Lecture Note_CH2_Proccess_2024-2_Fall
Lecture Note_CH2_Proccess_2024-2_Fall
CHAPTER 2
Modern CMOS/Device Technology
ENE531000
Fall Semester
LG
LDD
…………….
CMOS NOR Figure 2-1 Cross section of the final CMOS integrated
circuit. A PMOS transistor is shown on the left, an NMOS
device on the right.
OUTPUT= 𝐈𝐍𝟏 𝐈𝐍𝟐
Flip‐flop (at least 20 transistors)/Single Bit Full Adder ( > 8 transistors)
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Well/Active channel formation
Standard Process Flow Charts (without option process)
*Define PMOS & NMOS regions Ion implantation
Field oxide Bird’s beak
(a) (b) (c) (d)
Mask 6 Mask 7
Mask 8 Mask 9
10 nm amorphous oxide
=> To prevent from Channeling
Mask 10
Mask 11
TiSi2 TiN
ohmic contact (10 Ω/sq)
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(y) (z) (aa)
Mask 12
(cc)
(bb)
Mask 13
…………….
Figure 2-2 Following initial cleaning, an SiO2 layer is
Compressive Tensile thermally grown on the silicon substrate. A Si3N4 layer is
then deposited by LPCVD. Photoresist is spun on the
2.2.2 Active region formation wafer to prepare for the first masking operation.
(a) Thermal growth of thin SiO2 layer (~40 nm): 15 min at 900 ℃ in an H2O atmosphere or 45
min at 1000 ℃ in pure O2 atmosphere SiO2 is under compressive stress.
(b) Growth of thin nitride layer (~80 nm) by LPCVD: 3SiH4 + 4NH3 → Si3N4 + 12H2 The Si3N4 is
under tensile stress, and can be partially compensated by the underlying SiO2, reducing the
stress in Si.
(c) Spinning and patterning of photoresist
(d) Dry etching of Si3N4 (using CF4 or NF3 gas): Si3N4 + 12F → 3SiF4 + 2N2
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(e) Remove the resist by using O2 plasma or sulfuric acid:
both of them do not attack Si3N4 and SiO2.
(f) LOCOS at 1000 ℃ for 90 min in H2O to grow ~500 nm
of SiO2 on the exposed region Si3N4 is a very dense
material and prevents H2O and O2 from diffusing to the
underlying Si.
The lateral diffusion of oxidant (H2O) from SiO2 cause
bird’s beak and reduce the active region (decrease
…………….
device density). Figure 2-3 Mask 1 patterns the photoresist. The Si3N4
( g ) Stripping Si3N4 in hot phosphoric acid. layer is removed where it is not protected by photoresist
The acid is highly selective between Si3N4 and SiO2. by dry etching.
Active region shrinking
(Bird’s beak)
(h) Alternative to SiO2/Si3N4 stack:
Poly SiO2/Si3N4/SiO2 (Poly-buffered LOCOS)
Poly SiO2 (~100 nm) is formed by LPCVD. Expansion of field oxide
Poly SiO2 helps release large stresses which
would cause defects in Si during the LOCOS.
(a) Using optical lithography to define the region where P well is to be formed.
(b) Implantation of boron ions for P well.
(c) Strip resist chemically or in O2 plasma.
The energy of the boron ions must be large enough to (d) Thermal annealing for repairing the damaged
go through “thin” and “thick” oxide regions, but small lattice: Ex.10 sec. at 1000 ℃ or 30 min at 800 ℃
enough not to go through the resist layer. (e) Follow similar procedure of optical lithography
for the N well formation.
The energy is in the range of 150 – 200 keV. (Boron)
Thick oxide ~ 0.5 μm. Thin oxide
The dose depends on the desired doping level in the ~ < 0.1 μm. Photoresist ~ 1 μm.
well. For doping level 1017cm-3, we need dose on the (f) Implantation of phosphorus ions for N well.
13
order of 10 cm . -2
The energy of the phosphorus ions
must be large enough to go through
“thin” and “thick” oxide regions, but
small enough not to go through the
resist layer.
The energy is in the range of 300 – 400
keV to reach the same depth in Si
Thick oxide ~ 0.5 μm Thin oxide
because phosphorus is a heavier atom.
(Phosphorus)
(field oxide) < 0.1 μm
…………….
To avoid parasitic Figure 2-9 Photoresist is used to mask the regions where PMOS devices
inversion problem will be built using mask 2. A boron implant provides the doping for the P
wells for NMOS devices.
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(g) Removing the resist and anneal at 1000-1100 ℃
for 4-6 hrs to reach a junction depth of 2-3
µm (drive-in process).
Field implant
Drive‐in process
………………… …………………
Figure 2-13 Process option for active region formation after Figure 2-14 Process option for active region formation after the
LCCOS. The boron implanted regions diffuse ahead of growing P and N wells are formed.
oxide producing the P-doped regions under the field oxide.
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(ii) Buried and epitaxial layer
This option is to shunt the parasitic PNPN structures with low
resistance, preventing the PNPN devices (letch up) from
turning on.
(a) High-dose (1015 cm-2) is used to implant N+
buried layer.
Due to the thin oxide layer, a low-energy (~50 keV) N+ for low-resistance shunt
is sufficient. We do not want the implanted atoms
diffuse too far away in subsequent high temperature
process, so we use low diffusion-coefficient As or Sb.
…………….
(b) Remove the resist and do the LOCOS at Figure 2-15 Process option incorporating buried and
1000 ℃ for 2 hrs. epitaxial layers. Mask 1 defines the regions for N+
buried layers. An AS+ implant dopes the silicon locally.
It drives in the N+ layer to a depth of 1~2 μm.
It grows a thick oxide layer on top of N+ buried layer.
The thick oxide form a mesa which indicates the
location of buried layer and hence acts as an
alignment marker for later process.
…………….
Figure 2-18 Process option incorporating buried and
epitaxial layers. The P+ and N+ buried layer are driven
together.
Figure S5 CMOS structure with latch‐up parasitics in cross section view & equivalent
circuit for latch‐up parasitics.
2ε 𝑞𝑁 2ф
𝑽𝑻𝑯 𝑉 2ф
𝐶
𝑉 Gate voltage required to compensate for work
function difference between the gate and substrate
Because NA achieved by ion implantation is not constant (nonuniform profile), we modify the above
equation with the first order approximation of the implant dose QI.
ф 𝒒𝑸𝑰
𝑽𝑻𝑯 𝑉 2ф
𝑪𝒐𝒙
Therefore, the VTH can be obtained by adjusting QI through (b) to (d), and COX through (e) to (f).
scaled down as the dimension does because then new ICs VDS = 5 V
………………… …………………
Figure 2-34 An unmasked oxide etch removes the SiO2 from Figure 2-33 A final high-temperature drive-in
the devices source drain regions and from the top surface of activates all the implanted dopants and diffuses
the polysilicon. junctions to their final depth.
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On the side where Ti exposes to N2 a layer of TiN
is formed. It is also conductive, but not as high as normal Ti film
metals. It can be used for local interconnect, but not for
long-distant interconnect in which significant RC delays
occur.
(d) Optical lithography to define the pattern where we want
to remain TiN on the wafer.
(e) The remaining TiN is etched in NH4OH:H2O2:H2O
(1:1:5). …………………
(f) Annealing in an Ar ambient at ~800 ℃ for 1 min to Figure 2-35 Titanium is deposited on the wafer
reduce the resistivity of the TiN and TiSi2 to the final surface by sputtering.
value.
TiN forms a continuous film on top
The spacer also serves the function of separating TiSi2 is only formed in the area contacted
the TiSi2 on the poly gates from contacting the Si
doped regions.
…………………
………………… Figure 2-36 Titanium is reacted in an N2
Figure 2-37 Photoresist is applied and mask 11 is used to define the ambient, forming TiSi2 where it contacts silicon
regions where TiN local interconnects will be used. The TiN is then or polysilicon (black regions in the figure) and
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2.2.10 Multilevel metal formation
Till now, the surface is full of hills and valleys which make
the subsequent metal interconnects discontinuous. We
need to flatten the surface topography.
(a) The first method is to grow a fairly thick
SiO2 layer by CVD.
The SiO2 layer (~1 μm) is thicker than the largest steps.
This SiO2 layer is often doped with phosphorus and
sometimes with boron as well, known as PSG
(phosphosilicate glass) and BPSG (borophosphosilicate …………………
Figure 2-38 After stripping the photoresist, a
glass), respectively. conformal SiO2 layer is deposited by LPCVD.
Phosphorus provides some protection against mobile
ions like Na+ which causes instabilities in MOS
devices. (Chap. 4)
Boron reduces the temperature at which the glass “flows”.
Spinning a layer of photoresist to make the whole wafer
flat because resist is a liquid and can fill up the valleys
well.
Plasma etching with a recipe which has 1:1 etching rate
for the resist and SiO2 until the underlying SiO2 is etched …………………
everywhere. Figure 2-39 Chemical-Mechanical Polishing
(CMP) or resist etchback is used to polish or
(b) The second method which is widely used etchback the deposited SiO2 layer. This
today is chemical mechanical polishing (CMP). planarizes the wafer surface.
………………… …………………
Figure 2-42 CMP is used to polish back the W and TiN Figure 2-41 A thin TiN barrier/adhesion layer is
layers, leaving a planar surface on which the first level deposited on the wafer by sputtering, followed by
of metal can be deposited. deposition of a W layer by CVD.
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(j) Al with a small percentage of Si and Cu is
deposited and then etched, as shown in Fig. 2-43.
The containing Si is to
prevent the absorption of Si from underlying Si-rich
layers. The Cu is added to prevent from
electromigration in Al.
…………………
Figure 2-44 The steps to form the second level of Al
interconnect follow those in Figures 2-38 to 2-43.
Mask 14 is used to define via holes between metal 2
and metal 1. Mask 15 is used to define metal 2. The
last step in the process is deposition of a final
passivation layer, usually Si3N4 deposited by PECVD.
The last mask “16” is used to open holes in this mask
over the bonding pads.
Figure S3 Approach to fabricate 3-D stacked-Si nanosheet for GAA (GAA = gate-all-around)
devices. (a) Stack of Si/SiGe superlattice grown on SOI substrate. (b) Anisotropic plasma
etching achieved in an inductively coupled plasma (ICP) reactor. (c) Innovative process
proposed to achieve the isotropic and selective etching of SiGe layers in an Reactor
protection system (RPS) reactor: cycle of a two-step process alternating oxidation and etch.
(d) Release of horizontal Si nanowires.
(Double
side
polished)
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Latch‐up effect
Figure S5 CMOS structure with latch‐up parasitics in cross section view & equivalent
circuit for latch‐up parasitics.
Input Outpu
t Input Output
GND
GND
Diffusion layer drawing Well layer drawing Metal layer drawing
VDD
Input Output
GND
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