20-03-2025

1201CJA1010212400118 JM

PART-1 : PHYSICS

SECTION-I

1) Block A of mass 1 kg is placed on a trolley B of mass 10 kg as shown. The coefficient of friction

between A and B is 0.5, while the horizontal surface on which trolley is placed is smooth. If the value
of F is half of the limiting value of F for no slipping between A and B, then the magnitude of friction

force between A and B is :

(A) 2.4N
(B) 2.57N
(C) 2.18N
(D) 1.285N

2) Two plano-convex lenses each of focal length 10 cm and refractive index are placed as shown.

In the space left, water is filled. The whole arrangement is in air. The optical power of the

system is (in diopters)

(A) 6.67
(B) –6.67
(C) 33.3
(D) 20

3) A current I increases at a steady rate in a long straight wire. The variation of current with time is
I = 3.36 (1 + 2t) × 10–2 A. A small circular loop of radius 10–3 m has its plane parallel to the wire and
is placed at a distance of 1 m from the wire. The resistance of the loop is 8.4 × 10–4 Ω. The
magnitude of the induced current in the loop is.

(A) 1 × 10–11 A
(B) 3 × 10–11 A
(C) 5 × 10–11 A
(D) 7 × 10–11 A

4) Two coherent point sources, emitting light of wavelength λ, are placed at a separation of 4λ along
positive y-axis. The number of minima, detected by a detector, which is travelling from –∞ to +∞
along x-axis, is

(A) 4
(B) 6
(C) 8
(D) 9

5) The engineer of a train blows the train whistle as he approaches a crossing. A few moments later
he hears a echo from the whistle. The engineer hears the echo of the whistle because of:

(A) reflection
(B) refraction
(C) constructive interference
(D) destructive interference

6) A skier plans to ski a smooth fixed hemisphere of radius R. He starts from rest from a curved
smooth surface of height (R/5). The angle θ at which he leaves the hemisphere is:

(A)

(B)

(C)

(D)

7) Three bugs A, B and C of masses 3g, 5g and 2 g respectively are moving on a horizontal carboard
placed on smooth table. Bug A is moving with an acceleration of 1 cm/s2 in East direction, while bug
C is moving with an acceleration of 2 cm/s2 in North direction. Bug B is moving such that the

cardboard remains stationary. Mark the correct option.

(A) The bug B remains stationary
(B) The bug B moves with an acceleration 2.5 cm/s2 in a direction 53° South of West.
(C) The bug B moves with an acceleration 1 cm/s2 in a direction 53° South of West.
(D) The bug B moves with an acceleration 1 cm/s2 in South-West direction.

8) As shown in figure, a rod of mass ‘m’ and length ‘R’ fixed on ring of same mass and radius R. The
system is placed on perfectly rough surface and is gently displaced so that ring rotates. Find out the

velocity of center of ring when rod becomes horizontal.

(A)

(B)

(C)

(D)

9) Estimate the minimum frequency of a γ-ray that causes a deuteron to disintegrate into a proton
and a neutron. The masses of the particles are md = 2.0141 mu,
mp = 1.0078 mu,
mn = 1.0087 mu

(A) 5.4 × 1020 Hz

(B) 6.9 × 1011 Hz
(C) 6.2 × 106 Hz
(D) 7.3 × 1014 Hz

10) In a water supply system, horizontal nozzles are attached to the main supply pipe at regular
interval of 10m. Each nozzle discharges water horizontally at the rate of 2 kg/s with velocity 5 m/s.
An empty tank of mass 100 kg and length 20m is placed over smooth horizontal rails below the
supply line initially at the rest. Find the velocity of the tank (in m/s) after 100sec. Ignore vertical gap
between the tank and water supply line. Water started moving with the tank as it falls in it.

(A) 2
(B) 4
(C) 6
(D) 8
11) A solid disk of mass M and radius R is pivoted about a horizontal axis through a point A on its
rim as shown in the figure. It is released from rest in the shown position. What is the magnitude of

the acceleration of point B when AB make an angle of 37° with the horizontal?

(A)

(B)

(C) g

(D)

12) A sample of radioactive material can decay by two processes A and B with half-lives hour and
hour respectively. Now, the radioactive sample decays for 7 hour in such a way that for 1 hour it
decays according to process A and for next hour decays according to B and this decaying with
different processes in alternate hours continues upto 6 hour and then, in 7th hour, it decays
simultaneously with both the processes. If N0 nuclei of sample are present at t = 0, then number of
radioactive nuclei after 7 hour would be

(A)

(B)

(C)

(D)

13) 24 identical cells, each of internal resistance 0.5 Ω, are arranged in a parallel combination of n
rows, each row containing m cells in series. The combination is connected across a resistor of 3Ω. In
order to send maximum current through the resistor, we should have

(A) m = 12, n = 2
(B) m = 8, n = 3
(C) m = 2, n = 12
(D) m = 3, n = 8

14) In the given circuit, the rms value of current drawn from the source
(A) 20 A
(B) 10 A
(C) 5 A
(D)

15) The value of net resistance of the network as shown in the given figure is :

(A)

(B)

(C) 6 Ω

(D)

16) Two loudspeakers L1 and L2 driven by a common oscillator and amplifier, are arranged as shown.
The frequency of the oscillator is gradually increased from zero and the detector at D records a
series of maxima and minima. If the speed of sound is 330 ms–1, then the frequency at which the first

maximum is observed is

(A) 165 Hz
(B) 330 Hz
(C) 495 Hz
(D) 660 Hz
17)
Using the given P-V diagram, the work done by an ideal gas along the path ABCD is-

(A) 4 P0V0
(B) 3 P0V0
(C) –4 P0V0
(D) – 3 P0V0

18) The work done in increasing the side length of square from a to 2a uniformly, as shown in figure.

(A)

(B)

(C)

(D)

19) To get output Y = 1 from circuit of figure, the inputs must be

A B C

(A) 0 1 0

(B) 1 0 0

(C) 1 0 1

(D) 1 1 0
(A) A
(B) B
(C) C
(D) D

20) The diagram shows part of a magnetic relay, M is part of the core of the magnet L is part of the
armature which is attached to the core when a current flows through the coil. S is a stud which stops
the armature being attracted too strongly. Which line of the table gives the best materials for M, L

and S ?

M L S

(A) Iron Iron Iron

(B) Iron Iron Copper

(C) Iron Copper Copper

(D) Copper Copper Copper

(A) A
(B) B
(C) C
(D) D

SECTION-II

1) A ball is projected vertically upwards with a velocity 40 m/s returns back on the ground with
velocity 30 m/s. If the air resistance is proportional to the speed of the ball. The airtime of the ball
(in sec) is. Acceleration of free fall is 10 m/s2.

2) A body of mass 400 kg is suspended at the lower end of a light vertical chain and is being pulled
up vertically (see figure). Initially the body is at rest and the pull on the chain is 6000g N. The pull
gets smaller uniformly at the rate of 360g N per each meter through which the body is raised. What
is the speed (in m/s) of the body when it has been raised 5m ?

3) A container has water filled upto a height 7 m. A pressure guage at the bottom of the container
measures the pressure as 150kPa. The net hydrostatic force (in kN) on the conical surface ABC as

shown in the diagram.

4) In the circuit shown the capacitors are initially uncharged. In a certain time the capacitor of
capacitance 2 µF gets a charge of 20 µC. In that time interval find the heat produced in 3Ω

resistance in micro joule.

5) Two men A and B of mass M and 2M are standing 120° apart on a circular platform of mass 4M
and radius R. Now men interchange their position with respect to disc by walking along periphery

only. If Δθ represents magnitude of angle rotated by platform with respect to ground. Find
(Platform is free to rotate about its centre, while men are standing at periphery)

PART-2 : CHEMISTRY

SECTION-I
1) As2S3 H3AsO4 + H2SO4
50% of the electrons released by 5 mole of As2S3 is used to reduce 35 moles of ions of element A as :
A+x → A–x. Find value of 'x' ?

(A) 1
(B) –1
(C) 2
(D) –2

2) In 90 g of water, 2 moles of non-volatile solute B is added which slowly trimerises into an

insoluble solid B3. This trimerisation process has rate constant k = 6.93 × 10–2 min–1. Find vapour
pressure of solution after 10 min of addition of solute 'B'. (V.P. of H2O at 25°C = 60 mm Hg)

(A) 55 mm Hg
(B) 45 mm Hg
(C) 50 mm Hg
(D) 52.5 mm Hg

3) Consider the following equilibrium at 25°C

CuSO4·5H2O(s) ⇌ CuSO4·3H2O(s) + 2H2O(g)
If this reaction takes place at two cities A and B having relative humidity 60% and 80% respectively.
The vapour pressure of water at 25°C is 20 mm Hg and KP for the above reaction is 4 × 10–2 (atm)2 at
25°C then CuSO4· 5H2O acts as efflorescent in which city?

(A) At A only
(B) At B only
(C) At both A and B
(D) Neither at A nor at B

4) Which of the following ligand can exhibit linkage isomerism when present in complex compound.
(I) SO4–2 (II) PO4–3 (III) SO3–2
(IV) CO3–2 (V) CN– (VI) SCN–
(VII) C2O4–2

(A) I, II, V, VI
(B) V, VI
(C) III, V, VI
(D) V, VI, VII

5) V2O5 reacts with alkalies to give

(A)
(B)
(C)
(D)
6)
The products of the reaction are -

(A)

(B)

(C)

(D)

7) Consider the reaction, N2(g) + 3H2(g) ⇌ 2NH3(g). The equilibrium constant of the above reaction
is KP. If pure ammonia is left to dissociate, the partial pressure of ammonia at equilibrium is given by
(Assume that at equilibrium)

(A)

(B)

(C)

(D)

8) At total pressure P1 atm and P2 atm, N2O4 is dissociated to an extent of 33.33% and 50.00%,
respectively. The ratio of pressures P1 and P2 is

(A) 3:8
(B) 2:1
(C) 8:3
(D) 1:2

9) 10 mole of SO3 was placed in a 4 litre vessel at a fixed temperature. The following equilibrium was
established in the vessel. 2SO3(g) ⇌ 2SO2(g) + O2(g) The equilibrium mixture completely reacted
with 2 mole of K2Cr2O7 in acidic medium. Then value of KC for the reaction is (Given : SO2 + K2Cr2O7
SO3 + Cr3+) :-
(A) 16.501 mol/L
(B) 1.6875 mol/L
(C) 1.8875 mol/L
(D) 2.8875 mol/L

10)

The ratio
Then calculate the value of IP1 and IP2 respectively
if

(A)

(B)

(C)

(D)

11) The ground state electronic configurations of the elements, U, V, W, X, and Y (these symbols do
not have any chemical significance) are as follows :
U 1s2 2s2 2p3
V 1s2 2s2 2p6 3s1
W 1s2 2s2 2p6 3s2 3p2
X 1s2 2s2 2p6 3s2 3p6 3d5 4s2
Y 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6
Among these only, determine which sequence of elements satisfy the following statements :
(i) Element with highest IE2 value.
(ii) Element with maximum paramagnetism.
(iii) Element has largest atomic radius.
(iv) Element forms only acidic oxide.

(A) VWYU
(B) VXYW
(C) UWYX
(D) VXWU

12) Which of the following represent Z-isomer ?

(A)
(B)

(C)

(D)

13) Total geometrical isomers possible for :

(A) 3
(B) 4
(C) 5
(D) 8

14) A compound with molecular formula C7H7Cl ,shows how many benzenoid aromatic isomers ?

(A) 4
(B) 3
(C) 5
(D) 6

15) The thermal decomposition of azoisopropane to hexane and nitrogen follows first order kinetics.
(CH3)2CH – N = N – CH(CH3)2(g) —→ N2(g) + C6H14(g)
If P1 is the initial pressure of the reactant and P is the total pressure after time (t). The correct
expression for the rate constant in terms of P1 and P is

(A)

(B)

(C)

(D)
16) For the reaction A(g) ⇌ B(g) at 495 K, ΔrGo = –9.478 kJ mol–1.
If we start the reaction in a closed container at 495 K with 22 millimoles of A, the amount of B is the
equilibrium mixture is _______ millimoles. (Round off to the Nearest Integer). [R = 8.314 J mol–1K–1;
ℓn 10 = 2.303]

(A) 20
(B) 40
(C) 60
(D) 80

17) For the given first order reaction

A→B
the half life of the reaction is 0.3010 min. The ratio of the initial concentration of reactant to the
concentration of reactant at time 2.0 min will be equal to ___(Nearest integer)

(A) 200
(B) 100
(C) 300
(D) 400

18) The conductance of 0.0015M aqueous solution of a weak monobasic acid was determined by
using a conductivity cell consisting of platinised Pt electrodes. The distance between the electrodes
is 120 cm with an area of cross section of 1cm2. The conductance was found to be 5 × 10–7S. The pH
of the solution is 4. The value of limiting molar conductivity of this weak monobasic acid in aq.
solution is :-

(A) 600 S cm2 mol–1

(B) 400 S cm2 mol–1
(C) 300 S cm2 mol–1
(D) 500 S cm2 mol–1

19) Which order is correct in spectrochemical series of ligands?

(A)
(B)
(C)
(D)

20) The correct combination of the main forces which stabilize the 2° and 3° structures of proteins
is:

(A) Covalent bond, electrovalent bond, hydrogen bond, peptide linkages.

(B) Hydrogen bond, electrovalent bond, van der Waal's forces, peptide linkages
(C) Hydrogen bond, disulphide linkages, Van der Waal's forces, electrostatic forces of attraction
(D) Peptide linkages, disulphide linkages, Van der Waal's forces, electrostatic forces of attraction.
 SECTION-II

1)

From the above data, calculate molar enthalpy of sublimation of H3BO3 at 300 K (in kJ/mole).

2) The standard reduction potential for Cu+2/Cu electrode is 0.34 V. The solubility product of
Cu(OH)2 is 1.0 × 10–19. The pH of solution at which the reduction potential for the electrode becomes

0.31 V if Cu+2 concentration is maintained by Cu(OH)2 salt ?

3) How many of the following relations is/are correct?

(a) Mg > Al (electropositive character)
(b) Al > Ga (electronegativity)
(c) N+ > N (ionization energy)
(d) Se > S (magnitude of ΔHeg)
(e) He+ > H (size)
(f) (paramagnetic nature)
(g) C2 > N2 (Number of π bonds)
(h) F2 > B2 (bond order)
(i) B2 > F2 (bond length)
(j) (bond angle)
If total correct options are "A" then write your answer as "A × 100"

4) Number of possible product formed (Including stereoisomers)

5)
[R = C(n–2)H2n–3]
If number of hydrogens in the product is 24. The value of ‘n’ is :

PART-3 : MATHEMATICS

SECTION-I
1) Let .
Then the number of elements in the set

is

(A) 3
(B) 4
(C) 5
(D) None of these

2) If α and β are the roots of equation

then the equation whose roots are and is

(A) x2 – 5x – 3 = 0
(B) 3x2 + 5x – 1 = 0
(C) 3x2 – 10x + 2 = 0
(D) x2 – 10x – 6 = 0

3) The exhaustive set of values of parameters m for which function

f(x) = 9x3 + 9 (m – 1)x2 + 3(m + 5) x + 7 is increasing for is than value of 6k2 is

(A) 4
(B) 3
(C) 6
(D) None of these

4) A circle C1 passes through the origin O and has diameter 4 on the positive x-axis. The line y = 2x
gives a chord OA of a circle C1. Let C2 be the circle with OA as a diameter. If the tangent to C2 at the
point A meets the x-axis at P and y-axis at Q, then AP : PQ is equal to

(A) 1 : 5
(B) 2 : 5
(C) 4 : 5
(D) None of these

5) Let the function f(x) = 2x2 – logex, x > 0, be decreasing in (0, a) and increasing in (a, 4). A tangent
to the parabola y2 = 4ax at a point P on it passes through the point (8a, 8a – 1) but doesn't pass

through the point . If the normal at P meets the curve again at Q, then slope of tangent at Q
is

(A) – 9/2
(B) – 2/9
(C) 2/9
(D) None of these

6) If and then the value of is

(A)
(B)
(C)
(D)

7) If exists and is equal to 1, then the value of is

(A)

(B) 6
(C) 3
(D) None of these

8) Let f and g be differentiable function satisfying g' (a) = 2, g(a) = b and fog = I (where I is Identity
function). Then f '(b) is equal to

(A) 1/2
(B) 2
(C) 2/3
(D) None of these

9) Let the unit vectors be the position vectors of the vertices of a triangle ABC. If is the
position vector of the mid point of the line segment joining its orthocentre and centroid then

(A) 1
(B) 2
(C) 3
(D) None of these

10) A box contains 12 mangoes out of which 5 are rotten and rest are good. Two mangoes are
randomly taken out together. If it is known that atleast one of them is good, then the probability that
both are good is :

(A)

(B)
(C)

(D) None of these

11) Let v and w be distinct, randomly chosen roots (real or complex) of the equation
z9 – 1 = 0. The probability that

(A)

(B)

(C)

(D) None of these

12) Calculate the standard deviation for the following :

Size of Team : 6 7 8 9 10 11 12
Frequency : 3 6 9 13 8 5 4
(A) 1.607
(B) 4.507
(C) 7.709
(D) 2.335

13) The direction cosines ℓ, m, n of two lines are given by pℓ + qm + rn = 0 and aℓ2 + bm2 + cn2 = 0
where p, q, r, a, b, c, are arbitrary constants. If these two lines are parallel then

(A)

(B)

(C)

(D)

14) For the hyperbolas and their eccentricities are x and f(x) then

is

(A) 4
(B)
(C) 6
(D) 8
15) Four Ellipse E1, E2, E3, E4 are drawn such that En touch En–1 at end points of its major axis and En

has focii at end points of minor axis of En–1 where n ∈ {2, 3, 4}. If eccentricity of E1 is then
eccentricity of E4 is

(A)

(B)

(C)

(D)

16) The smaller area bounded by the circle

x2 + y2 = 2 and y = f(x) above X-axis where f(x) is a polynomial of least degree satisfying

is

(A)

(B)

(C)

(D)

17) are in H.P. α, γ are roots of

and β, δ are roots of
then product of slopes of normals drawn to hyperbola xy = c2 at

is

(A) 243
(B) 625
(C) 576
(D) None of these

18) A tangent drawn to the curve y = f(x) at

p(x, y) cuts x axis and y axis at A and B respectively such that BP : AP = 2 : 1, given that f(1) = 1.
(A)
Equation of curve is

(B)
Equation of curve is
(C) Curve passes through (2, 2)
(D) Normal at (1, 1) is 2y = x + 1

19) If the roots of equation

x3 – 12x2 + kx – 28 = 0 are in A.P. then value of k is

(A) 13
(B) 39
(C) 4
(D) None of these

20) Number of ways N = 68600 can be expressed as product of 3 distinct co-prime integers is:

(A) 3
(B) 4
(C) 5
(D) None of these

SECTION-II

1) 2(cosx + cos2x) + (1 + 2cosx) sin2x = 2sinx

Total no. of solutions in [–π, π] is

2) p(x) is a cubic polynomial satisfying p(–1) = 10 and p(1) = 6, p(x) maximised at x = –1 and p'(x)
minimum at x = 1, then |10p(3)| is

3) (t – 1) x + (3t + 1) y + 2tz = 0
(t – 1) x + (4t – 2) y + (t + 3) z = 0
2x + (3t + 1) y + 3 (t – 1) z = 0
has non trivial for t1 and t2 and in this context ratio of x : y : z = a : b : c, when t has the smallest
value, then a + b + c + (sum of all the different value of t) is

4) A and B are 2 × 2 matrices with tr(A) = tr(B) and det(A – B) ≠ 0, where tr(A) denotes trace of
matrix A. Then the absolute value of is

5) The number of natural numbers n such that the highest power of 6 in n! is 117, is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C A C C A C C D A B B B A C C B D C C B

SECTION-II

Q. 21 22 23 24 25
A. 7 34 293 50 5

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A C A C A A B C B C B B C A A A B A A C

SECTION-II

Q. 46 47 48 49 50
A. 25 5 400 18 12

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C B C C B B B A C B D A C C D B C D B B

SECTION-II

Q. 71 72 73 74 75
A. 5 20 6 2 0
 SOLUTIONS

PART-1 : PHYSICS

1)
The block will start slipping if fAB = fℓ.
fℓ = µN = µ[mg – F sin30°]
Also, F + Fcos30° = (m + M)a .... (i) &

... (ii)
From (i) & (ii)

Now Fapplied = = 1.2845 N

∴ Both will move together.

= 0.2179 m/s2
∴ f = 2.18 N

2) The given system will be equivalent to

Given,

∴ Power of the system

=

3)

∴ Current induced

∴ Induced current

= 5.024 × 10–11A

4)
Maximum path difference = 4λ
Minimum path difference = 0
∴ No. of minimum = 8
(4 on each side of origin)

5) Echo is phenomenon of reflection of sound.

7) Since cardboard has to remain stationary

∴ fnet on cardboard = 0
 at 53° South of West.

8) Using work-energy theorem,

9) Δm = (1.0087 + 1.0078 – 2.0141) = 0.0024mu.

∴ Energy required = 0.0024 × 931.5 MeV = 2.2344MeV.

= 0.54 × 1021 Hz = 5.4 × 1020 Hz

10) Total momentum (horizontal) of the water filled inside the tank till time t.
P = 2λtv0
Using linear momentum conservation

11) From work energy theorem,

Also, from torque equation,

12)
Now, at t = 0, no. of nuclei = N0

t = 1hr, no. of nuclei =

t = 2hr, no. of nuclei =

t = 3hr, no. of nuclei =

t = 4hr, no. of nuclei =

t = 5hr, no. of nuclei =

t = 6hr, no. of nuclei =

t = 7hr, no. of nuclei =

13) We have,
Eeq = mε

∴ Current =
Given mn = 24

For maximum current, n = 2

∴ m = 12, n = 2

14) All three are in parallel.

≡
∴ Net current =
∴ irms = 5
15)
Diode 2 is in reverse bias
So current will not flow in branch of 2nd diode, So we can assume it to be broken wire.
Diode 1 is in forward bias
So it will behave like conducting wire. So new circuit will be

Correct answer (C)

16) Path diff

∴ For maxima, Δx = nλ.
∴ For 1st maxima, n = 1

∴ Δx = λ ⇒

17)

18)
19) Given circuit is
(A + B)·C = Y
∴ For Y to be 1, C must be 1 & either or both of A & B must be 1.

20) From the given information,

M & L must be ferromagnet while S must be diamagnet.

21)

Fair = kv

22) Fnet = T – mg

T = (6000 g – 360g y)

v2 = 1175
v = 34.27

23)
24) The capacitors 2µF and 1µF are in parallel combination.
So, let 1µF get a charge q1 and 2µF get a charge of q2.
q1 : q2 = C1 : C2
=1:2
So, given q2 = 20 µJ
So, q1 = 10 µJ

So, energy stored in

and energy stored in

So, total energy stored in capacitor
= 100 + 50 = 150 µJ
Now, if we calculate energy dissipated in resistors from the formulation

It will be same as Estored in capacitor

So, HTotal = 150 µJ

Now,
Energy dissipated in the branch of 3Ω & 6Ω will be 75 µJ

H1 : H2 = 6 : 3 = 2 : 1

So,
 25)
τ0 on the system = 0
Let disc rotate by angle θ
Case I for θ to be minimum,

Use II : for θ to be maximum,

PART-2 : CHEMISTRY

26)
no of moles of eletron lost by 1 mole of As2S3 = 2 × 2 + 3 × 8 = 28
Electron lost by 5 mole = 28 × 5 = 140
50 % electron = 70 mole
Now,
Cange in oxidation number = 2x
Now 35 × 2x = 70
x=1

27) Half-life for trimerisation process

No of moles of B undergoes trimerisation

=
Now,

mm Hg

28)
= 760 × 2 × 10–2
= 15.20 atm
City A having relative humidity = 60%

aquous tension = 12 mm Hg

City B the aqueous tension =

= 16 mm Hg

29) exhibit linkage isomers

30)

32)

N2(g) + 3H2(g) ⇌ 2NH3(g) KP

But question is about diosociation NH3, so we have to reverse the reaction.

2NH3(g) ⇌ N2(g) + 3H2(g)

t=0 a atm

t=teq

Ptotal = P =

As ,
P = 2x

Writing equilibrium constant for the reaction

33)

N2O4 ⇌ 2NO2 PT = P0(1 + α)

t = 0 P0

0 0 0
t=t P (1–α) 2P α P =

0
KP = 4P

34)

2SO3(g) 2SO2 + O2(g)

SO2 + K2Cr2O7 SO3 + Cr3+
neq of SO2 = neq of K2Cr2O7
2×

2SO3(g) 2SO2 + O2(g)

10 mol
10 – x x x/2

At eqm, 4mol 6mol 3mol

KC = 1.6875 mol/L

35)

IP1 + IP2 + x = 5x

36)

(i) Alkali cation has highest IE2 in a given period.

(ii) Transition having unpaired d-electrons.
(iii) In case of Kr van der Waal’s radius is considered, which is largest atomic radius →Y
(iv) Si atom has only acid SiO2 →W
37) (A)
Same no. ⇒ opposite side ⇒ E

(B)
Same No. ⇒ same side ⇒ Z

(C) (E)

(D) (E)

38)

Total G.I. Ans. (5)

39) C7H7 – Cl

where m ⇒ no. of mono valent atoms

t ⇒ no. of trivalent atoms
=

=
Benzoidal isomers

40)

P1 - -
Pi-x x x
P = Pi - x + x + x = Pi + x x = P - Pi

41) ΔG° = –RT ℓn Keq

Given ΔG° = –9.478 KJ/mole
T = 495K R = 8.314 J mol–1
So –9.478 × 103 = –495 × 8.314 × ℓn Keq
ℓn Keq = 2.303
= ℓn 10
So Keq = 10
Now A(g) ⇌ B(g)
t = 0 22 0
t = t 22–x x

Keq =
or x = 20
So millimoles of B = 20

42)
 43)

Scm–1

= 600 S cm2 mol–1.

44) Weak field ligand

< F– < OH– < ox2– < O2– < H2O

Strong field ligands
NCS– < Edta4– < py ≈ NH3 < en
< dipy < o – phen < < CN– < CO
For d4 ions, two possible patterns of electron

45) NCERT Page

46)

Molar heat of sublimation = KJ/mole

48) (a), (c), (f), (i) are correct.

49)

PART-3 : MATHEMATICS
51)

No. of solution is is 5.

52)

and

Let

53) f(x) = 9x3 + 9(m – 1)x2 + (m + 5) x + 7

f'(x) = 27x2 + 18 (m – 1) x + 3 (m + 5)
f'(x) = 3 [9x2 + 6(m – 1)x + (m + 5)]

(1)

… (i)
(2)

..... (ii)
From (i) and (ii),
 k = 1, 6k2 = 6
Ans. 6

54) C1 : (x – 2)2 + y2 = 22

C2 is a circle with OA as diameter.

∴ tangent at A is perpendicular to OA
let OA = ℓ
∴ QA = ℓ cot q
PA = ℓ tan q

Hence, .

55) f(x) = 2x2 – ℓnx

∴ Parabola is y2 = 2x
Now, any point on parabola be P(x1, y1)
 rejected.

Let

∵ Normal at P(t1) meets the parabola again at Q(t2).

∴ Slope of tangent at

56)

57)

For limit to exist 2 – n = 0

58)
Putting x = a, we get
59) Let the circumcentre of the triangle be the origin.

and the centroid is .

60) Required probability

61) Consider unit circle |z| = 1 with a regular polygon of 9 vertices inscribed in it with one of

the vertices as 1. 'v' and 'w are any two distinct vertices such that

This implies that

Thus, the total number of pairs v and w can be

62)

63) Eliminate n form given equations

The lines are parallels then DCs are equal then roots are equal
B2 – 4AC = 0
⇒ [2cpq]2 = 4(ar2 + cp2)(br2 + cq2)
⇒ abr2 + acq2 + bcp2 = 0

64)
65)

66) exists so

For least degree

So we have y = x4 x2 + y2 = 2

67)
are in H.P.
 root of t1x2 – 4x + 1 = 0 ⇒ t1 = 3

root of t2x2 – 6x + 1 = 0 ⇒ t2 = 8

Normal to xy = c2 at is
xt3 – yt – ct4 + c = 0
Slope = t2
So product of slopes

68)
Let A (h, 0) and B (0,K)
Using section formula

(1)

(2)

Slope of tangent

Solving different equation

Normal (1, 1) is

69) Let a – d, a, a + d are 3 roots of equation

Sum of root = (a – d) + a + ( a + d) = 12
3a = 12
a=4
Product of roots : a(a – d) (a + d) = 28
a (a2 – d2) = 28
a = 4 put in equation ∴ k = 39

70) N = 68600 = 23 × 52 × 73

71) Given : 2cosx + 2cos2x + sin2x + 2cosx sin2x = 2sinx

= 2cosx + 2cos 2x + 2sinx cosx + (sin3x – sinx) = 0
= 2 cos x + 2 cos2x + 2sinx cosx + 2cos2x sinx = 0
= 2 cosx (1 + sinx) + 2 cos 2x (1 + sinx) = 0
(1 + sinx) (2 cosx + 2 cos2x) = 0
2 (1 + sinx) (cosx + cos2x) = 0

are solution in [–π, π]

All solutions =
5 solutions.

72)
p(x) → cubic
p'(x) → quadratic
p'(x) min at x = 1
⇒ p''(x) = 0 at x = 1
p''(x) = λ(x – 1)

p'(x) = λ( – x) + c
p'(–1)= 0 as p(x) take maximum at x = –1

p'(x) = λ( –x– )

On solving
|10p(3)| = 20

73) Given system of eq. have non-zero solution.

D=0
 = D = 6t (t – 3)2
t = 0 and t = 3
Smallest value of t = 0
–x+y=0 ... (i)
– x – 2y + 3z = 0 ... (ii)
2x + y – 3z = 0 ... (iii)
From eq. (1) : –x + y = 0
x=y
Put these x = y in eq. (ii)
– x + 2y + 3z = 0
–3x + 3z = 0
x=z
we can say
x=y=z
Put in eq. (iii) and check
3x – 3z = 0 satisfies
x:y:z=1:1:1
a=1=b=c
a+b+c=3
Sum of all diff. value of t = 0 + 3 = 3
Ans. 3 + 3 = 6

74) Let A – B = C ⇒ tr(C) = 0

Characteristic equation of matrix C is

∴ C2 – (tr(C))C + |C| I = 0
⇒ tr(C2) – (tr(C))2 + |C| × 2 = 0

75) Let x be the highest power of 3 in n!.

Now x = 117

For n = 237,

∴ When n = 240 highest power of 3 will be 116 for n = 241, n = 242 this will remain same but
when n = 243, highest power will be 121.
∴ There does not exist any n.