SECTION-I (PHYSICS)

SECTION - A 5. Two small balls having equal charges Q, are

1. The capacitor of capacitance 4 F and 6 F are suspended from a hook with two insulating threads
connected in series. A potential difference of 500 each of length L. This arrangement is carried in the
volts is applied to the outer plates of the two space, where there is no gravitation. The tension in
capacitor system. Then the charge on each each string will be-
capacitor is numerically-
kQ 2
(1) 6000 C (1)
4 L2
(2) 1200 C
(2) 0
(3) 1200 C
kQ
(4) 6000 C (3)
4 L2

2. In a region where E = 0, the potential (V) varies kQ 2

(4)
with distance r as- L2
(1) V  1/r
(2) V  r 6. Three capacitors are connected to D.C. source of
100 volts as shown in the adjoining figure. If the
(3) V  1/r2
charge accumulated on plates of C1, C2 and C3 are
(4) V = constant
qa, qb, qc, qd, qe and qf respectively, then-

3. Two spherical conductors A1 and A2 of radii (r1)

and (r2) (r2 > r1) are placed concentrically in air. A1
is given a charge +Q while A2 is earthed. Then the
capacitance of the system is-
r1  r2
(1) 40
r2 − r1
(2) 40 (r2 − r1 ) 100
(1) qb + qd + qf = C
(3) 40 . r2 2
(2) qb + qd + qf = 0
r2
(4) 40 2 (3) qa + qc + qe = 50 C
r2 − r1
(4) qb = qd = qf

4. One quantum of charge should be at least be equal

to the charge in coulomb- 7. If a body is charged by rubbing it, its weight-
(1) 1.6 × 10–17 C (1) Always decreases slightly
(2) 1.6 × 10–19 C (2) Always increases slightly
(3) 1.6 × 10–10 C (3) May increase slightly or may decrease slightly
(4) 4.8 × 10–10 C (4) Remains precisely the same
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8. Six charges +Q each are placed at the corners of a 12. A small circular ring has a uniform charge
regular hexagon of side (a), the electric field at the distribution. On a far-off axial point distance x
centre of hexagon is- from the centre of the ring, the electric field is
(1) Zero proportional to-
(1) x–1
1 6Q2
(2)  2 (2) x–3/2
40 a
(3) x– 2
1 Q2 (4) x5/4
(3)  2
40 a
13. An electric dipole consists of two opposite charges
1 6Q 2 each of magnitude 1 × 10–6 C separated by a
(4) 
40 a 2 distance 2 cm. The dipole is placed in an external
field of 10 × 105 N/C. The maximum torque on the
9. In the circuit diagram shown in the adjoining dipole is -
figure, the resultant capacitance between P and Q (1) 0.2 × 10–3 N-m
is- (2) 1.0 × 10–3 N-m
(3) 2 × 10–2 N-m
(4) 4 × 10–3 N-m

14. The capacitance of a spherical condenser is 1 F.

If the spacing between the two spheres is 1 mm,
then the radius of the outer sphere is-
(1) 30 cm
(2) 6 m
(1) 47 F
(3) 5 cm
(2) 3 F (4) 3.5 m
(3) 60 F
(4) 10 F 15. A capacitor having capacitance C is charged to a
voltage V. It is then removed and connected in
10. Two particles A and B having masses equal and parallel with another identical capacitor which is
charges q and 4q. If these are accelerated from rest uncharged. The new charge on each capacitor is
through same potential difference, then what will now-
be the ratio in their speeds? (1) CV
(1) 4 : 1 (2) CV/2
(2) 1 : 4 (3) 2 CV
(4) CV/4
(3) 2 : 1
(4) 1 : 2
16. Two charges 4q and q are placed 30 cm. apart. At
what point the value of electric field will be zero-
11. In a conductor the charges reside on the - (1) 10 cm. away from q and between the charge
(1) Outer surface of the charged conductor (2) 20 cm. away from q and between the charge
(2) Inner surface of the charged conductor (3) 10 cm. away from q and out side the line
(3) Inner as well as outer surface of the charged joining the charge.
conductor (4) 10 cm. away from 4q and out side the line
(4) None of the above joining them.
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17. The dimensions of potential difference are- (1) 1.5 and 1.33
(1) ML2T–3A–1 (2) 1.33 and 1.5
(2) MLT–2A–1 (3) 3.0 and 2.67
(3) MT–2A–2 (4) 2.67 and 3.0
(4) ML2T–1A–1
21. The force between two point charges in vacuum is
18. Four condensers each capacity 4 F are connected 15 N, if a brass plate is introduced between the two
as shown in figure VP – VQ = 15 volts. The energy charges, then force between them will-
stored in the system is- (1) Becomes zero
(2) Remains the same
(3) Becomes 30 N
(4) Becomes 60 N

22. Four capacitors of each capacity 3 F are

connected as shown in the adjoining figure. The
(1) 2400 ergs ratio of equivalent capacitance between A and B
(2) 1800ergs
and between A and C will be-
(3) 3600 ergs
(4) 5400 ergs

19. A square of side ‘a’ has equal charge ‘q’ at its

corners. The magnitude of force at B will be-

(1) 4:3
(2) 3:4
(3) 2:3
(4) 3:2
1 kq 2
(1) (1 + 2 2) 23. An electron falls a distance of 4 cm in a uniform
2 a2
electric field of magnitude 5 × 104 N/C. The time
1 k 2q2 taken by electron in falling will be
(2)
2 a2 (1) 2.99 × 10–7 s
4kq 2 (2) 2.99 × 10–8 s
(3)
a2 (3) 2.99 × 10–9 s
(4) None of these (4) 2.99 × 10–10 s

20. A capacitor 4 F charged to 50 V is connected to 24. An electric field can deflect

another capacitor of 2 F charged to 100 V with (1) X-rays
plates of like charges connected together. The total (2) Neutrons
energy before and after connection in multiples of (3) -particles
(10–2 J) is- (4) -rays
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25. The K.E. in electron Volt gained by an -particle (1) Pressure v/s temperature of a given gas
when it moves from rest at point where its potential (constant volume)
is 70 to a point where potential is (2) Kinetic energy v/s velocity of a particle
50 volts, is (3) Capacitance v/s charge at a constant potential
(1) 20 eV
(4) Potential v/s capacitance at a constant charge
(2) 20 MeV
(3) 40 eV
(4) 40 MeV 29. The surface of a conductor
(1) Is a non-equipotential surface
26. Four plates of the same area A of cross-section are (2) Has all the points at the same potential
joined as shown in the figure. The distance between (3) Has different points at different potential
each plate is d. The equivalent capacity across AB
(4) Has at least two points at the same potential
will be

30. A glass slab is put with in the plates of a charged

parallel plate condenser. Which of the following
quantities does not change?
(1) Energy of the condenser
2 0 A (2) Capacity
(1)
d (3) Intensity of electric field
3 0 A
(2) (4) Charge
d
3 0 A
(3) 31. Charge 2q, –q & –q lies at the vertices of a
2d
equilateral triangle. The value of E and V at the
0 A
(4) centroid of the triangle will be-
d
(1) E  0 and V  0
27. The force between an -particle and an electron (2) E = 0 and V = 0
separated by a distance of 1 Å is (3) E  0 and V = 0
(1) 2.3 × 10–8 N attractive (4) E = 0 and V  0
(2) 2.3 × 10–8 N repulsive
(3) 4.6 × 10–8 N attractive 32. Two-point charges in air at a distance of 20 cm.
(4) 4.6 × 10–8 N repulsive from each other interact with a certain force. At
what distance from each other should these charges
28. What physical quantities may X and Y represent? be placed in oil of relative permittivity
5 to obtain the same force of interaction –
(1) 8.94 × 10–2 m
(2) 0.894 × 10–2 m
(3) 89.4 × 10–2 m
(4) 8.94 × 102 m
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33. In the connection shown in the adjoining figure. the 36. The energy of a charged capacitor resides in -
equivalent capacity between A and B will be- (1) The electric field only
(2) The magnetic field only
(3) Both the electric and magnetic fields
(4) Neither in electric nor magnetic field

37. A charge Q is divided in two parts Q1 and Q2 and

these charges are placed at distance R. there will be
maximum repulsion between them, when-
(1) Q2 = (Q/R), Q1 = Q – (Q/R)
(1) 8 F
(2) Q2 = (Q/3), Q1 = (2Q/3)
(2) 12 F
(3) 20 F (3) Q2 = (Q/4), Q1 = (3Q/4)
(4) 10 F (4) Q1 = Q2 = Q/2

38. A proton is first placed at A and then at B between

34. In the fig. given below, the potential energy of the the two plates of a parallel plate capacitor charged
system will be to a P.D. of V volt as shown. Then force on proton
at A is

(1)
kq 2
a
(
2 −4 )
kq 2
(2)
a
(3) 0
(1) More than at B
(4)
kq
a
( 2 −4 ) (2)
(3)
Less than at B
Equal to that at B
(4) Nothing can be said
35. Two condensers of capacities 2 C and C are joined
in parallel and charged upto potential V. The 39. Two similar charge of +Q, as shown in figure are
battery is removed and the condenser of capacity C placed at A and B. –q charge is placed at point C
is filled completely with a medium of dielectric midway between A and B. –q charge will oscillate
constant K. The p.d. across the capacitors will now if
be -
3V
(1)
K +2
3V
(2)
K
V
(3) (1) It is moved towards A
K +2 (2) It is moved towards B
V (3) It is moved upwards AB
(4)
K (4) Distance between A and B is reduced
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40. A parallel plate condenser has plates of area 0 A
200 cm2 and separation 0.05 cm has been filled (1)
 1
with a dielectric having K = 8 and then charged to d + t 1 − 
 K
300 volts. The final energy of condenser is
(1) 1.6 × 10–5 J 0 A
(2)
(2) 2.0 × 10–6 J  1
d + t 1 + 
(3) 12.8 × 10–5 J  K
(4) 64 × 10–5 J 0 A
(3)
 1
41. Seven capacitors each of capacitance 2 F are to d − t 1 − 
 K
be so connected to have total capacity
10 0 A
µF. Which will be the necessary figure as (4)
 1
11 d − t 1 + 
shown  K

44. A solid conducting sphere having a charge Q is

(1)
surrounded by an uncharged concentric conducting
hollow spherical shell. Let the potential difference
between the surface of the solid sphere and that of
the outer surface of the hollow shell be V. If the
shell is now given a charge of 3 Q, the new potential
(2)
difference between the same two surfaces is
(1) V
(2) 2 V
(3) (3) 4 V
(4) –2 V

45. In fig. shown the electric lines of force emerging

(4)
from a charged body. If the electric fields at A and
B are EA and EB are respectively and the distance
between A and B is r then
42. The electric potential V at any point (x, y, z) in
space is given by V = 4x2 volt. The electric field
E (in V/m) at the point (1, 0, 2) is
(1) +8 in x direction
(2) 8 in –x direction
(3) 16 in +x direction
(4) 16 in –x direction

43. Separation between the plates of a parallel plate

(1) EA > EB
capacitor is d and the area of each plate is A. When
a slab of material of dielectric constant K and (2) EA < EB
thickness t (t < d) is introduced between the plates, (3) EA = EB
its capacitance becomes. (4) EA = (EB)/r2
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46. The flux emerging out from any one face of the
cube when a point charge q is placed at its centre

q
(1)
60

q
(2)
30

q
(3)
0
(1) 0
q
(4) (2) Er
4 0
(3) Er/2
(4) Er/4
47. The capacitance of a capacitor, filled with two
dielectrics of same dimensions but of dielectric
constants K1 and K2 respectively as shown will be
49. A RC series circuit is connected to a battery of
e.m.f E. The time required by the capacitor to
acquire maximum charge, depends upon
(1) R only
(2) C only
(3) R C
0 A
(1) ( K1 + K 2 ) (4) Applied potential difference
2d
0 A
(2) ( K1 + K 2 ) 50. The bob of a pendulum carries an electric charge of
d
39.2 × 10–10 coulomb in a horizontal electric field
0 A  K1K2  of 20 × 103 V/m and it is at rest. The angle made
(3)  
2d  K1 + K2  by the pendulum with the vertical will be, if the
mass of pendulum is 8 × 10–6 kg and
0 A  K1K2  g = 9.8 m/s2
(4)  
d  K1 + K2 
(1) 27°
(2) 45°
48. In the adjacent fig. a unit positive charge moves (3) 87°
along the path ABC in an electric field E. The
potential difference between A & C will be (4) 127°

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 SECTION-II (CHEMISTRY)
SECTION - A
51. The packing efficiency of the two dimensional
square unit cell shown below is (3)

(1) 39.27% (4)

(2) 68.02%
(3) 74.05%
(4) 78.54%
55. A graph between log t1/2 and log a (abscissa)
52. TiO2 is well known example of:
[a being the initial concentration of A in the
(1) Triclinic system
reaction] is given below for reaction A → 4B the
(2) Tetragonal system
rate law is
(3) Monoclinic system
(4) None of these

53. 𝑎 ≠ 𝑏 ≠ c,  = γ = 90o,   90° represents:

(1) Tetragonal system
−d[A]
(2) Orthorhombic system (1) =K
(3) Monoclinic system dt
(4) Triclinic system −d[A]
(2) = K[A]
dt
54. N2O5 → 2NO2 + O2
−d[A]
When N2O5 decompose, its t12 does not change (3) = K[A]2
with its changing pressure during the reaction, so dt
which one is the correct representation for −d[A]
(4) = K[A]3
“pressure of 2NO2 vs time” during the reaction dt
when initial pressure of N2O5 is equals to Po.

56. Compounds A and B react with a common reagent

(1) with first order kinetics in both cases. If 99% of A
must react before 1% of B has reacted. What is the
minimum ratio for their respective rate constants?
(1) 916
(2) 229
(2)
(3) 500
(4) 458
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57. The activity per ml of a solution of radioactive 61. Consider a Body Centered Cubic(bcc)
substance is x. How much water be added to arrangement. Let de, dfd, dbd be the distances
200 ml of this solution so that the activity falls to between successive atoms located along the edge,
x/20 per ml after 4 half-lives? the face-diagonal, the body diagonal respectively
(1) 100 ml in a unit cell.Their order is given by:
(2) 150 ml (1) de < dfd < dbd
(3) 80 ml (2) dfd > dbd > de
(4) 50 ml. (3) dfd > de > dbd
(4) dbd > de > dfd,
58. The inversion of cane sugar proceeds with half life
of 600 minute at pH = 5 for any concentration of 62. The shortest distance between I st and Vth layer of
sugar, However at pH = 6, the half life changes to HCP arrangement is:
60 minute, The rate law expression for sugar
2
inversion can be written as (1) 8 r
3
(1) r = k [sugar]2 [H+]°
(2) r = k [sugar]' [H+]° 3
(2) 4 r
(3) r = k [sugar]2 [H+]1 2
(4) r = k [sugar]°[H+]-1 (3) 16
2
r
3
59. The reaction 2NO + Br2 ⎯⎯
→ 2NOBr follows the (4) 8
3
r
mechanism: 2
Fast
(1) NO + Br2 NOBr2
Show
63. Which of the following shaded plane in fcc lattice
(2) NOBr2 + NO ⎯⎯⎯ → 2NOBr contains arrangement of atoms as shown by
Which of the following is false regarding this: circles:
(1) The order of the reaction with respect to NO
is two
(2) The molecularity of the steps (1) and (2) are
two each.
(3) The molecularity of the overall reaction is Figure
three.
(4) The overall order of the reaction is three. (1)

60. In the following gaseous phase first order reaction

A(g) ⎯⎯ → 2B(g) + C(g) (2)
initial pressure was found to be 400 mm of Hg and
it changed to 1000 mm of Hg after 20 min. Then
Half life for A is: (3)
(1) 10 min
(2) 20 min
(3) 30 min (4)
(4) 50 min
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64. If the close packed structure of AB type solid have fraction of liquid A in liquid and vapour phase
cation radius of 75 pm, what would be the respectively) is linear with slope and y intercepts
maximum and minimum sizes of the anions which respectively:

( PAº − PBº )
form voids in unit cell ?
(1) r –minimum = 101.45, r –maximum = 303.3 pm PAº
(1) and
(2) r –minimum = 105.45, r –maximum = 300.3 pm PBº PBº

(3) r –minimum = 102.45, r –maximum = 333.3 pm

– – (2)
PAº
and
( PBº − PAº )
(4) r minimum = 98.4, r maximum = 333.3 pm
PBº PBº

65. In an FCC unit cell, atoms are numbered as shown

(3)
PBº
and
( PAº − PBº )
below. The pair of atoms not touching each other
PAº PBº
are:
(Atom numbered 3 is face centre of front face).
(4)
PBº
and
( PBº − PAº )
PAº PBº

68. Two liquids A and B have PA0 : PB0 = 1: 3 at a

certain temperature. If the mole fraction ratio of XA :
(1) 3 & 4
XB = 1:3, the mole fraction of A in vapour in
(2) 1 & 3 equilibrium with the solution at a given
(3) 1 & 2 temperature is:
(4) 2 & 4 (1) 0.1
(2) 0.2
66. Analysis show that nickel oxide consist of nickel
(3) 0.5
ion with 96% ions having d8 configuration and 4%
having d7 configuration. Which amongst the (4) 1.0
following best represents the formula of the oxide.
(1) Ni1.02O1.00 69. Elevation in boiling point of an aqueous solution
(2) Ni0.96O1.00 of glucose is 2K. Find the depression in freezing
(3) Ni0.96O0.98 point of the same solution. (Kf = 1.86 K kg/mole
and Kb = 0.52 K kg/mole)
(4) Ni0.98O1.00
(1) 2.16 K

67. Consider two liquids A & B having pure vapour (2) 7.14 K
pressures PA0 & PB0 forming an ideal solution. The (3) 3.38 K
1 1 (4) 6.28 K
plot of v/s (where XA and YA are the mole
XA YA

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70. When FeCl3 reacts with K4[Fe(CN)6] in aqueous 73. H2O2 solution used for hair bleaching is sold as a
solution, blue colour of ferri ferrocyanide, solution of approximately 5.0 g H2O2 per 100 mL
Fe4[Fe(CN)6]3 is obtained. There are 0.1 M FeCl3 of the solution. The molecular mass of H2O2 is 34.
and 0.01 M K4[Fe(CN)6] solution separated by a The molarity of this solution is approximately:
semi-permeable membrane as shown and osmosis (1) 0.15 M
occurs then (2) 1.5 M
(3) 3.0 M
(4) 3.4 M

74. A radioactive substance decays 20% in 10 minutes.

In how much time, number of atoms are reduced
from 5 × 1020 to 1018 atoms.
(1) 6.6 hr
(1) blue colour is seen in side-B (2) 4.65 hr
(3) 2.77 hr
(2) blue colour is seen in side-A
(4) 3.6 hr
(3) blue colour is seen in both sides A and B.
(4) no blue colour is seen in either side. 75. Two compounds A[half life = 54min] and
B[half life = 18min] kept in same flask, decay by
first order Kinetics. Initially [A] = [B] then in how
71. 5 g of urea is dissolved in one kg of water. Up to many minutes, Concentration of A become 4
what temperature, the solution may be cooled times that of B?
before ice starts crystallizing out? (1) 54
(Kf of water = 1.86) (2) 18
(3) 27
(1) –0.310°C (4) 36
(2) –0.240°C
76. A solution containing 10 g/dm3 of urea is isotonic
(3) –0.195°C
with 5% (%w/v) solution of a non-volatile solute.
(4) –0.155°C What is molar mass of that solute?
(1) 250
(2) 200
72. Benzene and toluene form an ideal solution.
(3) 350
The vapour pressure of pure benzene at 55°C is
(4) 300
400 mm Hg while the vapour pressure of pure
toluene at 55°C is 130 mm Hg. What is the vapour 77. Molar mass of AB [rock salt structure] = 6.023 Y
pressure of a solution consisting of 0.5 mole amu; Observed density = 20 kg/m3; the edge =
fraction of benzene and 0.5 mole fraction of
2(y)1/3 nm What type of defect crystal is expected
toluene at 55°C? to have?
(1) Lower than 130 mm Hg (1) Frenkel defect
(2) Between 130 and 400 mm Hg (2) Schottky defect
(3) Metal deficiency defect
(3) Exactly 400 mm Hg
(4) Metal excess defect
(4) Greater than 400 mm Hg
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