INTERNAL PAPER 15-02-2021
INTERNAL PAPER 15-02-2021
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(A) 1 sec (B) 2 sec (C) 4 sec (D) 8 sec
5. Which of the following transitions of He ion will give rise to spectral line which has
same wavelength as some spectral line in hydrogen atom?
(A) n 4 to n 2 (B) n 6 to n 5 (C) n 6 to n 3 (D) None of these
6. A particle is attached to the lower end of a uniform rod which is hinged at its other end
as shown in the figure. Another identical particle moving horizontally, collides
inelastically and sticks to it. The minimum speed of moving particle so that the rod with
particles performs circular motion in a vertical plane will be : [length of the rod is ,
consider masses of both particles and rod to be same]
70 175
(A) 10 g (B) 20 g C) g (D) g
3 3
7. The circuit shown in the figure is in steady state for a long time. The connection to
battery is suddenly broken (switch S is opened up). What is the charge (in C ) on the
capacitor after 0.001 sec.?
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24 24 24 24
(A) m,3 m / s (B) m,3 m / s (C) m, 4 / 3 m / s (D) m,8 / 3 m / s
45 25 45 25
9. In the figure, there is a conducting wire having current i and which has a shape of
x2 y2
closed half ellipse 2 2 1 is kept in a uniform magnetic field B as shown. The
a b
magnitude of magnetic dipole moment of loop and torque acting on it are-
abi abiB ab i
(A) abi, 0 (B) ab i, abiB (C) , (D) ,0
2 2 2
10. What minimum speed does a 100 g particle need at point B to reach point A ? The
graph shows potential energy versus position.
(A) 5 s and 10 s (B) 0.5 s and 4.5 s (C) 2 s and 3 s (D) Only 10 s
13. Figure shows the anode potential vs photo-current graph when photons of 6eV are
incident on cathode in a photoelectric experiment set-up. In the same experimental set-
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up, if photons of 8eV and same intensity are incident on cathode, then anode-potential
vs photo-current graph will be (assume 100% efficiency of photons to eject photo-
electrons in both cases)
1 1 1 2
(A) (B) (C) (D)
2 4 3 3
16. At t 0, the capacitor is charged and the switch is opened. At t 0 the switch is closed.
The shortest time T at which the charge on the capacitor will be zero is given by
3
(A) LC (B) LC (C) LC (D) 2 LC
2 2
17. In the circuit shown swith S is connected to position 2 for a long time and then joined
to position 1. The total heat produced in resistance R1 is:
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LE 2 R1 R2
2
LE 2 LE 2 LE 2
(A) (B) (C) (D)
2 R22 2R12 2R1R 2 2 R12 R22
18. A solid cylinder attached to horizontal massless spring can roll without slipping along
horizontal surface. Find time period of oscillation.
M 3M 2M 3M
(A) 2 (B) (C) (D) 2
2k 2k 3k 2k
19. Assuming the sun to be a spherical body (e 1) of radius R at a temperature of TK
evaluate the total radiant power, incident on Earth having radius r0 , at a distance r from
the Sun, where r0 is the radius of the earth and is Stefan's constant.
r02 R 2 T 4 r02 R 2 T 4 R 2 T 4 4 r02 R 2 T 4
(A) (B) (C) (D)
r2 4 r 2 r2 r2
20. The minimum and maximum distance of a satellite from the centre of the earth are 2R
and 4R , respectively, where R is the radius of earth and M is the mass of earth. The
radius of curvature at the point of maximum distance is
8R 4R 3R 3R
(A) (B) (C) (D)
3 3 8 4
SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the numerical value has more than
two decimal places, Truncate/Round-off the value of Two decimal places. Answer to each question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
21. A plastic circular disc of radius 10 cm is placed on a thin oil film of thickness 2 mm
spread over a flat horizontal surface. The torque (N m) required to spin the disc about
its central vertical axis with a constant angular velocity 8 rad/sec is (coefficient of
viscosity of oil is 1.0 kg / m s ) (take 3.14 )
22. Calculate the value of output voltage V0 (in V ) if the Si diode and Ge diode conduct
at 0.7 V and 0.3 V respectively as shown in figure.
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23. In Young's double slit experiment, the wavelength of red light is 7800Å and that of blue
light is 5200A 0 . The minimum value of n for which n th bright band due to red light
coincides with (n 1)th bright band due to blue light, is :
24. A railway track (made of iron) is laid in winter when the average temperature is 18 C .
The track consists of sections of 12.0 m placed on after the other. How much gap
(in cm ) should be left between two such sections so that there is no compression during
summer when the maximum temperature goes to 48 C ? Coefficient of linear expansion
of iron 11106 / C
25. A string of mass per unit length is clamped at both ends such that one end of the
string is at x 0 and the other end at x L . When string vibrates in fundamental mode,
amplitude of the midpoint of string is a and tension in string is F . Find the total
oscillation energy (in J) stored in the string.
1
(Use L 1 m, F 10 N, a
m
26. A massless metal plate is placed on a horizontal tabletop lubricated with oil. The sheet
is a square of side length 1.0 m and the oil layer has thickness h 1.0 mm. Initially one
edge of the sheet coincides with one edge of the table. The sheet is pulled outwards
without rotation with a constant force F 15 N. If coefficient of viscosity of the oil is
0.2 N s / m2 , how long (in second) will it take to pull half of the sheet out of the
table?
27. Write the value of current i3 (in mA ) in the circuit shown in the figure.
28. A monochromatic light of wavelength 6500Å is used in YDSE. Now both slits are
covered by two thin slab of refractive index 3.2 and 2.7 respectively. By doing so
central bright fringe shifts to original 7 th bright fringe. If both slabs have same
thickness then thickness of slab is (in m ).
29. A hollow sphere (mass m , radius R ) is put inside a hollow cone (mass m , radius 3R
and semi-angle 30 ) as shown in the figure. The whole arrangement is rigidly fixed to
the ground at the apex of the cone. Both the sphere and the cone are made of the same
material 104 / C . Considering that major changes in dimensions could happen
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only due to heating effects, find the increase in potential energy (in Joule) of the system
if it's temperature is increased by 100 C.
30. A rod is clamped at both of its ends and stationary longitudinal waves are produced in
it. In first experiment, the rod has a total of 4 nodes with amplitude of each anti-node to
be 1 mm. In other experiment, the rod has a total of 6 nodes with amplitude of each anti
node to be 2 mm. The energy of vibrations in the rod in two cases is E1 and E 2
E1
respectively. Write value of
E2
CHEMISTRY MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31. Incorrect statement among the following is:
(A) Ethoxymethyl chloride reacts with Nucleophiles 10 times faster than
1-Chlorobutane
(B) Ethoxymethyl chloride follows SN1 mechanism when reacts with
Nucleophiles
(C) 2 -Phenylthioethyl chloride reacts with water 600 times as fast as 1 -chloropropane
(D) Higher rate of 2 -Phenylthioethyl chloride is because the neighbouring group
participation by phenyl ring.
32. Which of the following ionic species has maximum ionisation energy?
(A) O (B) S- (C) Se- (D) Te-
33. Out of the following, which is the correct match for radial probability of finding the
electron of 2 s orbital?
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(A) IV I II III (B) IV II III I
(C) IV III II I (D) IV > I > III > II
35. Which of the following is correct:
(A) S3O9 Contains no S-S linkage (B) HNO4 contains no O-O linkage
(C) HPO3 3 contains P P linkage (D) S2O82 contains S S linkage
36. At 373 K, a gaseous reaction A(g) 2 B( g) C(g)is found to be of first
order. Starting with pure A, the total pressure at the end of 10 min was 176 mm Hg and
after a long time when A was completely dissociated, it was 270 mmHg. Then pressure
of A at the end of 10 minutes was:
(A) 94 mm (B) 47 mm (C) 43 mm (D) 90 mm
37. Incorrectly matched among the following is:
38. If Hund's rule is violated, then which among the following will become diamagnetic
from paramagnetic
(A) C2 (B) CN (C) N 22 (D) BN
39. Which one is false in the following statements?
(A) A catalyst is specific in its action
(B) A very small amount of the catalyst alters the rate of a reaction
(C) The number of free vacancies on the surface of the catalyst increases on sub-
division
(D) Nickel is used as a catalyst in the manufacture of ammonia
40. In which of the following reaction 1 amine is not obtained as a major product.
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(A) (B)
(C) (D)
41. The compound Na 2 IrCl6 reacts with triphenylphosphine in diethyleneglycol in an
atmosphere of CO to give IrCl(CO) PPh 3 2 known as 'Vaska's compound'. (Atomic
number of Ir 77 )
Which of the following statements is correct?
(A) The IUPAC name of the complex is carbonylchlorideobis (triphenylphosphine)
iridium (III)
(B) The hybridisation of the metal ion is sp3
(C) The magnetic moment (spin only) of the complex is zero
(D) The complex shows geometrical as well as ionization isomerism
42. The cell shown below generates a potential of 0.643 V at 300 K. Find log K sp for
AgBr:
Ag | AgBr ( s) | NaBr (0.1M ) || AgNOs (0.1M )∣Ag
2.303RT
Take 0.06
F
(A) -30.2 (B) -15.6 (C) -12.71 (D) -8.9
43. Incorrectly matched reaction among the following is :
(A) (B)
(C) (D)
44. Choose the incorrect statement from the following:
(A) The slag obtained during extraction of iron is heavy and has lower melting
point than that of metal.
(B) At temperature below 983 K (approx) CO is chief reducing agent in blast furnance.
(C) In zone refining impurities moves in the direction of heater.
(D) Electrolytic reduction of Al2O3 is known as Hall-Heroult process.
45. We have taken a saturated solution of AgBr. K sp of AgBr is 12 1014 . If 107 mole of
AgNO3 are added to 1 litre of this solution find conductivity (specific conductance) of
this solution in terms of 107 S m1 units.
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Given: 6 103 Sm 2 mol1
A
8
47. Which of the following cation produces ppt. with only one of the given condition
(I) In aqueous solution produce ppt with dil. HCl
(II) In acidic aqueous solution produce ppt with H 2 S
(A) Pb2 (B) Hg 22 (C) Ag (D) Sn 2
48. Select the incorrect statement.
(A) Three moles of phenylhydrazine and one mole of aldose required to produce
phenylosazone
(B) Glucose form gluconic acid with Br / HOH
(C) Glucose form Glucaric acid with HNO3
(D) Lowering in carbon chain can be done by Kiliani Fischer method.
49. Select the INCORRECT statement:
(A) At Boyle's temperature a real gas behaves like an ideal gas irrespective of
pressure.
b2
(B) At Boyle's temperature; Z 1
Vn Vm b
(C) On increasing the temperature four times, collision frequency (Z,) becomes
double at constant volume.
(D) At high pressure Van der Waals constant 'b' dominates over 'a'.
50. How many statements are correct?
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(iv) P4 is
(A) 1 (B) 2 (C) 3 (D) 4
SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the numerical value has more than
two decimal places, Truncate/Round-off the value of Two decimal places. Answer to each question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
51. Among the following the total number of elements which produce H 2 gas with NaOH
is Zn, Al,Sn, Pb, P,S
52. What volume in ml of 5MH 2SO4 should be added to 150ml of 1MH 2SO4 to obtain a
solution of molarity 2.5M, if upon mixing volume of solution decreases by 10% ?
53. An organic compound P contains 62.07% carbon and 10.34% hydrogen and rest
oxygen. Its vapour density is 29. This compound does not react with sodium metal, but
its 2.9 g combines with Xg of bromine (to give dibromo addition product). Find out
value of (Y X). (Where Y is total number of possible isomers of given organic
compound P )
[Atomic mass: Br 80]
54. How many of the following reagent/s will liberate at least one oxide of nitrogen as a
product?
(i) Ag conc. HNO3
(ii) Sn dil. HNO3 (20%)
(iii) Cu conc. HNO3
(iv) C conc. HNO3
(v) Zn conc, HNO3
(vi) Zn dil. HNO3 (20%)
(vii) P4 conc. HNO3
(viii) S8 conc. HNO3
(ix) Cu dil. HNO3 (20%)
55. One mole ideal monoatomic gas is heated in two different processes according to path
q AC
AB and A C. If temperature of state B and state C are equal. Calculate
q AB
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56. In white phosphorous P4 if x is total number of triangle y is total number of plane of
(y z)
symmetry z is total number of P P bond then calculate value of
x
57. Total number of species in which atleast one atom have same hybridization as in
central atom of azide ion.
N 2O, C2 H 2 , CO2 , C3O2 , BeF2 , NO2 , PF3
58. What is the molecular weight of the final product in the following reaction sequence
59. An ionic compound A B crystallizes in rock salt structure. If the ionic radii of A
and B is 200pm and 400pm respectively, then calculate distance between nearest
anions in A
60. 6.84gmAl 2 SO 4 3 is needed to coagulate 2.5 L of As 2 S3 sol completely in 2.0hrs. The
coagulation value of Al2 SO 4 3 in terms of millimoles per litre is :
[Atomic mass: Al 27, S 32]
MATHEMATICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
61. The series of natural numbers is divided into groups as (1), (2,3,4),(3,4,5,6,7) ,
(4,5, 6, 7,8,9,10) .. If sum of elements in the 20th group is , then is equal to
(A) 1368 (B) (38)2 (C) (39)2 (D) 38 39
y z
62. The lines L1 : x y z, L2 : x and a line L3 is passing through (1,1,1) form a
2 3
triangle of area 6 units, (1,1,1) being one of the vertices of the triangle. Then the
point of intersection of the L3 with L2 is
(C) , , 4
4 8
(A) (1,2,3) (B) (2,4,6) (D) (1,5,7)
3 3
63. The combined equation of 2 altitudes of an equilateral triangle is
x 2 3 y 2 4 x 6 3 y 5 0 . The third altitude has equation.
(A) x 2 0 (B) y 3 (C) x 2 (D) None of these
64. The mean marks of students of a school is 56. The mean marks of girls is 60 and that
9n
of boys is 50 . If number of boys and girls are n and m respectively, then equals
m
(A) 9 (B) 2 (C) 3 (D) 6
65. C1 and C2 are two circles whose equations are given as x 2 y 2 25 and
x 2 y 2 10 x 6 y 1 0 . Now C3 is a variable circle which cuts C1 and C2 orthogonally.
Tangents are drawn from the center of C3 to C1 , if the locus of the mid point of the
chord of contact of tangents is ax 3 y
b
13 2
x y 2 0, (where a, b Z and a and b are
b
relative prime), then is
a
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(A) 1 (B) 2 (C) 4 (D) 5
66. A line is drawn from a point P(x, y) on curve y f (x), making an angle in anti-
clockwise with the twe x-axis which is supplementary to the one made by the tangent
to the curve at P(x, y). The line meets the x -axis at A . Another line perpendicular to
the first, is drawn from P(x, y) meeting the y -axis at B .If OA OB, where O is the
origin, then the curve which passes through (1,1)
(A) x 2 y 2 4 xy 4 (B) x 2 y 2 2 xy 2 0
(C) x 2 y 2 2 xy 2 (D) x 2 y 2 4 xy 4 0
67. Let p : Sindhu plays to win q: Sindhu gets Bharath Ratna Then the contrapositive of
" ~ (~ q p) is
(A) If Sindhu plays to win then she gets Bharath Ratna
(B) If Sindhu gets Bharat Ratna then she plays to win
(C) If Sindhu does not plays to win then she does not gets Bharath Ratna
(D) If Sindhu does not get Bharath Ratna then she does not plays to win
68. Let A and B are non-singular matrices of order 3 such that | A | 5 and A 1 B2 AB 0
then A 2 A2 adj(adjB) is equal to
(A) null matris (B) 25 A2 5 B (C) 25 A2 (D) 50 A2
69. Number of points of non-differentiability of f ( x) || x | 1| | cos x |; 2 x 2 is
(A) 7 (B) 6 (C) 5 (D) 4
70. If C0 , C1 ,., C2012 are binomial coefficients in the expansion of (1 x)2012 and a0 , a1 ,.
a2012 are real numbers in arithmetic progression then value of a0C0 a1C1 a2C2
a3C3 .. a2012C2012 is a
(A) Even Number (B) Odd number (C) Natural number (D) Prime number
1
71. In a set of real numbers a relation R is defined as xRy such that | x | | y | , then
2
relation R is
(A) reflexive and symmetric but not transitive
(B) symmetric but not transitive and reflexive
(C) transitive but not symmetric and reflexive
(D) none of reflexive, symmetric and transitive
72. If a , b and c -are three mutually perpendicular unit vectors and d is a unit vector
which makes equal angles with a, b and c then the value of | a b c d |2
(A) 4 2 2 (B) 4 2 3 (C) 2 5 (D) 3 5
73. Let the area enclosed by the curve y 1 x and the line y a, where 0 a 1, be
2
A(0)
represented by A(a). If k, then
1
A
2
3 3 5 5
(A) 1 k (B) k 2 (C) 2 k (D) k 3
2 2 2 2
74. If system of linear equations (a 1) x z , x (b 1)y and and y (c 1)z where
a, b, c I and , , R, does not have a unique solution, then maximum possible
value of | a b c | is
(A) 5 (B) 1 (C) 3 (D) 4
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75. ABCD is a rectangular field A vertical lamp post of height 12 m stands at the corner A
. If the angle of elevation of its top from B is 60 and from C is 45 , then the area of
the field is
(A) 48 2 sq.meter (B) 48 3 sq.meter
(C) 48 sq. meter (D) 12 2 sq.meter
76. Smallest positive x satisfying the equation cos3 3x cos3 5x 8cos3 4 x cos3 x is
(A) 15 (B) 18 (C) 22.5 (D) 30
77. The set of values of x satisfying simult aneously the inequalities
(x 8)(2 x)
0 and 2x 3 31 0 is
10
log 0.3 log 2 5 1
7
(A) a singleton set (B) an empty set
(C) an infinite set (D) a set consisting of exactly two elements
78. A bag contains 2 white and 4 black balls. A ball is drawn 5 times, each being replaced
before another is drawn. The probability that atleast 4 of the balls drawn are white is :
4 10 11
(A) (B) (C) (D) None
81 243 243
79. The modulus of the complex number z such that | z 3 i | 1 and arg( z ) is equal to
(A) 1 (B) 2 (C) 3 (D) 4
e 1 1 x2 2x 1 e x2 2
80. Let J 0 exp dx and K 1 x n x exp dx. The value of
x 1 2 2
(J K) is equal to
(A) ( e )e 1 (B) ( e )e 1 (D) ( e)e 2
2 2 2
(C) 0
SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the numerical value has more than
two decimal places, Truncate/Round-off the value of Two decimal places. Answer to each question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
81. If a, b are odd integers then number of integral root, of equation x10 ax9 b 0 is
equal to
p
82. If the number of distinct positive rational numbers smaller than $1,$ where
q
p, q {1, 2,3, 6} is k then k is
83. If two distinct chords of a parabola y 2 4ax passing through (a, 2a) are bisected on the
line x y 1, then the sum of integral values of the length of possible latus rectums is
equal to
sec2
2 2 5 x
84. If the value of lim sin is e-A then ‘A’ is
x 0
2 3x
85. If a , b , c be three vectors of magnitude 3,1, 2, such that a (a c ) 3b 0, if is
the angle between a and c , then cos2 is equal to
(2 x 1) 40 (4 x 1)5 L
86. If lim L , then value of is
x (2 x 3) 45
128
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x
1 sin 2 , x 1
87. If the function f (x) ax b , 1 x 3
x
6 tan , 3 x 6
12
a b
is continuous in the interval (,6) then value of is
8
1.5
88. Value of
0
x 2 dx is equals to (where [.] denotes greatest integer function)
k
89. If the area bounded by curve x | y | 1 and the y-axis is k , then is equals to
4
90. If value of
a b a b c . a 2b c is k then k is
abc 4
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