Engg Physics Unit v Superconductivity Nanophysics Notes
Engg Physics Unit v Superconductivity Nanophysics Notes
Q1 What is nanotechnology ?
Defination:- Nanotechnology is a field of science and engineering that focuses on the design and
manufacture of extremely small devices and structure.
- Generally, materials and devices
- On the scale of atoms and molecules.
- A nanometre is one-billionth of a metre:
- Ten times the diameter of a hydrogen atom.
- The diameter of a human hair is, on average, 80,000 nanometres.
- 1 nm is equivalent to 10 H atoms or 5 Si atoms aligned in a line = 𝟏𝟎−𝟗 𝒎
What are nanomaterials?
Nanomaterials are materials that have at least one dimension (height, width, or length) that is less than
100 nanometers. They have unique properties compared to their larger counterparts
Q.3 What is Surface to volume ratio ? How does it affect properties of Nanoparticle?
When compared to the same mass of material in bulk form, nanoscale materials have a relatively larger
surface area. This can make materials more chemically reactive and affect their strength or electrical
properties.
-Large surface to volume ratio
- High percentage of atoms/molecules on the surface
- Surface forces are very important, while bulk forces are not as important.
Effect :-
i)As the percentage of atoms at the surface increases, the mechanical, optical, electrical, chemical, and
magnetic properties change. – For example optical properties (color) of gold and silver change, when
the spatial dimensions are reduced and the concentration is changed.
ii) Melting point as a function of particle size • Nanoparticles have a lower melting point than their bulk
material as large number atom present on surface
iii) Nanoparticle are highly reactive than bulk materials due to high surface to volume ratio
Q.4. Explain synthesis method of nanomaterial a) Ball Milling Method b) Physical Vapour Deposition
Fig :-
The working of a ball mill can be understood as follows:
A powder mix is positioned in ball mill and is subjected to high energy collision by the balls
(Figure 1). The ball milling process can be summed up as:
a. It consists of stainless steel chamber and several small iron, silicon carbide, hardened steel, or
tungsten carbide balls to rotate inside the mill.
b. Powder of material is put in the steel chamber. The powder is reduced to nanosize using ball mill. A
magnet is positioned outside the chamber to apply pulling force on the material. This force raises
milling energy as the milling chamber or container rotates the metallic balls. 2
c. The ball and material - mass ratio is generally kept at 2:1.
d. These metallic balls impart very high energy to the powder resulting in crushing of the powder. The
ball milling process generally takes 100 to 150 hrs to give uniformly crushed fine powder.
e. It is mechanical processing technique; consequently the structural as well as chemical changes are
caused by the mechanical energy.
f. The size of the nanopowders produced by this technique depends on the speed of rotation of the balls
and the dimensions of 2 to 20 nm can be achieved.
1.Evaporation
2.Transportation
3.Reaction
4.Deposition
• Thermal evaporation
A material is heated to its melting point, evaporates, and then settles on a substrate as a
thin film.
ELECTRON BEAM PHYSICAL VAPOR DEPOSITION
In which the material to be deposited is heated to a high vapor pressure by electron
bombardment in "high" vacuum.
SPUTTER DEPOSITION :-
In which a glow plasma discharge (usually localized around the "target" by a magnet)
bombards the material sputtering some away as a vapor
Advantages :-
- High purity of deposited materials.
- Precise control over film thickness and composition.
- Ability to synthesize various nanostructures.
Limitations :-
- High cost of vacuum systems.
- Limited scalability for large-area deposition.
Applications :-
- Thin film coatings for optoelectronic devices.
- Nanostructured layers for sensors and catalysts.
- Protective and decorative coatings.
Fig a: hardness curve for bulk Fig b: hardness curve for nanoparticles
i) Optical Properties :-
The colour of nanoparticle is different from the bulk material . when bulk material is
reduced in size to a few hundred atom, the energy band structure of the bulk material changes to set
of discret energy levels. Atomic clusters of different size having different energy level . as cluster of
different size having different energy level separation i.e. colour of cluster is depends on size . so
due to transition from bulk size to nano size colour of bulk material get ultered or changed . eg.
Gold in bulk form appears yellow in colour. But gold nano particle appears red in colour. Coloured
glasses are produced by dissolving metal nanoparticle like gold, silver, cobalt, iron etc. due to these
metal nano particle glass appeared as coloured.
Nano zink oxide particle have ability to block superior Ultra Violet light. As compared to bulk
particle so, zink oxide used in cosmetic or in sunscreen lotions.
Q.4. Explain application of nanomaterials in i) Medical or drug delivery ii) Electronics iii) Space iv)
Defence v) Automobile
i) Medical or drug delivery :-
Due to the smaller particle size , nanoparticle are used in drug delivery for cancer or tumor
therapies. Because they can be easily injected and targeted towards the specific portion of body.
Nanotechnology based research is going on to help diebetic and HIV affects patients. Applying
nanotechnology to drug delivery should achieve the following benefits:
-Improve the ability to deliver drugs that are poorly water
soluble.
-Provide site-specific targeting to reduce drug accumulation
within healthy tissue.
-Help retain the drug in the body long enough for effective
treatment.
-Allow for the transportation of drugs across epithelial and
endothelial barriers.
Treatment and faster recovery of injuries is possible
through nanotech.
iii) Space :-
Nanotechnology is an area of science and technology that holds highly promising prospects for military
applications, considering its wide applicability in defensive as well as offensive operations.
-Less vulnerable corrosive material is helpful in satellite manufacturing as well.
-The life of satellites, to a large extent, is determined by the amount of fuel they can carry on board.
-Onboard ignitors wear out quickly and cease to perform effectively.
-Apart from onboard fuel, satellites in outer space use solar power as a power source for various
activities.
-Satellite designers are continuously working on finding the means to reduce the weight of such solar
cells.
-Lighter nanoporous materials like aerogels are found to have wider applicability in spacecraft
manufacturing.
-Even some special lightweight suits, jackets etc. could be made using aerogels.
iv) Defence :-
a) Bio-Defence
-Nanotubes is fast emerging as a new frontier in bio-defence. being used in the development of bio-
sensors.
-Some countries are working on extremely small machines and tools that can enter the human body.
-By using a person’s saliva, body fluids, or blood, nanobiosensors can be created to reliably work with
pathogens such as viruses.
-Drug and virus development costs can be reduced by using nanochips to test various medications or a
combination of chemicals and vaccines.
b) Chemical defence
-In the arena of chemical weapons terrorism, NT offers solutions against the usage of chemical
agents like VX, HD, GD, and GB.
-Some nanoparticle oxides like CaO, Al2O3, and MgO interact with such chemicals much
faster than microparticles and are ideally suited for fast decomposition of such chemicals.
-A sensing device for detection of nerve-gas agents in the atmosphere has been developed
based on NT applications.
c) Conventional Weapons/Ammunition
-Nanotube based stronger and lighter materials would allow the building of conventional barrel-type
weapons with reduced mass.
-It is conceivable that small arms and light weapons could use barrels, locks etc. made of nanofibre
composites.
-Even in respect of ballistic and air-breathing missiles, the reduced mass could translate into a marked
increase in speed, range, or payload as well as a reduction in carrier size.
v) Automobiles:
The body of the vehicles is fabricated by steel and some alloys. The body structure should be strong
and deformable. The nano tube composites have mechanical strength mechanical strength than steel.
Hence they can replace steel. Nano particles provide smooth, thin and attractive coatings.
By using nano particles light and less rubber consuming thinner tires can be made, this will increase
mileage of the vehicle as weight is reduced.
Nanoparticles can be used as a catalyst to convert harmful gases into relatively less harmful gases
which may reduce.
Nano fluids use as lubricant that last for long time with reduction in cost and improve performance
Dr.D.Y.Patil Technical Campus
(Engineering and MCA)
(Approved by AICTE, DTE-Govt of Maharashtra, Affiliated to Savitribai Phule Pune University, Pune)
Sr.No.32/1/A/7, Near Talegaon Railway Station, A/P Varale, Talegaon Dabhade
Tal-Maval, Dist-Pune 410507
Department of Engineering Science
SUBJECT :- ENGINEERING PHYSICS .
UNIT- V NOTES BY :- PROF. ABHIRAJE SHINDE
UNIT V : CHAPTER 1 – SUPERCONDUCTIVITY
d) Meissner Effect :-
Q.3. State & Explain Meissner Effect and show that Superconductor are Diamagnetic in In
Superconducting state . [ 6 Marks]
Meissner Effect :-
Meissner found that if superconductor is cooled in Magnetic Field then above the transition
temperature , magnetic flux pass through the specimen but below the critical temperature
magnetic flux push out of specimen in superconducting state. i.e. in superconducting state
material become perfect diamagnetic.
Defination :- “ The phenomenon of exclusion or
ejection of magnetic flux from interior of bulk of
superconductor when they cooled below the
transition temperature is called Meissner Effect”
If we cooled specimen below transition
temperature and then placed in magnetic field
then also Meissner effect is observed means
converse of Meissner effect also satisfied.
We know that,
B=0(M+H)
But in superconducting state inside material Mag. Field = 0 i.e. B=0
0(M+H)=0 M= -H
𝑀
Magnetic Succeptibility = 𝐻 but M= -H
= -1
Thus in superconducting state is perfect diamagnetic.
e) Critical Current[Ic] :-
The minimum current that can be flowing through in superconductor in superconducting state
without destroying its supeconducting state is called Critical Current (Ic).
If current exceeds critical current value then superconductor become normal conductor.
f) Persistence Current :-
The current in superconductor persist for long time mean electric current set up
in a perfect superconductor. It can persist for very long time without any
application of e.m.f
A current can be induced in superconductor material by cooling it in a
magnetic field below transition temperature. When field is switched off the
magnetic field outside the material is disappear but inside ring some magnetic
field trapped. Collapse of magnetic field outside the ring induces a persistant
current inside the ring itself and maintain the trap flux.
Once the current is setup it will persist for long time that is more than 105 years.
g) Isotope Effect:-
Effect :- “The transition temperature(Tc) of superconductor is varies with the isotopic mass(M) of
superconductor.”
𝟏 𝟏
Tc 𝑴−𝟐 i.e. Tc 𝑴𝟐 = Constant
Thus larger the isotopic mass, lower the transition temperature.
Now we know that, mean square amplitude of atomic lattice vibration at low temperature is
𝟏
proportional to 𝑴−𝟐 and Debye temperature(d)
Which indicate that,lattice vibration are involved in causing supercounductivity i.e. electron
phonon reaction might be playing an important role for occurance of superconductivity.
d. The energy of system is lowest when total momentum of each pair is same and is zero. This is
the single quantum mechanical state into which electron pair condense. The flow of cooper pair
constitute the supercurrents in superconductor.
1.Superconducting Electromagnet:-
A superconducting magnet is an electromagnet made from coils of superconducting wire. They
must be cooled to cryogenic temperatures during operation. In its superconducting state the wire
can conduct much larger electric currents than ordinary wire, creating intense magnetic fields.
Superconducting magnets can produce greater magnetic fields than all but the
strongest electromagnets and can be cheaper to operate because no energy is dissipated as heat in
the windings. They are used in MRI machines in hospitals, and in scientific equipment such
as NMR spectrometers, mass spectrometers and particle accelerators
2.Bearing :-
Flywheels have long been used to store energy in the form of rotational kinetic energy. While
past applications of the conventional mechanical bearings that had relatively high losses due to
friction, the development of magnetic bearings constructed using High Temperature
Superconductors (HTSC) has greatly decreased the losses due to friction and increased efficiency
immensely. While even modern application of magnetic bearings face the same safety problems
that were faced at the turn of the century, the increased efficiency of magnetic bearings as well as
their limited environmental harm make flywheels a promising modern energy storage device. [1]
Further continued developments in HTSC and design improvements in hybrid bearings may see
the development of economical bearing systems for various applications in the near future.
3. Magnetic-levitation Train :-
Although the technology has now been proven, the wider use of MAGLEV vehicles has been
constrained by political and environmental concerns (strong magnetic fields can create a bio-
hazard).
4. Josephson effect :-
In the superconducting state , electrons are attracted by each oter and form bound pairs, called as
Cooper pair. The josephson effect occurs when these pair of electrons tunneled through a thin
insulating barrier placed between two superconductors, the whole arrangement being called
Josephson Junction and this phenomenon is called as Josephson Effect.
There are two types of Josephson Effect.
1. DC Josephson Effect :-
When no voltage is applied across the junction a direct current flows through the junction upto
critical value Ic . due to tunneling of cooper pair through the junction.
“ Flow of current through the Josephson junction even though there is no any voltage applied
across the Junction is called as DC Josephson Effect.”
2. AC Josephson Effect :-
When a direct voltage is applied across the junction , a small oscillating current states flowing
back and fourth through the junction which depends on applied voltage . This phenomenon is
known as AC Josephson Effect
“ Generation of AC currents by using DC current across Josephson junction is called as AC
Josephson Effect “