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Equilibrium Statistical Physics 3rd Edition Michael
Plischke Digital Instant Download
Author(s): Michael Plischke, Birger Bergersen
ISBN(s): 9789812560483, 9812560483
Edition: 3
File Details: PDF, 21.64 MB
Year: 2006
Language: english
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World Scientific
EQUILIBRIUM
STATISTICAL
PHYSICS
3rd Edition
This page is intentionally left blank
EQUILIBRIUM
STATISTICAL
3rd Edition
Michael Plischke
Simon Fraser University, Canada
Birger Bergersen
University of British Columbia, Canada
For photocopying of material in this volume, please pay a copying fee through the Copyright
Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, USA. In this case permission to
photocopy is not required from the publisher.
1 Review of Thermodynamics 1
1.1 State Variables and Equations of State 1
1.2 Laws of Thermodynamics 3
1.2.1 First law 3
1.2.2 Second law 5
1.3 Thermodynamic Potentials 9
1.4 Gibbs-Duhem and Maxwell Relations 12
1.5 Response Functions 14
1.6 Conditions for Equilibrium and Stability 16
1.7 Magnetic Work 18
1.8 Thermodynamics of Phase Transitions 20
1.9 Problems 24
2 Statistical Ensembles 29
2.1 Isolated Systems: Microcanonical Ensemble 30
2.2 Systems at Fixed Temperature: Canonical Ensemble 35
2.3 Grand Canonical Ensemble 40
2.4 Quantum Statistics 43
2.4.1 Harmonic oscillator 44
2.4.2 Noninteracting fermions 44
2.4.3 Noninteracting bosons 45
2.4.4 Density matrix 46
v
vi Contents
9 Simulations 349
9.1 Molecular Dynamics 350
9.1.1 Conservative molecular dynamics 351
9.1.2 Brownian dynamics 353
9.1.3 Data analysis 355
9.2 Monte Carlo Method 357
9.2.1 Discrete time Markov processes 358
9.2.2 Detailed balance and the Metropolis algorithm 359
9.2.3 Histogram methods 363
9.3 Data Analysis 365
9.3.1 Fluctuations 365
Contents ix
Bibliography 583
Index 603
Preface to the First Edition
During the last decade each of the authors has regularly taught a graduate or
senior undergraduate course in statistical mechanics. During this same period,
the renormalization group approach to critical phenomena, pioneered by K. G.
Wilson, greatly altered our approach to condensed matter physics. Since its
introduction in the context of phase transitions, the method has found appli-
cation in many other areas of physics, such as many-body theory, chaos, the
conductivity of disordered materials, and fractal structures. So pervasive is its
influence that we feel that it now essential that graduate students be intro-
duced at an early stage in their career to the concepts of scaling, universality,
fixed points, and renormalization transformations, which were developed in
the context of critical phenomena, but are relevant in many other situations.
In this book we describe both the traditional methods of statistical mechan-
ics and the newer techniques of the last two decades. Most graduate students
are exposed to only one course in statistical physics. We believe that this
course should provide a bridge from the typical under-graduate course (usu-
ally concerned primarily with noninteracting systems such as ideal gases and
paramagnets) to the sophisticated concepts necessary to a researcher.
We begin with a short chapter on thermodynamics and continue, in Chap-
ter 2, with a review of the basics of statistical mechanics. We assume that the
student has been exposed previously to the material of these two chapters and
thus our treatment is rather concise. We have, however, included a substantial
number of exercises that complement the review.
In Chapter 3 we begin our discussion of strongly interacting systems with a
lengthy exposition of mean field theory. A number of examples are worked out
in detail. The more general Landau theory of phase transitions is developed
and used to discuss critical points, tricritical points, and first-order phase tran-
sitions. The limitations of mean field and Landau theory are described and
the role of fluctuations is explored in the framework of the Landau-Ginzburg
model.
xi
Xll Preface
Chapter 4 is concerned with the theory of dense gases and liquids. Many
of the techniques commonly used in the theory of liquids have a long history
and are well described in other texts. Nevertheless, we feel that they are
sufficiently important that we could not omit them. The traditional method
of viral expansions is presented and we emphasize the important role played
in both theory and experiment by the pair correlation function. We briefly
describe some of the useful and still popular integral equation methods based
on the Ornstein-Zernike equation used to calculate this function as well as the
modern perturbation theories of liquids. Simulation methods (Monte Carlo
and molecular dynamics) are introduced. In the final section of the chapter
we present an interesting application of mean field theory, namely the van der
Waals theory of the liquid-vapor interface and a simple model of roughening
of this interface due to capillary waves.
Chapters 5 and 6 are devoted to continuous phase transitions and crit-
ical phenomena. In Chapter 5 we review the Onsager solution of the two-
dimensional Ising model on the square lattice and continue with a description
of the series expansion methods, which were historically very important in the
theory of critical phenomena. We formulate the scaling theory of phase tran-
sitions following the ideas of Kadanoff, introduce the concept of universality
of critical behavior, and conclude with a mainly qualitative discussion of the
Kosterlitz-Thouless theory of phase transitions in two-dimensional systems
with continuous symmetry.
Chapter 6 is entirely concerned with the renormalization group approach to
phase transitions. The ideas are introduced by means of technically straight-
forward calculations for the one- and two-dimensional Ising models. We discuss
the role of the fixed points of renormalization transformations and show how
the theory leads to universal critical behavior. The original e-expansion of
Wilson and Fisher is also discussed. This section is rather detailed, as we have
attempted to make it accessible to students without a background in field
theory.
In Chapter 7 we turn to quantum fluids and discuss the ideal Bose gas,
the weakly interacting Bose gas, the BCS theory of superconductivity, and the
phenomenological Landau-Ginzburg theory of superconductivity. Our treat-
ment of these topics (except for the ideal Bose gas) is very much in the spirit of
mean field theory and provides more challenging applications of the formalism
developed in Chapter 3.
Chapter 8 is devoted to linear response theory. The fluctuation-dissipation
theorem, the Kubo formalism, and the Onsager relations for transport coef-
ficients are discussed. This chapter is consistent with our emphasis on equi-
librium phenomena — in the linear response approximation the central role is
Preface xni
Michael Plischke
Birger Bergersen
Vancouver, Canada
xiv
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