CODE-KvS(DR)/2024-25/PR

KENDRIYA VIDYALAYA SANGATHAN, DELHI REGION

MARKING SCHEME, ANNUAL EXAMINATION (2024-25)
CLASS - XI SUBJECT- CHEMISTRY (043)
M.M- 70 TIME - 3 HOURS

2 1
3 D
4 C 1
5 B 1
6
7 l
D 1
9 1
10 D 1
11C
12 C
13 D 1
14 B 1
15 D
16 |A 1
17 (a) Avogadro's law 1+1
(b) Molar mass of nitrogen = 28 g
28 g of nitrogen contain = 6.022 to 1023 molecules
: 14g of nitrogen contain = 6.022 to 1023 x 14
28
= 3.011x 1023 molecules
18 (a) Carbon possesses the highest ionisation enthalpy. It increases from left 1+1
to right along the period and also decreases as we go down the group.
(b) Aluminium possesses the most metallic character. On moving down, the
metallic character increases and decreases across the period from left to
right.
19 Hybridisation in PCls = sp³d h+h+1
Shape =trigonal bipyramidal
Axial bonds longer than equatorial bonds, axial bonds pairs suffer more
repulsion from equatorial bond pairs therefore the axial bond are
slightly elongated and hence weaker than equatorial bond.
Or
|Sigma bond Pi bond
Sigma bound is found by overlap of This is formed by sideway hx4=2
orbitals along their internuclear overlapping of Orbitals
axis
Itsoverlapping is quite large and Its overlapping is to a small extent
hence sigma bond is astrong bond hence pi bond is a weak bond
Sigma bond is found by It is found by our lap of P orbitals
overlapping between S-S, S-P, or P- only
P orbitals
20 (a) Forward direction ½x4=2
(b) Forward direction
(c) Backward direction
(d) Forward direction
Or
(a) NH = Bronsted base and its conjugate acid is NH3 hx4=2
(b) H;0+ = Bronsted acid and its conjugate base is H,0

21 (a) But-3-en-al 1+1

(b) Correct structure
or

(a) It is defined as the complete transfer of shared pair of pi electrons to one

of the atom joined by multiple bond on the demand of an attacking
reagent.
The Organic compounds having multiple bonds show this effect in the
presence of an attacking reagent only.
(b) 3

22 (a) (i) 2s and (ii) 4d 1+1+1

(b) The photoelectric effect is a phenomenon of ejection of electron from
metal surface, when certain frequency of light fall on it.
(c) 1s² 2s² 2p6 3s² 3p3d6 4s0
23 (a) Property of an element are periodic function of their atomic number. 1+1+1
(b) Because a cation is found by the loss of one or more electrons by the
neutral atom, Increases the effective nuclear charge as a result the
force of attraction of the nucleus for electron increase and hence
ionic radii decreases. In contrast, anion is formed by the addition of
one or more electron to the neutral atom which decrease the
effective nuclear charge as a result the force of attraction of the
nucleus for the electrons decreases and hence ionic radius increases.
(c) Sulphur has more negative electron gain enthalpy than Oxygen.
Oxygen has less negative electron gain enthalpy because in it the
added electron goes to the smaller energy level (n = 2)and hence
suffers significant repulsion from the electrons already present in
this shell.
24 Molecular orbital diagram ofO2+ 3
Bond order = 2.5
Magnetic behaviour = Paramagnetic
Or
(a) Ortho-Nitrophenol will form intramolecular hydrogen bond because
NO; and OH group are closed together in comparison to that in para
nitrophenol.
(b) Para-nitrophenol will have higher melting point because it forms
intermolecular hydrogen bonds thus more and more molecules are
joined together through hydrogen bond formation.
(c) Due to intramolecular hydrogen bonding ortho-nitrophenol will not
 be able to form hydrogen bond with water thus will be less soluble in
it while para-nitrophenol can form hydrogen bond with water more
easily and it will be soluble in water.
25 Oxidising agent = Mn04
Reducing agent = Fe2t
MnO4 + 5Fe2+ + 8H+ ’ Mn2* + 5Fe3+ +4H20
26 (a) Crystallisation is based on difference in the solubility of compound
and impurity in a suitable solvent.
Chromatography is based on principle of differential adsorption.
(b)
Problem 12.23
In Carius method estirmation
halogen, 0,15gof an oreanle com
ave 0.12 g of AgBr. Fnd out the
percentage of bromine in the compound.
Solution
Molar mass of AgBr = 108 80
188 gmol!
188 g AgBr contalns 80 g bromine

0.12 gAgBr contains 0*02gbromine

188
80 x0.12x100
Percentage uf bromine
188x0.1I5
34.04%

27 (a) The suppression in the dissociation of a weak electrolyte by the

addition ofa strong electrolyte having a common ion.
(b) CH4 < NH3< H,0 < HF
(c) Sodium chloride will be precipitated out.
or

(a) Predict the extent of a reaction / Predict the direction of the

reaction/ Calculate equilibrium concentration
(b)
Solution
For the reaction the reaction quotient Q.
ls given by.
9.-(B|C)/ IAP
as [A] =(B] (C]=3 x 10"M
9,(3 x10)(3 x10)/(3 x10 =1
as 9. > K so the reaction will proceed in
the reverse direction.

1+
28 (a)CH4 +Na2C03 formed
(b) CH3 CH; Cl + alc. KOH CH2=CH + HCI
(c) Correct reaction
Or
(a) Correct structure
Cis -but-2-ene has higher boiling point due to high polarity in
molecules.
(b) A: CHy-CH=CH- CH3
IUPAC Name = But-2-ene
1+
29 a. Law of conservation of mass
 b. The reactant which is completely consumed in a reaction is called
limiting reagent.
c. () B is the limiting reagent
(ii) A is the limiting reagent
OR
According to the given equation, 28 g of N2 reacts with 3 mol of H2
i.e., 6 g of H2
. 2000 g of N2 will react with H2 =6 x 2000 g
28
= 428.6g
Amount of H2 given = 1000 g
Thus N2 is the limiting reagent while His the excessive reagent.
As 28 g of N2 produce NH3 = 2 x 17 = 34 g
: 2000 g of N2 will react with NH3 = 34 x 2000 g
28
= 2428.6g

30 (a) torsional strain 1+1+2

(b) small energy barrier
(c) Correct structures
Or
Correct structures
31 (a) No two electron in an atom can have same set of four quantum 1+1+3
number or Only two electrons may exist in the same orbital and
these electron must have opposite spin
(b) Angular nodes = 2 and radial nodes =0
(c) ()2 = 616 nm= 616 x10-9 m, c= 3 x 108 ms-1
v=c/ =3x108 ms-1/616 x 10-9 m
frequency =4.87 x1014 s-1
(ii) Energy of quantum, E= h v
= 6.626 x 10-34 Js x 4.87 x 1014 g-1
= 3.23 x 10-19 J

OR
(a) Neutron, since it is a neutral and cannot be deflected by an
electric field.
(b) Orbit is the definite circular path for electrons to revolve around
the nucleus. It is represents the two dimensional motion of
electron around the nucleus.
it is reason around the nucleus where the probability of finding
an electron is maximum.
(c) setution
e t specara ie he vtego

AR 21

Te frequrn u e potnahng

626LOM
32 (a) If a reaction takes place in several steps then its standard reaction 1+1+3
enthalpy is the sum of the standard enthalpies of the intermediate
reactions into which the overall reaction may be divided at the same
temperature.
(b) AU = Wad, wall is adiabatic
(c)
Solution. The equation we require is:
C(s) + 2H,(g) +V20,(g)’ CH,OH():
Multiply eqn. (üi) by 2 and add to eqn (ü)
Clo) + 2H,(g) +20,)
Co,(e) +21i,00 ..iu)
AH =-(393+522) =-965 kl mol-!
Subtract egn. () rom eqn. (iv)

fCio) +2H, w)+20, (e)

-CH,OH) W20,(*)
co, (g) +2H,0 U)]
-C0, (g)- 2H,0 )
AH=-965-(-726) =-239 kJ mo!
or Co)+2H,)+0,4) CH,0H0:
AH- 239 kJ mol

Or
(a) Entropy of any pure crystalline substance approaches zero as the
temperature approaches absolute zero.
(b) () increases (ii) decreases
(c)
For the raction, 2A(¢)+B(g)+2D(, 4U: - 15M and A' -#10 JN"
Caleulate 4G' for he reaction and predict whether the reaction may oCur spontaneousty:
Fr the given reation, dn, =2-() =-1
AR= U"+An, RTs-105J+-)8314x 10U(098)=-10-248 =-1298J
SG=A- TAS' =-1298 J-298 (-44-1 x10-28U+1310U=0 03
(a) AsG comes out to be +ve, the reaction willnot ocur spontancously.
33 (a) O2N CH; CH2 0 is more stable than CH, CH, 0-because N02 group 1x5 =5
has -I effect and hence it tends to disperse the -ve charge on 0-atom.
In contrast CH3 CHz exerts +lI effect. It, therefore, tends to intensity
the -ve charge and hence destabilizes it.
(b) ()Position Isomers (ii) Geometrical isomers
(c) More hyperconjugation structures/+I inductive effect in (CH3)3C*
than CH3CH2+.
(d) Neutral or negatively charged species which are capable of acting as
electron pair donor: Example -NH3 or CN etc.
(e)Sodium fusion extract is acedified with acetic acid and lead acetate is
added to it. Ablack ppt of lead sulphide indicates the presence of
sulphur. Or On treating sodium fusion extract with sodium
nitroprusside, appearance of Violet colour indicates the presence of
sulphur.
 OR
(a) By sublimation because Camphor is sublimable but calcium
sulphate is not.
(b)Correct structures.
(c) When carbon tetrachloride is heated the silver nitrate solution
white precipitate of silver chloride will not be formed. The reason
being that carbon tetrachloride is a covalent compound,
therefore. it does not ionize to give chloride ions needed for the
formation of precipitate of silver chloride.
(d) It is the ratio of distance moved by the substance from the
baseline to the distance moved by the solvent from the baseline.
(e) Correct structure.