PHASE TEST – II 9 Mains

Chemistry PART – II

SECTION – A
(One Options Correct Type)

This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE option is correct.

1. The enthalpy change for the reaction, C H (g) ⟶ 2C(g) + 6H(g) is X KJ. The bond energy of C − H bond
is:

(A) (B)

(C) (D) Data insufficient

2. A cyclic process ABCD is shown in P-V diagram for an ideal gas, which of the following diagram
represents the same process?

(A) (B)

(C) (D)

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PHASE TEST – II 10 Mains

3. There are two radio nuclei A and B. A is a α-emitter and B is a β-emitter. Their disintegration constant are
in the ratio of 1: 2. What should be the number of atoms ratio of A and B at time = 0, so that initially
probability of getting α and β-particles are same.

(A) 2: 1 (B) 4: 1

(C) 1: 2 (D) 1: 4

4. For the reactions

KI
(i) A P

KII
(ii) B Q , following observations are made.

Calculate , where K and K are rate constant for their respective reaction.

(A) 2.303 (B) 1

(C) 0.36 (D) 0.693

5. For the reaction CO(g) + Cl (g) ⇌ COCl (g), the value of is equal to:

(A) √RT (B) RT

(C) (D) 1.0

6. In the reaction X(g) + Y(g) ⇌ 2Z(g), 2 moles of X, 1 mole of Y and 1 mole of Z are placed in a 10 litres
vessel and allowed to reach equilibrium. If final concentration of Z is 0.2 M, then K for the given reaction
is:

(A) 1.60 (B)

(C) (D) None of these

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PHASE TEST – II 11 Mains

7. Attainment of equilibrium A(g) ⇌ 2C(g) + B(g) gave the following graph. Find the correct option. (%
dissociation = fraction dissociated × 100)

(A) At = 5 sec equilibrium has been reached and K = 40 (mol/litre)2

(B) At = 5 sec equilibrium has been reached and % dissociation of A is 20%

(C) At = 5 sec equilibrium has been reached and % dissociation of A is 30%

(D) None of these

8. 4g of NaOH and 4.9 g of H SO are dissolved in water and volume is made upto 250 ml. The pH of this
solution is:

(A) 7.0 (B) 1.0

(C) 2.0 (D) 12.0

9. Silver ions are added to a solution with [Br ] = [Cl ] = [CO ] = [AsO ] = 0.1 M. Which compound will
precipitate with lowest [Ag ]?

(A) AgBr (K = 5 × 10 ) (B) AgCl (K = 1.8 × 10 )

(C) Ag CO (K = 8.1 × 10 ) (D) Ag AsO (K = 1 × 10 )

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PHASE TEST – II 12 Mains

10. Consider the plots for the types of reactions nA ⟶ B + C

These plots respectively correspond to the reaction orders:

(A) 0, 2, 1 (B) 0, 1, 2

(C) 1, 1, 2 (D) 1, 0, 2

11. In Silicon dioxide

(A) Each silicon atom is surrounded by four oxygen atoms and each oxygen atom is bonded to two
silicon atoms

(B) Each silicon atom is surrounded by two oxygen atoms and each oxygen atom is bonded to two
silicon atoms

(C) Silicon atoms is bonded to two oxygen atoms

(D) There are double bonds between silicon and oxygen atoms

12. The state of hybridization of boron and oxygen atoms in boric acid (H BO ) are respectively

(A) sp and sp (B) sp and sp

(C) sp and sp (D) sp and sp

13. Standard entropy of X , Y and are 60, 40 and 50 JK mol , respectively. For the reaction,

X + Y ⟶ XY , ΔH = −30 KJ, to be at equilibrium, the temperature will be

(A) 1250 K (B) 500 K

(C) 750 K (D) 1000 K

14. can be taken as the time taken for the concentration of a reactant to drop to of its initial value. If the
rate constant for a first order reaction is K, then can be written as

(A) 0.10/K (B) 0.29/K

(C) 0.69/K (D) 0.75/K

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PHASE TEST – II 13 Mains

15. Methane gas and steam in equimolar amounts are taken in a flask and sealed where the following
equilibrium was established:

CH (g) + H O(v) ⇌ CO(g) + 3H (g)

2H (g) + CO(g) ⇌ CH OH(g); K = atm

At equilibrium if partial pressure of CO(g) as found to be 0.5 atm and total pressure inside the flask was 5
atm, then K of the first reaction is (approximately)

(A) 3.5 atm (B) 7. 5 atm

(C) 10.5 atm (D) 12. 5 atm

16. Heat of dissociation of CH is . The bond energy of is . The heat of dissociation of acetone is .
Calculate the approximate bond dissociation energy of

(A) z− +2 (B) − +

(C) 4 − − (D) + −

17. The sum of first three ionization energies is the highest for which of the following elements?

(A) Tl (B) Al

(C) Ga (D) B

18. Which of the following carbides consists of type of anionic part?

(A) Al C (B) CaC

(C) B C (D) Mg C

19. A weak base (BOH) with = 10 is titrated with a strong acid HCl. At th of the equivalent point, pH of
the solution is:

(A) 5 + log 3 (B) 5 − log 3

(C) 14 − 5 + log 3 (D) 9 − log 3

20. Thermal decomposition of a compound is of first order. If 50% of a sample of the compound is
decomposed in 120.4 minutes, then the time required from the 90% decomposition of the compound is

(A) 400 min (B) 410 min

(C) 250 min (D) 120 min

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PHASE TEST – II 14 Mains
PART – B(Numerical based )
This Section contains 5 questions. Numerical based questions, the answer of which may be positive or negative or
decimal (e.g. 6.25, 7.00, .30, 30.27,  127.30) and each carries + 4 marks for correct answer and there will be no
negative marking.

1. A vessel contains 10 moles of an ideal gas at 298 K and 10 atm. What will be the work done, if the gas is
allowed to expand isothermally into a vacuum?

2. At high temperature, the following equilibrium exist in a mixture of Carbon, oxygen and their
compounds:

C(s) + O (g) ⇌ CO (g); K = 10

2C(s) + O (g) ⇌ 2CO(g); K = 10

C(s) + CO (g) ⇌ 2CO(g); K =

2CO(g) + O (g) ⇌ 2CO (g); K =

What will be the ratio of and ?

3. The rate of decomposition of NH (g) at 10 atm on platinum surface is zero order. What is rate of
formation (in M min-1) of H (g), if rate constant of reaction

2NH (g) ⟶ N (g) + 3H (g) is 2.0 M min-1

4. Calculate the ratio of sodium formate and formic acid (K = 2 × 10 ) in a buffer solution of pH = 4.3.
[log 2 = 0.3 ; 10 . ≃ 4]

5. In a Carnot cycle involving ideal non-linear triatomic gas, if during adiabatic expansion volume increases
from 2L to 16L and heat absorbed during isothermal expansion is 8 Kcal, then calculate magnitude of
work done by Carnot engine (in Kcal )

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PHASE TEST – II 20 Mains

Answer Key
MAINS

PHYSICS
Single option correct type :
1. A 2. B 3. C 4. B 5. D
6. D 7. D 8. B 9. C 10. C
11. B 12. B 13. C 14. B 15. C
16. D 17. B 18. A 19. B 20. B

Numerical Type :
1. 1 2. 9 3. 2 4. 7 5. 1

CHEMISTRY
Single option correct type :

1. D 2. C 3. A 4. D 5. B
6. C 7. B 8. A 9. A 10. D
11. A 12. D 13. C 14. B 15. B
16. A 17. D 18. D 19. D 20. A

Numerical Type :
1. 0 2. 1 3. 6 4. 4 5. 4

MATHEMATICS

Single option correct type :

1. A 2. C 3. C 4. D 5. A
6. B 7. D 8. C 9. A 10. B
11. C 12. B 13. D 14. A 15. C
16. B 17. D 18. D 19. A 20. B

Numerical Type :
1. 8 2. 44 3. 10 4. 8 5. −

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