Unit 2 Material
Unit 2 Material
TECH
UNIT II
MECHANICS AND THERMODYNAMICS
Mechanics
Moment of inertia (M.I) - Radius of gyration – parallel axes theorem – perpendicular axes theorem - M.I
of rod, circular disc, solid cylinder, hollow cylinder, solid sphere and hollow sphere (Qualitative) - K.E
of a rotating body - Torsional pendulum.
Thermodynamics
Zeroth Law of thermodynamics(Statement only) - first law of Thermodynamics (Statement only) - Work
done by a gas - Heat engines - second law of Thermodynamics (Statement only) - Reversible and
Irreversible process – Entropy - Carnot Engine - Newton's law of cooling.
MECHANICS
No great discovery was ever made without a bold guess.
- Issac Newton
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LEARNING OBJECTIVES
2.1 INTRODUCTION
We know that, according to Newton's first law of motion, a body must continue in its
state of rest or of uniform motion along a straight line, unless acted upto by an external force. This
inertness or inability of a body to change. by itself its position of rest, or of uniform motion, is
called Inertia; and is a fundamental property of matter. Thus, it is by virtue of its inertia that a
body at rest resists or opposes being put into motion, and a body, in linear or translatory motion,
opposes not only being brought to rest but also any changes in the magnitude and direction of its
motion. And, we know, by experience. that the greater the mass of a body, the greater its inertia or
opposition to the desired change; for, the greater is the force required to be applied for the purpose.
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The mass of a body is thus taken to be a measure of its 'inertia for translatory motion', as
it is this that opposes the acceleration, (positive or negative), desired to be produced in it by the
applied force. Exactly in the same manner, in the case of rotational motion, we find that a body,
free to rotate about an axis, opposes any change desired to be produced in its state of rest or
rotation, showing that it possesses 'inertia' for this type of motion. And, obviously, the greater the
couple or torque, required to be applied to a body to change its state of rotation, i.e., to product in
it a desired angular acceleration, the greater its opposition to the desired change, or the greater its
'inertia for rotational motion'. It is this 'rotational inertia' of the body which is called its moment of
inertia about its axis or rotation, —this name being given to it on the analogy of the moment of the
couple which it opposes.
It will thus be seen that the moment of inertia of a body, in the case of rotational motion,
plays the same part as, or is the analogue of, the mass of a body in the case of translatory motion;
and we may, therefore, for purposes of analogy, describe the moment of inertia of a body, in
rotational motion, as the 'effectiveness of the mass'. Or, pushing the analogy of a little further, we
may define mass as the 'coefficient of inertia' for translatory motion, and the moment of inertia. as
the 'coefficient of rotational inertia'.
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Source: https://physicsabout.com/motion/
Yet, with all this seeming similarity, there is all the difference between the two cases.
For in the case of translatory motion(linear dynamics), the inertia of the body depends wholly upon
its mass and is, therefore, measured in terms of it alone. In the case of rotational motion(rotational
dynamics), on the other hand, the rotational inertia, or the moment of inertia, of the body depends
not only upon the mass (M) of the body but also upon the 'effective distance', (K) of its particles
from the axis of rotation and is measured by the expression MK2.
Displacement 𝑠 𝜃
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Velocity 𝑣 𝜔
Acceleration 𝑎 𝛼
Work 𝑊 = 𝐹. 𝑠 𝑊 = 𝜏. 𝜃
Kinetic energy 1 1
KT = 2 𝑚𝑣 2 . KR = 2 𝐼𝜔2
Momentum 𝑃 = 𝑚𝑣 𝐿 = 𝐼𝜔
r m
r m
r m
y
Fig.2.1.
𝐼 = 𝑚1 𝑟1 2 + 𝑚2 𝑟2 2 + 𝑚3 𝑟3 2 + ⋯ = ∑𝑚𝑟 2
Unit: 𝑘𝑔 𝑚2
Dimensional formula [𝐼] = [𝑀𝐿2 ]
Radius of Gyration: Suppose the whole mass of the body (M) is concentrated at a point distance
k from the axis such that 𝑀. 𝑘 2 = ∑ 𝑚𝑟 2 = I.
Then k is called radius of gyration of the body about the given axis. 𝑘 = √𝐼 ⁄𝑀 .
Derivation:
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Uses:
➢ The radius of gyration is used to compare how various structural shapes will behave
under compression along an axis.
➢ It is used to predict buckling in a compression beam or member
International unit of gyradius or radius of gyration
• The SI unit for the radius of gyration is the length or in inches or millimetres or in feet.
• It is the sq. root of inertia divided by the area of the object.
Factors that radius of gyration depends
• A portion of the elements that impact the estimation of the radius of gyration is the size
and state of the body.
• It is the arrangement of the rotational axis and position.
• It likewise relies upon the mass appropriation regarding the rotational axis of the body.
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Theorems of Moment of
inertia
Perpendicular axes
Parallel axes theorem
theorem
and 𝐼 ′ is the moment of inertia about a parallel axis at a perpendicular distance h from the
Proof: AB is an axis passing though the centre of the mass of the body G(Fig.2.2). CD is parallel
axis at a perpendicular distance h from AB. M is the mass of the body.
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Using the parallel axis theorem, what is the moment of inertia of the rod of
mass m about the axis shown below?
Answer:
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𝐼= 𝑚𝐿2
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Statement: If 𝐼𝑥 and 𝐼𝑦 are the moment of inertia of a lamina about two rectangle axes 𝑂𝑋 and
𝑂𝑌 in its plane. Its moment of inertia about an axis 𝑂𝑍, perpendicular to its plane, 𝐼𝑧 = 𝐼𝑥 + 𝐼𝑦 .
z
X
O
9 Y x
r P
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𝑥, 𝑦 and 𝑟 are the distance of the particle from 𝑂𝑌, 𝑂𝑋 and 𝑂𝑍 respectively.
Moment of inertia of the particle about 𝑂𝑍 = 𝑚𝑟 2
∴ M.I of the lamina about 𝑂𝑍 = ∑𝑚𝑟 2
Similarly, M.I of the lamina about 𝑂𝑋 = ∑𝑚𝑦 2
M.I of the lamina about 𝑂𝑌 = ∑𝑚𝑥 2
But
𝑟2 = 𝑥2 + 𝑦2
∑𝑚𝑟 2 = ∑m(𝑥 2 + 𝑦 2 ) = ∑𝑚𝑥 2 + ∑𝑚𝑦 2
∑𝑚𝑟 2 = 𝐼𝑧 ; ∑𝑚𝑥 2 = 𝐼𝑦 ; ∑𝑚𝑦 2 = 𝐼𝑥
𝐼𝑧 = 𝐼𝑦 + 𝐼𝑥
2.6 MOMENT OF INERTIA OF SOME RIGID BODIES.
Common Method for Computation of Moment of Inertia:
The moment of inertia of a continuous homogeneous body with definite geometrical shape
about a given axis can be evaluated in the following manner :
(i) First of all, an infinitesimal element of mass dm of the body is so chosen that every
particle of it lies at the same distance from the given axis.
(ii) The mass (dm) of the element is then multiplied by the square of the distance from the
given axis, the expression for moment of inertia of this element (r2 dm) about the
given axis is found.
(iii) The expression r2 dm is then integrated within the limits so as to cover whole of the
body.
2.6.1 Calculation of MOI of rigid bodies
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𝑀
( 𝑙 . 𝑑𝑥) . 𝑥 2 ⋯1
′
The moment of inertia of the whole rod about 𝑌𝑌 is determined by integrating the eqn.(1) within
the limits
𝑙 𝑙
𝑥 = − 𝑡𝑜 𝑥 = +
2 2
+𝑙⁄2
+𝑙⁄2 𝑀 𝑀 +𝑙⁄2 𝑀 𝑥3
𝐼𝐶𝐺 = ∫−𝑙⁄2 ( 𝑙 . 𝑑𝑥) . 𝑥 2 = ∫−𝑙⁄2 𝑥 2 . 𝑑𝑥= [3]
𝑙 𝑙 −𝑙⁄2
2
𝑀𝑙
𝐼𝐶𝐺 =
12
(𝑖𝑖) About an axis passing through its one end and perpendicular to its length:
The moment of inertia 𝐼 about a parallel axis 𝑌1 𝑌1 ′ passing through one end 𝐴 can be obtained
by using the theorem of parallel axis. According to which,
𝑀𝑙 2 𝑙 2
𝐼 = 𝐼𝐶𝐺 + 𝑀. (𝐺𝐴)2 = + 𝑀. (2)
12
𝑀𝑙2
∴𝐼= 3
2.6.3 MOMENT OF INERTIA OF A CIRCULAR DISC
(i) About an axis through its centre and perpendicular to its plane
Consider a uniform circular disc of mass M. R is the radius of the disc, O the centre and 𝜌 the
mass per unit area. Consider an elementary ring of radius 𝑥 and width 𝑑𝑥 (Fig 2.5) .
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I = O∫R r2σ(πr)dr
I = 2 π σO∫R r3dr
I = 2 πσ r4 / 4 |oR
I = 2 πσ (R4 / 4 – 0)
I = 2 π (m / 4 )(R4 / 4)
I = 2 π (m / π r2 )(R4 / 4)
1
𝐼 = 2 𝑀𝑅 2 .
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1
(𝑖𝑖) M.I of the disc about the diameter = 𝐼𝑑 = 𝑀𝑅 2 by perpendicular axes theorem.
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(𝑖𝑖𝑖) Moment of Inertia about a Tangent in its plane.
By the application of theorem of the parallel axes
1 5
𝐼𝑡 = 𝐼𝑑 + 𝑀𝑅 2 = 4 𝑀𝑅 2 + 𝑀𝑅 2 = 4 𝑀𝑅 2 .
2.6.4 MOMENT OF INERTIA OF A SOLID CYLINDER
(𝑖)about the central axis.
➢ The solid cylinder has to be cut or split into infinitesimally thin rings.
➢ Each ring consists of the thickness of dr with length L.
➢ We have to sum up the moments of infinitesimally these thin cylindrical shells.
3. Alternatively, we have to find the expression for density as well. We use the equation;
𝜌 = 𝑀⁄𝑉
𝜌 = 𝑀⁄𝜋𝑅 2 𝐿
4. The final step involves using integration to find the moment of inertia of the solid
cylinder. The integration basically takes the form of a polynomial integral form.
𝐼 = 2𝜋𝐿𝜌[𝑅 4 ⁄4 ]
𝑀
𝐼 = 2𝜋𝐿 2 [𝑅 4 ⁄4 ]
𝜋𝑅 𝐿
𝑀
𝐼 = 2𝜋𝐿 2 [𝑅 4 ⁄4 ]
𝜋𝑅 𝐿
1
= 𝑀𝑅 2
2
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ρ = M/V
Now,
ρ = M / hπ(r22 – r12)
4. The next step involves using integration to find the moment of inertia. The integration
basically occurs from the inner radius to the outer radius:
dl = ρ 2 π r3 h dr
I = 2 ρ π h r1∫r2 r3 dr = 2 ρ π h [r24/ 4 – r14/ 4]
= (ρ π h/2) [r24– r14]
I =(π h/2) [ M / π (r22 – r22) h] [ (r22 – r12) (r22 + r12)]
I = ½ M (r22 + r12)
Now, if we take a thin hollow cylinder, setting r = r1 = r2 and replacing it into the first equation
we get;
I = Mr2
2.6.6 MOMENT OF INERTIA OF A SOLID SPHERE
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𝑀𝑅 2
dI = = (1 − 𝑐𝑜𝑠 2 𝜃) 𝑠𝑖𝑛𝜃 𝑑𝜃
2
Integrating within the limits of 0 to π radians. From one end to another.
𝑀𝑅 2 𝜋
𝐼= ∫ (1 − 𝑐𝑜𝑠 2 𝜃) 𝑠𝑖𝑛𝜃 𝑑𝜃
2 0
we use substitution where u = cos θ.
𝑀𝑅 2 −1 2
𝐼= ∫ (𝑢 − 1) 𝑑𝑢
2 1
−1
𝑀𝑅 2 𝑢3
𝐼= [ − 𝑢]
2 3 1
𝑀𝑅 2 (−1)3 (1)3
𝐼= [ − (−1) − ( − (1))]
2 3 3
𝑀𝑅 2 −1 1
𝐼= [ + 1 − + 1]
2 3 3
𝑀𝑅 2 2+6
𝐼= [− ]
2 3
𝑀𝑅 2 4
𝐼= [ ]
2 3
2
𝑰 = 𝑴𝑹𝟐
3
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The rotational kinetic energy of the grindstone is converted to heat, light, sound, and vibration.
(source: Zachary David Bell, US Navy)
A KERS (kinetic energy recovery system) flywheel used in cars. (source: “cmonville”/Flickr)
In order to derive an expression for the rotational kinetic energy, suppose a rigid body is rotating
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about an axis 𝑋𝑌 with a uniform angular velocity 𝜔. Let the body be composed of a large number
of tiny particles of masses 𝑚1 , 𝑚2 , 𝑚3 ⋯etc. situated at a distance 𝑟1 , 𝑟2 , 𝑟3 , ⋯etc. from the axis of
rotation (Fig.2.10).
X
r1 m1
r2
r3
r4 m2
r5
r6
m3
y
Fig. 2.10. A rigid rotating body about a fixed axis
As the body rotates, all the particles of the body have the same angular velocity 𝜔, but move with
different linear velocities. Let 𝑣1 , 𝑣2 , 𝑣3⋯ etc. be the linear speeds of masses 𝑚1 , 𝑚2 , 𝑚3⋯ etc.
respectively. A particle of mass 𝑚1 at a distance 𝑟1 from the axis of rotation has a linear velocity
1 1
𝑣1 = 𝑟1 𝜔. Its kinetic energy is, therefore, 2 𝑚1 𝑣12 = 2 𝑚1 𝑟12 𝜔2 .
Similarly the kinetic energy of another particle of mass 𝑚2 at a distance 𝑟2 from the axis rotation
1
is 2 𝑚2 𝑟22 𝜔2 and so on. The total kinetic energy E of the body is the sum of kinetic energies of the
various particles with which the body is made. Hence the kinetic energy of the body,
1 1 1
𝑇 = 𝑚1 𝑟12 𝜔2 + 𝑚2 𝑟22 𝜔2 + 𝑚3 𝑟32 𝜔2 + ⋯
2 2 2
1 2
= 𝜔 (𝑚1 𝑟12 + 𝑚2 𝑟22 + 𝑚3 𝑟32 + ⋯ )
2
1 2 1
= 𝜔 ∑𝑚𝑟 2 = 𝐼𝜔2 [∴ 𝐼 = ∑𝑚𝑟 2 ]
2 2
𝟏
𝑻 = 𝑰𝝎𝟐
𝟐
Hence the kinetic energy of rotation of the body is half the product of moment of the inertia of
the body about the axis of rotation and the square of the angular velocity of the body.
Now if 𝜔 = 1, 𝐼 = 2.K.E
Thus the moment of inertia of the body about its axis of rotation is equal to the kinetic energy
of the body when it rotates with unit angular velocity about that axis.
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Answer:
The initial rotational kinetic energy of the propeller is
1 1
K0 = 𝐼𝜔2 = (800)(4 × 2𝜋)2 = 2.53 × 105 J
2 2
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𝐼
𝑇 = 2𝜋√𝐶 ⋯ (1)
Where I=moment of inertia of the suspended body; C=couple/unit twist
But we have an expression for couple per unit twist C as,
1 𝜋𝜂𝑟 4
𝐶=2 ⋯ (2)
𝑙
Where 𝑙 =length of the suspension wire; r=radius of the wire; 𝜂=rigidity modulus of the
suspension wire
Substituting (2) in (1) and squaring,
we get an expression for rigidity modulus for the suspension wire as,
8𝜋𝐼𝑙
𝜂 = 𝑟 4𝑇 2 ⋯ (3)
We can use the above formula directly if we calculate the moment of inertia of the disc,I as
(1/2)MR2.
Now, let I0 be the moment of inertia of the disc alone and I1 & I2 be the moment of inertia of the
disc with identical masses at distances d1&d2 respectively. If Ig is the moment of inertia of each
identical mass about the vertical axis passing through its centre of gravity, then
𝐼1 = 𝐼0 + 2𝐼𝑔 + 2𝑚𝑑12 ⋯ (4)
𝐼2 = 𝐼0 + 2𝐼𝑔 + 2𝑚𝑑22 ⋯ (5)
𝐼2 − 𝐼1 = 2𝑚(𝑑22 − 𝑑12 ) ⋯ (6)
Where T0,T1,T2 are the periods of torsional oscillation without identical mass,with identical pass
at position d1,d2 respectively.
Dividing equation (7) by (10) and using (5),
𝑇02 𝐼0 𝐼0
[𝑇22 −𝑇12 ]
= [𝐼 = ⋯ (11)
2 −𝐼1 ] 2𝑚(𝑑22 −𝑑12 )
Therefore, the moment of inertia of the disc,
𝑇02
𝐼0 = 2𝑚(𝑑22 − 𝑑12 ) [𝑇2 −𝑇12 ]
2 ⋯ (12)
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16𝜋𝑚(𝑑22 − 𝑑12 ) 𝑙
𝜂= ( 2 ) ⋯ (13)
𝑟 4 𝑇2 − 𝑇12
Applications of Torsional Pendulum
➢ Haller torsion pendulum anniversary clock: The working of “ Torsion pendulum
clocks " ( shortly torsion clocks or pendulum clocks), is based on torsional oscillation.
➢ The freely decaying oscillation of Torsion pendulum in medium (like polymers), helps
to determine their characteristic properties.
➢ New researches, promising the determination of frictional forces between solid surfaces
and flowing liquid environments using forced torsion pendulums.
Solved Problems
1. A 200-gram ball, m1 and a 100-gram ball, m2, connected by a rod with length of 60 cm.
Ignore rod’s mass. The axis of rotation located at ball m2. What is the moment of inertia of
the balls. Ignore rod’s mass.
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I = 0.08 kg m2
CONCEPT MAP
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SUMMARY
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THERMODYNAMICS
“Iron and heat are… the supporters, the bases, of the mechanic arts.”
— Nicolas Léonard Sadi Carnot
2.1 INTRODUCTION
Thermodynamics is a branch of physics that deals with heat, work, temperature, and
their relation to energy, radiation, and physical properties of matter. Thermodynamic system
employs the four laws of thermodynamics that form an axiomatic basis.
Thermodynamic system:
Heat
When an object at higher temperature is placed in contact with another object at lower
temperature, there will be a spontaneous flow of energy from the object at higher temperature
to the one at lower temperature. This energy is called heat.
Temperature:
Temperature is the degree of hotness or coolness of a body. Hotter the body higher is its
temperature. The temperature will determine the direction of heat flow when two bodies are in
thermal contact.
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Mathematically it is written as
∆𝑈 = 𝑄 − 𝑊
The internal energy of a thermodynamic system can be changed either by heating or by work
as shown in the Table 2.1
Table 2.1 Internal energy changes
Heat flows into the Internal energy
System gains heat Q is positive
system increases
Heat flows out of the Internal energy
System loses heat Q is negative
system decreases
Work is done on the Internal energy Work done on the
W is negative
system increases system
Work is done by the Internal energy Work done by the
W is positive
system decreases system
Based on the above table the sign convention is introduced to use first law of thermodynamics
appropriately. It is shown in the following Table 2.2 and the Figure 2.3
Even though we often explain first law of thermodynamics using gases, this law is universal
and applies to liquids and solids.
Quasi-static process:
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A quasi-static process is an infinitely slow process in which the system changes its variables
(P, V, T) so slowly such that it remains in thermal, mechanical and chemical equilibrium with
its surroundings throughout. By this infinite slow variation, the system is always almost close
to equilibrium state.
The force exerted by the gas on the piston 𝐹 = 𝑃𝐴. Here A is area of the piston and P is
pressure exerted by the gas on the piston.
Equation (1) can be rewritten as
𝑑𝑊 = 𝑃𝐴 𝑑𝑥 (2)
But 𝐴𝑑𝑥 = 𝑑𝑉 = change in volume during this expansion process. So the small work done
by the gas during the expansion is given by
𝑑𝑊 = 𝑃𝑑𝑉 (3)
Note here that 𝑑𝑉 is positive since the volume is increased. So 𝑑𝑊 is positive. In general the
work done by the gas by increasing the volume from 𝑉𝑖 𝑡𝑜𝑉𝑓 is given by
𝑉
𝑊 = ∫𝑉 𝑓 𝑃𝑑𝑉 (5)
𝑖
Suppose if the work is done on the system, then Vi > Vf . Then, W is negative. Note here the
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pressure P is inside the integral in equation (5). It implies that while the system is doing work,
the pressure need not be constant. To evaluate the integration we need to first express the
pressure as a function of volume and temperature using the equation of state.
PV diagram:
Heat engine is a device which takes heat as input and converts this heat in to work by
undergoing a cyclic process.
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Reservoir: It is defined as a thermodynamic system which has very large heat capacity. By
taking in heat from reservoir or giving heat to reservoir, the reservoir’s temperature does not
change.
Example:
A Schematic diagram for heat engine is given below in the figure 2.11
2. Working substance:
It is a substance like gas or water, which converts the heat supplied into work.
A simple example of a heat engine is a steam engine. In olden days steam engines were used
to drive trains. The working substance in these is water which absorbs heat from the burning
of coal. The heat converts the water into steam. This steam is does work by rotating the wheels
of the train, thus making the train move.
For example, in the automobile engine, the cold reservoir is the surroundings at room
temperature. The automobile ejects heat to these surroundings through a silencer.
The efficiency of the heat engine is defined as the ratio of the work done (output) to the heat
absorbed (input) in one cylic process.
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Let the working substance absorb heat QH units from the source and reject QL units to the sink
after doing work W units, as shown in the Figure 2.11(a).
We can write
Input heat = Work done + ejected heat
𝑄𝐻 = 𝑊 + 𝑄𝐿
𝑊 = 𝑄𝐻 – 𝑄𝐿
𝑄𝐿
η=1−
𝑄𝐻
Note here that 𝑄𝐻 , 𝑄𝐿 and W all are taken as positive, a sign convention followed in this
expression.
Since 𝑄𝐻 < 𝑄𝐿 the efficiency (η) always less than 1. This implies that heat absorbed is not
completely converted into work. The second law of thermodynamics placed fundamental
restrictions on converting heat completely into work.
We can state the heat engine statement of second law of thermodynamics. This is also
called Kelvin-Planck’s statement.
Kelvin-Planck statement
It is impossible to construct a heat engine that operates in a cycle, whose sole effect is to
convert the heat completely into work. This implies that no heat engine in the universe
can have 100% efficiency.
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Reversible process
A thermodynamic process can be considered reversible only if it possible to retrace the path in
the opposite direction in such a way that the system and surroundings pass through the same
states as in the initial, direct process.
Irreversible process:
All natural processes are irreversible. Irreversible process cannot be plotted in a PV diagram,
because these processes cannot have unique values of pressure, temperature at every stage of
the process.
2.2.8 Entropy
• Entropy is also called ‘measure of disorder’.
• All natural process occur such that the disorder should always increases.
• For reversible process entropy will not change”. Entropy determines the direction in
which natural process should occur.
• The heat always flows from a state of higher temperature to one of lower temperature
and not in the opposite direction. Because entropy increases when heat flows from hot
object to cold object.
• If heat were to flow from a cold to a hot object, entropy will decrease leading to
violation of second law thermodynamics.
Concept of entropy
In fact, it is very difficult to form a physical concept of entropy, as there is nothing physical to
represent it. Moreover, it cannot be felt like temperature, pressure etc. But according to
definition
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Unit of Entropy
Unit of entropy depends on the unit of heat used and the absolute temperature. It is measured
calories (or ergs or Joules) per degree Kelvin i.e., cal./K. S.I unit is Joule /K or Kcal/K.
In the year 1824 a young French engineer Sadi Carnot proved that a certain reversible engine
operated in cycle between hot and cold reservoir can have maximum efficiency. This engine is
called Carnot engine.
i. Source:
It is the source of heat maintained at constant high temperature TH. Any amount of heat can be
extracted from it, without changing its temperature.
ii. Sink:
It is a cold body maintained at a constant low temperature TL. It can absorb any amount of heat.
Carnot’s cycle:
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The working substance is subjected to four successive reversible processes is called Carnot’s
cycle.
The cylinder is placed on the source. The heat (QH) flows from source to the working substance
(ideal gas) through the bottom of the cylinder. Since the process is isothermal, the internal
energy of the working substance will not change. The input heat increases the volume of the
gas. The piston is allowed to move out very slowly (quasi-statically).
W1 is the work done by the gas in expanding from volume V1 to volume V2 with a decrease of
pressure from P1 to P2. Then the work done by the gas (working substance) is given by
𝑉2
𝑄𝐻 = 𝑊𝐴→𝐵 = ∫ 𝑃𝑑𝑉
𝑉1
Since the process occurs quasi-statically, the gas is in equilibrium with the source till it reaches
the final state. The work done in the isothermal expansion is given by
𝑉
𝑄1 = 𝑊𝐴→𝐵 = ∫𝑉 2 𝑃𝑑𝑉
1
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𝑅
= [𝑇 − 𝑇𝐿 ] = Area under the curve BC
𝛾−1 𝐻
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Here V3 > V4. So the work done is negative, implying work is done on the gas.
The cylinder is placed on the insulating stand again and the gas is compressed adiabatically till
it attains the initial pressure P1, volume V1 and temperature TH.
𝑉1
𝑊𝐷→𝐴 = ∫ 𝑃𝑑𝑉
𝑉4
= Area
= 𝑊𝐴→𝐵 + 𝑊𝐶→𝐷
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𝑤𝑜𝑟𝑘𝑑𝑜𝑛𝑒 W
η= =
𝐻𝑒𝑎𝑡 𝑒𝑥𝑡𝑟𝑎𝑐𝑡𝑒𝑑 QH
QH − Q QL
L
η= =1−
QH QH
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𝑉2
QL = 𝑅𝑇𝐿 𝑙𝑜𝑔 [ ]
𝑉1
Here we omit the negative sign. Since we are interested in only the amount of heat (QL) ejected
into the sink, we have
𝑑𝑇 𝑎
∫ =∫ 𝑑𝑡
𝑇 − 𝑇𝑠 𝑚𝑠
𝑎
𝑙𝑜𝑔 𝑇 − 𝑇𝑠 = − 𝑡 + 𝑏1
𝑚𝑠
Where b1 is the constant of integration. Taking exponential both sides, we get
𝑎
𝑇 = 𝑇𝑠 + 𝑏2 𝑒 −𝑚𝑠𝑡
Here, b2 = eb1 = constant.
The cooling curve is an exponential decay curve. It is observed from the graph that the
logarithm of the excess of temperature of hot body over that of its surroundings varies
linearly with time as the body cools.
Applications
1. It helps to find the temperature of a soda placed in a refrigerator by a certain amount of
time.
2. It helps to predict that how long it will take for a hot body to cool down at a certain
temperature.
3. It helps to indicate the time of death given the probable body temperature at the time of
death and current body temperature.
4. It helps to determine the specific heat capacity of a substance.
5. It also helps to design radiators/cooling systems in thermal machines.
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