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TOPICS
& Symmetry operators and symmetry elements
& Point groups
& An introduction to character tables
& Infrared spectroscopy
& Chiral molecules
Fig. 4.1 Rotation of the trigonal planar BF3 molecule through 1208 generates a representation of the structure that is
indistinguishable from the first; one F atom is marked in red simply as a label. A second 1208 rotation gives another
indistinguishable structural representation.
Rotation about an n-fold axis of symmetry prime marks, e.g. C2 , C2 ’ and C2 ’’. We return to this in the
discussion of XeF4 (see Figure 4.4).
The symmetry operation of rotation about an n-fold axis
(the symmetry element) is denoted by the symbol Cn , in
3608 Self-study exercises
which the angle of rotation is ; n is an integer, e.g. 2, 3
n
1. Each of the following contains a 6-membered ring: benzene,
or 4. Applying this notation to the BF3 molecule in borazine (see Figure 13.21), pyridine and S6 (see Box 1.1).
Figure 4.1 gives a value of n ¼ 3 (equation 4.1), and therefore Explain why only benzene contains a 6-fold principal rotation
we say that the BF3 molecule contains a C3 rotation axis; in axis.
this case, the axis lies perpendicular to the plane containing
the molecule. 2. Among the following, why does only XeF4 contain a 4-fold
principal rotation axis: CF4 , SF4 , [BF4 ] and XeF4 ?
3608
Angle of rotation ¼ 1208 ¼ ð4:1Þ 3. Draw the structure of [XeF5 ] . On the diagram, mark the C5
n
axis. The molecule contains five C2 axes. Where are these
In addition, BF3 also contains three 2-fold (C2 ) rotation axes, axes? [Ans. for structure, see worked example 2.7]
each coincident with a BF bond as shown in Figure 4.2.
4. Look at the structure of B5 H9 in Figure 13.26a. Where is the
If a molecule possesses more than one type of n-axis, the
C4 axis in this molecule?
axis of highest value of n is called the principal axis; it is
the axis of highest molecular symmetry. For example, in
BF3 , the C3 axis is the principal axis.
In some molecules, rotation axes of lower orders than the
Reflection through a plane of symmetry
principal axis may be coincident with the principal axis. For
example, in square planar XeF4 , the principal axis is a C4 (mirror plane)
axis but this also coincides with a C2 axis (see Figure 4.4).
If reflection of all parts of a molecule through a plane
Where a molecule contains more than one type of Cn axis
produces an indistinguishable configuration, the plane is a
with the same value of n, they are distinguished by using
plane of symmetry; the symmetry operation is one of reflec-
tion and the symmetry element is the mirror plane (denoted
by ). For BF3 , the plane containing the molecular frame-
work (the brown plane shown in Figure 4.2) is a mirror
plane. In this case, the plane lies perpendicular to the vertical
principal axis and is denoted by the symbol h .
The framework of atoms in a linear, bent or planar
molecule can always be drawn in a plane, but this plane can
be labelled h only if the molecule possesses a Cn axis perpen-
dicular to the plane. If the plane contains the principal axis, it is
labelled v . Consider the H2 O molecule. This possesses a C2
axis (Figure 4.3) but it also contains two mirror planes, one
containing the H2 O framework, and one perpendicular to it.
Each plane contains the principal axis of rotation and so
may be denoted as v but in order to distinguish between
them, we use the notations v and v ’. The v label refers to
the plane that bisects the HOH bond angle and the v ’
label refers to the plane in which the molecule lies.
Fig. 4.2 The 3-fold (C3 ) and three 2-fold (C2 ) axes of A special type of plane which contains the principal
symmetry possessed by the trigonal planar BF3 molecule. rotation axis, but which bisects the angle between two
90 Chapter 4 . An introduction to molecular symmetry
Fig. 4.4 The square planar molecule XeF4 . (a) One C2 axis coincides with the principal (C4 ) axis; the molecule lies in a h
plane which contains two C2 ’ and two C2 ’’ axes. (b) Each of the two v planes contains the C4 axis and one C2 ’ axis.
(c) Each of the two d planes contains the C4 axis and one C2 ’’ axis.
Chapter 4 . Symmetry operations and symmetry elements 91
(4.7) (4.8)
Show that B2 Br4 has one less plane of symmetry than B2 F4 Self-study exercises
which is planar.
1. Draw the structures of each of the following species and
3. Ga2 H6 has the following structure in the gas phase: confirm that each possesses a centre of symmetry: CS2 ,
[PF6 ] , XeF4 , I2 , [ICl2 ] .
2. [PtCl4 ]2 has a centre of symmetry, but [CoCl4 ]2 does not.
One is square planar and the other is tetrahedral. Which is
which?
3. Why does CO2 possess an inversion centre, but NO2 does not?
4. CS2 and HCN are both linear. Explain why CS2 possesses a
centre of symmetry whereas HCN does not.
(4.3) (4.4)
Identity operator
All objects can be operated upon by the identity operator E.
This is the simplest operator (although it may not be easy to
appreciate why we identify such an operator!) and effectively
identifies the molecular configuration. The operator E leaves
(4.5) (4.6) the molecule unchanged.
92 Chapter 4 . An introduction to molecular symmetry
3608
Fig. 4.5 An improper rotation (or rotation–reflection), Sn , involves rotation about followed by reflection through a
n
plane that is perpendicular to the rotation axis. The diagram illustrates the operation about one of the S4 axes in CH4 ; three
S4 operations are possible for the CH4 molecule. [Exercise: where are the three rotation axes for the three S4 operations in CH4 ?]
First draw the structures of cis- and trans-N2 F2 ; both are 5. The consequence of the different types of C2 axes,
planar molecules. and the presence of the v plane in the cis-isomer, is
that the symmetry planes containing the cis- and
trans-N2 F2 molecular frameworks are labelled v ’ and
h respectively.
Self-study exercises
1. The identity operator E applies to each isomer. 1. How do the rotation axes and planes of symmetry in Z- and E-
2. Each isomer possesses a plane of symmetry which con- CFH¼CFH differ?
tains the molecular framework. However, their labels
2. How many planes of symmetry do (a) F2 C¼O, (b) ClFC¼O
differ (see point 5 below).
and (c) [HCO2 ] possess? [Ans. (a) 2; (b) 1; (c) 2]
3. The cis-isomer contains a C2 axis which lies in the plane
of the molecule, but the trans-isomer contains a C2 axis
which bisects the NN bond and is perpendicular to
the plane of the molecule.
Worked example 4.2 Symmetry elements in NH3
The symmetry elements for NH3 are E, C3 and 3v . (a) Draw
the structure of NH3 . (b) What is the meaning of the E opera-
tor? (c) Draw a diagram to show the symmetry elements.
(b) The E operator is the identity operator and it leaves the In addition, BCl3 contains a h plane and three C2 axes
molecule unchanged. (see Figure 4.2).
(c) The C3 axis passes through the N atom, perpendicular to
a plane containing the three H atoms. Each v plane
contains one NH bond and bisects the opposite
HNH bond angle.
Worked example 4.3 Trigonal planar BCl3 versus 2. How do the symmetry elements of ClF3 and BF3 differ?
[Ans: BF3 , as for BCl3 above; ClF3 , E, v ’, v , C2 ]
trigonal pyramidal PCl3
Fig. 4.6 Successive C3 rotations in NH3 are distinguished using the notation C3 , C32 and C33 . The effect of the last operation is the
same as that of the identity operator acting on NH3 in the initial configuration.
Similar statements can be written to show the combined elements of a particular point group. These are listed in
effects of successive operations. For example, in planar character tables (see Sections 4.5 and 5.4, and Appendix 3)
BCl3 , the S3 improper axis of rotation corresponds to rotation which are widely available.
about the C3 axis followed by reflection through the h plane. Table 4.1 summarizes the most important classes of point
This can be written in the form of equation 4.4. group and gives their characteristic types of symmetry
S 3 ¼ C3 h ð4:4Þ elements; E is, of course, common to every group. Some
particular features of significance are given below.
Table 4.1 Characteristic symmetry elements of some important classes of point groups. The characteristic symmetry elements of
the Td , Oh and Ih are omitted because the point groups are readily identified (see Figures 4.8 and 4.9). No distinction is made in
this table between v and d planes of symmetry. For complete lists of symmetry elements, character tables (Appendix 3) should be
consulted.
Cs E, one plane
Ci E, inversion centre
Cn E, one (principal) n-fold axis
Cnv E, one (principal) n-fold axis, n v planes
Cnh E, one (principal) n-fold axis, one h plane, one The Sn axis necessarily follows from the Cn axis and h plane.
Sn -fold axis which is coincident with the Cn axis For n ¼ 2, 4 or 6, there is also an inversion centre.
Dnh E, one (principal) n-fold axis, n C2 axes, one h The Sn axis necessarily follows from the Cn axis and h plane.
plane, n v planes, one Sn -fold axis For n ¼ 2, 4 or 6, there is also an inversion centre.
Dnd E, one (principal) n-fold axis, n C2 axes, n v For n ¼ 3 or 5, there is also an inversion centre.
planes, one S2n -fold axis
Td Tetrahedral
Oh Octahedral
Ih Icosahedral
Fig. 4.7 Linear molecular species can be classified according to whether they possess a centre of symmetry (inversion centre) or
not. All linear species possess a C1 axis of rotation and an infinite number of v planes; in (a), two such planes are shown and
these planes are omitted from (b) for clarity. Diagram (a) shows an asymmetrical diatomic belonging to the point group C1v , and
(b) shows a symmetrical diatomic belonging to the point group D1h .
D1h point group [NH4 ]þ , P4 (Figure 4.9a) and B4 Cl4 (Figure 4.9b). Those
with octahedral symmetry include SF6 , [PF6 ] , W(CO)6
Symmetrical diatomics (e.g. H2 , [O2 ]2 ) and linear poly- (Figure 4.9c) and [Fe(CN)6 ]3 . There is no centre of sym-
atomics that contain a centre of symmetry (e.g. [N3 ] , metry in a tetrahedron but there is one in an octahedron,
CO2 , HCCH) possess a h plane in addition to a C1 axis and this distinction has consequences with regard to the
and an infinite number of v planes (Figure 4.7). These observed electronic spectra of tetrahedral and octahedral
species belong to the D1h point group. metal complexes (see Section 21.7). Members of the
icosahedral point group are uncommon, e.g. [B12 H12 ]2
(Figure 4.9d).
Td , Oh or Ih point groups
Molecular species that belong to the Td , Oh or Ih point Determining the point group of a molecule
groups (Figure 4.8) possess many symmetry elements, or molecular ion
although it is seldom necessary to identify them all before
the appropriate point group can be assigned. Species with The application of a systematic approach to the assignment
tetrahedral symmetry include SiF4 , [ClO4 ] , [CoCl4 ]2 , of a point group is essential, otherwise there is the risk that
96 Chapter 4 . An introduction to molecular symmetry
Self-study exercises
Fig. 4.10 Scheme for assigning point groups of molecules and molecular ions. Apart from the cases of n ¼ 1 or 1, n most
commonly has values of 2, 3, 4, 5 or 6.
Apply the strategy shown in Figure 4.10: Worked example 4.6 Point group assignments: 3
START
Is the molecule linear? No To what point group does POCl3 belong?
Does PF5 have Td , Oh or
Ih symmetry? No The structure of POCl3 is:
Is there a Cn axis? Yes; a C3 axis containing the
P and two axial F atoms
Are there three C2 axes
perpendicular to the Yes; each lies along an
principal axis? equatorial PF bond
Is there a h plane
(perpendicular to the Yes; it contains the P and
principal axis)? three equatorial F atoms.
STOP
The point group is D3h .
Self-study exercises
Apply the strategy shown in Figure 4.10: Follow the scheme in Figure 4.10:
START START
Is the molecule linear? No Is the molecule linear? No
Does POCl3 have Td , Oh or No (remember that Does S8 have Td , Oh or Ih
Ih symmetry? although this molecule is symmetry? No
loosely considered as Is there a Cn axis? Yes; a C4 axis running
being tetrahedral in through the centre of the
shape, it does not ring; perpendicular to the
possess tetrahedral plane of the paper in
symmetry) diagram (a)
Is there a Cn axis? Yes; a C3 axis Are there four C2 axes
running along the OP perpendicular to the principal Yes; these are most easily
bond axis? seen from diagram (c)
Are there three C2 axes Is there a h plane
perpendicular to the (perpendicular to the
principal axis? No principal axis)? No
Is there a h plane Are there n d planes Yes; these are most easily
(perpendicular to the (containing the principal seen from diagrams (a)
principal axis)? No axis)? and (c)
Are there n v planes Yes; each contains the
STOP
(containing the principal one Cl and the O and P
axis)? atoms The point group is D4d .
STOP
The point group is C3v .
Self-study exercises
†
See O.J. Curnow (2007) Journal of Chemical Education, vol. 84, p. 1430.
Chapter 4 . Character tables: an introduction 99
Table 4.2 The character table for the C2v point group. For The character table summarizes this information by stating
more character tables, see Appendix 3. ‘2C4 C2 ’, referring to C41 and C43 , and C42 ¼ C2 . The opera-
tion C44 is taken care of in the identity operator E. The two
C2v E C2 v ðxzÞ v ’ð yzÞ sets of C2 axes that we showed in Figure 4.4 and labelled
as C2 ’ and C2 ’’ are apparent in the character table, as are
A1 1 1 1 1 z x2 , y2 , z2 the h , two v and two d planes of symmetry. The symmetry
A2 1 1 1 1 Rz xy
B1 1 1 1 1 x; Ry xz operations that we did not show in Figure 4.4 but that are
B2 1 1 1 1 y, Rx yz included in the character table are the centre of symmetry,
i, (which is located on the Xe atom in XeF4 ), and the S4
axes. Each S4 operation can be represented as (C4 h Þ:
The left-hand column in a character table gives a list of
Each point group has an associated character table, and symmetry labels. These are used in conjunction with the
that for the C2v point group is shown in Table 4.2. The numbers, or characters, from the main part of the table to
point group is indicated at the top left-hand corner and the label the symmetry properties of, for example, molecular
symmetry elements possessed by a member of the point orbitals or modes of molecular vibrations. As we shall see
group are given across the top row of the character table. in Chapter 5, although the symmetry labels in the character
The H2 O molecule has C2v symmetry and when we looked tables are upper case (e.g. A1 , E, T2g ), the corresponding
at the symmetry elements of H2 O in Figure 4.3, we labelled symmetry labels for orbitals are lower case (e.g. a1 , e, t2g ).
the two perpendicular planes. In the character table, taking Symmetry labels give us information about degeneracies as
the z axis as coincident with the principal axis, the v and follows:
v ’ planes are defined as lying in the xz and yz planes, respec-
tively. Placing the molecular framework in a convenient . A and B (or a and b) indicate non-degenerate;
orientation with respect to a Cartesian set of axes has . E (or e) refers to doubly degenerate;
many advantages, one of which is that the atomic orbitals . T (or t) means triply degenerate.
on the central atom point in convenient directions. We In Chapter 5, we use character tables to label the symmetries
return to this in Chapter 5. of orbitals, and to understand what orbital symmetries are
Table 4.3 shows the character table for the C3v point allowed for a molecule possessing a particular symmetry.
group. The NH3 molecule possesses C3v symmetry, and Appendix 3 gives character tables for the most commonly
worked example 4.2 illustrated the principal axis of rotation encountered point groups, and each table has the same
and planes of symmetry in NH3 . In the character table, format as those in Tables 4.2 and 4.3.
the presence of three v planes in NH3 is represented
by the notation ‘3v ’ in the top line of the table. The notation
‘2C3 ’ summarizes the two operations C31 and C32 (Figure 4.6). 4.6 Why do we need to recognize
The operation C33 is equivalent to the identity operator, E,
symmetry elements?
and so is not specified again.
Figure 4.4 showed the proper axes of rotation and
So far in this chapter, we have described the possible sym-
planes of symmetry in the square planar molecule XeF4 .
metry elements that a molecule might possess and, on the
This has D4h symmetry. The D4h character table is given in
basis of these symmetry properties, we have illustrated how
Appendix 3, and the top row of the character table that
a molecular species can be assigned to a particular point
summarizes the symmetry operations for this point group
group. Now we address some of the reasons why the
is as follows:
recognition of symmetry elements in a molecule is important
to the inorganic chemist.
D4h E 2C4 C2 2C2 ’ 2C2 ’’ i 2S4 h 2v 2d Most of the applications of symmetry fall into one of the
following categories:
In Figure 4.4 we showed that a C2 axis is coincident with
. constructing molecular and hybrid orbitals (see Chapter 5);
the C4 axis in XeF4 . The C2 operation is equivalent to C42 .
. interpreting spectroscopic (e.g. vibrational and electronic)
properties;
. determining whether a molecular species is chiral.
Table 4.3 The character table for the C3v point group. For
more character tables, see Appendix 3. The next two sections deal briefly with the consequences of
symmetry on observed bands in infrared spectra and with
C3v E 2C3 3v the relationship between molecular symmetry and chirality.
In Chapter 21, we consider the electronic spectra of
A1 1 1 1 z x2 + y2 , z2
octahedral and tetrahedral d-block metal complexes and
A2 1 1 1 Rz
E 2 1 0 (x, y) (Rx , Ry ) (x2 – y2 , xy) (xz, yz) discuss the effects that molecular symmetry has on electronic
spectroscopic properties.
100 Chapter 4 . An introduction to molecular symmetry
4.7 Vibrational spectroscopy How many vibrational modes are there for a
given molecular species?
Infrared (IR) and Raman (see Box 4.1) spectroscopies
are branches of vibrational spectroscopy and the former Vibrational spectroscopy is concerned with the observation
technique is much the more widely available of the two in of the degrees of vibrational freedom, the number of which
student teaching laboratories. The discussion that follows can be determined as follows. The motion of a molecule
is necessarily selective and is pitched at a relatively simplistic containing n atoms can conveniently be described in terms
level. We derive the number of vibrational modes for some of the three Cartesian axes; the molecule has 3n degrees of
simple molecules, and determine whether these modes are freedom which together describe the translational, vibrational
infrared (IR) and/or Raman active (i.e. whether absorptions and rotational motions of the molecule.
corresponding to the vibrational modes are observed in the The translational motion of a molecule (i.e. movement
IR and/or Raman spectra). We also relate the vibrational through space) can be described in terms of three degrees
modes of a molecule to its symmetry by using the character of freedom relating to the three Cartesian axes. If there are
table of the relevant point group. However, a rigorous 3n degrees of freedom in total and three degrees of freedom
group theory approach to the normal modes of vibration for translational motion, it follows that there must be
of a molecule is beyond the scope of this book. The reading (3n 3) degrees of freedom for rotational and vibrational
list at the end of the chapter gives sources of more detailed motion. For a non-linear molecule there are three degrees
discussions. of rotational freedom, but for a linear molecule, there are
E X P E R I M E N TA L T E C H N I Q U E S
Fig. 4.11 The vibrational modes of CO2 (D1h ); in each mode of vibration, the carbon atom remains stationary. Vibrations (a)
and (b) are stretching modes. Bending mode (c) occurs in the plane of the paper, while bend (d) occurs in a plane perpendicular
to that of the paper; the þ signs designate motion towards the reader. The two bending modes require the same amount of energy
and are therefore degenerate.
only two degrees of rotational freedom. Having taken absorption bands in the IR spectrum. This is because the
account of translational and rotational motion, the number following selection rule must be obeyed: for a vibrational
of degrees of vibrational freedom can be determined (equa- mode to be IR active, it must give rise to a change in the mole-
tions 4.5 and 4.6).† cular dipole moment (see Section 2.6).
Number of degrees of vibrational freedom for a
For a mode of vibration to be infrared (IR) active, it must
non-linear molecule ¼ 3n 6 ð4:5Þ give rise to a change in the molecular electric dipole moment.
Number of degrees of vibrational freedom for a
linear molecule ¼ 3n 5 ð4:6Þ A different selection rule applies to Raman spectroscopy.
For a vibrational mode to be Raman active, the polarizability
For example, from equation 4.6, the linear CO2 molecule of the molecule must change during the vibration. Polarizabil-
has four normal modes of vibration and these are shown in ity is the ease with which the electron cloud associated with
Figure 4.11. Two of the modes are degenerate; i.e. they pos- the molecule is distorted.
sess the same energy and could be represented in a single dia-
gram with the understanding that one vibration occurs in the For a mode of vibration to be Raman active, it must give rise
plane of the paper and another, identical in energy, takes to a change in the polarizability of the molecule.
place in a plane perpendicular to the first.
In addition to these two selection rules, molecules with a
centre of symmetry (e.g. linear CO2, and octahedral SF6)
Self-study exercises are subject to the rule of mutual exclusion.
1. Using the VSEPR model to help you, draw the structures of
CF4 , XeF4 and SF4 . Assign a point group to each molecule. For centrosymmetric molecules, the rule of mutual exclusion
Show that the number of degrees of vibrational freedom is states that vibrations that are IR active are Raman inactive,
independent of the molecular symmetry. [Ans. Td ; D4h ; C2v ] and vice versa.
One of the important consequences of precisely denoting The transition from the vibrational ground state to the first
molecular symmetry is seen in infrared and Raman spectro- excited state is the fundamental transition.
scopy. For example, an IR spectrum records the frequency of
a molecular vibration, i.e. bond stretching and molecular
deformation (e.g. bending) modes. However, not all modes Linear (D1h or C1v ) and bent (C2v ) triatomic
of vibration of a particular molecule give rise to observable molecules
We can readily illustrate the effect of molecular symmetry
†
For further detail, see: P. Atkins and J. de Paula (2006) Atkins’ Physical on molecular dipole moments, and thus on infrared active
Chemistry, 8th edn, Oxford University Press, Oxford, p. 460. modes of vibration, by considering the linear molecule
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political supremacy of the isolated American people in the affairs of
this earth. What will come of that nobody knows.
The Breakspeares conceived it, imagined it, planned it; the Thanes
tooled it. There was of course labor. But labor no more invents the
tools that are the means to economic conquest than soldiers invent
the weapons of war, and has generally less understanding of ends
than soldiers have of the strategy.
The men controlling the steel industry came to be grouped in three
main divisions. There was the original Pittsburgh group, under the
leadership of a round head named Carmichael; it had founded itself
in iron and then gone into steel. It was steady and powerful and had
gained some influential support in Wall Street. There was the
western group, always falling down and getting up again, very
unstable, yet dangerous as competitors.
And thirdly was the Breakspeare group, extremely unpredictable,
whose interests lay in every direction.
John naturally attracted men who loved risk and lived easily with
danger. Slaymaker learned the attitude, not thoroughly, but
sufficiently, and walked doggedly along. His goal was wealth for its
own sake. Although John’s high adventures often threatened to
involve all of them in colossal bankruptcy, yet this never quite
happened, and each time it didn’t happen Slaymaker took a part of
his profit and hid it away, never to be risked again. Jubal Awns, the
lawyer, became superstitious about John and followed him blindly.
Besides these two, who had been in from the start, there were three
others who would be called general partners. They not only were
very large stockholders and directors in John’s companies; they
joined their capital with his in new undertakings. One was Isaac
Pick, a wordless man who conversed in gestures and disbelieved
everything including the fact of his own existence. He had made a
fortune in scrap iron and was brought into the group by Slaymaker
at a time when new capital was urgently needed. Another was Col.
Wingreene, an exceedingly profane man, one of the railroad officials
whom John had induced to take original stock in the American Steel
Company when it began to make rails. Wingreene had bought out
the other railroad people and now devoted himself entirely to the
steel business. A third was Justinian Creed, a Cleveland banker, very
obese, who believed in the better way and twice a year was in a
grovelling panic about his sins, never thinking, however, to divest
himself of the fruits thereof. Thane was a partner, too, only his work
was in other material. There were many others loosely affiliated, but
these five,—Slaymaker, Awns, Pick, Wingreene and Creed,—were
John’s own, whom he led, and who came to be known generically as
the Breakspeare Crowd.
When the game was hot they worked at high pressure, wholly
sustained one would have thought by strong waters; when it was
won they let down with a bang. They were men of strong habits,
strong wills, strong feelings and strong humor. One of their odd
passions was for getting one another’s goat. In their practical jokes
they were serious, grim and imaginative, with an amazing power of
deception. Never was a time when some absurd hoax was not
brewing; and if one knew of nothing in pickle for another he began
to be uneasy about himself. His defence was to prepare something
of his own against the field. They were always on guard and
regarded one another askance, with a kind of owlish suspicion. One
would have thought, seeing them together, that they were too
distrustful of themselves to look away or turn to spit. So they were.
But this was personal, part of a game, and had nothing to do with
business really.
Their code of conduct was intricate. If the word passed they could
trust one another implicitly. Yet they avoided the word so far as
possible, preferring in all normal circumstances unlimited freedom of
personal action, each fellow for himself. In an emergency they came
close together, stood back to back, and presented a solid ring to the
world. In all situations John led them. Often he moved them against
their judgment. Sometimes he was wrong. Generally he was right.
When they acted severally against his judgment, on their own, they
were always wrong. His character was perhaps no stronger than
theirs; his judgment intrinsically was no better. But he had above all
of them a faculty of intuition, and he could change his mind. Creed
used to say: “John, he looks where he isn’t going and goes where he
isn’t looking. His eyes are crossed inside.”
He said it cynically, and it was distorted by John’s enemies, who took
it to mean that he could not be trusted by his own crowd. That was
not so. He never broke the code. Creed, as it turned out, was the
only man who needed watching within the rules.
Fortuity was the stuff they worked in; hazard was what they played
with. They were always betting. No game of chance or skill but they
had to add stakes to make it interesting. As they grew richer and
more easily bored it was increasingly difficult to find a pastime in
which the stakes were high enough. John turned the leisure of their
minds to horse racing. They would appear in a body on the race
track and scare the bookmakers with the size of their wagers. John
was their oracle. They never believed him; they only followed him.
When he had involved them in enormous loss they were obliged to
go on; there was no other hope of getting out but by his star of luck.
And it was by no means infallible. Once at Saratoga they had a
frightful week. Twice they had telegraphed home for money. Their
losses had gone into six figures. Slaymaker met Awns, Wingreene,
Pick and Creed on the hotel veranda after breakfast. He was
exceedingly sore.
“As long as I live and have my senses I’ll never bet on another horse
John picks,” he said. “He dreams these things. He never had a real
tip in his life.”
They were all of one mind. They were through. Just then John’s
voice reached them from the doorway, saying: “We’ll get it all back
today.”
They groaned and turned their backs.
“No, now listen?” he said. “You always get cold feet at the wrong
time. This is our chance. It’s air tight. It’s so secret I can’t even tell
you what horse it is. Give me your money and I’ll bet it with mine.”
He sat down and went on with it until Slaymaker said: “I’m an
imbecile. If anybody knew what an imbecile I am there would be a
run on my bank. This is positively the last time.”
They all gave him their money. It was the third race. No more could
he tell them. The horses went to the post and still they did not know
which one carried their money.
“It’s on,” said John. “It’s down all right. Don’t worry about that.”
“Lord, no,” said Slaymaker. “That’s not what we are worried about.”
John watched the horses. The others watched him.
A horse named Leadbeater took the lead at the start, held all the
way and won by four lengths. John fell back with a blank expression.
“That the horse?” asked Slaymaker.
“Yes,” said John. “That’s it.”
“Then what’s the matter?”
“I didn’t bet on it,” said John.
“You didn’t—what!”
“That was the horse,” John explained. “Only after we came out here
I got what I thought was a better tip and bet all the money on....
Now, wait!”
They would not wait. They rose with one impulse and left him alone
in Saratoga. That night on the train they began to get telegrams
from him. Would they authorize him to lay five thousand apiece for
them on a horse that was bound to win the next day at odds of 100
to 1? They tore up the telegrams. More kept coming, overtaking
them en route all that night and until noon the next day. They would
not even reply. But that horse did win and John by himself broke half
the bookmakers at Saratoga.
It was the end of their racing sport for that season. The crowd was
too disgusted to touch it again and John did not care for it alone.
Slaymaker said it was forever; so did all the rest. Yet the next
season they did it all over again.
XXXVI
W hen the steel age walked across the ocean from Europe a
dilemma was created. The will and mentality were here; the
labor was there. Until then labor in American mills had been made
up of British, Irish, Welsh, Germans, Swedes and, choicest of all,
Buckwheats, meaning young American brawn released from the
farm by the advent of man-saving agricultural implements. The steel
age widened the gap between brain and muscle. It required a higher
kind of imagination at the top and a lower grade of labor below.
There was no such labor here,—at least, nowhere near enough.
Hence an inpouring of Hungarians, Slavs, Polacks and other inferior
European types,—hairy, brutish, with slanting foreheads.
Nobody thought of the consequences. Nobody thought at all. The
labor was needed. That was enough. There was no effort to
Americanize or assimilate it. There wasn’t time. It had to be fed raw
to the howling new genie. It lived wretchedly in sore clusters from
which Americans averted their eyes. Where it came from life was
wretched, even worse, perhaps; but here were contrasts, no
gendarmes, freedom of discontent, and a new weapon, which was
the strike. These men, bred with sullen anger in their blood,
melancholy and neglected in a strange land, having no bond with
the light, were easily moved to unite against the work bosses who
symbolized tyranny anew. Their impulse to violence was built upon
by labor leaders and the steel industry became a battle ground.
Strikes were frequent, bloody and futile, save for their educational
value, which was hard to see then and is not at all clear yet.
This was all in the way of business,—big business. We imported
labor and exported steel. We flung Slavs into our racial melting pot
and sold rails and bridges in Hungary. One can easily imagine an
invisible force to have been at work, a blind force, perhaps. The
centers of power were shifted in the world. Greatness was achieved.
The rest is hidden.
One advantage the Breakspeare mills had was almost complete
immunity from labor troubles. In every reign of terror destruction
passed them by. For this there was Thane to thank. He handled all
labor problems. In disputes between the workers and the steel
companies the question of wages was seldom the basic matter, even
when it seemed to be. The trouble was much more subtle, or more
simple, as you happen to see it, turning upon the ways and hungers
of humanity. Thane knew men, he knew what drudgery costs the
soul and how little it takes beyond what is due to overcome its
bitterness. He knew, besides, how and in what proportions to mix
different kinds of men so that the characteristics of one kind would
neutralize those of another kind by a sort of chemistry.
Seven miles down the river from the Agnes plant had been built a
magnificent new plate mill, called the Wyoming Steel Works. It had
every element of success save one. The manager had no way with
labor. He was continually engaged in desperate struggles with the
Amalgamated Unions and the plant for that reason had involved its
New York owners in heavy loss. These troubles, becoming chronic,
culminated in a strike that spread sympathetically over the whole
eastern steel industry. At the Agnes plant the men went out for the
first time. They had no quarrel of their own. That was made very
clear. But they felt obliged, as all other union workers did, to take up
the quarrel of the men at the Wyoming Works and settle it for good;
they would if necessary tie up every steel plant in the country in
order to bring pressure to bear upon their arch enemy, the Wyoming
manager, to whose destruction they had made a vow.
Not only did the strikers seize the Wyoming Works, as was the first
step in hostilities; they took possession of the town that had grown
up around the plant and organized themselves on a military basis.
An Advisory Committee of workers declared martial law, mounted a
siren on the town hall to give signals by a secret code, put sentinels
around the works, around the town, up and down the river front,
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