Classification of Elements and Periodicity in Properties: Educhem DPP
Classification of Elements and Periodicity in Properties: Educhem DPP
2. Which of the following will have highest negative 10. Select the correct statement
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5. Element having the smallest size in second period (3) S > Se > Te > Po > O (Electron affinity)
is (4) All of these
(1) Ne (2) F 12. Element with atomic number 102 is placed in
(3) O (4) N (1) s-block (2) p-block
6. Element Uup is placed in group and (3) d-block (4) f-block
block of periodic table. 13. The electron affinity values (in kJ/mol) of three
(1) 4th, d (2) 3rd, f halogens X, Y and Z are respectively –349, –333
and –325. Then, X, Y and Z are respectively
(3) 15th, p (4) 12th, d
(1) F, Cl and Br (2) Cl, F and Br
7. The correct increasing order of second ionisation
energy is (3) Cl, Br and F (4) Br, Cl and F
14. Select the incorrect statement 23. The element of atomic number 118 will be placed
(1) Bond energy of F2 > Cl2 in which of the following group of long form of
periodic table?
(2) Electronegativity of F > Cl
(1) 15 (2) 16
(3) F is more oxidising than Cl
(3) 18 (4) 17
(4) Electron affinity of Cl > F
15. If the electronic configuration of an element is [Ar] 24. CH4 NH3 H2 O HF
I II III IV
3d104s24p6 . The element belongs to
The correct increasing order of acidic nature is
(1) s-block (2) p-block
(1) I < II < III < IV (2) IV < III < II < I
(3) d-block (4) f-block
(3) III < I < II < IV (4) I < III < II < IV
16. In compound M–OH, the acidic nature increases
25. The highest third ionisation energy among the
when
following is
(1) I.E. of M is low
(1) Boron (2) Beryllium
(2) I.E. of M is very low
(3) Carbon (4) Nitrogen
(3) I.E. of M is high
26. There are 28 neutrons in the nucleus of the
(4) Acidic nature does not depend on I.E. of M element zM52. It belongs to
17. Which of the following is the most acidic oxide? (1) f-block (2) s-block
(1) NO (2) NO2 (3) p-block (4) d-block
(3) N2O3 (4) N2O5
27. Which of the following has no unpaired electrons?
18. Lowest ionisation enthalpy in the periodic table is
(1) Mg+2 (2) Fe+2
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shown by
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II 520 7300
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(3) Z = 80 (4) Z = 25
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.ed
III 900 1760 43. Among the following, the third ionization energy is
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maximum for
he
IV 1680 3380
m
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37. Which of the following elements has the most (2) Ca2+
negative electron gain enthalpy? (3) Cl–
(1) [Ne]3s23p3 (2) [Ne]3s23p4 (4) S2–
(3) [Ne]3s23p5 (4) [Ne]3s23p6 45. Which of the following is not correct?
38. Predict the formula of the stable binary compound (1) Number of s electrons in carbon is double that
that would be formed by the element M (Z = 114) of He
and fluorine (2) Number of paired electron is same in F – and
(1) MF (2) MF6 Ne
(3) MF3 (4) MF4 (3) Number of d electrons are same in Zn2+ and
Cu+ ion
39. The element with atomic number 57 belongs to
(4) Number of filled orbitals are same in F– and
(1) s-block Cl– ion
(2) p-block 46. Which of the following process is exothermic?
(3) d-block (1) K K+ (2) Mg+ Mg2+
(4) f-block (3) O O– (4) S– S 2–
47. The process involving highest release of energy will 57. In which of the following processes, maximum
be energy is released?
(1) F(g) + e– F– (2) Cl(g) + e– Cl– (1) O(g) + e– O– (g)
(3) O(g) + e– O– (4) O(g) + 2e– O2– (2) O–(g) + e– O2–(g)
48. The correct order of first ionisation energies of (3) S(g) + e– S–(g)
some elements is given in the order
(4) S–(g) + e– S2–(g)
(1) B > C < N > O (2) B < C < N > O
58. The element of the fourth period of the periodic
(3) B < C < N < O (4) B > C < N < O table having maximum number of unpaired
49. The period and group of the element in modern electrons is
periodic table which is present in 5th period and (1) 26Fe (2) 24Cr
VI B group of Mendeleev’s periodic table will be
(3) 29Cu (4) 34Se
respectively
59. Which of the following is the strongest reducing
(1) 5 and 6 (2) 5 and 8
agent in aqueous solution?
(3) 4 and 6 (4) 6 and 8
(1) Na (2) Li
50. If there are three electrons present in each orbital
(3) K (4) Cs
and Bohr-Burry principle is not followed in filling of
electrons, the number of elements in 4th period of 60. Ionisation energy of F– is – 320 kJ/mol. The
modern periodic table will be electron affinity of fluorine would be
(1) 18 (2) 27 (1) – 320 kJ/mol (2) – 160 kJ/mol
(3) 32 (4) 48 (3) 320 kJ/mol (4) 160 kJ/mol
51. Which of the following ion has the most negative 61. Which of the following statement is not correct?
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53. Element having symbol Unb belong to which period 62. The correct order of third ionization energies (IE3)
and group of periodic table respectively? of Na, Mg and Al is
54. Which of the following is correct electronic 63. The first element of rare earth metals is
configuration of Gd? (Atomic number = 64) (1) Cerium (2) Actinium
7
(1) [Xe]4f 5d 6s1 2 8
(2) [Xe]4f 6s 2 (3) Uranium (4) Lanthanum
64. Atomic radii of fluorine and oxygen in pm units are
(3) [Kr]4f 8 5s 2 (4) [Xe]6s 2 5d 8
respectively given by
55. The correct order of electron affinities is
(1) 72, 74 (2) 74, 72
(1) Cl > Si > Na > Ar (2) Si > Cl > Na > Ar
(3) 77, 77 (4) 88, 77
(3) Cl > Na > Si > Ar (4) Cl > Si > Ar > Na
65. In graph of atomic volume versus atomic weight,
56. Which of the following ions has the highest value the elements corresponding to peaks in the curve
of ionic radius? belong to
(1) Li+ (2) B3+ (1) Group –1 (2) Group –18
(3) O2– (4) F– (3) Group –4 (4) Group –14
66. If there are three possible values for spin quantum 73. The ionization enthalpies of lithium and sodium are
number, then how many total elements can be x kJ mol –1 and y kJ mol –1 respectively. Then
present in 3rd period of periodic table? energy required to convert all the atoms present in
(1) 12 (2) 8 7 mg of lithium (Li) vapours and 23 mg of sodium
(Na) vapours
(3) 6 (4) 10
(1) x J ; y J (2) x kJ ; y kJ
67. An atom of an element A has 2 electrons in its
outermost shell while one of the element B has x y x y
(3) J; J (4) J; J
6 electrons in its outermost shell. Then formula of 10 10 100 100
the compound formed by A and B is
74. Which of the following property increases for Na+,
(1) AB (2) A2B Mg2+, Al3+ respectively?
(3) A2B6 (4) A2B3 (I) Size
68. The ratio of cationic size to anionic size is (II) Hydration energy
minimum for the compound
(III) Polarising power
(1) LiF (2) LiI
(IV) Ionisation energy
(3) RbI (4) RbF
69. Which of the following statement is wrong? (1) (I), (II) (2) (I), (III)
(1) Neutron/proton ratio does not reflect the (3) (II), (III) (4) (II), (III), (IV)
periodicity in chemical properties of elements 75. Name of the tripositive ion which is represented by
(2) The I.E. of aluminium is greater than the given configuration 1s2 2s2 2p6 3s2 3p6 3d5
magnesium because penetrating effect of p (1) Fe3+ (2) Cr+3
orbital is greater than s orbital
(3) Co3+ (4) Ni3+
(3) The value of e– gain enthalpy for N is positive
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will be C > D > B > A (2) N3– > O2– > F– > Mg2+ > Na+
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70. I.E. is the amount of energy required to remove an (3) N3– > O2– > F– > Na+ > Mg2+
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(1) 6th period; d-block; 3rd group 79. Which of the following has highest 2nd ionization
energy?
(2) 7th period; d-block; 3rd group
(1) N (2) O
(3) 7th period; p-block; 2nd group
(4) 6th period; s-block; 2nd group (3) F (4) C
72. Which of the following electronic configuration is 80. Valence configuration and block number of element
correctly matched? with atomic number 89 is
(1) A(Z = 8) : 1s2 2s2 3s2 3p2 (1) [Rn]6d 17s2, d-block
(2) B2+(Z = 20) : 1s2 2s2 2p6 3s2 3p6 (2) [Rn]6f 17s 2, f-block
(3) C+(Z = 24) : 1s2 2s2 2p6 3s2 3p6 4s1 3d4 (3) [Rn]6d 2, d-block
(4) D2+(Z = 29) : 1s2 2s2 2p6 3s2 3p6 3d10 4s2 (4) [Rn]7s2, s-block
81. Which is true regarding Ionisation energy? (3) High charge/radius ratio
(1) I– <I (4) All of these
(2) Li < Li + 89. Which of the pair of oxides is neutral?
(3) IE1 of Mg < IE2 of Mg (1) CO & CO2 (2) SO3 & N2O
(4) All of these (3) NO & N2O (4) N2O & CO2
82. Maximum oxidation states of transition metal is 90. The non-transition metals exhibit variable valency
derived from due to
(1) ns electron (1) Unstable core configuration
(2) (n – 1) d electron (2) d – d transition
(3) (n + 1) d electron (3) Poor screening effect of d and f electrons
(4) [ns + (n – 1) d] electrons (4) Small size
83. Which of the following set of compounds are 91. The correct order of negative electron gain enthalpy
amphoteric in nature?
(1) O > S > Se > Te (2) S > O > Se > Te
(1) BeO, B2O3, B(OH)3 (2) BeO, Be(OH)2, Al2O3
(3) S > Se > Te > O (4) S > Se > O > Te
(3) Be(OH)2, NO2, SiO2 (4) Al2O3, MgO, SO3
92. Correct order of 2nd ionisation energy
84. The correct order of electronegativity of carbon atom (1) F > O > N > C (2) O > F > N > C
in C2H6, C2H2 and C2H4 is
(3) F > N > O > C (4) N > F > O > C
(1) C2H2 < C2H4 < C2H6 (2) C2H4 < C2H2 < C2H6
93. The one which is not incorrect statement?
(3) C2H6 < C2H4 < C2H2 (4) C2H6 < C2H2 < C2H4
(1) I.E2 of Na < I.E2 of Mg
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and 1.0 respectively. The approximate percentage (2) CO2 is less acidic than CO
.ed
(3) 65% (4) 30% 94. Which of the following will have highest 2 nd
86. Among Be, F, C and N, the highest third ionisation ionization enthalpy, if the outermost electronic
energy is of configuration is given below?
(1) Be (2) F (1) 2p4 (2) 2s1
(3) C (4) N (3) 2p1 (4) 3p6
87. Which of the following statement is incorrect? 95. General electronic configuration of actinoids and its
period is
(1) Acidic nature of oxide of elements of third
period increases from left to right (1) (n 2)f1-14 (n 1)d0-1ns2 , n = 5 and 6 period
(2) Acidic nature of hydracids increases from top
to bottom in a group of periodic table (2) (n 2)f1-14 (n 1)d0-1ns2 , n = 6 and 6 period
(3) Acidic nature of hydracids of element from
carbon to fluorine increases. (3) (n 2)f1-14 (n 1)d0-1ns2 , n = 6 and 7 period
(4) For an atom van der Waal’s radius > covalent
radius > metallic radius (4) (n 2)f1-14 (n 1)d0-1ns2 , n = 7 and 7 period
88. The anomalous behaviour of the first member of 96. Correct order of electron affinity is shown by
each group of representative elements in periodic
(1) Cl > S > F > O
table is due to
(2) Cl > F > S > O
(1) High electronegativity
(3) F > Cl > O > S
(2) Non-availability of d-orbitals in their valence
shelll (4) F > O > Cl > S
97. The chemical formula of the most stable chloride 104. The smallest size among the following ions is
of the element M, will be given by which of the shown by
following, if the IUPAC name of M is ununquadium?
(1) N–3 (2) O–2
(1) MCl (2) MCl2 (3) Ca+2 (4) K+
(3) MCl3 (4) MCl4 105. The element with atomic number 89 belong to
98. Which of the following process is endothermic in (1) d-block, group-3, 7th period
nature?
(2) d-block, group-3, 6th period
A. Al+2 Al+3 B. Cl Cl–
(3) f-block, group-3, 6th period
C. N N–1 D. O–1 O–2
(4) f-block, group-3, 7th period
E. H H+
106. When a graph is plotted between atomic volume vs
(1) A, E (2) A, D, E atomic mass, group-2 elements are present at
(3) A, C, D, E (4) A, B, C, D, E (1) Peak of the graph (2) Bottom of the graph
99. The maximum covalency and oxidation shown by (3) Ascending peak (4) Descending peak
nitrogen in compounds is respectively
107. The general electronic configuration of f-block
(1) 3, +3 (2) 5, +5 element can be given by
(3) 3, +5 (4) 4, +5 (1) (n – 2) f1–14 (n – 1) d1–10 ns2
100. Which of the following sets is mismatched (2) (n – 2) f1–14 (n – 1) d1–10 ns0–2
regarding the nature of oxides?
(3) (n – 2) f1–14 (n – 1) d0–1 ns2
(1) Neutral oxide - CO2, NO, N2O
(4) (n – 2) f1–14 (n – 1) d10 ns2
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(3) Acidic oxide - Cl2O7, SiO2 Then energy required in eV/mol to convert 3.9 gm
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of K to K+ is
he
to
F– Cl– Br–
uc
(i.e., 1.34 Å), then the atomic radii of K and F (3) 15 group (4) 18 group
respectively are 127. Identify the element which is a metalloid
(1) 1.34 Å, 1.34 Å (2) 0.67 Å, 1.99 Å (1) Cu (2) Al
(3) 1.99 Å, 0.67 Å (4) 1.99 Å, 1.34 Å (3) B (4) Co
117. Electronegativity on Pauling scale is based on 128. The maximum number of electrons which can be
(1) Bond length (2) Bond energy present in the outermost orbit of elements of third
period of the periodic table is
(3) Atomic radius (4) Covalent radius
(1) 7 (2) 8
118. Zinc, cadmium, mercury belong to which group of
periodic table? (3) 10 (4) 18
(1) 10 (2) 11 129. In third period, the most basic oxide is formed by
119. The ionisation energy will be maximum for the (3) Na (4) Mg
process 130. Which pair of elements is chemically similar?
(1) Ba Ba2+ (2) Be Be2+ (1) Li, Mg (2) Be, Al
(3) Cs Cs+ (4) Li Li+ (3) B, Si (4) All of these
120. Which one of the following pairs of elements has 131. Among the following elements, least electronegative
same number of electrons in their outermost shell? is
(1) Al, Tl (2) Si, Pb (1) O (2) F
(3) As, Bi (4) All of these (3) Cl (4) S
132. The formula of the compound formed by X:[Ne] 3s2, 142. If one orbital can accommodate three electrons then
3p1 and Y:[He] 2s22p5 is the number of elements in third period of periodic table
is
(1) XY2 (2) XY3
(1) 8 (2) 16
(3) X2Y (4) XY
(3) 12 (4) 18
133. The maximum tendency to form a tripositive ion lies
with the element having the electronic configuration 143. The expected atomic number of seventh noble gas
would be
(1) [Ne]3s2 , 3p2 (2) [He]2s2, 2p2
(1) 110 (2) 114
(3) [Ne]3s2, 3p1 (4) [Ne]3s2, 3p6
(3) 118 (4) 122
134. As compared to alkaline earth metals, alkali
144. The correct statement is
metals exhibit
(1) Acidic nature of oxides increases from left to
(1) Higher valency right in a period of periodic table
(2) Higher reducing power (2) Acidic nature of hydracids increases from left
(3) Greater hardness to right in a period of periodic table
(4) All of these (3) Acidic nature of hydracids increases from top
to bottom in a group of periodic table
135. Which pair of elements belongs to same group?
(4) All of these
(1) Element with atomic number 38 and 55
145. Representative elements belong to
(2) Element with atomic number 29 and 46
(1) s-Block (2) p-Block
(3) Element with atomic number 34 and 52
(3) d-Block (4) Both (1) & (2)
(4) Element with atomic number 18 and 35
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136. The least stable ion amongst the following is IE3, and IE4 are respectively 4.5 eV, 11 eV, 78 eV
.ed
and 110 eV
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(1) Na+ > Mg2+ > Al3+ < Si4+ 5. A : The ionic radii of Na+ is lesser than Mg2+.
R : Ionic radii increases with increase in effective
(2) Na+ < Mg2+ < Al3+ < Si4+ nuclear charge.
(3) Na+ > Mg2+ > Al3+ > Si4+ 6. A : Boron cannot show covalency greater than
four.
(4) Na+ < Mg2+ > Al3+ < Si4+
R : Boron has high ionization energy and high
SECTION - B electronegativity corresponding to 13th group
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elements.
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(A) is followed by a statement of reason (R) R : Second electron is removed from noble gas
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(4) If both Assertion and Reason are false 9. A : IE2 of oxygen is higher than that of fluorine.
statements, then mark (4). R : IE1 of He is higher than that of hydrogen.