Chapter 1_ Semiconductors – Diode
Chapter 1_ Semiconductors – Diode
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I- Introduction to Semiconductors
Valence electrons are located in an atomic nucleus’s outermost shell (the valence shell).
Atoms are the extremely small particles that are the basic building blocks of ordinary matter.
The structure of an atom is given by the following chemical notation:
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The mass of an atom is the sum of the masses of all its nucleons and electrons:
Where ; and
We refer to these shells as energy levels. From the nucleus outward, it is numbered
Since each electron shell is linked to a specific range of electron energy and can only
hold a certain number of electrons, each shell must be fully filled before electrons may be
added to an outer shell. Starting from the one closest to the kernel (Kernel means “nucleus”).
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Higher the value of ‘n’ the greater the distance of the shell from the nucleus.
( )
Energy separation between two shells decreases on moving away from the nucleus.
(( ) ( ) ( ) )
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An atom contains electrons at various energy levels. Each atom's level must split into N
levels in the solid when we attempt to create a solid's lattice with N atoms. Energy Bands are
created by this division of closely spaced, acute energy levels. A band gap is the space
between neighbouring bands that represent a range of energies devoid of electrons. So, in a
solid (crystal), which is made up of the assembly (interaction) of a very large number of
atoms, the energy levels are changed into energy bands, in contrast to an isolated atom
where electrons exist only at discrete energy levels. The energy bands are:
Two so-called permitted bands: the valence band and the conduction band.
A band known as the gap band.
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a- Valence Band (VB): The energy band involving the energy levels of valence
electrons is known as the valence band. It is the highest occupied energy band.
When compared with insulators, the band gap in semiconductors is smaller. It
allows the electrons in the valence band to jump into the conduction band on
receiving any external energy.
b- Conduction Band (CB): It is the lowest, unoccupied band that includes the
energy levels of positive (holes) or negative (free electrons) charge carriers. It
has conducting electrons resulting in the flow of current. The conduction band
possesses a high energy level and is generally empty. The conduction band in
semiconductors accepts the electrons from the valence band.
c- Gap Band (GB): contains no electrons (intermediate energy level). It is also
called the “Gap”, starting with the one closest to the nucleus.
For example, if you shine a light on a photovoltaic plate, the plate becomes conductive
and an electric current is created: this is the photoelectric effect
(𝑒𝑉)
where Eg(0), a and b are the fitting parameters. These fitting parameters are listed for
germanium (Ge), silicon (Si) and gallium arsenide (GaAs), in following Table:
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Example : Calculate the energy bandgap of germanium, silicon and gallium arsenide at 300,
400, 500 and 600° K(Kelvin).
Solution : The bandgap of silicon at 300 K equals:
Similarly one finds the energy bandgap for germanium and gallium arsenide, as well as at
different temperatures, yielding:
Important note: The lower the “Gap”, the more conductive the material. It therefore plays an
important role in distinguishing materials into insulators, semiconductors and conductors.
For conductors, the valence and conduction bands overlap (no GB). A small energy
source is enough to move a large number of free electrons from the VB to the CB.
For insulators, the GB is large ( of the order of 7e.V). The CB contains no electrons.
Even under high temperature or high voltage (e.m.f.), these materials do not conduct.
For semiconductors, the GB is relatively small ( of the order of 1e.V). Electrons
occupy energy levels within the VB.
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A semiconductor can be either pure, in which case it is said to be “intrinsic”, or doped with
impurities, in which case it is said to be “extrinsic”. Note: In the case of semiconductors: ρ
decreases if increases. can vary considerably in the presence of impurities (doping).
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Example:
Intrinsic semiconductor: the resistivity of pure silicon is of the order of .
Extrinsic semiconductor: the resistivity of silicon doped with boron or phosphorus is of
the order of .
The silicon doped with extra electrons is called an “N type” semiconductor. “N” is for
negative, which is the charge of an electron.
The silicon doped with material missing electrons that produce locations called holes is
called “P type” semiconductor. “P” is for positive, which is the charge of a hole.
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If the material is pure semiconductor material like silicon, the crystal lattice structure forms an
excellent insulator since all the atoms are bound to one another and are not free for current
flow. To make the semiconductor conduct electricity, other atoms called impurities must be
added “Impurities” are different elements. This process is called doping. Any doping will serve
to modify the balance between electrons and holes, to favor electrical conduction by one of
the two types of carrier.
Two of the most important materials silicon can be doped with, are boron (3 valence
electrons = 3-valent) and phosphorus (5 valence electrons = 5-valent). Other materials are
aluminum, indium (3-valent) and arsenic, antimony (5-valent).
The dopant is integrated into the lattice structure of the semiconductor crystal, the number of
outer electrons define the type of doping. Elements with 3 valence electrons are used for P-
type doping, 5-valued elements for n-doping. The conductivity of a deliberately contaminated
silicon crystal can be increased by a factor of 106.
If sufficient thermal energy is supplied to the crystal: (E G = 0.72eV for Ge; EG = 1.1 eV
for Si; EG = 1.42 eV for AsGa). Several of the covalent bonds can be destroyed, releasing an
electron. The atom with 1 electron less on its outer layer therefore carries a positive electric
charge q = + 1.6 10-19 C. Such a lack of an electron in a covalent bond is called a hole.
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of intrinsic semiconductor elements. They have four valence electrons (tetravalent). They are
bound to the atom by a covalent bond at absolute zero temperature.
At absolute zero Kelvin temperature: At this temperature, the covalent bonds are very
strong, there are no free electrons, and the intrinsic semiconductor behaves as a perfect
insulator.
As the temperature rises, the electron's energy increases, releasing it from the valence band
and creating a hole. Thermal agitation therefore creates electron-hole pairs, the number of
which is determined by intrinsic concentration given by:
𝑛 is the electron carrier
− density, 𝑝 is the hole
( ) ( )
carrier density
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with the electron mobility, the hole mobility, is the electron carrier density electron
carrier density, is the hole carrier density and intrinsic concentration of each type of free
carrier.
In intrinsic semiconductors, current flows due to the motion of free electrons, as
well as holes. The total current is the sum of the electron current due to
thermally generated electrons and the hole current .
N-Type Semiconductor
Mainly due to electrons
Entirely neutral
I = Ie and ne >> nh
Majority – Electrons and Minority – Holes
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Thus, the impurity atom donates a free electron for conduction in the lattice and is
called a “Donar“. Since the number of free electrons increases with the addition of an
impurity, the negative charge carriers increase. Hence, it is called an n-type semiconductor.
P-Type Semiconductor
Mainly due to holes
Entirely neutral
I = Ih and nh >> ne
Majority – Holes and Minority – Electrons.
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This result in a potential difference across the depletion region (i.e. between junction N
and P) called Junction potential or Barrier Potential:
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where is the diffusion current and is the saturation or leakage current due to the
transport of minority carriers. At equilibrium | | | |. The displacement of these minority
electrons creates a very small current called the saturation current . This current flows in
the opposite direction to the diffusion current
If a suitable positive voltage (Forward bias) is applied between the two ends of the PN
junction, it can supply free electrons and holes with the extra energy they require to
cross the junction as the width of the depletion layer around the PN junction is
decreased.
By applying a negative voltage (Reverse bias) results in the free charges being pulled
away from the junction resulting in the depletion layer width being increased. This has
the effect of increasing or decreasing the effective resistance of the junction itself
allowing or blocking the flow of current through the diodes PN-junction.
II.3.1- Forward Bias PN Juction Diode (see the following figure)
A PN junction is said to be “forward polarized” if the “P” region is connected to a higher
potential than the “N” region: . When a diode is connected in a Forward Bias
condition, a negative voltage is applied to the N-type material and a positive voltage is applied
to the P-type material. If this external voltage becomes greater than the value of the potential
barrier, approx. 0.7 volts for silicon and 0.3 volts for germanium, the potential barriers
opposition will be overcome and current will start to flow.
opposite to 𝐸𝑖
In this situation, this external field
created by the emf generator V
opposes to the internal field. Soe
the total field is given by:
𝐸 𝐸𝑒𝑥𝑡 𝐸𝑖 .
As soon as the external field exceeds
the internal field, the potential
barrier drops (𝑉 − 𝑉0
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condition, a positive voltage is applied to the N-type material and a negative voltage is applied
to the P-type material. The positive voltage applied to the N-type material attracts electrons
towards the positive electrode and away from the junction, while the holes in the P-type end
are also attracted away from the junction towards the negative electrode .
The depletion layer grows wider due to a lack of electrons and holes and presents a high
impedance path, almost an insulator and a high potential barrier is created across the
junction thus preventing current from flowing through the semiconductor material.
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A. Diode equation describes the exact current through a diode, given the voltage dropped
across the junction, the temperature of the junction, and several physical constants. So,
the voltage V between the anode and cathode of a diode, and the current I flowing
through it, are related by an exponential relationship such that:
( − ) ( )
Where is the diode current, is the saturatuion current (typically 10-12 A), is the charge
of an electron (1,6 10-19 C) , is the voltage applied across diode, kB is Boltzmann's constant
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(8,617× 10−5 eV K-1) , and T is the Junction temperature in Kelvins). η is the emission coefficient,
which is 1 for germanium devices and 2 for silicon devices.
B. The current-voltage characteristic of a diode is described by the diode equation
The expression is
exponential and
then tends to
become linear
(straight line)
from the
threshold voltage
𝑉0 (Knee).
To obtain the characteristic of a diode, we use the electrical circuit shown below and perform
the experiment by varying the source voltage E in forward and reverse bias.
Zone 0A: diode is forward-biased, but the voltage is too low to unblock the junction: this is
the forward-blocking zone.
Zone AB: the voltage V begins to unblock the diode: this is the elbow zone (Knee zone
Zone BC: the diode passes, a linear zone.
Zone OE: the diode is reverse-biased, the reverse blocking zone.
Zone EF: the intensity raises sharply, the breakdown zone.
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To make the diode work, we need to bias it. It means place diode in a circuit so as to create a
voltage between its terminals and a current of intensity (direct current or for
Forward) flowing through it:
Blocked diode: , preventing current flow:
Passing diode: , which results in Vseuil (or 0 or for Forward) is
the threshold voltage.
The real diode can be represented (modeling) by the equivalent diagram below:
𝑽𝑫 𝑽𝟎 𝑹𝑫 𝑰𝑫
Reverse biased diode : the current (in the opposite direction) increases very
slowly with the inverse voltage: reverse current. For a certain voltage value, called the
“Zener voltage” , this current increases rapidly: this is the avalanche phenomenon.
This phenomenon can lead to crystal destruction or “breakdown”.
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Approximations of junction diode characteristics: (a) the ideal diode; (b) ideal diode with an
offset voltage;
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Ideal diode The first approximation is viewing the diode as an ideal diode. With this
first approximation, the diode acts as a perfect switch that doesn't consume any
voltage and doesn't have any internal resistance. It is not used for real-life situations
but just as general approximations when preciseness isn't needed. For certain circuits
where the forward voltage needed to turn on diode is seen as trivial, the first
approximation can be adopted and used. The characteristic of an ideal diode is
illustrated in the figure opposite.
Perfect diode : Ideal diode with voltage offset . In the second approximation, the
diode is seen as as a diode that needs voltage in order to turn on. For a silicon diode,
the diode needs about 0.7V in order to turn on. When the voltage fed into the diode
forward biased is 0.7V or greater, the diode switches on. When the voltage is less than
0.7V, the diode turns off. Practical diode model or Constant Voltage Drop Model
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Real diode : In the third approximation, the diode is seen as a diode that consumes
0.7V (for silicon diode) and voltage across the internal bulk resistance of the diode.
This is most real-world form of a diode and is usually used when a circuit is in design.
The third approximation is crucial if the load resistance is very low. The bulk
resistance, . This model is useful when there is a small varying signal
superimposed to the biasing voltage: Piecewise linear model
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resistance of a is the function of the operating current. The resistance offered by the p-n
junction diode in forward biased condition is called forward resistance. There are two types of
forward resistance.
Static resistance or DC resistance
Dynamic resistance or AC resistance
1- Static resistance or DC resistance (Static Resistance = Voltage / Current)
given by:
( ) ( )
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− 𝑉𝐷 𝑉𝐷𝐷
𝑉𝐷𝐷 𝑉𝐷 𝑅x𝐼 𝐼𝐷 𝐼
𝑅 𝑅
Saturation point (maximum current)
Cut-off point (minimum current). (*)
Since the same current flows through each of the three elements in series, and the voltage
produced by the voltage source and resistor is the voltage across the terminals of the diode,
the operating point of the circuit will be at the intersection of the curve with the load line.
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point or the operating point of a device, also known as a bias point, or Quiescent point is
the steady-state DC voltage or current at a diode with no input signal applied. The static
operating point ( ) is the point of intersection between a diode's static load line and
The lighting emitting diode is a p-n junction diode. It is a specially doped diode and made
up of a special type of semiconductors. When the light emits in the forward biased, then it is
called a light-emitting diode. When an electric current between the electrodes passes through
this diode, light is produced. In other words, light is generated when a sufficient amount of
forwarding current passes through it. In many diodes, this light generated is not visible as
there are frequency levels that do not allow visibility. LEDs are available in different colours.
There are tricolour LEDs that can emit three colours at a time. Light colour depends on the
energy gap of the semiconductor used. The PN junction is formed using the lowest band gap
materials like Gallium Arsenide, Gallium Arsenide Phosphide, Gallium Phosphide, Gallium
Indium Nitride, Aluminum Gallium Nitride, Silicon Carbide etc.
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3- Zener Diode
A Zener diode is an assembly of two semiconductors whose electrical properties were
discovered by the American physicist Clarence Zener.
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The Zener diode is a special diode, that enables the current to flow not only from the
positive terminal (anode) to the negative terminal (cathode) but also in the opposite
direction.
Unlike conventional diodes, which only allow current to flow in one direction, the
forward direction, Zener diodes are designed to allow reverse current to flow as well,
but only if the voltage at their terminals is higher than the avalanche effect threshold.
Diode designed for operation in the reverse breakdown zone, characterized by a
negative threshold voltage or “Zener Voltage” (VZ)
The doping of the Zener diode is more than the conventional diode, so its depletion
Symbol
part has less area.
Application:
Zener diode is mostly used in types of electronic devices like computers, laptops etc, it is
the basic component of the electronic circuitries.
It is used for power stabilizer circuitries to maintain the voltage level for a particular
device.
Zener diode also provides protection to any circuitry from over-voltage, particularly from
ESD (electrostatic discharge). In ESD the current flows suddenly among two charged
points by a short circuit or breakdown of insulation.
Breakdown in Zener diode : There are 2 main breakdown areas in the Zener diode:
Avalanche Breakdown
Zener breakdown
Avalanche breakdown
This type of break-down not only exits in the Zener diode but also in the general diode due
to higher voltage in reversed biased conditions. Due to the larger quantity of electrons, the
backward current will flow from cathode to anode, in some conditions the general diode can
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be damaged. But the Zener diode may not burn because they are sketched to operate under
those conditions. The avalanche breakdown voltage for the Zener is 6 volts.
Zener Breakdown
This type of break-down appears in the high doping diode like Zener, as this diode has less
depletion area due to higher doping. When the voltage provided to the diode increases, in a
thin depletion area highly effective electrical field is established. When the reversed polarity
voltage almost equals the Zener voltage, the electric field in the depletion portion is such
strong that it pulls out the electrons from their valance shells. The outermost shell electron
that gets enough power from the field will break out from the effect of the mother atom.
Due to the free drift of the elections, the reverse current will flow in the diode. The less
increment in the voltage will cause to move current very fastly at the Zener breakdown
portion.
Zener Diode I-V Characteristics
Zener diode works in the reversed biasing conditions is reversed biased mode its anode
is connected with the negative terminal and cathode with the positive terminal of
supply.
The reversing biasing effect of the Zener is shown in the curve between the current and
the voltage.
When the value of applied voltage approaches the Zener voltage then a large amount
of the reversed current flows in the diode and the curve suddenly changes its state.
Due to the instant increase in the current value, the breakdown that happens in the
diode is called the Zener breakdown.
The quantity of the Zener breakdown voltage fluctuates according to the doping level
of the diode (doping level larger breakdown occurs at a lesser voltage; doping less
higher value of the revered supplied voltage).
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In forward bias:
When the applied voltage is lower than the threshold voltage V0 ( ), the
diode does not allow current through it but only the small leakage current.
Once the applied voltage crosses the threshold limit ( ) , the current increases
suddenly while the voltage remains constant. The forward bias operation in the Zener
diode is the same as in any normal diode.
In reverse bias:
The diode does not allow current (but only a small leakage current) until the voltage
reaches the Zener breakdown voltage .
In the region , the current through the diode flows in the reverse direction.
The value of the Zener voltage is determined by the doping concentration in the diode.
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Power Rating : This is the maximum rated power the diode can tolerate. It is the
product of Zener voltage and the current flowing through it. The power ratings of the
Zener diode can range between 400 mW and 5 W.
breakdown region). It is evident from the IV characteristic curve where the Curve is not
completely vertical in the breakdown region
Modeling (equivalent diagrams) of the Zener diode
Note:If the dynamic resistance Rz is neglected ( ), the voltage across the diode when it
conducts in reverse is constant, whatever the current flowing through it. The Zener diode is
ideal.
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( )
∫ ( ) ∫ ( ) ( ) ( )
0 0
( )
√ ∫ ( ) √ ∫ [ ( )] ( ) ( )
0 0
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( )−( − ) ( ) ( ) ( )
Diodes D3 and D4 conduct, and diodes D1 and D2 are blocked. In this case, a negative
current flows through diode D4, load R and diode D3. The voltage across load R is also
positive. The circuit corresponding to this state is shown by:
− ( )−( ) − ( ) ( ) − ( )
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During both half-periods, the load voltage has the same polarity and the output current the
same direction. The circuit is called a full-wave rectifier because it transforms the input AC
voltage into a wavy output voltage.
( )
∫ ( ) ∫ ( ) ( ) ( )
0 0
( )
√ ∫ ( ) √ ∫ [ ( )] ( ) ( )
0 0 √ √
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Considering the resistor R (load) in parallel with the capacitor C (“RC filter”) of the peak
detector circuit, the capacitor will discharge through this resistor according to a dynamic
depending on the time constant τ equal RC (if rapid discharge; if slow discharge)
.Note :
For better filtering, we choose τ much larger than T.
the diode is reverse biased it becomes blocking. The capacitor will retain its
maximum charge (it cannot discharge through R because ( )≈ open circuit).
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Determine filter capacity: During capacitor charging, the filtered voltage changes
from to , i.e.
Clipping is performed at a single level. The circuit used mainly comprises, in series, a
diode with a battery. We have series positive clipper or negative clipper with bias.
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