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C45

The document discusses atomic radii, defining it as the distance from the nucleus to the outermost electron shell, and categorizes it into covalent, metallic, and Van der Waals radii. It also explains factors affecting atomic radius, such as effective nuclear charge (Zeff) and electron shielding, particularly in relation to d and f block elements. Trends in atomic radius across different groups in the periodic table are highlighted, noting the impact of increasing Zeff and electron shell effects.

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Janak Deore
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5 views

C45

The document discusses atomic radii, defining it as the distance from the nucleus to the outermost electron shell, and categorizes it into covalent, metallic, and Van der Waals radii. It also explains factors affecting atomic radius, such as effective nuclear charge (Zeff) and electron shielding, particularly in relation to d and f block elements. Trends in atomic radius across different groups in the periodic table are highlighted, noting the impact of increasing Zeff and electron shell effects.

Uploaded by

Janak Deore
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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PeriodicProperties e

St is defined
as distance of outermost
AtomicRadins
from the nucleus not be
measured
of any
atom can
Noted Absolute At radius in bonded
state
are
measured
atoms
so radius of is further
classified as
bonded state radius
On the basis of
Covalent radius
Metallic radius
VanderWaal's radius
internuclear distance
between
C trad.us Half of covalently
bonded
atoms which are
two same
with each other
tea
Ea
covalent radius of te atom I
1402 NaHu Cath
o c c o

12,1 I 41,4 n'jest


0 Single bonded
covalent radius L
0
did Double bonded
covalent radius ely
Bondorder No ofbonds
radius Bady between two
atoms

Xa xa1
tags
o.os
u
4 9a
Electronegativity
inti X
stggqqa.su
da B MA 9 KAYA CBXB
d bond
Ite te 100pm tri calculate bondlength of H
150pm ish
da a o.SE
XH L
an I
0.75 A
3.5 Ga
XU 0.09 3.5 2
0.75
dad 0.5
1.25 0.135
1.115 A
Metallicbond
MetallicRading
0.0
a
Metallic radius I
Vanderwal'sbond

Vanderwal'sRadius

ids
VandaWaal's radius Covalentradius
Metallicradius
element Vanderwal's radius
For an

Factors affecting
At Radius
shell No
At radius
a
Shellate
In At radius x T

Zeff At radius Zeff


P.T
Trend of radius in
9ns p block due to increase in Zeff
C N 707 F Me
Onsame set hi Be 7 B
P s s Sa
Ar
Na My 7 se y si 7
Ge As se Ir Kr
K Ga
G
Rb In Sh sb Te I Xe
Sr
Is Tl Pb By Po Af Rn
Ba
Fr Ra
diff I l
Me hi Be B C M O F On differentscale

to
a
due in
a
increase f
shell a
x

CTL
VBS Gas Alk In
Ito
d contraction

present in d subshell
to e
Sn Ga there
are
d
contraction on
Zeff on
outer e so
which cause poor shielding is called d contraction
Sf
outer e s increases significantly

t
Zeff dominates over
Gn d block other
compensates each
zeff It
IIe if
over Zeff
At dins it dominates

Af No

V Zn
Se Ti

42Ss I I
due to f
contraction
SS se
a contract
g or Lentanoid
LC Hf Ta

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