0% found this document useful (0 votes)
35 views10 pages

Classification of Elements and Periodicity in Properties: Educhem DPP

The document contains a series of objective-type questions related to the classification of elements and periodicity in properties, covering topics such as ionization energy, electron gain enthalpy, and the properties of various elements. It includes multiple-choice questions with options for answers, focusing on trends in the periodic table and the behavior of elements. The questions are designed for educational purposes, likely for students studying chemistry.

Uploaded by

Rakhit Mahato
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
35 views10 pages

Classification of Elements and Periodicity in Properties: Educhem DPP

The document contains a series of objective-type questions related to the classification of elements and periodicity in properties, covering topics such as ionization energy, electron gain enthalpy, and the properties of various elements. It includes multiple-choice questions with options for answers, focusing on trends in the periodic table and the behavior of elements. The questions are designed for educational purposes, likely for students studying chemistry.

Uploaded by

Rakhit Mahato
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 10

EDUCHEM DPP

Classification of Elements and Periodicity in


Properties

(1) Na < Mg < Al < Si (2) Mg < Na < Al < Si


SECTION - A
(3) Mg < Al < Na < Si (4) Mg < Si < Al < Na
Objective Type Questions
8. The correct order of ionisation potential of Na, P, Cl
1. If a graph is plotted between  versus atomic is
number (Z), then ( is the frequency of X-rays
(1) Na > P > Cl (2) P > Cl > Na
emitted)
(3) Cl > P > Na (4) Cl > Na > P
(1) Straight line is obtained
9. The correct order of second ionisation energy for
(2) Parabola is obtained
the elements C, N, O and F would be
(3) Hyperbola is obtained
(1) O > F > N > C (2) O > N > F > C
w

(4) Curve is obtained


w

(3) C > N > O > F (4) F > O > N > C


w
.ed

2. Which of the following will have highest negative 10. Select the correct statement
uc

electron gain enthalpy?


he

(1) All isoelectronic ions belong to same period of


m

(1) Oxygen (2) Sulphur


.in

the periodic table


(3) Selenium (4) Tellurium (2) Negative electron gain enthalpy decreases from
3. Which of the following ions have pseudo inert gas fluorine to iodine in the group
electronic configuration? (3) The first ionisation potential of Al is less than
(1) Cu+ (2) Fe2+ the first ionisation potential of Mg

(3) O2– (4) Cu2+ (4) All of these

4. Beryllium is diagonally related to 11. Which is correct?

(1) Li (2) Al (1) Ti < Zr < Hf (Radii)

(3) B (4) Si (2) Cu1+ > Cu2+ (Stability in aqueous solution)

5. Element having the smallest size in second period (3) S > Se > Te > Po > O (Electron affinity)
is (4) All of these
(1) Ne (2) F 12. Element with atomic number 102 is placed in
(3) O (4) N (1) s-block (2) p-block
6. Element Uup is placed in group and (3) d-block (4) f-block
block of periodic table. 13. The electron affinity values (in kJ/mol) of three
(1) 4th, d (2) 3rd, f halogens X, Y and Z are respectively –349, –333
and –325. Then, X, Y and Z are respectively
(3) 15th, p (4) 12th, d
(1) F, Cl and Br (2) Cl, F and Br
7. The correct increasing order of second ionisation
energy is (3) Cl, Br and F (4) Br, Cl and F
14. Select the incorrect statement 23. The element of atomic number 118 will be placed
(1) Bond energy of F2 > Cl2 in which of the following group of long form of
periodic table?
(2) Electronegativity of F > Cl
(1) 15 (2) 16
(3) F is more oxidising than Cl
(3) 18 (4) 17
(4) Electron affinity of Cl > F
15. If the electronic configuration of an element is [Ar] 24. CH4 NH3 H2 O HF
I II III IV
3d104s24p6 . The element belongs to
The correct increasing order of acidic nature is
(1) s-block (2) p-block
(1) I < II < III < IV (2) IV < III < II < I
(3) d-block (4) f-block
(3) III < I < II < IV (4) I < III < II < IV
16. In compound M–OH, the acidic nature increases
25. The highest third ionisation energy among the
when
following is
(1) I.E. of M is low
(1) Boron (2) Beryllium
(2) I.E. of M is very low
(3) Carbon (4) Nitrogen
(3) I.E. of M is high
26. There are 28 neutrons in the nucleus of the
(4) Acidic nature does not depend on I.E. of M element zM52. It belongs to
17. Which of the following is the most acidic oxide? (1) f-block (2) s-block
(1) NO (2) NO2 (3) p-block (4) d-block
(3) N2O3 (4) N2O5
27. Which of the following has no unpaired electrons?
18. Lowest ionisation enthalpy in the periodic table is
(1) Mg+2 (2) Fe+2
w

shown by
w
w

(3) Mn+2 (4) V+3


.ed

(1) Chalcogens (2) Halogens


uc

28. The pair of elements which are members of third


he

(3) Alkali metals (4) Alkaline earth metals


period
m
.in

19. Element of atomic number 117 is placed in


(1) Be, P (2) Si, Cl
(1) 16th group, 6th period (2) 17th group, 7th period
(3) N, O (4) F, Al
(3) 13th group, 6th period (4) 14th group, 7th period
29. Boron shows diagonal relationship with element
20. Which is exothermic reaction ? having atomic number
(1) Ca  Ca+2 (1) 15 (2) 13
(2) N2 –  N3 – (3) 14 (4) 12
(3) N2 + O2  2NO
30. Highest electron affinity will be of
(4) O  O –
(1) N (2) P
21. Ionisation energy of Be +3 ion is x kJ then
(3) O (4) S
ionisation energy of He+ ion would be
x 31. Eka-aluminium and eka-silicon in Mendeleev’s
x
(1) kJ (2) kJ periodic table respectively are
16 4
x (1) Ga, Ta (2) Ga, Sn
x
(3) kJ (4) kJ
2 8 (3) Ge, Ga (4) Ga, Ge
22. Which of the following statement is correct? 32. The correct order of radii is
(1) Zeff = Z –  (1) Na+ > F– > Al+3 > Mg+2
(2) Z = Zeff –  (2) N–3 < Na+ < Mg+2 < O–2
(3) = Zeff – Z – number of penultimate electrons (3) Al+3 < Mg+2 < O–2 < S–2
(4) Zeff = Z – + number of penultimate electrons (4) Mg+2 < N–3 < O–2 < F–
33. General electronic configuration of first inner 40. Which of the following statement is incorrect?
transition series is (1) The first ionization potential of Al is less than
(1) (n – 2) f 1–14 (n – 1) s2p2 ns2 the first ionization potential of Mg
(2) (n – 3) f 1 – 4 (n – 2) d 0–1(n – 1) s2 (2) The second ionization potential of Mg is greater
than the second ionization potential of Na
(3) (n – 2) f 1 – 14 (n – 1) d 2 ns2
(3) The first ionization potential of Na is less than
(4) (n – 2) f 1–14 (n – 1) d 0 – 1 ns2 the first ionization potential of Mg
34. Predict the atomic number of the element in the (4) The third ionization potential of Mg is greater
periodic table satisfying the outer shell electronic than the third ionization potential of Al
configuration, (n – 1)d 1ns2 for n = 4
41. Which of the following statements is incorrect?
(1) 39 (2) 57
(1) Van der Waal’s radius of iodine is more than
(3) 21 (4) 23 its covalent radius
35. Predict the block to which an element with Z = 90 (2) All isoelectronic ions belong to the same
belongs period of the periodic table
(1) s-block (2) p-block (3) IE1 of N is higher than that of O while IE2 of
O is higher than that of N
(3) d-block (4) f-block
(4) The electron affinity of N is zero
36. The first and the second ionization enthalpies
(in kJ mol–1) of a few elements are given below : 42. Which of the following elements with atomic
numbers 25, 30, 48 and 80 has the highest vapour
Element IE1 IE2
pressure at room temperature?
I 2372 5251 (1) Z = 30 (2) Z = 48
w

II 520 7300
w

(3) Z = 80 (4) Z = 25
w
.ed

III 900 1760 43. Among the following, the third ionization energy is
uc

maximum for
he

IV 1680 3380
m
.in

Which of the above elements is likely to be a (1) Aluminium (2) Boron


metal that forms a stable binary halide of the (3) Magnesium (4) Beryllium
formula AX2? 44. Which of the isoelectronic ions, K+, Ca2+, Cl– and
(1) I (2) II S2– has the lowest ionization energy?
(3) III (4) IV (1) K+

37. Which of the following elements has the most (2) Ca2+
negative electron gain enthalpy? (3) Cl–
(1) [Ne]3s23p3 (2) [Ne]3s23p4 (4) S2–
(3) [Ne]3s23p5 (4) [Ne]3s23p6 45. Which of the following is not correct?
38. Predict the formula of the stable binary compound (1) Number of s electrons in carbon is double that
that would be formed by the element M (Z = 114) of He
and fluorine (2) Number of paired electron is same in F – and
(1) MF (2) MF6 Ne

(3) MF3 (4) MF4 (3) Number of d electrons are same in Zn2+ and
Cu+ ion
39. The element with atomic number 57 belongs to
(4) Number of filled orbitals are same in F– and
(1) s-block Cl– ion
(2) p-block 46. Which of the following process is exothermic?
(3) d-block (1) K  K+ (2) Mg+  Mg2+
(4) f-block (3) O  O– (4) S–  S 2–
47. The process involving highest release of energy will 57. In which of the following processes, maximum
be energy is released?
(1) F(g) + e–  F– (2) Cl(g) + e–  Cl– (1) O(g) + e–  O– (g)
(3) O(g) + e–  O– (4) O(g) + 2e–  O2– (2) O–(g) + e–  O2–(g)
48. The correct order of first ionisation energies of (3) S(g) + e–  S–(g)
some elements is given in the order
(4) S–(g) + e–  S2–(g)
(1) B > C < N > O (2) B < C < N > O
58. The element of the fourth period of the periodic
(3) B < C < N < O (4) B > C < N < O table having maximum number of unpaired
49. The period and group of the element in modern electrons is
periodic table which is present in 5th period and (1) 26Fe (2) 24Cr
VI B group of Mendeleev’s periodic table will be
(3) 29Cu (4) 34Se
respectively
59. Which of the following is the strongest reducing
(1) 5 and 6 (2) 5 and 8
agent in aqueous solution?
(3) 4 and 6 (4) 6 and 8
(1) Na (2) Li
50. If there are three electrons present in each orbital
(3) K (4) Cs
and Bohr-Burry principle is not followed in filling of
electrons, the number of elements in 4th period of 60. Ionisation energy of F– is – 320 kJ/mol. The
modern periodic table will be electron affinity of fluorine would be
(1) 18 (2) 27 (1) – 320 kJ/mol (2) – 160 kJ/mol
(3) 32 (4) 48 (3) 320 kJ/mol (4) 160 kJ/mol
51. Which of the following ion has the most negative 61. Which of the following statement is not correct?
w

value of enthalpy of interaction with water?


w

(1) Among halogens, oxidising behaviour increases


w
.ed

(1) NH4+ (2) OH– down the group


uc
he

(3) H+ (4) F– (2) Among alkali metals, lithium is the strongest


m

reducing agent in aqueous medium


.in

52. The highest second ionisation energy among the


following is (3) Fluorine is the most electronegative element
(1) Nitrogen (2) Oxygen (4) Lithium is the hardest metal among alkali
(3) Lithium (4) Carbon metals

53. Element having symbol Unb belong to which period 62. The correct order of third ionization energies (IE3)
and group of periodic table respectively? of Na, Mg and Al is

(1) 7, 4 (2) 6, 6 (1) Mg > Na > Al (2) Al > Mg > Na

(3) 7, 3 (4) 6, 5 (3) Na > Mg > Al (4) Mg > Al > Na

54. Which of the following is correct electronic 63. The first element of rare earth metals is
configuration of Gd? (Atomic number = 64) (1) Cerium (2) Actinium
7
(1) [Xe]4f 5d 6s1 2 8
(2) [Xe]4f 6s 2 (3) Uranium (4) Lanthanum
64. Atomic radii of fluorine and oxygen in pm units are
(3) [Kr]4f 8 5s 2 (4) [Xe]6s 2 5d 8
respectively given by
55. The correct order of electron affinities is
(1) 72, 74 (2) 74, 72
(1) Cl > Si > Na > Ar (2) Si > Cl > Na > Ar
(3) 77, 77 (4) 88, 77
(3) Cl > Na > Si > Ar (4) Cl > Si > Ar > Na
65. In graph of atomic volume versus atomic weight,
56. Which of the following ions has the highest value the elements corresponding to peaks in the curve
of ionic radius? belong to
(1) Li+ (2) B3+ (1) Group –1 (2) Group –18
(3) O2– (4) F– (3) Group –4 (4) Group –14
66. If there are three possible values for spin quantum 73. The ionization enthalpies of lithium and sodium are
number, then how many total elements can be x kJ mol –1 and y kJ mol –1 respectively. Then
present in 3rd period of periodic table? energy required to convert all the atoms present in
(1) 12 (2) 8 7 mg of lithium (Li) vapours and 23 mg of sodium
(Na) vapours
(3) 6 (4) 10
(1) x J ; y J (2) x kJ ; y kJ
67. An atom of an element A has 2 electrons in its
outermost shell while one of the element B has x y x y
(3) J; J (4) J; J
6 electrons in its outermost shell. Then formula of 10 10 100 100
the compound formed by A and B is
74. Which of the following property increases for Na+,
(1) AB (2) A2B Mg2+, Al3+ respectively?
(3) A2B6 (4) A2B3 (I) Size
68. The ratio of cationic size to anionic size is (II) Hydration energy
minimum for the compound
(III) Polarising power
(1) LiF (2) LiI
(IV) Ionisation energy
(3) RbI (4) RbF
69. Which of the following statement is wrong? (1) (I), (II) (2) (I), (III)

(1) Neutron/proton ratio does not reflect the (3) (II), (III) (4) (II), (III), (IV)
periodicity in chemical properties of elements 75. Name of the tripositive ion which is represented by
(2) The I.E. of aluminium is greater than the given configuration 1s2 2s2 2p6 3s2 3p6 3d5
magnesium because penetrating effect of p (1) Fe3+ (2) Cr+3
orbital is greater than s orbital
(3) Co3+ (4) Ni3+
(3) The value of e– gain enthalpy for N is positive
w

76. The correct order of ionic size


w

(4) The order of I.E.2 of elements A B C and D


w

(1) N3– > Na+ > F– > O2– > Mg2+


.ed

with atomic numbers 6, 7, 8 and 9 respectively


uc

will be C > D > B > A (2) N3– > O2– > F– > Mg2+ > Na+
he
m

70. I.E. is the amount of energy required to remove an (3) N3– > O2– > F– > Na+ > Mg2+
.in

electron from an isolated gaseous atom to infinity.


Then which of following statement regarding I.E. is (4) F– > O2– > N3– > Na+ > Mg2+
incorrect? 77. The hydration energy of Mg2+ ion is larger than that
(1) I.E1 of O+ is greater than O of
(2) I.E1 of noble gas is very high due to large size (1) Al3+ (2) Mg3+
(3) The I.E. of P > S (3) Na3+ (4) Na+
(4) The process of ionisation is an endothermic 78. Highest and lowest possible oxidation states of Ti
reaction is
71. An element with atomic number 56 belongs to (1) +4, –4 (2) +4, +2
which period, block and group of the periodic table
respectively? (3) +4, 0 (4) +2, 0

(1) 6th period; d-block; 3rd group 79. Which of the following has highest 2nd ionization
energy?
(2) 7th period; d-block; 3rd group
(1) N (2) O
(3) 7th period; p-block; 2nd group
(4) 6th period; s-block; 2nd group (3) F (4) C

72. Which of the following electronic configuration is 80. Valence configuration and block number of element
correctly matched? with atomic number 89 is
(1) A(Z = 8) : 1s2 2s2 3s2 3p2 (1) [Rn]6d 17s2, d-block
(2) B2+(Z = 20) : 1s2 2s2 2p6 3s2 3p6 (2) [Rn]6f 17s 2, f-block
(3) C+(Z = 24) : 1s2 2s2 2p6 3s2 3p6 4s1 3d4 (3) [Rn]6d 2, d-block
(4) D2+(Z = 29) : 1s2 2s2 2p6 3s2 3p6 3d10 4s2 (4) [Rn]7s2, s-block
81. Which is true regarding Ionisation energy? (3) High charge/radius ratio
(1) I– <I (4) All of these
(2) Li < Li + 89. Which of the pair of oxides is neutral?
(3) IE1 of Mg < IE2 of Mg (1) CO & CO2 (2) SO3 & N2O
(4) All of these (3) NO & N2O (4) N2O & CO2
82. Maximum oxidation states of transition metal is 90. The non-transition metals exhibit variable valency
derived from due to
(1) ns electron (1) Unstable core configuration
(2) (n – 1) d electron (2) d – d transition
(3) (n + 1) d electron (3) Poor screening effect of d and f electrons
(4) [ns + (n – 1) d] electrons (4) Small size
83. Which of the following set of compounds are 91. The correct order of negative electron gain enthalpy
amphoteric in nature?
(1) O > S > Se > Te (2) S > O > Se > Te
(1) BeO, B2O3, B(OH)3 (2) BeO, Be(OH)2, Al2O3
(3) S > Se > Te > O (4) S > Se > O > Te
(3) Be(OH)2, NO2, SiO2 (4) Al2O3, MgO, SO3
92. Correct order of 2nd ionisation energy
84. The correct order of electronegativity of carbon atom (1) F > O > N > C (2) O > F > N > C
in C2H6, C2H2 and C2H4 is
(3) F > N > O > C (4) N > F > O > C
(1) C2H2 < C2H4 < C2H6 (2) C2H4 < C2H2 < C2H6
93. The one which is not incorrect statement?
(3) C2H6 < C2H4 < C2H2 (4) C2H6 < C2H2 < C2H4
(1) I.E2 of Na < I.E2 of Mg
w

85. The electronegativity of two atoms A and B are 3.0


w
w

and 1.0 respectively. The approximate percentage (2) CO2 is less acidic than CO
.ed

covalent nature of bond formed between A and B is


uc

(3) PCl5 has trigonal bipyramidal geometry


he
m

(1) 54% (2) 46% (4) All of these


.in

(3) 65% (4) 30% 94. Which of the following will have highest 2 nd
86. Among Be, F, C and N, the highest third ionisation ionization enthalpy, if the outermost electronic
energy is of configuration is given below?
(1) Be (2) F (1) 2p4 (2) 2s1
(3) C (4) N (3) 2p1 (4) 3p6
87. Which of the following statement is incorrect? 95. General electronic configuration of actinoids and its
period is
(1) Acidic nature of oxide of elements of third
period increases from left to right (1) (n  2)f1-14 (n  1)d0-1ns2 , n = 5 and 6 period
(2) Acidic nature of hydracids increases from top
to bottom in a group of periodic table (2) (n  2)f1-14 (n  1)d0-1ns2 , n = 6 and 6 period
(3) Acidic nature of hydracids of element from
carbon to fluorine increases. (3) (n  2)f1-14 (n  1)d0-1ns2 , n = 6 and 7 period
(4) For an atom van der Waal’s radius > covalent
radius > metallic radius (4) (n  2)f1-14 (n  1)d0-1ns2 , n = 7 and 7 period
88. The anomalous behaviour of the first member of 96. Correct order of electron affinity is shown by
each group of representative elements in periodic
(1) Cl > S > F > O
table is due to
(2) Cl > F > S > O
(1) High electronegativity
(3) F > Cl > O > S
(2) Non-availability of d-orbitals in their valence
shelll (4) F > O > Cl > S
97. The chemical formula of the most stable chloride 104. The smallest size among the following ions is
of the element M, will be given by which of the shown by
following, if the IUPAC name of M is ununquadium?
(1) N–3 (2) O–2
(1) MCl (2) MCl2 (3) Ca+2 (4) K+
(3) MCl3 (4) MCl4 105. The element with atomic number 89 belong to
98. Which of the following process is endothermic in (1) d-block, group-3, 7th period
nature?
(2) d-block, group-3, 6th period
A. Al+2  Al+3 B. Cl  Cl–
(3) f-block, group-3, 6th period
C. N  N–1 D. O–1  O–2
(4) f-block, group-3, 7th period
E. H  H+
106. When a graph is plotted between atomic volume vs
(1) A, E (2) A, D, E atomic mass, group-2 elements are present at
(3) A, C, D, E (4) A, B, C, D, E (1) Peak of the graph (2) Bottom of the graph
99. The maximum covalency and oxidation shown by (3) Ascending peak (4) Descending peak
nitrogen in compounds is respectively
107. The general electronic configuration of f-block
(1) 3, +3 (2) 5, +5 element can be given by
(3) 3, +5 (4) 4, +5 (1) (n – 2) f1–14 (n – 1) d1–10 ns2
100. Which of the following sets is mismatched (2) (n – 2) f1–14 (n – 1) d1–10 ns0–2
regarding the nature of oxides?
(3) (n – 2) f1–14 (n – 1) d0–1 ns2
(1) Neutral oxide - CO2, NO, N2O
(4) (n – 2) f1–14 (n – 1) d10 ns2
w

(2) Amphoteric oxide - BeO, As2O3


w

108. If ionization enthalpy of potassium is z kJ/mol.


w
.ed

(3) Acidic oxide - Cl2O7, SiO2 Then energy required in eV/mol to convert 3.9 gm
uc

of K to K+ is
he

(4) Basic oxide - BaO, Na2O


m

(1) z × 1.6 × 1017 (2) z / 1.6 × 10–17


.in

101. According to Moseley, in the characteristic X-ray


spectra, straight line is obtained when the graph is (3) z / 1.6 × 10–19 (4) z × 1.6 × 10–18
plotted between 109. In Mendeleev’s periodic table, in group-8 the
element placed in each row are
(1)  vs Z ( = frequency, Z = atomic number)
(1) Fe, Co, Ni (2) Ru, Rh, Pd
(2) v vs Z (v = velocity, Z = atomic number) (3) Os, Ir, Pt (4) All of these
(3) v vs A (v = velocity, A = atomic mass) 110. The IP1, IP2, IP3, IP4 and IP5 of an element are 7.1,
14.3, 34.5, 46.8, 162.2 eV respectively. The
(4)  vs Z ( = frequency, Z = atomic number) element is likely to be
102. Maximum number of elements that can be (1) Ca (2) Si
accommodated in the periodic table according to
the format of modern periodic table is (3) F (4) Na
111. The correct order of decreasing second I.E. of Ti,
(1) 108 (2) 118
V, Cr and Mn in kJ mol–1 is
(3) 120 (4) 150
(1) Mn > Cr > Ti > V (2) Ti > V > Cr > Mn
103. Which of the following statement is incorrect?
(3) Cr > Mn > V > Ti (4) V > Mn < Cr > Ti
(1) In a period noble gases has maximum radii
112. Electronegativity of the element (A) is E1 and I.P.
(2) Sucessive ionization enthalpy is always higher is E2. Hence EA will be
(3) Ionic radius of Na+ is larger than that of atomic (1) 2E1 – E2 (2) E1 – E2
radius of sodium
E1 + E2
(4) As, Sb, Te are semi-metals (3) E1 – 2E2 (4)
2
113. Select equations having exothermic step 121. The possible electronic configuration of the atom
– 2– having maximum difference in first and second
a. S (g)  S (g) ionisation energies is
b. Na (g)  Cl– (g)  NaCl(s) (1) 1s2 2s2 2p6 3s1 (2) 1s2 2s2 2p6 3s2

c. N(g)  N (g) (3) 1s2 2s2 2p1 (4) 1s2 2s2 2p6 3s2 3p3
d. Al2 (g)  Al3 (g) 122. Which of the following has highest I.E1?

S  rhombic   SO2


e. (1) Sb (2) Se
(3) As (4) Te
Choose the correct code.
123. Identify the electronic configuration of the most
(1) b & e (2) a, b & e
electropositive element
(3) c, d & e (4) b & c
(1) [Kr]5s1 (2) [Kr]5s2
114. Ionisation energy of Na atom will be numerically
(3) [Ar]4s1 (4) [Ar]4s2
equal to
124. The set of atomic numbers representing
(1) Electron gain enthalpy of Na+ ion
chalcogens is
(2) Electron gain enthalpy of Na atom
(1) 14, 32, 50 (2) 18, 36, 54
(3) Ionisation energy of Na– ion
(3) 12, 20, 38 (4) 16, 34, 52
(4) Both (1) & (2)
125. Which of the atom has lowest first ionization
115. Which of the following matching is irrelevant? energy?
(1) N > O < F (IE) (1) ns2np3 (2) ns2np4
(2) Cl2O7 > SO3 > P4O6 (acidity) (3) ns2np5 (4) ns2np6
w
w

126. An element (A) forms the oxide A2O5. (A) belongs


w

(3) NF3 > NH3 > H2O (dipole moment)


.ed

to
F– Cl– Br–
uc

(4) > > (basic nature)


he

(1) 13 group (2) 14 group


116. If the ionic radii of K+ and F– are nearly the same
m
.in

(i.e., 1.34 Å), then the atomic radii of K and F (3) 15 group (4) 18 group
respectively are 127. Identify the element which is a metalloid
(1) 1.34 Å, 1.34 Å (2) 0.67 Å, 1.99 Å (1) Cu (2) Al
(3) 1.99 Å, 0.67 Å (4) 1.99 Å, 1.34 Å (3) B (4) Co
117. Electronegativity on Pauling scale is based on 128. The maximum number of electrons which can be
(1) Bond length (2) Bond energy present in the outermost orbit of elements of third
period of the periodic table is
(3) Atomic radius (4) Covalent radius
(1) 7 (2) 8
118. Zinc, cadmium, mercury belong to which group of
periodic table? (3) 10 (4) 18

(1) 10 (2) 11 129. In third period, the most basic oxide is formed by

(3) 12 (4) 13 (1) S (2) P

119. The ionisation energy will be maximum for the (3) Na (4) Mg
process 130. Which pair of elements is chemically similar?
(1) Ba  Ba2+ (2) Be  Be2+ (1) Li, Mg (2) Be, Al
(3) Cs  Cs+ (4) Li  Li+ (3) B, Si (4) All of these
120. Which one of the following pairs of elements has 131. Among the following elements, least electronegative
same number of electrons in their outermost shell? is
(1) Al, Tl (2) Si, Pb (1) O (2) F
(3) As, Bi (4) All of these (3) Cl (4) S
132. The formula of the compound formed by X:[Ne] 3s2, 142. If one orbital can accommodate three electrons then
3p1 and Y:[He] 2s22p5 is the number of elements in third period of periodic table
is
(1) XY2 (2) XY3
(1) 8 (2) 16
(3) X2Y (4) XY
(3) 12 (4) 18
133. The maximum tendency to form a tripositive ion lies
with the element having the electronic configuration 143. The expected atomic number of seventh noble gas
would be
(1) [Ne]3s2 , 3p2 (2) [He]2s2, 2p2
(1) 110 (2) 114
(3) [Ne]3s2, 3p1 (4) [Ne]3s2, 3p6
(3) 118 (4) 122
134. As compared to alkaline earth metals, alkali
144. The correct statement is
metals exhibit
(1) Acidic nature of oxides increases from left to
(1) Higher valency right in a period of periodic table
(2) Higher reducing power (2) Acidic nature of hydracids increases from left
(3) Greater hardness to right in a period of periodic table
(4) All of these (3) Acidic nature of hydracids increases from top
to bottom in a group of periodic table
135. Which pair of elements belongs to same group?
(4) All of these
(1) Element with atomic number 38 and 55
145. Representative elements belong to
(2) Element with atomic number 29 and 46
(1) s-Block (2) p-Block
(3) Element with atomic number 34 and 52
(3) d-Block (4) Both (1) & (2)
(4) Element with atomic number 18 and 35
w

146. Formula of chloride of element A whose IE1, IE2,


w
w

136. The least stable ion amongst the following is IE3, and IE4 are respectively 4.5 eV, 11 eV, 78 eV
.ed

and 110 eV
uc

(1) Al– (2) C–


he

(1) ACl (2) ACl2


m

(3) F– (4) Cl–


.in

(3) A2Cl3 (4) A3Cl2


137. Identify the weakest oxidizing agent
147. The correct order of radii is
(1) I2 (2) Br2
(1) Al3+ > Mg2+ > Na+ > F– > O2–
(3) Cl2 (4) F2
(2) Al3+ > Na+ > Mg2+ > O2– > F–
138. Hydration energy is least for (3) O2– > F– > Na+ > Mg2+ > Al3+
(1) O2– (2) S2– (4) F– > O2– > Na+ > Mg+2 > Al3+
(3) Te2– (4) Se2– 148. Position of element (Z = 108) in long form periodic
139. The element which does not show variable table and its IUPAC name is
oxidation is (1) d block, group 8 – unniloctium
(1) In (2) Ag (2) f-block, group 3 – unnilseptium
(3) Cr (4) W (3) p-block, group 17 – unniloctium
140. Among the following, choose the one which has (4) s-block, group 2 – unniloctium
high ionization enthalpy but zero electron gain 149. The largest atom of 3rd period
enthalpy?
(1) Na (2) Cl
(1) F (2) Na
(3) Fe (4) Ar
(3) He (4) B 150. Which set has the strongest tendency to form
141. The atomic number of first man-made element is anions?
(1) 43 (2) 45 (1) V, Cr, Mn (2) Ga, In, Tl

(3) 41 (4) 46 (3) Na, Mg, Al (4) N, O, F


151. The firmness with which an electron is held by an 1. A : First ionisation energy of nitrogen is greater
atom is a measure of its than oxygen.
(1) Electronegativity (2) Ionisation potential R : Nitrogen has half filled p-orbital (2p3) from
which electron is removed so more energy is
(3) Ionic character (4) Metallic character required.
152. Considering the elements B, Al, Mg and K, the 2. A : The electron affinity of oxygen is less than that
correct order of their metallic character is of nitrogen but greater than that of fluorine.
(1) B > Al > Mg > K (2) Al > Mg > B > K R : Nitrogen, oxygen and fluorine do not belong to
(3) Mg > Al > K > B (4) K > Mg > Al > B the same period of the periodic table.
3. A : Electron gain enthalpy for nitrogen is positive.
153. The element which belongs to group-3 and d-block
is R : Addition of electron in nitrogen is an
endothermic process due to half filled stable
(1) La (Z = 57) (2) Ce (Z = 58) configuration.
(3) Th (Z = 90) (4) Zr (Z = 40) 4. A : Chlorine has maximum negative electron gain
154. Na +, Mg2+, Al 3+
and Si4+ are isoelectronic, their enthalpy in periodic table.
ionic size will follow the order R : Chlorine has smallest size in periodic table.

(1) Na+ > Mg2+ > Al3+ < Si4+ 5. A : The ionic radii of Na+ is lesser than Mg2+.
R : Ionic radii increases with increase in effective
(2) Na+ < Mg2+ < Al3+ < Si4+ nuclear charge.
(3) Na+ > Mg2+ > Al3+ > Si4+ 6. A : Boron cannot show covalency greater than
four.
(4) Na+ < Mg2+ > Al3+ < Si4+
R : Boron has high ionization energy and high
SECTION - B electronegativity corresponding to 13th group
w

elements.
w
w

Assertion - Reason Type Questions


.ed

7. A : In each period, second ionisation energy of


uc

In the following questions, a statement of assertion alkali metal is highest.


he
m

(A) is followed by a statement of reason (R) R : Second electron is removed from noble gas
.in

configuration in alkali metals which is most


(1) If both Assertion & Reason are true and the
stable.
reason is the correct explanation of the
assertion, then mark (1). 8. A : Percentage ionic nature of bond is determined
by the expression 16(XA – XB) + 3.5(XA – XB)2
(2) If both Assertion & Reason are true but the where X A and X B are electronegativity of
reason is not the correct explanation of the element A and B.
assertion, then mark (2). R : Ionic nature of bond between two atoms
(3) If Assertion is true statement but Reason is decreases with increase in electronegativity
false, then mark (3). difference.

(4) If both Assertion and Reason are false 9. A : IE2 of oxygen is higher than that of fluorine.
statements, then mark (4). R : IE1 of He is higher than that of hydrogen.

‰ ‰ ‰

You might also like