26-03-2025

1306CJA101001240008 JA

PART-1 : PHYSICS

SECTION I(i)

1) The transverse displacement y(x, t) of a wave on a string is given by .

This represents a :-

(A) standing wave of frequency

(B)
standing wave of frequency

(C)
wave moving in +x directionwith speed
wave moving in –x direction with speed
(D)

2) A disc moves as shown in the figure, with a velocity of translation of 6v0 of its centre of mass and

an angular velocity of . The distance of instantaneous axis of rotation from its centre of mass is

(A) R
(B) 2R
(C) 3R
(D) 4R

3) A tube of length h (which is wide enough so that surface tension effects can be neglected) filled
with air at atmospheric pressure and closed at one end. Now the tube is lowered in a tank of
mercury to a depth 2h as shown. It is seen that mercury rises a distance x into the tube. If the
mercury barometer also reads h, then (Consider compression of air to be Isothermal)
(A) (3h – x) (h – x) = h2
(B) (2h – x) (h – x) = h2
(C) (2h – x) (h + x) = h2
(D) (2h) (h – x) = h2

4) A well insulated box contains water (specific heat = C and very large conductivity) of mass m0 and
temperature T0 at time t = 0. If heat is being added to it uniformly at a constant rate dQ/dt = R and

water is leaking from it at a constant rate then the temperature of the water at time t

will be :-

(A)
T=

(B)
T=

(C)
T=

(D)
T=

SECTION I(ii)

1) Temperature of a monatomic gas is increased from T0 to 2T0 in three different processes :

isochoric, isobaric and adiabatic. Heat given to the gas in these three processes are Q1, Q2 and Q3
respectively. Then, choose the correct option.

(A) Q1 > Q3
(B) Q2 > Q1
(C) Q2 > Q3
(D) Q3 = 0
2) We have a cylindrical container as shown I0 = 0.1 m, and the cross-sectional area S = 170 cm2.
The container wall and the two pistons are well insulated, and a spring having a stiffness coefficient
of K = 1.50 × 104 N/m is connected to the two pistons. There is a fixed partition with holes in the
partition. The wall of the cylinder has an opening and is open to the atmosphere. The atmospheric
pressure is p0 = 1.00 × 105 Pa. The two chambers contain the same ideal gas, the temperature is
T0 = 300 K, and the pressure is p0. Now the left side has absorbed heat Q = 1000 J. Find the gas
temperature of the two chambers and the pressure in it. Assume that the gas is monoatomic.

(A) Tleft = 990 K

(B) Tright = 367 K
(C) Pleft = 2.03 × 105 Pa
(D) Pright = 1.65 × 105 Pa

3) A solid wooden cone has been supported by a string inside water as shown in figure. The radius of
the circular base of the cone is R and its height is h. In equilibrium the base of the cone is at a depth
H below the water surface. Density of wood is d (< , density of water). Choose the correct option(s)

(A)
Tension of string

(B)
Tension of string
Force applied by water on slant surface of cone is
(C)

(D)
Force applied by water on slant surface of cone is

SECTION I(iii)

1) An evacuated thin tube has two tight caps C1 and C2 at its ends. The tube is adjusted as shown in
the figure below. Atmospheric pressure = P and density of the liquid = d, Neglect surface tension of
liquid. Match the entities of columns.

(A) P → 3,4;Q → 2,4;R → 1,5;S → 2,3,4,5

(B) P → 1,2;Q → 1,2;R → 1,3,4,5;S → 1,3,4,5
(C) P → 3,4,5;Q → 3,4;R → 2,4;S → 1,3,5
(D) P → 4,5;Q → 1,2,3;R → 3,4,5;S → 2,3,4,5

2) In column-II different situations are shown in which one object collides with the another object. In
each case friction is absent and neglect effect of non-impulsive forces. In column-I different direction
are given. You have to match the directions for each case in which momentum conservation can be
applied on object A or object B or system A&B (Assume that objects do not bounce off the ground).

Column - I Column - II

(A) Along the line of impact (P)

(B) Perpendicular to line of impact (Q)

 (C) In horizontal direction (R)

(D) In vertical direction (S)

(A) A → PQR;B → QS;C → P;D → S

(B) A → Q;B → RS;C → QR;D → P
(C) A → PR;B → S;C → Q;D → P
(D) A → S;B → PQRS;C → PQRS;D → QRS

3) A uniform plank of mass m, free to move in the horizontal direction, is placed on the top of a solid
cylinder of mass 2m and radius R. The plank is attached to a fixed wall with the help of a light spring
of force constant k. The plank is slightly displaced towards spring and released. There is no slipping
anywhere. For any displacement x, amplitude x0 and velocity v of the plank. Match the Column I with

Column II and mark the correct option from the codes given below.

Column–I Column–II

(P) Velocity of centre of cylinder (1)

(Q) Energy of oscillations of the system (2)

(R) Acceleration of the plank (3)

mv2 + kx2

(S) Angular frequency of oscillations (4)

(5)

(A) P → 2;Q → 3;R → 4;S → 5

(B) P → 2;Q → 1, 3;R → 4;S → 5
(C) P → 2;Q → 1;R → 4;S → 5
(D) P → 1;Q → 2;R → 3;S → 4

4) A sample ‘A’ of liquid water and a sample B of ice of equal mass are kept in 2 nearby containers
so that they can exchange heat with each other but are thermally insulated from the surroundings.
The graphs in list-II show the sketch of temperature T of samples versus time t. Match with
appropriate description in list-I.

List-I List-II

(P) Equilibrium temperature is above melting point of ice. (1)

(Q) At least some of water freezes. (2)

(R) At least some of ice melts. (3)

(S) Equilibrium temperature is below freezing point of water. (4)

(A) P → 2;Q → 1;R → 3;S → 3

(B) P → 1;Q → 2;R → 3;S → 4
(C) P → 3;Q → 2;R → 4;S → 1
(D) P → 4;Q → 3;R → 2;S → 1

SECTION II

1) A cylindrical vessel of radius R is filled with an ideal liquid of density ρ up to height h above its
flat bottom. It is now set into rotation about its vertical axis with constant angular velocity ω When a
steady state is achieved, the liquid does not overflow and no portion of the bottom is dry. Now at the
centre of the bottom a small orifice of radius r is made. How much liquid can flow out of the vessel?

If volume flown out is

2) Water in a glass aquarium forms a meniscus, as illustrated in the figure. The difference in height
h between the centre and the edge of the meniscus is _____mm. The surface tension of water is γ =
0.073 Nm–1. Wetting is complete.

3) Two strings of length l =0.5 m each are connected to a block of mass m = 2 kg at one end and
their ends are attached to the point A and B 0.5 m apart on a vertical pole which rotates with a

constant angular velocity = 7 rad/sec. Find the ratio of tension in the upper string (T1) and the

lower string (T2). [Use g = 9.8 m/s2]

4) A particle is projected from the horizontal surface. Times taken by the particle to pass through

two horizontal lines separated by height h are T1 and T2. If T2 = 3 T1 then find the value of .

5) The open-link chain of length L and mass ρ per unit length is released from rest in the position
shown, where the bottom link is almost touching the platform and the horizontal section is
supported on a smooth surface. Friction at the corner guide is negligible. Determine the velocity v1

of end A as it reaches the corner is . Fin y.

6) Two smooth sphere made of identical material having masses m and 2m undergo an oblique

impact shown in figure. The coefficient of restitution . The velocity of the mass 2m after collision

will be. . Find (a + b)

PART-2 : CHEMISTRY

SECTION I(i)

1)

Ratio of number of protons to neutrons in 3.011 × 1022 ions of D3O+ is -

(A) 2
(B) 1
(C) 4
(D) 3

2) Among the following, the incorrect statement is :

(A) Al(CH3)3 has the three-centre two-electron bonds in its dimetric structure
(B) BH3 has the three-centre two-electron bonds in its dimeric structure
(C) The Lewis acidity of BCl3 is greater than that of AlCl3
(D) AlCl3 has the three-centre two-electron bonds in its dimeric structure

3)

According to MO theory the bond orders for and NO+ respectively, are

(A) 1,3 and 3

(B) 1, 2 and 3
(C) 1, 3 and 2
(D) 2, 3 and 3

4) pH of water is 7 at 25°C. If water is heated to 80°C, it’s pH will :

(A) Decrease
(B) Remains the same
(C) H+ concentration increases, OH– concentration decreases
(D) Increase

SECTION I(ii)

1)

Which of the following statement are correct -

(A) 1gm of N2O and 1gm of CO2 contains same no. of atoms
(B) 1 litre of 20% w/v solution of NaOH and 1.3 kg of 5m urea solution contains same mass of solute
(C) If equal molecules of H2 and O2 reacts to form H2O2 then H2 will be limiting reagent
(D) Ferric sulphate contains 28% by mass of iron

2)

For the reaction :

Identify the compositions which will produce same amount of NH3.

(A) 140 gm N2 and 35 g H2
(B) 18 g H2, and 84 g N2
(C) Total 20 moles of mixture having N2 and H2 present in stoichiometric ratio (No limiting reagent)

(D)
136 gm of mixture having mass fraction of

3) Which of the following statements is/are correct ?

(S = 32, Cl = 35.5, C = 12)

1 gram of CS2 and 2 gm Cl2 is taken initially in the reaction then,

(A) 0.714 g of CS2 is used in reaction

(B) 0.286 g CS2 is in excess
(C) 1.45 g of CCl4 is formed
(D) 0.8 g Cl2 is in excess

SECTION I(iii)
1)

List-I (Violation of) List-II

(P) Only Aufbau's principle (1)

(Q) Only Pauli's exclusion principle (2)

(R) Only Hund's rule (3)

(S) Aufbau's & Hund's rule (4)

(A) P → 1;Q → 2;R → 3;S → 4

(B) P → 3;Q → 4;R → 2;S → 1
(C) P → 2;Q → 4;R → 1;S → 3
(D) P → 2;Q → 1;R → 4;S → 3

2)

List-I (Element) List-II (ΔHIE1 in kJ / mol)

(P) N (1) +800
(Q) O (2) +900
(R) Be (3) +1300
(S) B (4) +1400
(A) P → 2;Q → 3;R → 1;S → 4
(B) P → 1;Q → 2;R → 3;S → 4
(C) P → 4;Q → 3;R → 2;S → 1
(D) P → 1;Q → 4;R → 2;S → 3

3)

List-I (Ions) List-II [Ionic radius (in Å)]

2+
(P) Mg (1) 1.37
+
(Q) K (2) 1
+
(R) Li (3) 0.76
2+
(S) Ca (4) 0.72
(A) P → 2;Q → 1;R → 3;S → 4
(B) P → 1;Q → 2;R → 3;S → 4
(C) P → 4;Q → 3;R → 1;S → 2
(D) P → 4;Q → 1;R → 3;S → 2
4) Given x = % increase in volume M1 = Theoretical molar mass, M2 = Observed molar mass of gases
mixture.
D1 = Theoretical vapour density, D2 = Observed vapour density of gases mixture

List-I
List-II
(Extent of reaction = 100%)

P 1 x = 33.33%
NH3(g) —→ N2(g) + H2(g)

Q 2 x = 25%
SO3(g)—→ SO2(g) + O2(g)

R PCl5(g) —→ PCl3(g) + Cl2(g) 3 x = 100%

S 4 x = 50%
HCl(g) —→ H2(g) + Cl2(g)

5 M1 > M2

6 D1 = D2
(A) P → 3,5;Q → 4,5;R → 3,5;S → 6
(B) P → 2,5;Q → 4,5;R → 4,5;S → 6
(C) P → 3,5;Q → 6;R → 4,5;S → 2,5
(D) P → 4,5;Q → 4,5;R → 2,5;S → 6

SECTION II

1)

Double bond equivalent in following compound is

2)

How many carbons are selected in principle carbon chain of following compound:
3)

Find number of compound which can show tautomerism :

(i) (ii) (iii)

(iv) (v) CH3 – CH2 – NO (vi) (vii)

4)

Electronegativity of an element is 1.0 on the Pauling scale. Its value on Mulliken scale will be x ×
10–1. What is the value of x.

5) From the following list of orbitals, s, px, py, pz, dxy, dyz, dxz,

6) On a metal with work function 2.0 eV light of wavelength 400nm falls, maximum velocity of
ejected photoelectrons are 6.22 × 10x m/s. Hence x is.

PART-3 : MATHEMATICS

SECTION I(i)

1) Let a = and b = tan2 , then the value of log(2b-a) (2a-b) is ______,

(A) 2
(B) 1
(C) 3
(D) 4

2) If C1 : x2 + y2 - 4x - 6y - 3 = 0 and C2 : x2 + y2 + 2 px + 4 (p + 1)y - (2p + 1) = 0 are

orthogonal.
Then power of center of C1 w.r.t. circle C2 is :

(A) 8
(B) 4
(C) 16
(D) 2

3) By using the digits 1, 3, 4, 5, 7 five digit numbers are formed with different digit arranged in
ascending order of their values. Then number at 100th position is

(A) 71435
(B) 74150
(C) 71453
(D) 71451

4) Let S be the set of integral value of 'a' for which one root of quadratic equation.
(a2 - 2a + 3)x2 - 6ax + 4 = 0 is less than 1 while the other is greater than it, then the number of
point(s) P(a2, a) where a ∈ S lies in the region between the lines x + y = 6 & x + y = 12 is (are) :

(A) 0
(B) 3
(C) 4
(D) 5

SECTION I(ii)

1) Let S = {a + b : a, b ∈ Z}, T1 = {(-1 + )n : n ∈ N}, and T2 = {(1 + )n : n ∈ N}.

Then which of the following statements is (are) true ?

(A) Z ∪ T1 ∪ T2 ⊂ S

(B)
T1 ∩ = ϕ, where ϕ denotes the empty set
(C) T2 ∩ (2024, ∞) ≠ ϕ
For any given a, b ∈ Ζ, cos (π(a + b )) + i sin (π(a + b )) ∈ Ζ
(D)
if and only if b = 0, where i = .

2) Let a, b, c (in order) be the first three terms of a sequence and satisfying loge =0
2 th
and loge b = loge (a - 4) = loge (c - 2). If Tn and Sn denote n term and sum of first n terms of the
sequence, then :

(A) T10 = 31
(B) S10 = 120

(C) - 2T21T1 + = 1609

(D) S11 - S10 = 23

3) If one vertex of a equilateral triangle of side 2 lies at the origin and other lies on the line x - y
= 0, then the coordinates of the third vertex are :

(A) (0, 2)
(B) ( , )
(C) (2, 0)
(D) ( , 1)

SECTION I(iii)

1) Number of ways in which all the letters of the words given in column I can be arranged in matrix
of 3 × 3 such that no letter in any row or column is repeated :

Column I Column II

A INDIATIME P 33 × 6 !

B FORTUNATE Q 18 × 7 !

C SWEETNESS R 3×4!

D CANDIDATE S 6×6!

T 6×5!
(A) A → T;B → S;C → R;D → P
(B) A → S;B → Q;C → R;D → P
(C) A → S;B → Q;C → P;D → R
(D) A → S;B → T;C → P;D → Q

2) Match the column

Column I Column II

The coordinates of the point, which is at shortest distance from the line x + y = 7
A P
and lying on the ellipse x2 + 2y2 = 6 are (a, b), then a + b is equal to

The maximum distance of the center of the ellipse from the chord of
B Q 3
contact of two mutually perpendicular tangents of the ellipse is ,
then value of a - 2b is equal to, where a & b are coprime numbers.

A normal to the hyperbola = 1 have equal intercept on positive x and y

C R 4

axes. If the normal touches the ellipse , then a2 + b2 is equal to

D The length of the latus rectum of the hyperbola xy - 3x - 3y + 7 = 0 is S 6

(A) A → R;B → S;C → P;D → Q
(B) A → P;B → Q;C → R;D → S
(C) A → Q;B → P;C → S;D → R
(D) A → Q;B → S;C → P;D → R

3) If z = x + iy, then on the basis of information given in column I match the answer in column II

Column I Column II

||z + i| - |z - 5i|| = 2a represents a hyperbola then number of integral values of 'a'

A P 1
are

B Area enclosed by the rays with equations arg (z + 1) = ± and arg (z - 1) = Q 2

± is

ƒ(z) = (2z - 3)i where ƒ(z) is always real & -5 ≤ ƒ(z) ≤ 5, then number of common
C R 3
solution(s) of ƒ(z) & = 1 is/are

If roots of (z - 5)6 = 64 represents a regular hexagon and distance between its two
D S 6
parallel sides is λ ; value of is
(A) A → Q;B → Q;C → P;D → S
(B) A → Q;B → P;C → R;D → S
(C) A → Q;B → Q;C → S;D → P
(D) A → P;B → P;C → R;D → S

4) Match the column

Column I Column II

A The coefficient of x4 in (2-x + 3x2)6 is P 1024

10
B C0 22C11 - 11C1 20C11 + 11C2 18C11 - 11C3 16C11 +..... = Q 2048
5
C C1 5C5 - 5C2 10C5 + 5C3 15C5 - 5C4 20C5 + 5C5 25C5 = R 990

D The coefficient of x4 in the expansion of (1 + x + x2 + x3)11 is S 3125

T 3660
(A) A → R;B → P;C → S;D → Q
(B) A → R;B → P;C → Q;D → S
(C) A → T;B → Q;C → R;D → S
(D) A → T;B → Q;C → S;D → R

SECTION II

1) If real numbers x and y satisfy (x + 5)2 + (y - 12)2 = 196, then the maximum value of (x2 + y2)1/3 is :

2) Point O is the center of the ellipse with major axis AB and minor axis CD. Point F is one of the
focus of this ellipse. If OF = 6, and the diameter of inscribed circle of ΔOCF is 2, then the value of

3) Number of values of θ lying in the interval satisfying the equation (1 - tan θ) (1 + tan θ)
2
sec θ + is :

4) If α1, α2, α3 are the roots of equation z3 - 3z2 + 3z + 7 = 0, then the value of is :

5) If 1, α1, α2,...,α9 are the roots of equation z10 - 1 = 0, then find the value of .

6) equals :
 ANSWER KEYS

PART-1 : PHYSICS

SECTION I(i)

Q. 1 2 3 4
A. D C A B

SECTION I(ii)

Q. 5 6 7
A. A,B,C,D A,B,D A,D

SECTION I(iii)

Q. 8 9 10 11
A. B D A C

SECTION II

Q. 12 13 14 15 16 17
A. 4 4 9.00 1.00 2.00 7.00

PART-2 : CHEMISTRY

SECTION I(i)

Q. 18 19 20 21
A. B D A A

SECTION I(ii)

Q. 22 23 24
A. A,D A,C A,B,C

SECTION I(iii)

Q. 25 26 27 28
A. C C D A

SECTION II

Q. 29 30 31 32 33 34
A. 13.00 4.00 4.00 28.00 1.00 5.00

PART-3 : MATHEMATICS
 SECTION I(i)

Q. 35 36 37 38
A. A C C A

SECTION I(ii)

Q. 39 40 41
A. A,C,D B,C,D A,D

SECTION I(iii)

Q. 42 43 44 45
A. B D A D

SECTION II

Q. 46 47 48 49 50 51
A. 9 5 4 3 4 1
 SOLUTIONS

PART-1 : PHYSICS

2)

Instantaneous axis of rotation lies above the centre of mass where v – ωr = 0

3) P0h = P' (h – x)
2h +h = P' + x
3h – x = P'

(3h – x) (h– x) = h2

4)

6) After heating, assuming that the piston (left) just reaches the middle and the right piston
moves x,
ℓm = 2ℓ0 – (ℓ0 + x) = ℓ0 – x = 7.40 × 10–2 m
The gas pressure in the left and right chambers is equal to

0
p1 = p2 = p = = 1.65 × 105 Pa
V1 = 2ℓ0S = 3.40 × 10–3 m3
V2 = ℓmS = 1.26 × 10–3 m3

T1 = T2 =

a= ΔE = 640 J

W' = = 167 J
Q = W' + ΔU = 807J < 1000 J

1000 – 807 =
7) (a) Buoyancy force is FB = Vcone pg
weight of the cone W = Vconedg

where

Tension, T = FB – W =

(b)
Buoyancy is resultant of vertically upward force (F1) applied by water pressure on the base of
the cone and the vertically downward force (F2) applied by water on the slant surface. The
horizontal component of sums upto zero due to symmetry.

8)

Ans. (B)
Sol. If dgh1 > P ⇒ height of liquid will not cross h1, dgh1 < P ⇒ height of liquid will cross h1

11) New Ans. (A) By Hemant Kumar Sir

12)
 13)

F3 = Sℓ (surface tension is S)
ℓ = length of aquarium inside the plane of paper

F.B.D. of aquarium
F1 + F3 = F2

h = 4 mm

14)
in y - direction,

... (1)
in x - direciton

and

PART-2 : CHEMISTRY

18)

21)

With increase in temperature, Kw of water increases

So, degree of dissociation of water increase
∴ pH as well as pOH of water decrease.

22)

(A) 1gm N2O & 1 gm CO2

(N = 14, C = 12, O = 16)
Molar mass of N2O = 44 g/mol
Molar mass of CO2 = 44 g/mole

∴
∴ 1 molecule of N2O contains ⇒ 3 atoms.
∴ 1 molecule of CO2 contains ⇒ 3 atoms.
{Both contain same no. of molecule or moles. Hence they contain same no. of atoms.}
Ans. (A)

(B) 1 lit. 20%

∴ 20 =

∴
⇒ 5m ⇒ 5 moles of urea present in 1000 g of solvent
⇒ In 1000 g solvent
⇒ Mass of urea = (5 × Molar mass) [Urea NH2CONH2]
= 5 × 60 = 300 gm
∴ Total mass of solution = (1000 + 300)
= 1300 g = 1.3 kg.

(C) H2 + O2 → H2O2

moles moles
⇒ Lets assume : x is the no of molecules of H2 & O2. According to stoichiometry coefficient.
(molar ratio of H2 & O2 1 : 1) ← (reacting)

Given molar ratio ⇒ ⇒1:1

∴ Both are consumed after completion of reaction.
Ans. (C)
(D) Fe2(SO4)3 ⇒ Ferric sulphate

∴ %Fe =
M. wt. of comp. = (56 × 2) + (32 + 64) × 3 = 400 g/mol

∴ %Fe = = 28%.
Ans. (A & D)

23)

(A) N2 + 3H2 → 2NH3

Initial mole 5 17.5
Final mole 0 2.5 10
 (B) N2 + 3H2 → 2NH3
Initial mole 3 9
Final mole 0 0 6
(C) N2 + 3H2 → 2NH3
Initial mole 5 15
Final mole 0 0 10
(D) Mass of H2 = 24 gm, Mass of N2 = 112 gm
N2 + 3H2 → 2NH3
Initial mole 4 12
Final mole 0 0 8

24)

28)

The correct option is :-

(A) P → 3,5; Q → 4,5; R → 3,5 ; S → 6
(B) P → 2,5,; Q → 4,5; R → 4,5 ; S → 6
(C) P → 3,5; Q → 6; R → 4,5 ; S → 2,5
(D) P → 4,5; Q → 4,5; R → 2,5 ; S → 6

34) KEmax = hv – w0

=
= 3.1 – 2
= 1.1 ev

× 9.1 × 10–31 × U2max = 1.1 × 1.6 × 10–19

Umax = 6.22 × 105 m/s

PART-3 : MATHEMATICS