Assessment - 138

Answer Key & Solution

PART-1 : MATHEMATICS ANSWER KEY

Q. 1 2 3 4 5 6 7 8 9 10
A. C D C D B D C A,B,D B,C A,C
SECTION-I
Q. 11 12 13 14 15 16 17 18
A. A,D A,D A,B,D A,B,D C C B C

SOLUTION
SECTION-I 4. Ans. (D)
1. Ans. (C) Sol.
R(h,k)
ì2x + 4x - 4 x Î [ -2,2]
2 a
Sol. ƒ(x) = í Q P
î4x + 4 x Î (2, ¥ )

Chord of contact of R
hx + 2ky = 6
x
–2 –1 x compare with cos q + y sin q = 1
2 2
2h 2k
= =6
cos q sin q
–6
h2 + k2 = 9
\ Range : [–6, ¥) which is director circle of x2 + 2y2 = 6.
2. Ans. (D) 5. Ans. (B)
1 / a2
x -k y -2 z -k cos-1 ax
Sol. Line
1
=
k
=
2 ò sec -1 (ax + 2)
dx
Sol. lim 0
, let ax = t
Plane 2x – 4y + z = 7 a ®¥ 1
\ 2k – 8 + k = 7 Þ k = 5 a2
1/ a
& 2 – 4k + 2 = 0 Þ k = 1 cos-1 t
Þ no value of k exist.
ò sec -1 (t + 2)
dt
= lim 0

3. Ans. (C) a ®¥ 1
Sol. h2 + (k + 1)2 + h2 + (k – 2)2 = 3[h2 + (k – 1)2] a

2h2 + 2k2 – 2k + 5 = 3h2 + 3k2 + 3 – 6k p 1

cos-1
3
a
Þ h2 + k2 – 4k – 2 = 0 = lim = 2 =
a ®¥ æ1 ö p 2
Þ x2 + y2 – 4y – 2 = 0 sec -1 ç + 2 ÷
èa ø 3
6. Ans. (D) Again, A > Ar.(trapezium BFDC)
2 2 2
x + y = 5 Þ (x – y) = 5 – 2xy 1( 4
Þ A>3 + 44 ) ( e4 - e3 )
V = px2y – pyx2 = pxy ( 5 - 2xy ) 2
337 3
Let xy = t Þ A> (e (e - 1)) (Ans. D)
2
V = pt ( 5 - 2t ) 9. Ans. (B,C)
dv é (-2)t ù Sol. Put z = x + iy, (x,y Î R)
Þ = p ê 5 - 2t + ú = 5 – 2t –t = 0 Þ x2 – y2 + 2ixy – 2iy + 2|y|i = 8i
dt ë 2 5 - 2t û
ì x2 – y2 = 0 Þ x = y or x = –y
5 5 í
Þ t= Þ xy = î 2xy – 2y + 2|y| = 8
3 3
7. Ans. (C) Þ xy – y + |y| = 4 ....(1)
Sol. Let a point on y3 = x4 be (t3, t4) Case-I : when x = y
3y2y' = 4x3 Þ x2 – x + |x| = 4
4x 3 4 (i) if x > 0, then x = 2, y = 2
Þ y' = Þ y' = t
3y 2 3 Þ z = 2(1 + i)
Equation of tangent is (ii) if x < 0 Þ y < 0 (rejected)
4t Case-II : when x = –y
y - t4 = (x - t 3 ) Þ –x2 + x + |x| = 4
3
Q it is a normal to x2 + y2 – 2x = 0 x2 – x – |x| = –4
(i) if x > 0, then x2 – 2x + 4 = 0
\ it must pass through (1, 0)
Þ xÎf
3 t3 (ii) if x < 0 Þ x2 = –4
Þ - t3 = 1 - t 3 Þ =1
4 4 Þ xÎf
Þ t3 = 4 10. Ans. (A,C)
4t
Now m = -y dy
3 Sol. = xdx
1 - y2
3
æ 3m ö
÷ =t =4 -2y
3
Þ ç dy = xdx
è 4 ø
2 1 - y2
8. Ans. (A,B,D)
Sol. y æ -2y ö
ç 2 ÷ dy = xdx
J E D è2 1-y ø
44

4 G F
d ( )
1 - y 2 = xdx
3 H
x2
1 - y2 = +C
A 2
B C
1 e
3
e
4
x put x = 0, y = 1 Þ C=0
4
A is area bounded by curve between x = 1, x x4
Þ 1 - y2 = Þ + y2 = 1
x = e4 4 4
11. Ans. (A,D)
x = e3 is point of inflection
1
Now, A < Ar.( ABGF) + Ar.(( BCDE) Sol. tan -1 x + tan -1 = tan -1 3
y
Þ A < (e3 –1)34 + (e4 – e3)44
1
Þ A < 256e4 – 175e3 – 81 (Ans. A) x+
Also, A < Ar.( ACDJ) y
=3
Þ A < (e4 – 1)44 x
1-
Þ A < 256(e4 – 1) (Ans. B) y
 Þ xy + 1 = 3y – 3x Paragraph for Question 15 and 16
3y - 1 10 15. Ans. (C)
Þ x= =3- 1w
y +3 y+3
y + 3 = 5, 10 nW n–1W
y = 2, 7 Þ x = 1, 2
Sol. Case : I n+1B nB
12. Ans. (A,D)
Sol. Locus of P is a circle X2 + Y2 = 4 urn A urn B
2w
and locus of Q is |X| + |Y| = 2 n +2 n +1 n +1
n
C1 C2 C1 C1 .n +1 C1 13
Y 2n +1
´ 2n + 2
+ 2n +1
´ 2n + 2
=
C1 C2 C1 C2 25
(0,2)
Þ 29n2 - 46n - 24 = 0
X Þ ( n - 2 )( 29n + 12 ) = 0
O (2,0)
n=2
16. Ans. (C)
2 6
´
13. Ans. (A,B,D) 5 15 4
Sol. =
2 6 3 9 13
ìa a ´ + ´
Sol. x - 3x + b = 0 í
2
or 5 15 5 15
îb 3b Paragraph for Question 17 and 18
ìa a 17. Ans. (B)
x2 – ax + 6 = 0 í or
î3b b Sol. 2ƒ ( x ) .ƒ ' ( x ) - 2ƒ ' ( x ) -
2
=0
2 x
ìa + b = 3 1
Case-I : í 2 ( ƒ ( x ) - 1) ƒ ' ( x ) =
îa.3b = 6 2 x
Þ a = 1, b = 2 or a = 2, b = 1 integrating both the sides
Þ a = 7, b = 2 and a = 5, b = 2 ( ƒ ( x ) - 1)
2
- x +C
ìa + 3b = 3 Q ƒ(0) = 2 c = 1
Case-II : í
îab = 6 Þ ( ƒ ( x ) - 1) = x + 1
2

Þ (3 – 3b)b = 6
Þ ƒ (x ) = 1 + x +1
Þ b2 – b + 2 = 0
Þ no real value of b. ƒ (x) - 2 x +1 -1
Now, lim+ = lim+
14. Ans. (A,B,D) x ®0 x x ®0 x
Sol. adj(M) = 2N, adj(N) = M
x +1 -1 1
= lim+ =
( )
Þ |adjM|= 8|N|and |adjN|=|M| x ®0
x x +1 +1 2
Þ |M|2 = 8|N|and |N|2 =|M|
Þ |N| = 2 18. Ans. (C)
Now, MN = adj(N).M = |N|I 1 1
Sol. Q g ' ( y ) = Þ g ' (4) =
Þ MN = 2I Þ (B) ƒ ' (x ) ƒ ' ( 64 )
Now adj(M2N) + adj(MN2)
= adj(M.2I) + adj(2IM)
(Q ƒ (64 ) = 4 )
= 4(2N) + 4(M) 1
= = 96
Now, adj(MN–1) = adj(2N–2) Þ (A) 1
96
= 4(adjN)–2 = 4M–2 Þ (C)
PART-2 : PHYSICS ANSWER KEY
Q. 1 2 3 4 5 6 7 8 9 10
A. C C A B C A A B,C B,C,D B,D
SECTION-I
Q. 11 12 13 14 15 16 17 18
A. A,D D A,C B,C,D B A B D

SOLUTION
SECTION-I 2. Ans. (C)
1. Ans. (C) Sol. When identical resistor is inserted in BD
GMm then it forms a wheatstone bridge due to
Sol. Force on m due to M(F) = 2
(l + x 2 ) which current in the bulb becomes zero and
Net downward force on m = 2Fcosq it becomes dark.
m 3. Ans. (A)
q Sol. For mean position : qE = kx
x
qE
M M x= = Amplitude A
k
l l
A A
GMm x v=0
= 2 l2 + x 2 . 2
l + x2
qE Kx qE
2GMm x –ve mean +ve
= extreme position extreme
( l 2 + x 2 )3 / 2
x
if x << l
qE
2GMm x Þ A=
Fnet = = ma k
l3
Net force on block at any instant
Fnet = qE – kx
2GM x l3
a= Þ TP = 2 p
l3 2GM æ qE ö
Fnet = –k ç x -
è k ÷ø
For TS
= – k(x – x0)
l l w Fnet = –kX
M M
F ma = –kX
GMM k
F= = Mw2 l a=– .X
(2l )2 m

m
GM GM Þ T = 2p
Þ = w2 l Þ w= k
4l 2
4 l3
4. Ans. (B)
Sol. Let area of needle be A and length be l.
4l 3
Þ TS = 2p For needle to remain in equilibrium
GM
Force due to surface tension ³ weight of
TP 1 needle
= 2 S l ³ r (Al )g
TS 2 2
2S
A£
rg
 All India Open Test/Leader Test Series/Joint Package Course/JEE (Advanced)/PAPER-2
\ Watm + Wgas = DKEbullet
p D2 2S 8S 2
£ ÞD £
4 rg prg Pi Vi - Pf Vf 8P0 ´ 5 ´ 10-4 - P0 Vf
Wgas = =
g -1 0.5
on solving D £ 1.53mm & independent of
length. Also 8P0 × (5 × 10–4)g = P0 Vfg

5. Ans. (C) Þ Vf = 82 / 3 ´ 5 ´ 10 -4 m3 = 20 ´ 10 -4 m3
6. Ans. (A)
8P0 ´ 5 ´ 10 -4 - P0 ´ 20 ´ 10 -4
7. Ans. (A) \ Wgas =
0.5
Sol. We have
P0 ´ 104 ´ 20(2 - 1)
2T – 20 = 2b (i) = = 400J
0.5
20 – T = 2a (ii)
Given 10–2 × x = 5 × 10–4 Þ x = 5 × 10–2 m
Also 10–2 L = 20 × 10–4 Þ L = 20 × 10–2 m
\ Watm =
P1
P0 ( Vf - Vi ) = - P0 (15 ´ 10 -4 ) = -150 J
b
2kg m1
P2 b
x
T L

a m2 2kg
\ DKEbullet = 250 J
9. Ans. (B, C, D)
a – 2b = 0 Þ a = 2b (iii)
2T – 20 = 2b f

40 – 2T = 8b r1
20 = 10b Þ b = 2m/s2 r1
Sol. r1
\ a = 4 m/s2 r1
Also T = 12 N
f
12
\ vwave = = 20m / s
3 ´ 10 -2
7
apulley = 2 m/s2 1 sin f = sin r1
2
1 2
\ 0.2 = 20t + 2t since rays enters from air to glass Þ r2 £ qc
2
Þ t2 + 20t – 0.2 = 0 Thus no TIR from back surface

t = 0.01 s 10. Ans. (B, D)

8. Ans. (B, C) Sol. Since inductor is ideal Þ EMF inductor =

Potential difference inductor and EMF
Sol. Since no heat transferred Þ process is across resistor = 0
adiabatic
11. Ans. (A, D) Magnetic field at the centre,
Sol. flux through the strip,
m0 i m0 i m0 (2i / p)
Bnet = . + . - .
2p a 2p a 2 a
ém
df = ê 0
i m
+ 0
i ù
ú
ë 2p (a - x) 2p (a + x) û
2 a 2 - x 2 dx ( ) m0 i m0 i
= . -
p a pa
m0 é 1 1 ù
= i ê + ú ´ 2 a2 - x 2 dx
2po ë a - x a + x û =0
12. Ans. (D)
i Sol. Current in the element,
a

x dQ
i = –KA
dx
Q1 dx i Q2
i dx
x a
K=
Q
2m 0 ia dx
df = .
p a2 - x 2
l Q2
dQ
ò
i dx = - A µ ò Q
Total flux through the ring, 0 Q1

é 2m ia a dx ù æQ ö
f = 2ê 0 ò ú il = A µ ln ç 1 ÷ ...(i)
ëê p 0 a - x úû
2 2
è Q2 ø

a x Q
4m ia é æ x öù dQ
= 0 êsin -1 ç ÷ ú
p ë è a ø û0
Also, ò
i dx = - A µ
0
ò
Q1
Q

4m0 ia é p ù æQ ö
= = i x = A µ ln ç 1 ÷
p êë 2 úû èQø
f = 2m 0 ia
Q2 2m0 ia x/l
Mutual inductance, M = = = 2m0 a æ Q1 ö Q1
i^ i Using (i), ç ÷ =
è Q2 ø Q
e2 Mdi ^
Also, M = Þ e2 = x/l
di ^ / dt dt æQ ö
Q = Q1 ç 2 ÷
è Q1 ø
æ 2 ö
ç ÷t 2 13. Ans. (A, C)
è m0 ø
e2 = 2m0 ai.e .
m0
Sol. Velocity gradient
e2 = 4ai w

e2 dv wr cos q - 0
= r
Induced current in the ring, iR = dy r sin q
R q dy
(R resistance)
w w
= =
4ai 2i tan q q
iR = = (as q is small)
2pa p
 Considering elemental ring of radius x &
thickness dx torque on this elemental ring, dy dy
òr 2
=ò
B
é wù
dt = ê(2pxdx) ú xh
ë qû
é 1 1 ù gh
-ê - ú =
w ë r r0 û B

1 1 gh
- =
r0 r B
x dx

2 3 w 1 gh 1
Þ Net torque, t = pR h - =
3 q r0 B r
14. Ans. (B, C, D)
-1
Br0 æ r gh ö
r= = r0 ç 1 - 0 ÷
æ v - v0 ö B - r0gh è B ø
Sol. f = f0 ç v - v ÷
è s ø

æ r0gh ö
= r0 ç 1 +
If source is receding away, then
è B ÷ø

16. Ans. (A)

æ v ö
f = f0 ç v + v ÷ dp
è s ø Sol. = -rg = –g(r +by)
dy 0

so f decreases as vs increases
If observer receding away, then gh 2
dp = r0gh + b
2
æ v - v0 ö
f = f0 ç ÷ 17. Ans. (B)
è v ø
Sol. Least energetic photon corresponds to
so, f decreases as v0 increases but at high transition from n = 2 to n = 1,
speeds f will increase and at very high
1500 P2 1500 ´ 22
speeds no frequency will be detected so l = =
P2 - 1 22 - 1
15. Ans. (B)

= 2000 Å = 200 nm
BdV Bdr
Sol. rgdy = - =
V r 18. Ans. (D)

Bdr = r2g dy hc 1240 eV - nm

Sol. DE21 = = = 6.2 eV
l 200
r2gh
r=r+
B only in option (D), there is difference of
6.2 V in energy of first & second level.
æ rgh ö
= r ç1 +
è B ÷ø i.e, E2 – E1 = 6.2 eV
PART-3 : CHEMISTRY ANSWER KEY
Q. 1 2 3 4 5 6 7 8 9 10
A. D B D C D A C A,B,C,D A,B,C A,B,C,D
SECTION-I
Q. 11 12 13 14 15 16 17 18
A. B,C A,D A,D A,B,C,D D B B B

SOLUTION
SECTION-I
1. Ans. (D)
k sp (AgI) 10 -17
Sol. [Ag ] for ppt of I =
+ n – = =10 –16 M
[I- ] 0.1

k sp (AgBr) 10 -13
[Ag+] for pptn of Br– = -
= =10 –12 M
[Br ] 0.1

k sp (AgI) 10-17
Þ [I–] where AgBr starts precipitating = +
= -12 =10 –5 M
(Ag ) 10

10 –5
Þ % [I ] remaining in solution =
–
´100 = 0.01%
0. 1
Þ % [I–] precipitated =99.99%
2. Ans. (B)
Sol. ph = 3 Þ [H+] = 10–3 M
let the degree of dissociation be a

10 –3
Þ a= = 0.1
0.01
Þ i = 1 + (y – 1)a = 1.1
Þ p(osmotic pressure) = (1.1) (0.01) RT = 0.011 RT
3. Ans.(D)
Sol. (A) N2H4 + 2I2 ¾® 4HI + N2
(B) N2H4 + 2O2 ¾® 2H2O2 + N2
(C) N2H4 + 2CuSO4 ¾® Cu + N2 + 2H2SO4
4. Ans.(C)

H O O
+
Sol. (A) 2 N Cr Cr
O –
H H H
– O
O O O

(B) (NH4)2 Cr2O7 ¾¾ Cr2O3 + 4H O (this section is used for making artificial volcano)
D
® N2 + (green ) 2

(C) Metal nitrate ¾¾

D
® metal oxide + NO2 + O2
(D) Metal nitrates are generally soluble in water
5. Ans. (D)
CH3 CH3
Cl2
Sol. CH3 – CH – CH2 – CH3 CH3 – CH – CH2 – CH2 – Cl

CH3
CH3 – CH – CH – CH3
Cl

CH3
CH3 – C – CH2 – CH3
Cl

CH3
Cl – CH2 – CH – CH2 – CH3
6. Ans. (A)

SO3H

SO3 [KCP]
Sol. Low temperature
(X)

SO3H
High [TCP]
temperature

7. Ans. (C)

CH2 –Cl CH2

AlCl3
Sol. + CH2Cl2 (excess)
X

Br
NBS

Br OH O
Hydrolysis PCC

Z
8. (A, B, C, D)
Refer theory
9. Ans. (A, B, C)
Sol. (A) Carbon atoms occupy all lattice points and also are present in alternate tetrahedral voids.
(B) Two atoms in the closest neighbourhood are the ones present at any lattice point and into
the tetrahedral void.
æ 3a ö 3a
Þ d nearest = 2r = çç ÷÷ ´ 2 =
è 8 ø 4

1
(C) Contribution from atoms at corner = 8 ´ =1
8
1
contribution from atoms at face centres = 6 ´ = 3 contribution from atoms in half tetrahedral
2
1
voids = ´ 8 = 4
2
Þ Total atoms (effective) = 8
10. Ans.(A, B, C, D)
Sol. NO2– + I– ¾® NO + I2

FeSO4
I +
[Fe(H2O)5NO] SO4
Brown coloured complex

I +
[Fe(H 2O)5NO] SO4

dx2–y2 dz2

dxy dyz dxz dx2–y2 dz2

I
Fe Þ [Ar]3d7

dxy dyz dxz

µ= 15 B.M., brown coloured complex due to charge transfer, hybridisation Þ sp3d2

11. Ans.(B, C)
Sol. (A) Na+ & KÅ ions can form alums.
BaCl2 dil. HNO3
(B) K2SO4.Al2(SO4)3.24H2O BaSO4 Not Soluble
white ppt.
(C) Alums are used as a mordants in dyeing industry.
(D) All types of alums are not coloured.
12. Ans.(A, D)
+ – LAH
Sol. (A) NºC NH – CH3

H2/Pd
(D) O + H2N – Me N – Me CH – NH – CH3
–H2O
13. Ans. (A, D)
Sol. (A)

HO – C C – OH + CH 2 – CH2 H
C C – O – CH2 – CH2 – O + nH2O
O O OH OH O O
n
N Mole
O
COOH C – O – CH2 – CH2 – O —
(D) + CH2 – CH2 H

COOH OH OH C – O – CH2 – CH2 – O —

n
O
Pthallic Acid Glyptal
14. Ans. (A, B, C, D )
MgX
H H
H H
(i) RMg X
Sol. ¾¾¾¾
(ii) FeCl
® +R–H
2

FeCl2

MgX

Fe

MgX

15. Ans. (D)

300 mg
Sol. m mol of compound = 150 g / mol = 2

324 mg
m mole of H2O produced = = 18
18 g / mol
Þ m mole of H atom = (18 × 2)
18 ´ 2
Þ m mole of H atom in one m mole of compound = =18
2
m mole of C in 2 m mole compound = m mole of H2CO3
m moleof NaOH 0.3 ´ 80
= = =12 m mole
2 2
Þ m mole of C in 1 m mole compound = 6
æ 95 öæ 394 ö 1
m mole of N2 = ç ÷ç ÷´ ;2
è 760 øè 0.0821 ø 300
Þ m mole of N present in 1 m mole of compound = 2
Þ C6H18Ox.N2 º mol.wt = (6 × 12 + 18 × 1 + 16 × x + 14 × 2) = 150
Þ x=2
Þ formula = C6H18N2O2
16. Ans. (B)

æ 12 ö
Sol. n CO2 = n H2CO3 = ç ÷
è 1000 ø

2
n N2 =
1000

Þ n CO2 + n N2 = 0.014

17. Ans.(B)
Sol. (A) No change observed in test tubes.

+2 H2S
(B) Sn ¾¾¾¾¾¾
Basic medium
® SnS ¯
Brown ppt

H2S
Sn +4 ¾¾¾¾¾¾
Basic medium
® SnS2 ¯
Yellow ppt

dil. NaOH
(C) Sn +2 ¾¾¾¾¾ ® Sn(OH)2 ¯
white ppt

dil. NaOH
Sn +2 ¾¾¾¾¾ ® Sn(OH)4 ¯
white ppt

NaOH NaOH
(D) Sn +2 ¾¾¾¾ ® Sn(OH)2 ¯ ¾¾¾¾ ® [Sn(OH)4 ]-2
excess
white ppt so lub le

NaOH NaOH
Sn +2 ¾¾¾¾ ® Sn(OH)4 ¯ ¾¾¾¾
excess
® [Sn(OH)6 ]-2
white ppt so lub le

18. Ans.(B)
Sol. when tin(II) & tin (IV) compound dissolve in excess NaOH then [Sn(OH)4]–2 & [Sn(OH)6]–2 ions
are formed respectively.