
= 284 × 17 For constant term put x = 0
n 1 2b 1
 cos π 4 sin π 4
57. (b) We have,  π π f (0) = 1 1 2b
 − sin cos 
 4 4  2b 1 1
 1 1 
  = 11
( − 2b) − 2b(1 − 22b) + 11
( − 2b)
Let A =  2 2
− 1 1  = 1 − 2b − 2b + 23b + 1 − 2b
 2 2
= 2 − 3⋅ 2b + 23b

Page 40 of 44
60. (a) Equation of line AB is 61. (c) Given, equation of circle is
x
+
y
=1 x 2 + y 2 − 2x − 4 y − 20 = 0
5 −3
Center (1, 2) and radius = ()
1 2 + (2)2 + 20 = 5
⇒ 3x −5y = 15
Y Y y=7
B(1,7) C

=0
Q R(x,

0
y)

–2
(1,2)

y
A

–4
A(5

3x
,0)
X
X O D(4,–2)
P

Coordinate of intersecting point of tangents at B

B(0,–3) and D is C(16, 7).
∴ Area of quadrilateral ABCD
= 2 × ar(∆ABC)
Perpendicular line to AB is
1
5x + 3y = λ = 2 × × 15 × 5= 75sq units
2
λ
Coordinate of P is  , 0 π
5  62. (b) At x=−
2
and coordinate of Q is ( 0, λ 3)
LHL = − 2
Now, equation of line AQ is
RHL = − A + B
y
x 5+ =1 For continuity, LHL = RHL = f(− π 2)
λ3
⇒ −A + B = 2 ... (i)
⇒
x 3y
+ =1 At x = π 2
5 λ LHL = A + B
⇒
3y
=1 −
x RHL = 0
λ 5 For continuity, LHL = RHL = f(π 2)
1 1  x ⇒ A+ B=0 ... (ii)
⇒ = 1 −  ... (i)
λ 3y  5 On solving Eqs. (i) and (ii), we get
and equation of line BP is A = −1and B = 1
x y 63. (c) Given equation of curve,
+ =1
λ 5 −3 y = x2 − x + 1
5x y dy
⇒ − =1 ⇒ = 2x − 1
λ 3 dx
1 1 y  1
⇒ =  + 1 ... (ii) Slope of normal =
λ 5x  3  1 − 2x
From Eqs. (i) and (ii), Now, at x1 = 0, y1 = 1
1  x 1 y  ∴Slope of normal at (0, 1) = 1
1 −  =  + 1 ∴ Equation of normal, y − 1 = 1(x − 0)
3y  5  5x  3 
⇒ x − y+1= 0 .. (i)
5x 1 −  = 3y + 1
x y
⇒ At x 2 = − 1, y2 = 3
 5 3 
1
⇒ 5x − x 2 = y 2 + 3y Slope of normal at (−1, 3) =
3
⇒ x 2 + y 2 − 5x + 3y = 0 1
Equation of normal, y − 3 = (x + 1)
which is a circle. 3
⇒ 3y − 9 = x + 1

Page 41 of 44
 ⇒ x − 3y + 10 = 0 ... (ii) 1 1
⇒ ∫0 − x dx < I < ∫0 x dx
2 2
5 19
At x 3 = , y3 = 1 1
2 4  − x3   x3 
⇒   <I< 
 2 19 
Slope of normal at  ,  = −
1  3 0  3 0
5 4 4 −1 1
⇒ <I<
= −  x − 
19 1 5
Equation of normal, y − 3 3
4 4 2
43 67. (c, d) Given, curve,12y = x 3
⇒ x + 4y =
dy dx
2 and > ... (i)
⇒ 2x + 8 y = 43 ... (iii) dt dt
dy dx
Here, intersecting point of Eqs. (i) and (ii) is  ,  12 = 3x 2
7 9 Now, ... (ii)
 2 2 dt dt
and normal (iii) passes through it. Hence, normals From Eqs. (i) and (ii), we get
are concurrent. dx dx
3x 2 > 12
dt dt
64. (b) Let f (x) = x log x + x − 3
⇒ 3x 2 > 12
1
⇒ f ′(x) = x ⋅ + log x + 1 ⇒ x2 − 4 > 0
x
⇒ f ′(x) = log x + 2 > 0 ⇒ (x − 2) (x + 2) > 0
⇒ f()1 = − 2 and f (3) = 3log 3, f ()
1 ⋅ f (3) < 0 ⇒ x ∈ (− ∞ , − 2) ∪ (2, ∞)
Hence, exactly one root in x ∈(1, 3) as f (x) > 0 68. (b) Given, equation of circle
65. (c) Equation of PQ is 2x − y = 12 x 2 + y 2 = 2ax

Y ⇒ (x − a)2 + y 2 = a 2

2 ,2t)
Q(9,6) and equation of parabola is y 2 = ax , a > 0
R(t Y
A
X′ X x2 + y2 = 2ax

y2=4x X′ X
P(4,–4) (a,0)
Y′
y2 = ax
Perpendicular distance Y′
2t 2 − 2t − 12 2 Intersection points of circle and parabola
AR = = (t − 3) (t + 2)
5 5 ⇒ x 2 + ax = 2ax
1 ⇒ x 2 = ax
AR is Maximum, at t =
2
⇒ x 2 − ax = 0
∴R is  , 1
1
4  ⇒ x(x − a) = 0
⇒ x = 0, a
1 3
66. (b) I = ∫ x cos 32x dx Intersecting points are (0, 0) and (a , a).
0 2+ x
πa 2 a
Here, −1 < cos 3x < 1 ∴ Required area = − ∫ axdx
4 0
⇒ − x 3 < x 3 cos 3x < x 3 a
πa 2  x3 2 
−x −x
3
−x 3 3
x cos 3x 3 = − a 
⇒ < < < 4  3 2 0
x2 x 2 + x2 2 + x2
πa 2 2a 2 π 2
x3 x3 x3 = − = a 2  − 
< < < 2 4 3  4 3
2+ x 2
x x

Page 42 of 44
69. (a, d) Let α and β are the roots of x 2 + ax + b = 0 1 1 1
1
⇒ k k 1 = ± h2
and the roots of x − cx + d = 0 are α and β .
2 4 4
2
2− k k 1
Now, α + β = − a, αβ = b ... (i)
and α 4 + β 4 = c , α 4β 4 = d ... (ii) ⇒ 1(k − k) − 1(k − 2 + k) + 1(k2 − 2k + k2) = ± 2h2

From Eqs. (i) and (ii), ⇒ − (2k − 2) + (2k2 − 2k) = ± 2h2

b 4 = d and α 4 + β 4 = c ⇒ 2 − 2k + 2k2 − 2k = ± 2h2
(α + β ) − 2(αβ) = c
2 2 2 2
⇒ 2k2 − 4k + 2 = ± 2h2
⇒ [(α + β) − 2αβ] − 2(αβ) = c
2 2 2
⇒ k2 − 2k + 1 = ± h2
⇒ (a − 2b) − 2b = c
2 2 2
Hence, locus of a point is
⇒ 2b 2 + c = (a 2 − 2b)2 ⇒ (k − 1)2 = h2
⇒ 2b 2 + c = a 4 + 4b 2 − 4a 2b y −1 = ± x
⇒ 2b − c = 4a b − a
2 2 4 ⇒ x = y − 1or x = − (y − 1)
⇒ 2b 2 − c = a 2(4b − a 2) 73. (b) Given, 2a1 = 2 sinθ
and for equation x 2 − 4bx + 2b 2 − c = 0 ⇒ a1 = sinθ
D = (4b)2 − 41
() (2b 2 − c) and 3x 2 + 4 y 2 = 12
= 16b 2 − 8b 2 + 4c = 8b 2 + 4c x2 y2
⇒ + =1
= 4(2b + c) = 4(a − 2b) > 0 = real root
2 2 2
4 3
Now, f (0) = 2b 2 − c = a 2(4b − a 2) < 0 (Qa 2 > 4b) Here, a 2 = 4 and b 2 = 3
= roots are opposite in sign ∴ b 2 = a 2(1 − e 2)
70. (b, c) Required number of ways = 20
C2 × 2! ⇒ 3 = 4 (1 − e 2)
= 20
P2 ⇒ e2 = 1 −
3 1
=
4 4
 0 −1 −1
1
71. (a, c) A = 1 0 −1 ⇒ e=
  2
1 1 0 
Focus, F (ae , 0) = F  2 × , 0
1
 0 1 1  2 
⇒ A =  −1 0 1  = − A
′
  = F (1, 0)
 −1 −1 0
For hyperbola foci are same
⇒ A is a skew-symmetric matrix. a1 e1 = ae = 1
|A| = 0 + 1(0 + 1) − 11
( − 0)
∴ (sinθ) e1 = 1
= 0 + 1 − 1 = 0 = Singular
⇒ e1 = cosec θ
⇒ A is not invertible.
and b12 = a12(e12 − 1) = a12e12 − a12
72. (a, b) Given, ar (∆ABC) = h2
⇒ b12 = 1 − sin2 θ = cos2 θ
x
P(h,k) y= x 2 y2
y =k − =1
C(2–k,k) B(k,k) a12 b12
x2 y2
A(1,1) ⇒ − =1
sin θ cos2 θ
2

x+
y=
⇒ x 2cosec2 θ − y 2 sec2 θ = 1
y 2

Page 43 of 44
74. (a, c) f (x) = cos π  75. (c) Given, y = log a (x + x 2 + 1), a > 0, a ≠ 1
 x
π −π π π ⇒ a y = (x + x 2 + 1)
⇒ f ′(x) = − sin    2  = 2 sin
 x  x  x x ⇒ a− y =
1
For increasing function, f ′(x) > 0 x+ x2 + 1
π π
⇒ sin  > 0 ⇒ 2kπ < < (2k + 1) π = x2 + 1 − x
 x x
a y − a− y
⇒
1
> x>
1 ⇒ a y − a − y = 2x ⇒ x =
2k 2k + 1 2
e y log a − e − y log a
For decreasing function, f ′(x) < 0 ⇒ f −1 (y) =
π 2
⇒ sin  < 0  e x − e −x 
 x ⇒ f −1 (y) = sinh (y log a) Q = sinh (x)
π  1 1   2 
⇒ ∈ [(2k + 1) π , (2k + 2) π] ⇒ x ∈  , 
x  2k + 2 2k + 1 

Page 44 of 44