Sri Chaitanya IIT Academy.,India.
A.P T.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60, Elite,Target & LIIT BT's Paper -1(Adv-2011-P1-Model) Date: 20-04-2025
Time: 09.00Am to 12.00Pm GTA-28 $ Max. Marks: 240
KEY SHEET
CHEMISTRY
1) A 2) C 3) D 4) C 5) C 6) D 7) C 8) ABC
9) BC 10) ABD 11) ABC 12) A 13) B 14) A 15) A 16) D
17) 2 18) 6 19) 4 20) 6 21) 7 22) 8 23) 5
PHYSICS
24) A 25) B 26) B 27) D 28) C 29) D 30) C 31) ABD
32) BCD 33) AC 34) AC 35) D 36) C 37) B 38) C 39) B
40) 8 41) 8 42) 2 43) 4 44) 3 45) 6 46) 5
MATHEMATICS
47) B 48) C 49) A 50) B 51) A 52) C 53) B 54) BCD
55) BC 56) ABC 57) BCD 58) C 59) B 60) C 61) C 62) D
63) 2 64) 4 65) 9 66) 7 67) 1 68) 5 69) 6
Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
SOLUTIONS
CHEMISTRY
1. m 0m b c
260 0m b 0.25 ….. 1
250 0m b 1 …….. 2
The above equation 1 and 2
b= 20
0m 260 20 0.5 270
2. NaCN HCl NaCl HCN
P H P ka log
NaCN
HCN
3. For condensation H Ve S sur ve
S sys ve
For natural process Stotal 0
XeF2 BF3 XeF BF4
4.
XeF6 CsF CS XeF7
5.
6.
7. I–resonance; III sp 2 hybridized nitrogen; IV sp 2 hybridized nitrogen with positive charge on nitrogen.
8. Ce4 pb 2 pb 4 Ce 3
E 0 0.155V
MnO4 Pb 2 Pb 4 Mn 2
E 0 0.055V
Ce4 Mn 2 Ce3 MnO4
E 0 0.05484V
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
0.02 0.03 0.04
9.
V1 V2 V3
V1 : V2 : V3 2 : 3 : 4
2 200
V1 300 ml
9 3
3
V2 300 100ml
9
4 400
V3 300 ml
9 3
10. A. back bonding from O to Si
B. CH 3 3 SiO stabilized by back bonding
C. P SiH 3 3 is pyramidal
D. ClO4 does not polymerize
11. A- Enantimer B- Diastereo C- Identical D- No releationship
12. PA 2 PB
2 4
PA PB 2 PB and PA
3 3
8 4
From PV=nRT n A & nB
3 3
13.
A B
84
33
8 4 4 4
T = 5min
3 3 3 3
t1/2 5
In two half lives 75% completed
1 8 2
moles of ‘A’ left
4 3 3
4 10
moles of ‘B’ left 2
3 3
P 8.21 4 0.821 100
P=4
4
r1 P1 M 2 3
14. 2
r2 P2 M 1 2
3
NO2
15. Br is anti to -OH therefore it will migrate
16. oximes of P are geometrical isomers
Q are metamers
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
methyl is having less migrating aptitude than ethyl
17. At second end point we have Na2 HPO4
P ka2 P ka3
pH 10.5
2
ECell 1.3805 0.059 10.5 2
18. 10 M 1 3 25 0.4 5
M 1 1.66M
T f i k f m 2 1.86 1.66 6.2
19. NH 2COONH 4 2 NH 3 CO2
5L 4 2
K p 4 2 32
2
10L 2 1 p 1+p
2 2 1 p 1 p 32
2
1 p
3
8
p 1
Total pressure 3 1 p 6
20. 2.84D for
NiCl4 NiCl2 PPh3 NiF6
2 4
2 2 2
Ni NH 3 6 Ni cn 6 Ni H 2O 6
21. –COOH group, all OH groups, SH group and H of terminal alkynes react with MeMgBr
to give CH 4
22.
23. a, c, d, e, f are formed optically inactive
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
PHYSICS
1 s 3/2
2 2V
24. a K V ; V dv kds; s
2 0
0
3 K
25.
i iR2 ic2
22 22 2 2
hc
26. Cut off wavelength c where V is the accelerating voltage.
eV
1
Characteristic wave length
Z b
2
27. W F .dr F .dr
OA AB
4 6
W x 3dx 12 ydy
0 0
W 152 J
28. Apply Biot Savart’s law B B1 B2
0l
B1 (Due to semi-infinite straight wire)
4 a
0l 0l 1 1
B2 (Due to parabolic portion) B
8a 4a 2
29.
Let equivalent resistance be x
xR
R R
x R Rx
xR
2R
xR
R 5R
x 2 Rx R 2 0 , x
2
BA
30. BAkˆ.nˆ cos wt
2
BA BA
sin t i sin t
2 2R
BA2
m iAkˆ sin t kˆ
2R
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
B A 2 2
B 2 A2 ˆ
T m B sin t kˆ i sin 2 t
2R 2R
B 2 A2 2 ˆ
T sin i
2 R 6 4
I Q
II . 0
II P
BA
III. cos t
2
BA BA2
i sin t m sin t kˆ
2R 2R
B A
2 2
m B sin t kˆ sin tiˆ cos tˆ
2 2R
B 2 A2 sin t B 2 A2 ˆ
sin t ˆj sin t ˆj j
2R 2R 4
III S
BA BA2
BA
IV. sin t i
2 2R
cos t vecm
2R
cos t kˆ
B 2 A2 ˆ ˆ
m B
2R
k j cos 2 t
B A ˆ
2 2
2R
i .cos 2
6
3
iˆ IV R
4
31. For the blocks to remain stationary on the inclined surface:
1m2 2 m2
m1 m2 g sin 1m1g cos 2 m2 g cos tan
m1 m2
If N is the force applied by upper block on the lower block, then assuming both are
slipping on the incline: m1 m2 g cos 1m1g cos 2m2 g cos m1 m2 a
In this situation, using Newton’s laws for only lower block:
m1 g sin N 1m1s cos m1 a
Which shows, N 0 Under a situation that 1 2 with both blocks slipping on incline, the
lower block will have more acceleration that upper block causing the blocks to get
separated. Thus, the normal force will become zero
32. Internal force can also change the kinetic energy of system.
33.
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
30units 1.2 A
1unit 0.04 A
V13 1.2 250 300 30units 300Volt 1unit 10volt
34. Flux through a Gaussian surface (cylindrical shape) of length l and radius 2R
l 2 Rl
E.ds 2 E.ds 0
l
Total flux 2 R 0
0 2 R
35. At time t=0, the velocity is maximum (maximum momentum) and the displacement is
zero. It reaches maximum height when the momentum is zero and falls back with a
negative momentum.
36. E p 2
37. It comeback to equilibrium position
38 & 39.
ma mg mga
Ee ma E in SP Ee ma E in PA ENet
e e e
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
3R 15 R 15 Pa
RNet 3R
4 4 4S
mga 4mgaS 4mgS mga 4mga 7 mga i mgS
i VPQ 2R iRS
15 R 15ePa 15eP e 15 Re 15e 4 15eP
e
4
l 4r 2 l 2
40. 80
2
F 2mnA v0 v v0 v 2 10 20 10 25 1 5 2 5 2 =8N
2 2 2 2
41.
42. Since the boards are perpendicular so the impulses provided by board does not effect the
motions Perpendicular to the board. Let TA be the time internal between successive
8a 8b
collisions with board A and from board B is TB .TA ;TB
g cos a g cos a
Let the ball collides X ties with wall B form each time it bounces with wall A
a 4
xTB TA 1x tan a 1 2
b 1
43. P1 1.0atm, V1 1.0 L, T1 122 K , P2 1.0atm,V2 2.0 L, T2 244 K , K 2T1
P3 2.0atm,V3 2.0 L, T3 488 K , K 4T1 ,
P4 0.0157 atm, V4 64 L, T4 122 K , K T1
7 7
For 1 & 2 Q1 nC p T nR T2 T1 n R T1
2 2
5 5
For 2 & 3 Q2 nC p T nR T3 T2 n R 2T1 5nRT1
2 2
V
For 3 4 Q3 0 , For 4 1 Q4 nRT ln 2
V1
1 Q nRT1 ln 64 6 ln 2 12
nRT1 ln nRT1 ln 64 n 1 1 1 1 ln 2
64 Q 7 17 17
5nRT1
2nRT1 2
44. Total flux coming out of complete closed surface is given as
q
hemisphere cone ……….. (1)
0
Through the hemisphere, half of flux originated by q will come out, given as
q q
hemisphere .Thus equation-(1), flux coming out of conical surface is given as come
2 0 2 0
nq q
n3
6 0 2 0
3R 1 3R 2 3R 4
45. net 8 0 R 3 gR
8 3 4 2 3
3 4 1
net R 4 104 R 410 4 net R 4 104 net 21.6 105 Nm
2 3 6
46. All the elements of circuit are in parallel arrangement
1 1 1 1 1 1 1 4 2 V2
5 Power 20W
Req 40 40 40 40 20 20 40 20 R
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
MATHEMATICS
1 tan 2 2 tan
47. we know that cos 2 and sin 2
1 tan 2 1 tan 2
2 2
tan , tan ( are unequal) are the roots of
2 2
1 t 2
2t
x a 2 y 2 a xt 2 2 yt 2a x 0
1 t 1 t
2a x
tan tan ..... i
2 2 x
2y
and tan tan ...... ii
2 2 x
2 2
Now tan tan tan tan 4 tan tan . But tan tan 2e
2 2 2 2 2 2 2 2
2
2y 2a x 4 y2 2a x
2e 4
2
4e 2 4
2
x x x x
y 2 2a x
e 2
2
, i.e, y 2 2ax 1 e 2 x 2
x x
48. Consider the first relation given in the problem carefully. We will apply this relation to
itself, so that
f x, y f 2 x 2 y , 2 y 2 x
f a, b ( where a 2 x 2 y , b 2 y 2 x)
f 2a 2b, 2b 2a
f 8 y , 8 x
Again,
f x , y f 8 y , 8 x
f c, d wherec 8 y, d 8 x
f 8d , 8c
f 64 x, 64 y
f 4096 x,4096 y
f 212 x,212 y
Now, if we put y = 0 and substitute 2 x in place of x, we have
f 2 x ,0 f 212 x ,0 g x g x 12
Thus, g x is periodic with period 12. The correct option is (c).
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
x y
49. Tangent to the ellipse at P a cos , a sin is cos sin 1
a b
Tangent to the circle at Q a cos , a sin is cos ax sin ay a
Now angle between tangents is ,
b
cot cot
Then tan a
b
1 cot cot
a
b
cot 1
a ab a b
b 2
2
1 cot a tan b cot a tan b cot 2 ab
a
ab
Now the greatest value of the above expression is when
2 ab
a tan b cot
a b
max imum tan 1
2 ab
50. (b) Let n1 and n2 be the vectors normal to the faces OAB and ABC.
Then
iˆ ˆj kˆ
n1 OA OB 1 2 1 5iˆ ˆj 3 ˆj
2 1 3
iˆ ˆj kˆ
and n2 AB AC 1 1 2 iˆ 5 ˆj 3kˆ
2 1 1
If is the angle between the faces OAB and ABC, then
n .n
cos 1 2
n1 n2
559 19 19
cos cos 1
25 1 9 1 25 9 35 35
51.
f x f ' x f '' x f ''' x .......
f ' x f '' x f ''' x f '''' x .......
2 f ' x f ' x f '' x f ''' x .......
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
f ' x 1
2 f ' x f x
f x 2
1
On integrating w.r.t x; we get l nf x xc
2
x 0; f 0 1 c 0
x
x
Hence l nf x f x e 2
2
1
52. G 0, t 0 for t 0 so g 0 f t . 0 dt 0
0
1
G 1, t t.1 1 0 for t 1. Hence g 1 f t .0 dt ,
0
x 1 x 1
Also g x f t t x 1 dt f t x t 1 dt x 1 tf t dt x f t t 1dt
0 x 0 x
x 1
Hence, g ' x x 1 xf x tf t dt f t t 1 dt xf x x 1
0 x
Thus g x f x
''
53. As the roots are of opposite signs, product of roots < 0.
a 2 b 2 1 0 a 2 b 2 1 a ib 1
So, the point a ib lies inside a circle of centre (0,0) and radius 1.
5an 1 3n 5
54.
5an 3n 2
5a2 5a3 5an 8 11 14 3n 2
a2 ........ an 1 ......
5 a1
5 5 5 8 11 3n 1
5 an
3n 2
a1
5an 3n 2 an log 5 3n 2
5 5
an 3 log 5 3n 2 3,4
n 41,42,........207
623 3123
an 4 n
3 3
208, 209,.......,1041
55. A) Order of the differential equation is 2
xdy ydx
xdy ydx x2
B) dx dx
x2 y 2 y
2
1 x 2
y y2 y x2 y 2
ln 1 2 ln Cx ; Cx i.e y x 2 y 2 Cx 2
x x x x
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
C) y e A cos x B sin x
x
dy
e x A cos x B sin x e x A sin x B cos x y e x A sin x B cos x
dx
d 2 y dy
2
e x A sin x B cos x y
dx dx
dy dy dy
y y 2 y
dx dx dx
1
dy dx 1 e tan y
D) 1 y x 2e tan y
1
2
x
dx dy 1 y 2 1 y2
1 1
1 y 2 dy e tan y
tan 1 y tan 1 y
2 e tan 1 y 1 1
IF e e xe . dy xe tan y e 2 tan y k
1 y 2
x 6 x 8 16. Let x 6 y 1 x 8 y 1
4 4
56.
Now, y 1 y 1 16 y 4 6 y 2 7 0 y 2 7 0 and y 2 1 0
4 4
y 7i or y 1 x 7 1or x 7 7i a 7, b 1, c 7, d 7
n 1
1
C1 nC2 ... n Cn1
n
2n 2
57. n
C1 C2 ... Cn 1
n n n 1
n 1
P
n 1
n 1
1
C0 n C1 nC2 ... n Cn
n
2n
Also, C0 C1 C2 ... Cn1 Cn
n n n n n n 1 P
n 1 n 1
58. a 20 6 , b 10 30, c sin 1 sin 4 10 10 3
So, a b c
sin 1 sin x x x ,
2
So, largest integer x = 3.
59. 5sec1 x 10sin 1 y 10
sec 1 x and sin 1 y
2
x 1, y 1
So,tan 1 1 cos 1 0
4 2 4
60. For Cn circle let centre by n ,1 and it touches line Ln and Ln 1
x y x y
i.e 1, 1
xn 4 xn1 4
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
4 n xn 4 xn
1 ....... i
16 xn2
4 n xn1 4 xn1
1 ........ ii
16 xn21
3 xn 1 xn 16 xn2 16 xn21
1
Let xn 4cot n 0 n tan n1 tan n
2 2 2 2
22 1
n
1 1 n 1 15
As x1 3 tan tan n xn n1 x2
2 2 2 2 2 2
31
Putting is (i), we got 2
4
n
x 22 1
lim nn lim n1 n 2
n 2 n 2 2
61. For Cn circle let centre by n ,1 and it touches line Ln and Ln 1
x y x y
i.e 1, 1
xn 4 xn1 4
4 n xn 4 xn
1 ....... i
16 xn2
4 n xn1 4 xn1
1 ........ ii
16 xn21
3 xn 1 xn 16 xn2 16 xn21
1
Let xn 4cot n 0 n tan n1 tan n
2 2 2 2
22 1
n
1 1 1 15
As x1 3 tan tan n n xn n1 x2
2 2 2 2 2 2
31
Putting is (i), we got 2
4
n
xn 22 1
lim n lim n1 n 2
n 2 n 2 2
62. For Cn circle let centre by n ,1 and it touches line Ln and Ln 1
x y x y
i.e 1, 1
xn 4 xn1 4
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
4 n xn 4 xn
1 ....... i
16 xn2
4 n xn1 4 xn1
1 ........ ii
16 xn21
3 xn 1 xn 16 xn2 16 xn21
1
Let xn 4cot n ,0 n tan n1 tan n
2 2 2 2
1 1 n 1 22n 1 15
As x1 3 tan tan n xn n1 x2
2 2 2 2 2 2
31
Putting is (i), we got 2
4
n
x 22 1
lim nn lim n1 n 2
n 2 n 2 2
63. We observe that
1 x 1 x 1 x 2 1 x4 .... lim
n
1 x2 n
1 sin ce x 1
1
Thus, 1 x 1 x 2 1 x 4 ....
1 x
We now take the log of both sides and differentiate:
1 2x 4 x3 1
....
1 x 1 x 1 x2 4
1 x
1
Thus, f x . This is a hyperbola, which touches the given circle at (2, -1) and
1 x
(0,1) (verify).
i
r 0 2 2
r 1
64. Let i be the event that is the upper left corner of required square
95 417
P 1 2 3 4 P 1c 2c 3c 4c
512 512
65. Suppose there are Tn ways to cover n steps
Tn Tn 1 Tn 2 Tn3 , T1 1, T2 2
3 32 33 1
66. l lim18 2 4 6 ...... 18 9
n
3 3 3 1
3 1
3
2 22 1 9 12
m lim12 2 4 ...... 12 12 An 7
n
2 2 1 3
2 1
2
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Sri Chaitanya IIT Academy 20-04-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2011 –P1)_GTA-28_Key& Sol’s
67. A at12 , 2at1 , B at22 , 2at2 , C at32 ,2at3 , D at42 , 2at4
2 2
ABC 900 1 t1 t2 t2 t3 4
t1 t2 t2 t3
2 2
ABC 900 1 t1 t4 t3 t4 4
t1 t4 t3 t4
t2 , t4 are roots of
t t1 t t3 4 0 t 2 t1 t3 t t1t3 4 0 t2 t4 t1 t3
68. Use the concept, t t t 1, t R
So,3 x 7 x 2 3 x 2 3 x 7 1and 3x I
7 8 9 10 11
Solving, x , , , ,
3 3 3 3 3
1 sin cos
69. cos 1 1 0
sin 1 1
Applying C3 C3 C2 , then
1 ... sin sin cos
cos 1 0 0
sin 1 0
Expanding along C3 , then
sin cos cos sin 0
sin cos
2
0
sin cos 0
sin cos
tan 1
3
0,
4
8
Hence, 6
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