Air Pollution Final
Air Pollution Final
gravity as a shallow envelope, which sustains life on earth, saves it from hostile
environment of outer space and plays a key role in maintaining heat balance of earth.
3 roles:
1. Provide us life supporting gas O2
2. Save us from harmful UV rays & meteors
3. Maintain heat balance
Lapse rate = rate of change of atmospheric temperature (t) to the height of atmosphere (h)
= dt/dh
How Atmosphere maintain heat balance ?
➢ Sun is the only source of heat on earth and radiation heat balance can be determined
following two laws:
➢ Stefan Boltzmann law: The total rate at which radiation energy is emitted by a black
body is given by 𝐸 = 𝜎𝐴𝑇 4
Here, Surface area=A, Temperature of black body = T,
Stefan Boltzmann constant = = 5.67 X 10 -8 W/m2K4
➢ Solar flux (S) is the solar radiation per area arrives just outside the object with an average
annual intensity.
𝑆𝜋𝑅 2 = 𝜎. 4𝜋𝑅 2 . 𝑇 4
1 1Τ
𝑆 Τ4 1372 4
∴ T= =
4𝜎 4 𝑋 5.67 𝑥 10−8
T= 279 K = 6 0 C
Modified model considering albedo
Albedo = The fraction of incoming solar radiation that is reflected by object.
Earth’s albedo = 30 %
This 30% is due to
• clouds
• dust, smoke
• scattering by air molecules
• reflections from land, oceans,
ice etc.
Thus, at equilibrium condition ;
Incoming radiation = Outgoing radiation
Outgoing radiation = 𝜎. 4𝜋𝑅 2. 𝑇 4
Incoming radiation = 𝑆 (1-) 𝜋 𝑅2 4
2 2
∴ 𝑆 1 − 𝛼 𝜋𝑅 = 𝜎. 4𝜋𝑅 . 𝑇
1ൗ
1372(1 − 0.3) 4
𝑇𝑒𝑞 = 𝑻𝒆𝒒 = 𝟐𝟓𝟓𝑲 = −𝟏𝟖𝟎 𝑪
4 𝑋 5.67 𝑋 10−8
Step 4: Some of this heat is trapped by greenhouse gases in the atmosphere, keeping the
Earth warm enough to sustain life.
Step 5: Human activities such as burning fossil fuels, agriculture and land clearing are
increasing the amount of greenhouse gases released into the atmosphere.
Step 6: This is trapping extra heat, and causing the Earth's temperature to rise.
Impact of Global Warming
➢ Earth’s rising temperatures are fueling longer and hotter heat waves, more frequent
droughts, heavier rainfall, and more powerful hurricanes.
➢ As the heat waves, droughts, and floods associated with climate change become more
frequent and more intense, communities suffer and death tolls rise. If we’re unable to
reduce our emissions, scientists believe that climate change could lead to the deaths of
more than 250,000 people around the globe every year and force 100 million people into
poverty by 2030.
➢ Disappearing glaciers, early snowmelt, and severe droughts will cause more dramatic water
shortages and continue to increase the risk of wildfires in the American West.
➢ Rising sea levels will lead to more coastal flooding, which cause destruction of ecosystem
and destroying cities.
➢ Forests, farms, and cities will face troublesome new pests, heat waves, heavy downpours,
and increased flooding. All of these can damage or destroy agriculture and fisheries.
➢ Disruption of habitats such as coral reefs and alpine meadows could drive many plant and
animal species to extinction.
➢ Allergies, asthma, and infectious disease outbreaks will become more common due to
increased growth of pollen-producing ragweed, higher levels of air pollution, and the
spread of conditions favorable to pathogens and mosquitoes.
Ozone Layer Depletion
Basic Ozone Layer Science
Most atmospheric ozone is concentrated in a layer in
the stratosphere, about 15 to 30 km above the Earth's
surface. At any given time, ozone molecules are
constantly formed and destroyed in the stratosphere.
The total amount has remained relatively stable during
the decades that it has been measured. The stratosphere
is in a constant cycle with oxygen molecules and their
interaction with ultraviolet rays.
The ozone layer is created when ultraviolet rays react with oxygen molecules (O 2) to create
ozone (O3) and atomic oxygen (O). This process is called the Chapman cycle.
Ozone layer concentration is the ratio of rate of formation to rate of destruction of ozone in
atmosphere.
The ozone layer in the stratosphere absorbs the portion of UV light from the sun, mostly
UVB, preventing it from reaching the planet's surface. UVB has been linked to many harmful
effects including skin cancers, cataracts, and harm to some crops and marine life.
Scientists have established records spanning several decades that detail normal ozone levels
during natural cycles. Ozone concentrations in the atmosphere vary naturally with sunspots,
seasons, and latitude. Each natural reduction in ozone levels has been followed by a recovery.
Beginning in the 1970s, however, scientific evidence showed that the ozone shield was being
depleted well beyond natural processes.
Ozone Layer Depletion
In 1970 Dr. P. Crutzen proposed the following catalytic reaction that results in destruction of O3.
X + O3 => XO + O2
O3 + XO => X + 2O2
Net Reaction: 2 O3 + UV => 3 O2
In this sequence of reactions, X is an atom or molecule that acts as a catalyst.
The important radicals represented by X include chlorine (Cl), hydroxyl (OH), nitric oxide
(NO), and bromine (Br). These compounds contribute to ozone depletion, and are called
ozone-depleting substances. (ODS)
ODS include chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), halons, methyl
bromide, hydrobromofluorocarbons, chlorobromomethane, and methyl chloroform.
In 1930s useful chemical compounds known as chlorofluorocarbons (CFCs) were produced
for use in refrigeration, air conditioning, solvents, aerosol spray cans etc.
They are very stable in the troposphere with lifetimes of approximately 100 years. This long
lifetime allows CFCs that are emitted near the surface to be carried by the winds upward. In
the stratosphere CFCs are dissociated by UV light producing chlorine atoms. The destruction
of O3 then follows with the following chemical reactions:
CFC are group of molecules made up of chlorine, fluorine and carbon atoms and are
extremely stable. This extreme stability allows CFC's to slowly make their way into the
stratosphere (most molecules decompose before they can cross into the stratosphere from the
troposphere). When the CFC's come into contact with high energy photons in stratosphere,
their individual components are freed from the whole.
The following reaction displays how Cl atoms have an ozone destroying cycle:
Wind velocity & direction of blowing: The higher the wind velocity, the rapidly the
pollutants are carried away from the source. The direction of wind should opposite the
locality.
Air temperature profile: The ease with which pollutants can disperse vertically into the
atmosphere is largely determined by lapse rate. Two types of lapse rate- Adiabatic lapse rate
(ALR), & Ambient or Environment lapse rate (ELR).
Lapse rate= rate of change of atmospheric temperature (t) to the height of atmosphere (h)
= - dt/dh
Adiabatic lapse rate: Theoretically determined value considering the movement of air
follows adiabatic process. It is constant and its value 10C/100 m.
𝑑𝑇
Γ= = −100𝐶/𝑘𝑚 (prove that)
𝑑𝑧
Environment lapse rate: Observed value at a particular time and particular height. It
varies with locality and time.
The product of maximum mixing height and average wind speed within the mixing depth is
called atmospheric dispersive capability. It is used as an indicator of air quality.
Atmospheric dispersive capability = maximum mixing height (m) X average wind speed(m/s)
= ventilation coefficient (m2/s)
Smoke Stack Plume
1. Fanning- in stable air
2. Looping – in unstable air
3. Coning – in neutral air
4. Lofting – above temperature inversion
5. Fumigation – below temperature inversion.
THE POINT SOURCE GAUSSIAN PLUME MODEL
▪ Buoyant plumes — Plumes which are lighter than the surrounding ambient air because
of higher temperature and lower density, or because they are at about the same
temperature as the ambient air but have a lower molecular weight and hence lower
density than the ambient air. For example, an emission plume of methane gas at ambient
air temperatures is buoyant because methane has a lower molecular weight than the
ambient air.
▪ Dense gas plumes — Plumes which are heavier than surrounding ambient air because of higher
density. A plume may have a higher density than air because it has a higher molecular weight than
air (for example, a plume of carbon dioxide). A plume may also have a higher density than air if the
plume is at a much lower temperature than the air. For example, a plume of evaporated gaseous
methane from an accidental release of liquefied natural gas (LNG) may be as cold as -161 °C.
▪ Passive or neutral plumes — Plumes which are neither lighter nor heavier than air.
Gaussian model
The Gaussian plume model is a (relatively) simple mathematical model that attempts to relate
emissions to air quality and is typically applied to point source emitters, such as smokestack
or coal-burning electricity-producing plants. This model may be applied to non-point source
emitters, such as line sources(emissions from automobile along a highway) or area sources.
3. Criteria pollutants: There are six air pollutants which have the main contribution in
creating health hazards and air pollution.
CO SO2 NO2 Pb PM O3
Carbon monoxide
Source:- Natural- volcanic action, forest fire, natural gas emission, marsh gas.
Anthropogenic – automobile, iron-steel-petroleum industry
Effect:- CO interferes with the blood’s ability to carry O 2 to brain, heart & other tissue.
Control:-
1. Modification of IC engine to reduce the amount of pollutants formed during fuel
combustion.
2. Development of exhaust system reactors which will complete the combustion process.
Example: catalytic convertor.
3. Development of substitute fuel- LPG, CNG, methanol.
4. Development of alternative power source- steam, electric, solar etc.
Catalytic converter
A catalytic converter is a device used to reduce the emissions from an internal combustion
engine (used in most modern day automobiles and vehicles). Not enough oxygen is available to
oxidize the carbon fuel in these engines to convert completely into carbon dioxide and water;
thus toxic by-products are produced. Catalytic converters are used in exhaust systems to
provide a site for the oxidation and reduction of toxic by-products (like nitrogen oxides, carbon
monoxide, and hydrocarbons) of fuel into less hazardous substances such as carbon dioxide,
water vapor, and nitrogen gas.
Functions
A three-way catalytic converter has three
simultaneous functions:
Source: These gases, especially SO2, are emitted by the burning of fossil fuels — coal, oil,
and diesel etc. Sources include power plants, metals processing and smelting facilities, and
vehicles. Sulfur dioxide is also a natural byproduct of volcanic activity.
Impact :
Short-term exposures to SO2 can harm the human respiratory system and make breathing
difficult. People with asthma, particularly children, are sensitive to these effects of SO 2.
Longer exposures can aggravate existing heart and lung conditions.
Beyond human health impacts, sulfur dioxide’s contribution to acid rain can cause direct harm
to trees and plants by damaging exposed tissues and, subsequently, decreasing plant growth.
Sulfur oxides can react with other compounds in the atmosphere to form fine particles
(particulate matter) that reduce visibility
Deposition of particles can also stain and damage stone and other materials, including
culturally important objects such as statues and monuments.
The collected particles may be removed from the collector plates as dry material (dry ESPs), or
they may be washed from the plates with water (wet ESPs). ESPs are capable of collection
efficiencies greater than 99 percent.
ESPs provide a large air volume, operate favorably in various temperatures, and require little
maintenance. Their limitations include their physical size, operation expenses and inconsistent
collection efficiencies.