ABS - Notes + BITS
ABS - Notes + BITS
The bitter and sour taste in food is because of the acids and bases present in
them.
PROPERTIES OF ACIDS
Sour taste
pH Range of acids are 0 to 7
pH Range of strong acids 0 to 3
pH Range of weak acids 4 to 7
It releases H +¿¿ in water
Corrosive in nature
PROPERTIES OF BASES
Bitter taste
pH Range of bases are 7 to 14
pH Range of strong bases are 11 to 14
pH Range of weak bases are 7 to 10
It releases OH −¿¿ ions in water
Soapy feeling
Soluble bases are called alkali (alkaline)
Note:
pH=−log ¿ (concentration)
pH α 1
¿¿
pH α ¿ ¿
Litmus paper is obtained from lichen trees
CLASSIFICATION OF ACIDS:
1) Based on occurrence:
Organic acids – Acids which come from plants and animals is called
organic acids
Example: Lactic acid (milk), Acetic acid (vinegar), Formic acid (ants),
Citric acid (lemon, orange), tartaric acid (turmeric), Oxalic acid
(vegetables)
Mineral acids – Acids which come from minerals are called mineral
acids
Example – Sulphuric acid ( H 2 S O 4 ¿ , Nitric acid (H N O3), Hydrochloric
acid (HCl), Carbonic acid ( H 2 C O3)
2) Based on strength:
Strong acids – Complete ionisation of H +¿¿ ions in water
Example: H 2 S O 4, HCl, H N O3
Weak acids – Partial ionisation of H +¿¿ ions in water
Example: H 2 C O3, CH 3 COOH , H 2 S O3
3) Based on amount:
Concentrated (conc.) – More amount of acid and less amount of water
Diluted (Dil.) – Less amount of acid and more amount of water
CLASSIFICATION OF BASES
1) Based on strength – Complete ionisation of OH −¿¿ ions in water
Strong base-
Example: KOH, NaOH, Ca ¿, LiOH
Weak bases- Partial ionisation of OH −¿¿ ions in water
Example: NH 4 OH , Al ¿, Mg ¿ , Zn¿
Antacid- help to neutralize the stomach acid
Synthetic indicators:
o Indicators that are man-made and prepared in lab are called
synthetic indicators
o Examples of synthetic indicators –
Olfactory indicators:
o Substances whose odour changes in acidic or basic media are
called olfactory indicators
o Used by blind people to know whether it is acid or base
o Examples of olfactory indicators –
ACTIVITY 2.1:
ACTIVITY 2.2:
Onion smell – lost in NaOH and remains in HCl
Vanilla extract smell - lost in NaOH and remains in HCl
Clove smell - lost in NaOH and remains in HCl
Other reactions:
Colours:
CuO - black
C uCl 2 – Bluish green
Since metallic oxides react with acids to give salts and water, similar to the
reaction of a base with an acid, metallic oxides are said to be basic oxides.
Since this is similar to the reaction between a base and an acid, we can
conclude that non-
metallic oxides are
acidic in nature
QUESTIONS:
1. Why should curd and sour substances not be kept in brass and copper
vessels?
Curd and sour substances contain some acids. When these acids react with the
brass and copper vessels, it leads to corrosion and the formation of salts which
are harmful to consume
The presence of hydrogen gas can be tested by bringing a candle near the gas.
2.2.1 WHAT
HAPPENS TO ACID OR BASE IN A WATER SOLUTION
ACTIVITY 2.9:
(Do acids produce ions in only aqueous solution?)
The colour of litmus
paper changes
when it is wet
HCl shows acidic
character only in
water
Calcium chloride is used to absorb moisture from the surrounding
Hence, dry HCl cannot produce hydrogen ions while only solution of HCl
can.
Hydrogen ions cannot exist independently, hence the exist in the form
of hydronium ions (or) H +¿¿ (aq)
Neutralisation reaction:
ACTIVITY 2.10:
The temperature increases. Hence, it is exothermic
Dilution of NaOH in water also
releases heat. Hence, it is also
exothermic.
DILUTION OF ACIDS AND BASES
Bases/ Acid + water → Ions
+¿¿
Acid + water → H 3 O + Anion
Base + Water → Cation + OH −¿¿
+¿¿
Example – HCl + H 2 O → H 3 O +Cl−¿¿
NaOH + H 2 O → Na+¿¿+OH −¿¿
Water is a material in which flow of electrons/ charge will conduct electricity
Example – NaCl does not conduct electricity in solid state, but conducts
electricity in liquid state
Electron or ions should move to generate electricity
Acid or bases when dissolved in water dissociates into ions
The ions in acid or base are helpful for electrical conductivity
It is an exothermic reaction
When water is added to acids it is highly exothermic. So, the acid must be
added slowly by stirring. If water is added to acid, it may cause the mixture to
splash out and cause burns. The glass may also break sue to excessive local
heating
During dilution of acids, the pH of the solution increases
During dilution of bases, the pH of the solution decreases
¿ ¿> ¿ ¿ in acids
¿ ¿in bases
¿ ¿ in neutral (like water)
Mixing an acid or base with water results in decrease in the concentration of
−¿ ¿
ions ( H 3 O+¿/OH ¿) per unit volume. Such a process is called dilution and the
acid or the base is said to be diluted.
QUESTIONS:
1. Why do HCl, HN O3 , etc., show acidic characters in aqueous solutions while
solutions of compounds like alcohol and glucose do not show acidic
character?
HCl, HN O3 ionise in water to form H +¿¿ ions. H +¿¿ ions in aqueous
responsible for the acidic character. Since, glucose and alcohol do not release
+¿¿
H ions in water, they do not show acidic character.
4. While diluting an acid, why is it recommended that the acid should be added
to water and not water to the acid?
When water is added to acids it is highly exothermic. So, the acid must
be added slowly by stirring. If water is added to acid, it may cause the mixture
to splash out and cause burns. The glass may also break sue to excessive local
heating. Therefore, it is recommended that acid should be added to water and
not water to the acid
+¿¿
5. How is the concentration of hydronium ions ( H 3 O ) affected when a
solution of an acid is diluted?
When acids are diluted the concentration of hydronium ions present
in unit volume is decreased
6. How is the concentration of hydroxide ions (OH −¿¿ ) affected when excess
base is dissolved in a solution of sodium hydroxide?
The concentration of hydroxide ions will increase when excess base is
dissolved in a solution of sodium hydroxide, but it happens to a limited extent
only after which the concentration becomes almost constant.
ACTIVITY 2.11:
The strength of acids and bases depends on the number of H+ ions and OH–
ions produced, respectively
QUESTIONS:
1. You have two solutions, A and B. The pH of solution A is 6 and pH of solution
B is 8. Which solution has more hydrogen ion concentration? Which of this is
acidic and which one is basic?
Solution A has more hydrogen ion concentration and is acidic in nature
Solution B has less hydrogen ion concentration and is basic in nature
+¿¿
2. What effect does the concentration of H (aq) ions have on the nature of the
solution?
When the concentration of hydrogen ions is more, the solution is acidic.
When the concentration of hydrogen ions is less, the solution is basic
3.
Do
basic solutions also have H +¿¿ (aq) ions? If yes, then why are these basic?
Basic solutions also have H +¿¿ ions, but they are comparatively less
when compared to the OH −¿¿ ions in the bases. They are called bases as
generate more OH −¿¿ when dissolved in water compared to the amount of
+¿¿
H ions generated
4. Under what soil condition do you think a farmer would treat the soil of his
fields with quick lime (calcium oxide) or slaked lime (calcium hydroxide) or
chalk (calcium carbonate)?
Quick lime, slaked lime and chalk are all basic in nature. So, the soil
should be acidic in nature in order for the farmer to treat it with bases
2.4.2 pH OF SALTS:
ACTIVITY 2.14:
Types of salts
Neutral salts
o pH = 7
o Strong acid + strong base
o Example –
HCl + NaOH → NaCl + H 2 O
HN O3 + KOH → KN O3 + H 2 O
Acidic salts
o pH < 7
o Strong acid + weak base
o Example –
H 2 S O 4 + N H 4 OH → (N H 4 )2 S O4 + H 2 O
Basic salts
o pH > 7
o Weak acid + strong base
o Example – H 2 C O3, CH 3 COOH
CH 3 COOH + NaOH → CH 3 COOHNa + H 2 O
H 2 C O3 + KOH → K 2 C O3 + H 2 O
Seawater contains many salts dissolved in it. Sodium chloride is separated from these salts
Deposits of solid salt are also found in several parts of the world
These large crystals are often brown due to impurities
This is called rock salt
Beds of rock salt were formed when seas of bygone ages dried up
Rock salt is mined like coal
1. Sodium hydroxide
NaOH
Common name – Caustic soda
Chemical name – Sodium hydroxide
Preparation:
o When electricity is passed through an aqueous solution of sodium chloride
(called brine), it decomposes to form sodium hydroxide
o The process is called the chlor-alkali process because of the products
formed– chlor for chlorine and alkali for sodium hydroxide
o Chlorine gas – anode, hydrogen gas- cathode and sodium
hydroxide solution is also found near the cathode
Uses:
o Chlorine – Water
treatment, swimming
pools, PVC (polyvinyl chloride), disinfectants, CFCs
(chlorofluorocarbons), pesticides
o Hydrogen – Fuels, margarine, ammonia for fertilisers
o Sodium hydroxide – De-greasing metals, soaps and detergents,
paper making, artificial fibres
2. Bleaching powder
CaOCl 2
Common name – Bleaching powder
Chemical name – Calcium oxy-chloride
Preparation
o Chlorine gas produced during the electrolysis of the brine
solution is used and also dry slaked lime is used
Uses
o for bleaching cotton and linen in the textile industry, for
bleaching wood pulp in paper factories and for bleaching washed
clothes in laundry;
o as an oxidising agent in many chemical industries
o to make drinking water free from germs.
3. Baking soda
NaHCO 3
o It is a mild, non-corrosive basic salt.
Common name- baking soda
Chemical name- Sodium hydrogen carbonate (or) Sodium bicarbonate
Preparation
Another reaction: Here Sodium carbonate has bitter taste
Uses
o Commonly used in the kitchen for making tasty crispy pakoras,
etc
o Sometimes it is added for faster cooking
o Making of baking powder
o Sodium hydrogen carbonate is also an ingredient in antacids.
Being alkaline, it neutralises excess acid in the stomach and
provides relief
o It is also used in soda-acid fire extinguishers
NaHCO 3 + HCl →NaCl + H 2 O + CO 2
Here carbon dioxide is the fire extinguisher
Hydrogen carbonate is not stable, so it dissociates into water
Baking powder
NaHCO 3
Common name – baking powder
Chemical name – Sodium hydrogen carbonate/ sodium bicarbonate
Preparation:
o Baking powder = Baking soda + mild edible acid (eg. Tartaric,
citric)
o When baking soda is heated or mixed with water, the following
reaction takes place
4. Washing Soda:
Na2 CO 3. 10 H 2 O
Common name: Washing soda
Chemical name: Sodium carbonate decahydrate
Preparation:
o sodium carbonate can be obtained by heating baking soda
o recrystallisation (technique used to purify chemicals) of sodium
carbonate gives washing soda
o It is also a basic salt
o This is
called water of crystallisation and Sodium carbonate becomes a
little wet.
Uses:
o Sodium carbonate (washing soda) is used in glass, soap and
paper industries.
o It is used in the manufacture of sodium compounds such as
borax
o Sodium carbonate can be used as a cleaning agent for domestic
purposes.
o It is used for removing permanent hardness of water.
Gypsum:
Ca SO4 . 2 H 2 O
Common name: Gypsum
Chemical name: Calcium sulphate di-hydrate
It has two water molecules as water of crystallisation
Preparation:
1 1
o Ca SO4 ⋅ H 2 0 + 1 H 0 → Ca SO4 . 2 H 2 O
2 2 2
Uses:
o Used to make plaster of Paris
o Used in minerals and cosmetics
o Used in chalk
o Fertiliser in Agriculture
Plaster of Paris:
1
Ca SO4 ⋅ H 2 0
2
Common name: Plaster of Paris
Chemical name: Calcium Sulphate semi hydrate
Preparation:
Uses:
o The substance which doctors use as plaster for supporting
fractured bones in the right position
o Making of gypsum
o Used for making toys, materials for decoration and for making
surfaces smooth
QUESTIONS:
1. What is the common name of the compound CaOCl 2
The common name for the given compound is bleaching powder
3. Name the sodium compound which is used for softening hard water
The sodium compound used for softening hard water is sodium
carbonate it is also known as washing soda.
4. What will happen if a solution of sodium hydrocarbonate is heated? Give
the equation of the reaction involved.
On heating sodium hydrocarbonate it gives sodium carbonate and
carbon dioxide gas is evolved
5. Write an equation to show the reaction between Plaster of Paris and water
EXERCISES:
1. Marked in the book
2. Marked in the book
3. Marked in the book
4. Marked in the book
6. Compounds such as alcohols and glucose also contain hydrogen but are not
categorised as acids. Describe an Activity to prove it.
Take solutions of glucose, alcohol, hydrochloric acid, sulphuric acid, etc.
Fix two nails on a cork, and place the cork in a 100 mL beaker.
Connect the nails to the two terminals of a 6-volt battery through a
bulb and a switch
Now pour some dilute HCl in the beaker and switch on the current.
The bulb does not glow in glucose and alcohols as they do not
dissociate into ions when dissolved in water
7. Why does distilled water not conduct electricity, whereas rain water does?
Distilled water does not contain any ions while rain water does. Hence,
distilled water does not conduct electricity while rain water does
(a) 7
(b) 11
(c) 1
(d) 4
(e) 9
C<E<D<A<B
10. Equal lengths of magnesium ribbons are taken in test tubes A and B.
Hydrochloric acid (HCl) is added to test tube A, while acetic acid (C H 3 COOH)
is added to test tube B. Amount and concentration taken for both the acids
are same. In which test tube will the fizzing occur more vigorously and why?
More fizzling will occur in test tube A as hydrochloric acid is a strong
acid while acetic acid is a weak acid
11. Fresh milk has a pH of 6. How do you think the pH will change as it turns into
curd? Explain your answer.
Milk contains a carbohydrate lactose. When milk sets into curd, lactose
gets converted into lactic acid. Due to the formation of lactic acid, pH of milk
falls below 6.
12. A milkman adds a very small amount of baking soda to fresh milk.
(a) Why does he shift the pH of the fresh milk from 6 to slightly alkaline?
(b) Why does this milk take a long time to set as curd?
(a) It is done to increase the shelf life of milk. Milk is made slightly alkaline so
that it may not get sour easily due to the formation of lactic acid in it
(b) The alkaline milk takes a longer time to set into curd because the lactic acid
being formed has to first neutralise the alkali present in it.
15. Give two important uses of washing soda and baking soda
Uses of washing soda
Sodium carbonate (washing soda) is used in glass, soap and paper industries.
It is used in the manufacture of sodium compounds such as borax
Uses of baking soda
Sodium hydrogen carbonate is also an ingredient in antacids. Being alkaline, it
neutralises excess acid in the stomach and provides relief
It is also used in soda-acid fire extinguishers