Masstransport Advective Bulk flout Diffusion

Convective
flow Diffusive flow
TAK CACHA LA
JAA CDAB TOCA
CaVa Ca D

M
Éi
Cours
CazCAVA

n
Na

sina.noaa.na acn.tw
OCA NAINA
m S
CDABILE NA
Nap Diffusivity
Na OCA NatNB CDAB
CDABTOCA
It
Homogenous reactions Bulk Source sink inthe Governing
reaction 3 Surface conditions
equation paki
Heterogenous Boundary
K'inCa
Naelsurface surface

Tgwfftasioneinhfghtiagnant
ga'sfilm
chemical reaction
Diffusion with a homogenous

Homogenous reaction

Heterogenous reaction

equations identify the processes

s
write the governing
conditions Identifythe
solve using boundary
Use a shell balance and 8th
Write the spicies flux equation
Gas stream of Aa B
MoÉÉtf A moving outfifty
pts ppicessess

2 22
Concentration gradient is imposed
B in the negative Z direction
of

Miffy
Diffusion
out due to A
Banana a gang pushed
of
and B due to an imposed
diffusing movement
i Net
concentration gradient Thisis a dynamic
of B
O Stagnant
gas film
process
 OCA CNAat Nba
CRABdate
Naz
0
NBz
On Naz CDABdate
Naz

well i w d go.ge
0
mass

0 At steady
balance equation

SNaz
S Na
Iz z state

the tube
S cross sectional area of
Governing equation
d

4ft
0
for this problem
so Expandedformof
governing equation

C and DAB are constants

data 0
2 fan
U
Ci l Ka
Iea data use sea
doc
É doc

I Iz
conditions
II
Apply boundary inv
Slept Oca OH
At 2 2
OCA 042
2 22

S
I C
Variation
of
mole fraction
of
A as a function of Z
peppy
gym ftp.jht
 Average conc
of B Hogg
3,37
B alongthe
Length average value of molefraction of
the tube
lengthof
and perform the integration
Plug values of EBay
AB PCB
in
Obong Titans I
mean
concentration
log
difference

Naz z z 97 It z z

d
Coff 12 4

Can be used to
k Mi 4

IM
zi

p.fiy evaluate DAB

experimentally

DAB at Different Temperatures

Can also find

wigcreaio
Irreversible 1st order reaction
2
É concentration

Noted is sparingly
distribution
of
soluble in B
Act B

z
 3 Oca Na at Nba DAB deaf
Naz

A is sparingly
soluble in B There is no convective flux
B OCACN.net NBz can be dropped
of A
or

d
spin wine me
the processes
sp iif.IE on and identify

Make as hell
step Generation

S Naz Depletion o
S Naz z
a a

molests
S Naz K CAS02 0
SNAz
Iz 2,02

Governing equation
y
1dniztk.cn
CDab doff k on so
2 f
1 oa
m
df.tt

f MI the interface Ca Go Interface concentration

or solubility of Aai B
in heat transfer
At 2 L similar to insulated surface
beyond 2 L
A molecules can penetrate
No diffusing
Impervious wall boundary condition
D
I Naz z a
 CDabdhel

dfzlz.IO
Jkietot
Cfo fbi
oshbj.gg
tanh b
cat 4412 I
Naa is a function of
a dying o
Note
sink term
because of a
 balance how to the mole fraction
Using shell get
volatile species A
and molar
flux of A highly

diffusing though
a stagnant gag film a sparingly
and getting converted
soluble species A entering a liquid
be neglected
to another product
convective
flux can

conditions surface
concentration solubility at
Boundary i Naz wale
Impervious wall
the interface mass
Depletion of A appears on the balance
d
reaction
fusion with a fast heterogenous
with a slow heterogenous reaction
Diffusion
Consider a catalytic reactor as shown in the
fig
A diffuses through a thin filmof gas around the cataly
e
Two molecules Gas A reacts on the catalyst surface to form
of
a molecule
of B 2A B

I Find the profile

concentration
Is
y
Bea
A in the stagnant gas film
of
Can the conversion
find to
rate of A to B Help

iii
2 0
reactor catalytic
design such
a

Naz
OCA NAINA CDABdgy
stepI
Two nobsof A moving on the
For I mole of B moving
z direction plus 2 direction
in the
be equal
At steady state the rates must
 and Na is contained in pipe at
of He
Mixture a

ask and I atm Point partial pressurepa

is 0.60 atom Point 2 o.am pass ozatm
steady state if
Calculate the
flux ofMe at
Dar Me Na is 0087 0 m's atm 1.01325 105Pa
of
Ja't C
Darth Jat 92 Dao da R g314 Jmol K
8.314 m3 Pa1kgnot
DAB
dog
Jat Da
ma2
Dab Ga Ca

a
I
PV nap

JB f DBA T WB X DBA TWA

wa WB L
ta v
Ja ewa

ee
I flip Vat
OBDB
i ztWADDTWBOB

rtEg.g É AaMtXBMZ
M

Diffusion velocity wi g

to stationery co ordinates
writ
mass
flea
mass
ni fine
Ni Ci Vi molar

co ordinates
writ to moving
 l D 2 For a binary mixture
ji
Jat Ca Ka OH
Ji Ci ti o
Ca sa caget

ji't fi Ji F ca sea BOB

na I
Jit Ti O Natha
Ci
Jt Na Ka

Jat CDABdata

NatNB CDABdata
Na JCA

e 8
Tidying
Ata Wasat was
I

CATATCBDB DADat ABIB

i
I
gi
TAC Da se
NA la Da Ja
Na case Ja Cal ta v

Int la ra set

Tnt Ca Va D ca ra ca I Cacatobas
xn
ftp.na
NA NatNB
DABdqztXa
NB DBA dogg ADB CNATNB

IB NABdye DBA doe

Nat NB Na N B Coca
dz
 DBA
CD AB
day dye
sea toes I
dye
dye

e
Oca
oraainym.fm
DAB duty
Nat NB
NA

OCB CNA NB CABA

NB dog
NAME NAFI
CRABdogs
COCATIB CDA LEI
CDAB COBA
data debt
OCA t OCB I
d
dat doggo 3 080daL
DAB NBA
data dozy

dish 0 ca cant
t.ir
fi
C2 EIJI yes
fI Yz
ca
ca C Z ca c

car 422 4
fcz
aai
g.tt 8fÉ 3
 a aca
zdc.ae Pro66m3
a

concentration
Togetthe
0ms
ÉE o PM'das afunctionof
ofca

F dat
dig
Dabdfy

o
o

i
Homogenous
reactions with
the liquid
on a thin film
slow reactions Diffusion
Heterogenous
close to the catalyticsurface
gas

a solid to a liquid
When we talk about diffusion from

Nao KCCCAO Cab

Molar at the surface

Nao flex
concentration
Cao 7 surface
bulk stream
Cab 0 concentration is the fluid
ke s convective mass transfer coefficient
D h ADT
Nao KcCCao Cab analogous to I
convective heattransfer
coefficient
 Consider a vessel with two gases A and B separated
removed the
by a thin film
When the
film is
Find the
into each other
start diffusing
gases
species A at steady state
concentration profile of as a function of
equinolar counter diffusion process
in Z direction eggs
the length

My

Na
MMMMM HADLEY

CDAB dogg
MY
digg o day Te o

d o

OCA C Z C2
tT I
042 222 C2
At 2 2 Dca Xp
y y
2 22 OCA 062

Oca 4415,71
2
2 Cz aM
É

fr
i
 one
PEE
scan
C
sea
C
an a

I
N2 CO2
NO CO
12
K Ca No reaches the catalyst surface
ra a
only process through
one dimensional diffusion 1.2ha
by thickness 500 C presume
L Temp
thin gas film of 1mm k 0.05 mls
of the film
is
Thickness NO
104m21s Mole fractionof
am DAD
A 200
b Vac o.pt
or the exhaust gases
NO at the
What is the mole fraction of
catalyst surface
What is the no removal rate for a surface
A 200 am
area

t
 Na Oca NAJIB C DAB
dogs

Na Chas date

dog
o day dja
d so as pastors
1 Ola Otc
By At 2

wealthy
L three is a reaction happening
At 2
C AB
Naz
K ca defy
E
Ka C CDAB
K
DIE
reaction
Equality of diffusion rate and
rate

K oca Da d

K Ola DAB Cr

acting
a
4i 42
 Cz
Oca C L 02
TAL
kif I

1C2
Ht kg
i sent
a
kiss
a
KYLE

2 0 OCA OGS

oats
 t
Homogenous reactions with the liquid
Heterogenous slow reactions Diffusion on a thin film
gas close tothe catalyticsurface

liquid
When we talk about diffusion from a solid to a

Nao Kc C CAO Cab

Nao Molar at the surface

flex
Cao 7 surface concentration

Cab 0 concentration is the bulk fluid stream

ke s convective mass transfer coefficient

Nao KcCCao Cab analogous to D h ADT
I
the
function of geometry 8 convective heattransfer
velocity
properties of the fluid coefficient
 Éist

shaded area inert coating

É is a diffusion only process

inert coating andreaches
Onedimensional

diffusion only
the
Drag diffuses through
process
intestine
the outside shell in
end caps i Make a
Because both ends are blocked by
a a.am the inert coalingregion
am no affusion
o
Also not a function of

Area 252L
A Rateofdrug
Area x Radial molar flux of release

i No generation or depletion terms

No reaction

Na Oca NatNB DABdate

since it is a diffusion only process the

term be ocACNatNBJ o
convective
flux can neglected

aByy.y
c
1na
 balance the
Skp2 Make a shell and write mass
for
shell
within the inner core
Consider a shell

riff
to D
S Nazir S Nar yo

252 L NA fr 12TH'DNA stor o

Nar equation
I r o Governing

Nar COAB
It
I r dogs o

a ta
d a of og
Profile
inert material
dat year 1 follows a logarithmic

fanscilnrtff distribution ofthe radius

conditions
steps Apply boundary

Ben Ab r ri ka ki Kaicintits
the coating the diffusive
By At the outer surface of
must be equal to the convective flux
flux
 i
DAB Ctdeff Kac Cro Co

Diffusive flex
Convective
flux
Cro Kao Ct
NAB Kac Dao Ce
Gct Co 0

DAB Kae Oo
go

kag.IM
fa
n

a in this equation

c lnritc
I substitute for
ocai

Kai Ola Inri tea

Kaj
xaitkaczotnr.TL
fcz

Oca C Int Cz

sea Ino sasi Inri

karting kagato
 Kai Mri Int
Kago
des

1
Kai tn

Kac O i m Is 5 106

DAB 10
10
m2 Is
IDE
5 106060 In
ro g mo g sea Dai

Kai O 9

Faitxologiggomatrroao
Af r ro OCA 070 ri 3 10 m

ago In
oho Kai 5 10
3
060 a 5 10 In3g Dai

suo
eating
Ignis
no 3.527
rw
i
I ms
the inert
outer area outer core
of material

2Tro L Kac IcaoCt

10
0.1 X O U X 3.527
3 3
2 IT 5 10 5 10
m m ms kgm3 Kgs

184103mi h

inner
_imam
core
g to the outer core

from the
the outer core
Convective mass
flux from intestine
inert material into the
the
of
at the outer edge
the diffusive
i Steady state

flux
convective flux convective
Area
Rate of drug release concentration
coefficient
difference