Top of Pyramid - Test #49 - Thermodynamics

Contact Number: 9667591930 / 8527521718

1.
(a) crystallization of sucrose from solution
Work done in reversible adiabatic process is given by:
(b) rusting of iron
(a) 2.303RTlog(V2/V1) (b)
nR

(γ−1)
(T2 − T1 )
(c) melting of ice

(c) 2.303RTlog(V2/V1) (d) none of these (d) vaporization of camphor

2. 8.

Change in enthalpy for reaction, The entropy change for the reaction given below,

2H2O2(l)→ 2H2O(l) + O2(g) 2H2 (g) + O2 (g) →2H2O(l)

if the heat of formation of H2O2(l) and H2O(l) are -188 is ... at 300 K. Standard entropies of H2 (g), O2(g) and
and -286 kJ/mol respectively is H2O(l) are 126.6, 201.20 and 68.0 JK-1mol-1
respectively.
(a) -196 kJ/mol (b) + 196 kJ/mol
(c) +948 kJ/mol (d) -948 kJ/mol (a) -318.4 JK-1mol-1 (b) 318.4 JK-1mol-
1
3.
-1 -1
One mole of a non-ideal gas undergoes a change of state (c) 31.84 JK mol (d) none of these
(2.0 atm, 3.0 L, 95 K)→(4.0 atm, 5.0 L, 245 K) with a 9.
change in internal energy, ΔU = 30.0 L atm. The change
in enthalpy (ΔH) of the process in L atm is: If S° for H2, Cl2 and HCl are 0.13, 0.22 and 0.19 kJ K-
1mol-1 respectively. The total change in standard entropy
(a) 40.0
for the reaction, H2 + Cl2 →2HCl is:
(b) 42.3
(c) 44.0 (a) 30 J K-1mol-1 (b) 40 J K-1mol-1

(d) not defined, because pressure is not constant (c) 60 J K-1mol-1 (d) 20 J K-1mol-1
4. 10.
At absolute zero, the entropy of a perfect crystal is zero. Change in entropy is negative for:
This is........... of thermodynamics.
(a) Bromine (l)→Bromine(g)
(a) first law (b) second law
(b) C(s) + H2O(g) →CO(g) + H2(g)
(c) third law (d) none of these
(c) N2(g,10 atm)→N2(g,1 atm)
5.
(d) Fe ( 1mol, 400 K) → Fe( 1mol, 300 K)
At constant pressure and temperature, the direction of
any chemical reaction is one where, the...... decrease. 11.
(a) entropy (b) enthalpy Which statements are correct?
(c) Gibbs energy (d) none of these (a) 2. 303 log
P2
=
ΔHvap. [ T2 −T1 ]
is called Clausius-
P1 R T1 T2

6. Clapeyron equation
The work done by a mass less piston in causing an ΔHvap.

(b) = 88 J mol
−1
K
−1
is called Trouton's
expansion ΔV (at constant temperature), when the Boiling Point

opposing pressure, P is variable, is given by: rule

(a) W= − ∫ P Δ V (b) W=0 (c) Entropy is a measure of unavailable energy, i.e.,

(c) W= -PΔV (d) none of these unavailable energy = entropy x temperature

7. (d) All of the above

Entropy decreases during:

12. Page: 1
 Top of Pyramid - Test #49 - Thermodynamics
Contact Number: 9667591930 / 8527521718

A gaseous system changes from state A(P1, V1, T1) to (1) -1165
B(P2,V2,T2), B to C(P3, V3, T3) and finally from C to A. (2) -2486
The whole process may be called:
(3) +1165
(a) reversible process (b) cyclic process
(4) +2486
(c) isobaric process (d) spontaneous
process 17.

13. If ΔH (C2H4) and ΔH (C2H6) are x1 and x2 kcal/mol

∘

f
∘

then heat of hydrogenation of C2H4 is :-

All the naturally occurring processes, i.e., spontaneous
proceed spontaneously in a direction which leads to: (1) x1 + x2
(a) decrease of free energy (b) increase of (2) x1 - x2
free energy
(c) decrease of entropy (d) increase of (3) x2 - x1
enthalpy
(4) x1 + 2x2
14.
18.
Warming ammonium chloride with sodium hydroxide in
a test tube is an example of: For the reaction, X2O4(l) →2XO2(g)

1. closed system 2. Isolated system Δ U = 2.1 kcal, ΔS = 20 cal K-1 at 300 K. Hence, ΔG is
3. open system 4. None of these (a) 2.7 kcal
(b) -2.7 kcal
15. (c) 9.3 kcal
Predict which of the following reaction(s) has a positive (d) -9.3 kcal
entropy change?
19.
(i) Ag+ (aq) + Cl-(aq) →AgCl(s)
The enthalpy of fusion of water is 1.435 kcal/mol. The
(ii) NH4Cl(g) →NH3(g) + HCl(g) molar entropy change for the melting of ice at 0°C is

(iii) 2NH3(g)→N2(g) + 3H2(g) (a) 10.52 cal/(mol K)

(b) 21.04 cal/(mol K)
(1) i & ii
(c) 5.260 cal/(mol K)
(2) iii
(d) 0.526 cal/(mol K)
(3) ii & iii
20.
(4) ii
The enthalpy and entropy change for the reaction :
Br2(l)+Cl2(g) → 2BrCl(g) are 30 kJ mol-1 and 105 JK-1
16.
mol-1 respectively.
For given following equations and ΔH° values
determine the enthalpy of reaction at 298 K for the The temperature at which the reaction will be in
reaction equilibrium is :

C2H4(g) + 6F2(g) → 2CF4(g) + 4HF(g) (a) 285.7 K

(b) 273 K
H2(g) + F2(g) → 2HF(g) ΔH
∘
1
= -537 kJ
(c) 450 K
C(s) + 2F2(g) →CF4(g) ΔH
∘
2
=-680 kJ
(d) 300 K
2C(s) + 2H2(g) →C2H4(g) ΔH
∘
= 52 kJ
3
21.
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 Top of Pyramid - Test #49 - Thermodynamics
Contact Number: 9667591930 / 8527521718

The temperature of the system decreases in an by

(1) Adiabatic compression (1) Decrease in entropy
(2) Isothermal compression (2) Increase in entropy
(3) Isothermal expansion (3) Change in enthalpy
(4) Adiabatic expansion (4) Change in free energy
22. 27.
Mark the correct statement An irreversible process occuring isothermally in an
isolated system leads to
(1) For a chemical reaction to be feasible, ΔG should be
zero (1) Zero entropy
(2) Entropy is a measure of order in a system (2) An increase in the total entropy of the system
(3) For a chemical reaction to be feasible, ΔG should be (3) A decrease in the total entropy of the system
positive
(4) None of these
(4) The total energy of an isolated system is constant
28.
23.
When enthalpy and entropy change for a chemical
Which of the following is not a state function reaction are –2.5 × 103 cal and 7.4 cal deg–1 respectively.
(1) Internal energy Predict the reaction at 298 K is [AFMC 1998; MH CET
1999; CBSE PMT 2000]
(2) Enthalpy
(1) Spontaneous
(3) Work
(2) Reversible
(4) Entropy
(3) Irreversible
24.
(4) Non-spontaneous
The work done in ergs for the reversible expansion of
one mole of an ideal gas from a volume of 10 litres to 20 29.
litres at 25°C is The entropy changed involved in the conversion of 1
(1) 2 .303 ×298 × 0 .082 log 2 mole of liquid water at 373 K to vapour at the same
temperature will be [ΔH = 2 .257 kJ /gm] [MP
vap

(2) 298 × 10 × 8 .31 ×2 .303 log 2

7
PET 2002]
(3) 2 .303 ×298 × 0 .082 log 0 .5 (1) 0.119 kJ
(4) 8 .31 ×10 7
× 298 − 2 .303 log 0 .5 (2) 0.109 kJ
25. (3) 0.129 kJ

An ideal gas expands in volume from 1 × 10–3 m3 to 1 × (4) 0.120 kJ

10–2 m3 at 300 K against a constant pressure of 1 × 105 30.
Nm–2. The work done is [AIEEE 2004]
When a liquid boils, there is [JIPMER 2002]
(1) 270 kJ
(1) An increase in entropy
(2) –900 kJ
(2) A decrease in entropy
(3) –900 J
(3) An increase in heat of vaporization
(4) 900 kJ
(4) An increase in free energy
26.
31.
Mixing of non-reacting gases is generally accompanied
For a carnot engine, the source is at 500 K
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 Top of Pyramid - Test #49 - Thermodynamics
Contact Number: 9667591930 / 8527521718

and the sink at 300 K. What is efficiency of this engine 4. 35 ml acid and 15 ml alkali
[BHU 2004]
36.
(1) 0.2
The heats of neutralisation of four acids A, B, C and D
(2) 0.4 are -13.7, -9.4, -11.2 and -12.4 kcal respectively when
they are neutralised by a common base. The acidic
(3) 0.6 character obeys the order :
(4) 0.3 1. A>B>C>D
32. 2. A>D>C>B
A solution of 500 ml of 0.2 M KOH and 500 ml of 0.2 M 3. D>C>B>A
HCl is mixed and stirred; the rise in temperature is T1.
The experiment is repeated using 250 ml each of 4. D>B>C>A
solution, the temperature raised is T2. Which of the 37.
following is true [EAMCET 1987; MP PET 1994]
If a process is both endothermic and spontaneous, then :
(1) T1 = T2
1. ΔS > 0
(2) T1 = 2T2
2. ΔS < 0
(3) T1 = 4T2 3. ΔH < 0

(4) T2 = 9T1 4. ΔG > 0

33. 38.

The heat of formation of HCl(g) from the reaction The bond energies of C=C and C-C at 298 K are 590 and
331 kJ mol-1 respectively. The enthalpy of
H2(g) + Cl2(g) ; ΔH = − 44 kcal is polymerization per mole of ethylene is
1. +44 kcal 1. -70 kJ
2. -44 kcal 2. -72 kJ
3. +22 kcal 3. 72 kJ
4. -22 kcal 4. -68 kJ
34. 39.
The heat of neutralisation of HCl by NaOH is -55.9 The gas absorbs 100 J heat and is simultaneously
kJ/mole. If the heat of neutralisation of HCN by NaOH is compressed by a constant external pressure of 1.50 atm
-12.1 kJ/mole, then energy of dissociation of HCN is- from 8 lit. to 2 lit. in volume. Hence ΔE will be-
1. -43.8 kJ 1. -812 J
2. 43.8 kJ 2. 812 J
3. 68 kJ 3. 1011 J
4. -68 kJ 4. 911 J
35. 40.
In which case of mixing of a strong acid and a base, each The standard heat of combustion of Al is -837.8 kJ mol-1
of 1(N) concentration, temperature-increase is the highest at 25 C which of the following releases 250 kcal of heat
∘

? ?
1. 20 ml acid and 30 ml alkali 1. The reaction of 0.624 mol of Al
2. 10 ml acid and 40 ml alkali 2. The formation of 0.624 mol of Al2O3
3. 25 ml acid and 25 ml alkali
Page: 4
 Top of Pyramid - Test #49 - Thermodynamics
Contact Number: 9667591930 / 8527521718

3. The reaction of 0.312 mol of Al The enthalpies of the following reactions are shown
alongwith.
4. The formation of 0.150 mol of Al2O3
1 1 −1
H2 (g)+ O2 (g)→ OH (g) ; Δ H = 42. 09 kJ mol
41. 2 2

−1
H2 (g)→ 2H (g); Δ H = 435. 89 kJ mol
Following reaction occurs at 25 ∘
C : −1
O2 (g)→ 2O(g); Δ H = 495. 05 kJ mol
−5 −2
2N O(g, 1 × 10 atm)+Cl2 (g, 1 × 10 atm)
Calculate the O-H bond energies for the hydroxyl radical.
−2
⇌ 2N OCl(g, 1 × 10 atm)

∘
Δ G is :
1. 223.18 kJ mol-1

1. -45.65 kJ 2. 423.38 kJ mol-1

2. -28.53 kJ 3. 513.28 kJ mol-1
3. -22.82 kJ 4. 113.38 kJ mol-1
4. -57.06 kJ
42. Fill OMR Sheet
For the reaction :
X2 O4 (l)→ 2XO2 (g)

ΔE = 2. 1 kcal. Δ S = 20 cal/K at 300 K. H ence Δ G is :

1. 2.7 kcal
2. -2.7 kcal
3. 9.3 kcal
4. -9.3 kcal
43.
The bond energies ofC ≡ C , C-H, H-H and C=C are
198, 98, 103 and145 kcal respectively. The enthalpy
change of the reaction H C ≡ CH + H → C H is 2 2 4

1. 48 kcal
2. 96 kcal
3. -40 kcal
4. -152 kcal
44.
The enthalpies of formation of CO2(g) and CO(g) at 298
K are in the ratio 2.57 : 1. For the reaction,
CO2 (g)+C(s)→ CO(g), Δ H = 172. 5 kJ ,

ΔHf of CO(g) is

1. -150.6 kJ mol-1

2. -109.8 kJ mol-1

3. -130.2 kJ mol-1

4. -141.8 kJ mol-1
45.
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Contact Number: 9667591930 / 8527521718

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