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chemistry Question (25 question)

The document contains a series of chemistry questions focused on solutions, solubility, and Raoult's law. It covers topics such as the behavior of gases and liquids in solutions, the effects of temperature and pressure on solubility, and the characteristics of ideal and non-ideal solutions. Each question presents multiple-choice answers related to these concepts.

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4 views

chemistry Question (25 question)

The document contains a series of chemistry questions focused on solutions, solubility, and Raoult's law. It covers topics such as the behavior of gases and liquids in solutions, the effects of temperature and pressure on solubility, and the characteristics of ideal and non-ideal solutions. Each question presents multiple-choice answers related to these concepts.

Uploaded by

operations.nashik
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Chemistry Questions

1. Which of the following is not a solid solution?


(a) Alloys (b) Gasoline (c) Amalgam (d) 𝐻2 in palladium
2. Which of the following concentration terms is/are independent of temperature?
(a) Molarity (b) Molarity and mole fraction
(c) Mole fraction and molality (d) Molality and normality
3. The solubility of a gas in water depends on
(a) Nature of the gas (b) Temperature
(c) Pressure of the gas (d) All of these
4. The solubility of a gas in liquid at a temperature is directly proportional to its
(a) Density (b) Melting point (c) Boiling point (d) Pressure
5. The solubility of a solid in a liquid depends on
(a) Nature of solute (b) Nature of solvent
(c) Temperature (d) All of these

6. 𝑝𝐴 and 𝑝𝐵 are the vapour pressure of pure liquid components 𝐴 and 𝐵, respectively of an
ideal binary solution. If 𝑥𝐴 represents the mole fraction of component 𝐴, the total
pressure of the solution will be
(a) 𝑝𝐵 + 𝑥𝐴 (𝑝𝐵 − 𝑝𝐴 ) (b) 𝑝𝐵 + 𝑥𝐴 (𝑝𝐴 − 𝑝𝐵 )
(c) 𝑝𝐴 + 𝑥𝐴 (𝑝𝐵 − 𝑝𝐴 ) (d) 𝑝𝐴 + 𝑥𝐴 (𝑝𝐴 − 𝑝𝐵 )
7. The vapour pressure of two liquids 𝑋 and 𝑌 are 80 and 60 Torr, respectively. The total
vapour pressure of the ideal solution obtained by mixing 3 moles of 𝑋 and 2 moles of 𝑌
would be
(a) 68 Torr (b) 140 Torr (c) 48 Torr (d) 72 Torr
8. For dilute solutions, Raoult’s law states that
(a) The relative lowering of vapour pressure is equal to mole fraction of solute
(b) The lowering of vapour pressure is equal to the mole fraction of solute
(c) The vapour pressure of the solution is equal to mole fraction of the solvent
(d) The relative lowering of vapour pressure is proportional to amount of solute in
solution
9. The vapour pressure of water depends upon
(a) Surface area of container (b) Volume of container
(c) Temperature (d) All of these

10. If liquids 𝐴 and 𝐵 form an ideal solution, the


(a) Enthalpy of mixing is zero
(b) Entropy of mixing is zero
(c) Free energy of mixing is zero
(d) Free energy as well as the entropy of mixing are zero
11. Which of the following liquid pairs shows a positive deviation from Raoult’s law?
(a) Water-hydrochloric acid (b) Benzene-methanol
(c) Water-nitric acid (d) Acetone-chloroform

12. In a mixture of 𝐴 and 𝐵, components show negative deviation when


(a) 𝐴 − 𝐵 interaction is stronger than 𝐴 − 𝐴 and 𝐵 − 𝐵 interaction
(b) 𝐴 − 𝐵 interaction is weaker than 𝐴 − 𝐴 and 𝐵 − 𝐵 interaction
(c) 𝛥𝑉𝑚𝑖𝑥 > 0, 𝛥𝑆𝑚𝑖𝑥 > 0
(d) 𝛥𝑉𝑚𝑖𝑥 = 0, 𝛥𝑆𝑚𝑖𝑥 > 0
13. Which one of the following is not correct for an ideal solution?
(a) It must obey Raoult’s law (b) 𝛥𝐻 = 0
(c) 𝛥𝑉 = 0 (d) 𝛥𝐻 = 𝛥𝑉 ≠ 0
14. Which of the following mixture does not show positive deviation from Raoult’s law?
(a) Benzene + acetone (b) Acetone + ethanol
(c) Acetone + chloroform (d) Water + ethanol
15. Which of the following is not correct for ideal solution?
(a) 𝛥𝑉mix = 0 (b) 𝛥𝐻mix = 0 (c) 𝛥𝑆mix = 0 (d) Obey's Raoult’s law
16. Which of the following is true when components forming an ideal solution are mixed?
(a) 𝛥𝐻𝑚 = 𝛥𝑉𝑚 = 0 (b) 𝛥𝐻𝑚 < 𝛥𝑉𝑚
(c) 𝛥𝐻𝑚 = 𝛥𝑉𝑚 = 1 (d) 𝛥𝐻𝑚 > 𝛥𝑉𝑚
17. Which of the following liquid pair shows a negative deviation from Raoult’s law?
(a) Water-nitric acid (b) Acetone-chloroform
(c) Water-All of these
18. Increasing the temperature of an aqueous solution will cause
(a) Decrease in molarity (b) Decrease in molality
(c) Decrease in mole fraction (d) Decrease in % w/w
19. The elevation of boiling point method is used for the determination of molecular weight
of
(a) Non-volatile and soluble solute (b) Non-volatile and insoluble solute
(c) Volatile and soluble solute (d) Volatile and insoluble solute
20. The vapour pressure of two pure liquids (A) and (B) are 100 torr and 80 torr,
respectively. The total pressure of solution obtained by mixing 2 moles of (A) and 3
moles of (B) would be
(a) 120 torr (b) 36 torr (c) 88 torr (d) 180 torr
21. Which of the following statements is true for non ideal solutions?
(a) The vapour pressure of non-ideal solutions always lies between vapour pressure of
pure components.
(b) Non-ideal solution do not obey Raoult’s law over entire range of concentrations.
(c) No heat is evolved or absorbed when two components are mixed forming non ideal
solutions.
(d) In non-ideal solutions solvent-solute, solute-solute and solvent-solvent molecular
interactions are comparable.
22. Which of the following mathematical expressions is correct regarding Raoult’s law for a
binary mixture of two volatile liquids if 𝑥2 , 𝑥1 are mole fractions and 𝑃10 , 𝑃20 are vapour
pressure of pure liquids?
(a) 𝑃 = (𝑃10 + 𝑃20 )𝑥1 − 𝑃20 (b) 𝑃 = (𝑃20 + 𝑃10 )𝑥1 − 𝑃20
(c) 𝑃 = (𝑃20 + 𝑃10 )𝑥2 − 𝑃10 (d) 𝑃 = (𝑃20 + 𝑃10 )𝑥1 − 𝑃10
23. Which of the following statements is NOT true for ideal solutions?
(a) Ideal solution obey Raoult’s law over entire range of concentration.
(b) There is no change in total volume of solution when two components are mixed.
(c) No heat is evolved absorbed when two components forming an ideal solution are
mixed.
(d) Vapour pressure of the ideal solutions can be higher or lower than those of pure
components.
24. What is the unit of Henry’s low constant?
(a) mol dm3 bar−1 (b) mol dm−3
(c) mol dm−3 bar−1 (d) mol dm−3 bar
25. Which of the following laws represents the quantitative relationship between the
solubility of gas in liquid and its pressure?
(a) Raoult’s law (b) Charle’s law
(c) Avogadro’s law (d) Henry’s law

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